共查询到19条相似文献,搜索用时 171 毫秒
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包钴铁氧体型,γ-Fe2O3磁粉(简记为CoFe-γ-Fe2O3)是针状γ-Fe2O3磁粉与Co++和Fe++溶液起反应,在每个针状颗粒上包覆了一层钴铁氧体固溶体。经此种方法处理后的γ-Fe2O3磁粉的矫顽力及其它磁特性有较大的提高。如矫顽力由原来415Oe增加到715Oe;剩磁和矫顽力随时间及温度变化小等。我们利用穆斯堡尔效应并配合其它研究手段进行了研究,认为:CoFe-γ-Fe2O3磁粉矫顽力的提高,主要是由于γ-Fe2O3磁粉表面包覆了一层钴铁氧体固溶体,γ-Fe2O3与钴铁氧体固溶体之间发生磁耦合作用之故。
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以铁箔为原材料和基片,通过控制热氧化过程中的宏观实验条件(载气流量及其组分、压强、温度分布和反应时间等),实现了α-Fe2O3一维纳米结构的可控生长,获得了大面积(10mm×10mm)、单分散性好、沿[110]方向生长的α-Fe2O3纳米带或纳米线阵列. 对不同宏观实验条件下所制备的样品进行形貌和晶格结构表征和分析,认为热氧化过程中α-Fe2O3一维纳米结构的生长遵循类似气-
关键词:
2O3')" href="#">α-Fe2O3
一维纳米结构
热氧化法 相似文献
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包钴型γ-Fe2O3磁粉的矫顽力可比原γ-Fe2O3磁粉提高8000—32000A/m。木文研究探讨了两种包钴型γ-Fe2O3磁粉(包钴γ-Fe2O3和包钴包亚铁γ-Fe2O3)的单轴各向异性的起源和矫顽力增大的机制。包钴γ-Fe2O3磁粉矫顽力
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Srinivasan G. 《物理学报》2006,55(5):2548-2552
讨论了Ni0.8Zn0.2Fe2O4 (NZFO)与锆钛酸铅(PZT)的双层膜结构样品的磁电(ME)效应.NZFO粉料由溶胶-凝胶法制成,再经900℃热压,并高温烧结.在该双层膜中测量到了很强的磁电相互作用.发现横向的磁电效应比纵向效应大一个数量级,并且随NZFO烧结温度的提高而增加.当烧结温度从950℃上升到1380℃时,横向ME电压系数(αE)的最大值变化范围为25.6 mV Am-2≤αE≤199.6 mV Am-2.理论分析显示NZFO-PZT双层膜样品中ME效应源于NZFO与PZT之间相对良好的磁电耦合.
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镍铁氧体
PZT
热压法
ME效应 相似文献
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Fengyuan Shi Hua Xiang J. Joshua Yang M.S Rzchowski Y.A. Chang P.M. Voyles 《Journal of magnetism and magnetic materials》2012
We have found inverse tunneling magnetoresistance (TMR) with a non-symmetric bias voltage dependence in a nominally symmetric Si (001)/Ag/CoFe/AlOx/CoFe/IrMn/Ag magnetic tunnel junction after field cooling. The O K edge fine structure extracted from electron energy loss spectroscopy spectrum images taken at the interfaces of junctions with inverse TMR shows a thin, discontinuous Fe3O4 layer at the CoFe/AlOx interfaces. The Fe L2,3 edge core level shifts are also consistent with those of Fe3O4. We find no Fe3O4 layer in junctions with normal TMR. We believe this Fe3O4 layer is responsible for the inverse TMR. 相似文献
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A tunneling-type magnetoresistance (MR) as large as 158% is observed at T = 300 K in a polycrystalline Zn0.41Fe2.59O4 sample, in which the Zn0.41Fe2.59O4 grains are separated by insulating alpha-Fe2O3 boundaries. The huge room-temperature MR is attributed to the high spin polarization of Zn(0.41)Fe(2.59)O4 grains and antiferromagnetic correlations between magnetic domains on both sides of the insulating alpha-Fe2O3 boundary. The MR exhibits strong temperature dependence below 100 K and its magnitude is enhanced to reach 1280% at 4.2 K, which may arise from the Coulomb blockade effect. 相似文献
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Wearthering steels treated with and without zinc phosphate solution were exposed to atmosphere for 15 years and rust layers produced on the steels were analysed by scattering Mössbauer spectrometry (CEMS and XMS). γ-FeOOH, fine α-FeOOH, 5Fe2O3·9H2O, γ-Fe2O3 and Fe3O4 were identified to be present in the rust formed on the steel without phosphate coating. Large particles of γ-Fe2O3 and Fe3O4 formed on the uncoated steel exposed to atmosphere in a position facing north on vertical plane. The layer structure of rust was affected by the position. The thin rust layer formed on the phosphate + carylite resin coated steel was considered to consist of γ-FeOOH, fine α-FeOOH, and fine γ-Fe2O3. 相似文献
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Monica Sorescu L. Diamandescu D. Tarabasanu-Mihaila B.H. Howard 《Journal of Physics and Chemistry of Solids》2004,65(5):1021-1029
Structural and morphological characteristics of (1−x)α-Fe2O3-xSnO2 (x=0.0-1.0) nanoparticles obtained under hydrothermal conditions have been investigated by X-ray diffraction (XRD), transmission Mössbauer spectroscopy, scanning and transmission electron microscopy as well as energy dispersive X-ray analysis. On the basis of the Rietveld structure refinements of the XRD spectra at low tin concentrations, it was found that Sn4+ ions partially substitute for Fe3+ at the octahedral sites and also occupy the interstitial octahedral sites which are vacant in α-Fe2O3 corundum structure. A phase separation of α-Fe2O3 and SnO2 was observed for x≥0.4: the α-Fe2O3 structure containing tin decreases simultaneously with the increase of the SnO2 phase containing substitutional iron ions. The mean particle dimension decreases from 70 to 6 nm, as the molar fraction x increases up to x=1.0. The estimated solubility limits in the nanoparticle system (1−x)α-Fe2O3-xSnO2 synthesized under hydrothermal conditions are: x≤0.2 for Sn4+ in α-Fe2O3 and x≥0.7 for Fe3+ in SnO2. 相似文献
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Qian Gao Fenghua Chen Jilin Zhang Jiazuan Ni 《Journal of magnetism and magnetic materials》2009,321(8):1052-1057
The surface structure of the iron oxide nanoparticles obtained by the co-precipitation method has been investigated, and a thin layer of α-FeOOH absorbed on surface of the nanoparticle is confirmed by analyses of Fourier transform infrared (FTIR), X-ray photoelectron spectra (XPS) and surface photovoltage spectroscopy (SPS). After annealed at 400 °C, the α-FeOOH can be converted to γ-Fe2O3. The simple-annealed procedure resulted in the formation of Fe3O4@γ-Fe2O3 core/shell structure with improved stability and a higher magnetic saturation value, and also the simple method can be used to obtain core/shell structure in other similar system. 相似文献
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J.E. Knowles 《Journal of magnetism and magnetic materials》1981,22(3):263-266
It is known that acicular particles, initially of Fe3O4, which have been partially oxidised, show anomalous properties e.g. in the variation of Hc with composition. It is shown that these can be explained by considering the particles to comprise an inner core of Fe3O4 with an outer layer of γ-Fe2O3. Owing to the large change in volume which occurs on oxidation, these mutually stress each other. Over a certain range of composition, the stress field interacts with the magnetization to increase Hc, and it is also responsible for Hc increasing with time after the oxidation process. A similar situation applies to partially reduced γ-Fe2O3. 相似文献
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We report on the synthesis of Zn0.7Ni0.3Fe2O4 nanoparticles via microwave assisted combustion route by using urea as fuel. XRD and FT-IR analyses confirm the composition and structure as spinel ferrite. The crystallite size estimated from XRD (16.4 nm) and the magnetic core size (15.04 nm) estimated from VSM agree well, while a slightly smaller magnetic diameter reflects a very thin magnetically dead layer on the surface of the nanoparticles. Morphological investigation of the products was done by TEM which revealed the existence of irregular shapes such spherical, spherodial and polygon. Magnetization measurements performed on Zn0.7Ni0.3Fe2O4 nanoparticles showed that saturation was not attained at even in the high magnetic field. The sample shows superparamagnetic behavior at around the room temperature and ferromagnetic behavior below the blocking temperature which is measured as 284 K. 相似文献
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We test the hypothesis that electron-hole pair separation following light absorption enhances photochemistry at oxide/oxide heterojunctions which exhibit a type II or staggered band alignment. We have used hole-mediated photodecomposition of trimethyl acetic acid chemisorbed on surfaces of heterojunctions made from epitaxial α-Cr2O3 on α-Fe2O3(0001) to monitor the effect of UV light of wavelength 385 nm (3.2 eV) in promoting photodissociation. Absorption of photons of energies between the bandgaps of α-Cr2O3 (Eg = 4.8 eV) and α-Fe2O3 (Eg = 2.1 eV) is expected to be strong only in the α-Fe2O3 layer. The staggered band alignment should then promote the segregation of holes (electrons) to the α-Cr2O3 (α-Fe2O3) layer. Surprisingly, we find that the α-Cr2O3 surface alone promotes photodissociation of the molecule at hν = 3.2 eV, and that any effect of the staggered band alignment, if present, is masked. We propose that the inherent photoactivity of the α-Cr2O3(0001) surface results from the creation of bound excitons in the surface which destabilize the chemisorption bond in the molecule, resulting in photodecomposition. 相似文献
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The characterization of the calcination products of the precipitates obtained from the bio-oxidation with Thiobacillus ferrooxidans of sulphuric water pickling liquors has been carried out by means of Mössbauer spectroscopy, x-ray powder diffraction, infrared spectroscopy and transmission electron microscopy. The results show that a full transformation of the precipitates into α-Fe2O3 is achieved at temperatures higher than 850°C. Calcination at 700°C during two hours results in the formation of α-Fe2O3, ζ-Fe2O3 and Fe12O3(SO4)15. The Mössbauer parameters of ζ-Fe2O3 and Fe12O3(SO4)15 at 298 and 17K are reported. 相似文献