Doppler spectroscopy of a beam in the channel of a H− ion source

It is shown that high-accuracy contact-free measurements of the divergence and emittance of an accelerated H⁻ ion beam at the exit from the source can in principle be performed by passive Doppler spectroscopy of a beam of excited hydrogen atoms produced by neutralization of the ions with excitation on the residual gas in the source channel. The intensity of the H_α-line radiation detected by the Doppler system is calculated, taking into account the principal processes leading to the excitation and deexcitation of the 3s, 3p, and 3d levels of the hydrogen atoms in the beam, for residual gas densities of the order of 10⁻⁴–10⁻⁵ Torr in the source channel. The computed H_α-line intensity was confirmed experimentally, making it possible to perform photoelectronic detection of the spectral contour of the line in the current mode rather than the photon-counting mode. Zh. Tekh. Fiz. 68, 15–18 (June 1998)     

Luminescence in collisions of low-energy ions with graphite and Al<Subscript>2</Subscript>O<Subscript>3</Subscript>

Excitation of H⁺, H₂ ⁺, H₃ ⁺, He⁺, and Ar⁺ ions by impact on graphite and Al₂O₃ was investigated by means of emission spectroscopy in the 50–1000 eV energy range of the projectiles. Emission of Balmer series from excited neutral hydrogen is observed for both targets. In addition, for the Al₂O₃ target a continuum emission is observed. The continuum probably originates from excited M_nO_m molecules produced in the collision cascade, when surface atoms bound by ionic bonds are released after the bond breaking caused by neutralization. The spectra obtained under Ar⁺ -bombardment show Ar II lines emitted by backscattered ions.     

Characteristic features of the formation of the vibrational distribution function of H2 molecules in a hydrogen stream

A theoretical analysis is made of the flow of vibrationally excited hydrogen in a channel. It is shown that coverage of the channel walls with adsorbed hydrogen atoms can substantially increase the concentration of vibrationally excited molecules in the stream. The possibility of applying these results to bulk sources of negative H⁻ hydrogen ions is discussed. It is shown that the rate of H⁻ ion generation in the source may be enhanced appreciably under conditions where this generation is achieved by dissociative attachment of thermal electrons to H₂ molecules injected into the discharge chamber, whose vibrational distribution function has been pre-enriched in excited molecules by suitably organizing the hydrogen flow in the channel. Zh. Tekh. Fiz. 69, 15–21 (June 1999)     

Balmer Hβ vs. Dβ line intensity in the collisions of H+, H2 +, H3 +, D+, D2 +, and D3 + ions with “realistic” metal surface at energies below 1 keV

The intensities of hydrogen H_β and deuterium D_β spectral lines of the Balmer series were measured as a function of collision energy when H⁺, H₂ ⁺, H₃ ⁺, D⁺, D₂ ⁺, and D₃ ⁺ ions impinged on Al, Ti, Cu, Mo, W, and Pb targets. The collision energies were kept in the 100–1000 eV range. The target surface was contaminated with hydrocarbons from the vacuum pumping system and possibly also by oxygen molecules due to limited vacuum conditions. At projectile velocities above 200 km/s the luminescence of backscattered deuterium atoms is about 30–50% weaker than that of hydrogen atoms.     

Spectroscopic observation of helium-ion- and hydrogen-catalyzed hydrino transitions

Four predictions of Mills’ Grand Unified Theory of Classical Physics (GUTCP) regarding atomic hydrogen undergoing a catalytic reaction with certain atomized elements and ions which resonantly, nonradiatively accept integer multiples of the potential energy of atomic hydrogen, m · 27.2 eV wherein m is an integer, have been confirmed experimentally. Specifically, a catalyst comprises a chemical or physical process with an enthalpy change equal to an integer multiple m of the potential energy of atomic hydrogen, 27.2 eV. For He⁺ m = 2, due to its ionization reaction to He²⁺, and two H atoms formed from H₂ by collision with a third, hot H can also act as a catalyst with m = 2 for this third H. The product is H(1/p), fractional Rydberg states of atomic hydrogen called “hydrino atoms” wherein n = 1/2, 1/3, 1/4, …, 1/p(p≤137 is an integer) replaces the well-known parameter n = integer in the Rydberg equation for hydrogen excited states. The predictions for the hydrino reaction of (1) pumping of the catalyst excited states, (2) characteristic EUV continuum radiation, (3) fast H, and (4) hydrino products were observed in multiple catalyst-hydrogen plasma systems.     

Exact Results for Thermodynamics of the Hydrogen Plasma: Low-Temperature Expansions Beyond Saha Theory

We study hydrogen in the Saha regime, within the physical picture in terms of a quantum proton-electron plasma. Long ago, Saha showed that, at sufficiently low densities and low temperatures, the system behaves almost as an ideal mixture made with hydrogen atoms in their groundstate, ionized protons and ionized electrons. More recently, that result has been rigorously proved in some scaling limit where both temperature and density vanish. In that Saha regime, we derive exact low-temperature expansions for the pressure and internal energy, where density ρ is rescaled in units of a temperature-dependent density ρ ^* which controls the cross-over between full ionization (ρ ≪ ρ ^* ) and full atomic recombination (ρ≫ρ ^* ). Each term reduces to a function of ρ/ρ ^* times temperature-dependent functions which decay exponentially fast when temperature T vanishes. Scaled expansions are ordered with respect to the corresponding decay rates. Leading terms do reduce to ideal contributions obtained within Saha theory. We consistently compute all corrections which are exponentially smaller by a factor exp (β E _H ) at most, where E _H is the negative groundstate energy of a hydrogen atom and β=1/(k _B T). They include all effects arising from both the Coulomb potential and the quantum nature of the particles: excitations of atoms H, formation of molecules H ₂, ions H ₂⁺ and H ⁻, thermal and pressure ionization, plasma polarization, screening, interactions between atoms and ionized charges, etc. Scaled low-temperature expansions can be viewed as partial resummations of usual virial expansions up to arbitrary high orders in the density.     

Quantum-chemical modeling of structural,electronic, and spin characteristics of NV centers in nanostructured diamond: Surface effect

The effect of the surface of diamond on atomic, electronic, and spin properties of diamond nanocrystals containing single nitrogen-vacancy defects ([NV]⁻ centers) is studied. The surface was modeled with clusters C₃₃H₃₀[NV]⁻, C₆₆H₇₂[NV]⁻, which were constructed based on bulk clusters C₃₃H₃₆[NV]⁻ and C₆₉H₈₄[NV]⁻, respectively. In all cases, clusters in the triplet state S = 1 are considered with the cluster charge being −1. The geometric structure of clusters is optimized using the principle of minimization of the total energy of the system; then, the electronic and spin characteristics of clusters are calculated by the density functional theory. The isotropic and anisotropic hyperfine interaction constants of the electron spin of the NV center with the nuclear spin of the nitrogen atom and ¹³C atoms located at different sites in the cluster are calculated. It is found that, in contrast to bulk clusters with [NV]-centers in which the spin density is mainly localized at the three carbon atoms that are the nearest neighbors of the vacancy of the center, upon arrangement of the NV center in the immediate proximity to the surface, the spin density is redistributed such that it is mainly localized at the three carbon atoms that are the nearest neighbors of the nitrogen atom of the center and at C atoms that form the first atomic layer of the (111) surface of the nanocrystal.     

Messung von Lebensdauern und relativen Besetzungszahlen angeregter Zustände des Wasserstoffatoms mit der Methode der Ionenstrahlspektroskopie

H ⁺₂ ions or protons, accelerated to energies between 80 and 300 keV, are sent through a thin carbon target. Light emitted by the excited atoms moving out of the foil with a definite velocity is analyzed using interference filters and a cooled photomultiplier. Intensities of theH _α,H _β, andH _γ lines are measured as functions of the distance from the foil. The data is analyzed with a computer program, which yields (in agreement with theory) mean lives of the hydrogen atom excited states involved, and the relative initial state populations of states belonging to the same principal quantum number. There is no indication of cascading.

     

Anomalous Doppler broadening caused by exothermic reactions: application to hydrogen Balmer lines

The three- and one-dimensional velocity distributions of a product species created by an exothermic reaction are calculated using the energy conservation, with the aim of evaluating the impact of such processes on the anomalous broadening of Doppler lines. The calculations are performed to the reaction H₂⁺ + H₂ → H₃⁺ + H, in which according to Christoffersen (1964) an amount of 1.56 eV is transferred to the product species. It is shown that the deviations relatively to Maxwell-Boltzmann distributions are significant as the internal energy defect ΔE increases, even within energies lower than 1.56 eV, and hence the profiles of excited H^∗ atoms, associated with the emission of hydrogen Balmer lines, created in the sequence of H(n = 1) produced by the above reaction are not of Gaussian-type. The profiles are markedly flatter and squarer than Gaussian distributions. The validity of the species temperature determined from the full width at half maximum (FWHM) of the lines, as well as the fit of the lines by multimodal Gaussian functions, is then analyzed.     

Radial distribution of hydrogen atoms in H 2 plasma

The radial intensities of the H _α and H ₂ Fulcher α (d ³Π_u − a ³Σ_g) system spectral lines were used to obtain the radial distribution of hydrogen atoms in H ₂ plasma discharge. We have obtained new equations in order to describe the distribution of atoms in molecule discharges. Abel’s integral equation has been solved by Tikhonov’s regularization procedure. Model functions have been introduced to examine the limitations in the applicability of this method. An estimation of the degree of dissociation in the radial direction has been obtained.     

Structural stability and electronic properties of Au5Hn (n=1–10) clusters

A systematic study on the geometrical structures, electronic and magnetic properties of Au₅H _n (n=1–10) clusters has been performed by using the all-electron scalar relativistic density functional theory with generalized gradient approximation at the PW91 level. It is found that all Au₅H _n clusters prefer to keep the planar structures like pure Au₅ cluster, the Au₅ structures in Au₅H₄, Au₅H₅ and Au₅H₆ clusters are distorted obviously. The adsorption of a number of hydrogen atoms enhances the stability of Au₅ cluster and all Au₅H _n clusters are more stable than pure Au₅ cluster energetically. The odd-even alteration of magnetic moment is observed in Au₅H _n clusters and may be served as the material with tunable code capacity of “0” and “1” by adsorbing odd or even number of H atoms. It seems that the most favorable adsorption between Au₅ cluster and a number of hydrogen atoms takes place in the case that the odd number of hydrogen atoms is adsorbed onto Au₅ cluster and becomes Au₅H _n cluster with even number of valence electrons.     

A spectroscopic method in studying the dissociation kinetics of hydrogen molecules

The actinometry method was used to study experimentally the kinetics of the formation of hydrogen atoms in a low-pressure glow discharge initiated in a hydrogen-argon mixture. Dependences of the steady-state concentration of hydrogen atoms on current and pressure have been obtained for the ranges i/R=1 to 16 mA/cm and pR=0.7 to 10 Torr·cm, respectively. It has been established that for discharge-activated hydrogen, when the temperature of the system varies only slightly, the recombination frequency parameter v_H=γ_HD_H/Λ² can be used. Ivanovo State University. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 5, pp. 13–17, May, 1999.     

Sensitized anti-Stokes luminescence centers in microcrystals of Zn<Subscript>0.6</Subscript>Cd<Subscript>0.4</Subscript>S solid solutions with adsorbed dye molecules and few-atomic silver clusters

The sensitized anti-Stokes luminescence excited by radiation with wavelengths from 610 to 750 nm and flux densities of 10¹⁴–10¹⁵ quanta/(cm²·s) is detected for microcrystals of Zn _0.6 Cd _0.4 S solid solutions with adsorbed organic malachite green and methylene blue dye molecules. The position of its excitation spectra coincides with that of the absorption spectra of adsorbed dye molecules, which suggests the cooperative mechanism of its occurrence. The possibility of amplification of the anti-Stokes luminescence by means of adsorption of silver atoms and few-atomic silver clusters, in addition to the dye molecules, on the Zn _0.6 Cd _0.4 S surface is investigated. It is assumed that in the latter case, the anti-Stokes luminescence is excited as a result of two-quantum optical transitions with electron or electron excitation energy transfer from the dye molecules adsorbed on the Zn _0.6 Cd _0.4 S surface to silver atoms and few-atomic silver clusters creating deep local states with photoionization energies of 1.8–2.0 eV in the gap. __________ Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 3, pp. 21–26, March, 2008.     

Excited state absorption and energy transfer losses in thulium doped fluoroindogallate glass

Thulium doped fluoroindogallate glass was characterized by means of excited state absorption experiment in the 0.95 to 1.55 μm spectral range. The three bands corresponding to the electronic transitions ³ F ₄→³ F ₂ (at 1.05 μm), ³ F ₄→³ F ₃ (at 1.125 μm), and ³ F ₄→³ H ₄ (at 1.45 μm) were observed. The energy transfer microscopic parameters for the reverse cross relaxation process ³ F ₄, ³ F ₄→³ H ₆, ³ H ₄ were calculated for different multipolar interaction mechanisms using the Kushida model, and it was verified that the probability of this process is 100 times lower than that of the direct ³ H ₄, ³ H ₆→³ F ₄, ³ F ₄ cross relaxation, responsible for the 1.8 μm emission pumping. PACS 78.20.-e; 78.55.Qr; 42.70.Hj; 42.55.Wd     

Acceleration of pπ-atoms in a Coulomb de-excitation cascade

An improved adiabatic approach (IAA) previously proposed in atomic physics is extended to the case of collisions of mesic atoms in excited states n⩾2. The computed rates λ _nn′ ^C (E) of the Coulomb de-excitation processes (pπ)_n+p→(pπ) _n′+p are substantially different from the IAA results. It is shown that the Coulomb de-excitation rates λ _nn′ ^C are high enough to explain the appearance of pπ mesic atoms with kinetic energy ∼70 eV, which were observed in [J. E. Crawford, M. Daum, R. Frosch, et al., Phys. Lett. B 213, 391 (1988) and Phys. Rev. D 43, 46 (1991)]. Pis’ma Zh. éksp. Teor. Fiz. 64, No. 3, 129–133 (10 August 1996)     

Collective defect formation in the high-temperature superconductor YBa2Cu3O7 under the influence of adsorbed water molecules

The mechanisms for defect formation stimulated by the adsorption of water molecules in the surface of YBa₂Cu₃O₇ ceramic are studied, together with the types of defects and their distributions. It is found that a water layer physically bound to the surface reduces the rates of annihilation and capture of positrons, changes the amount of barium and copper on the surface by a factor of two, and inhibits diffusive jumps of nickel atoms. A layer of adsorbed water excites subthreshold formation of 10²¹ cm⁻³ interstitial Ba and Cu1 atoms and transitions of oxygen from O1 to O5, and vice versa in the volume of crystallites, and the migration of defects and accumulation of Ba atoms in the surface layer, which block diffusive jumps of Ni within the volume of the crystals. These effects are related to the excitation of collective, low-frequency weakly damped motion of heavy holes in the crystal volume when defects are formed on the surface by physically adsorbed H₂O molecules, which is accompanied by Coulomb repulsion of cations from intermediate layers into interstitials and the migration of defects in the field of the collective excitations. Zh. éksp. Teor. Fiz. 116, 586–603 (August 1999)     

Angular characteristics of processes of electron detachment from negative ions and hydrogen atoms in gases

The results of experimental measurement of spatial-angular distributions of hydrogen particles (H⁻, H⁰, H⁺) obtained in scattering of a collimated ribbon beam of H⁻ ions and H⁰(1s) atoms in He, Ar, Kr, Xe, H₂, O₂, and CO₂ gas targets for certain values of energy in the range from 0.6 to 15 MeV are reported. The experimental setup and the measurement procedure with an angular resolution of 5×10⁻⁶ rad are described. The angular characteristics of measured distributions, i.e., full width at half maximum and standard deviation, were determined. It is shown that the shape of distribution for a beam of hydrogen atoms produced by neutralization of H⁻ ions in a gas target varies with the type and thickness of the target, and the angular spread is smallest for the H₂ target. The variations in the shape of distribution are due to the contribution of scattering processes without changing the charge of particles.     

Calculation of decay widths of ppμ* ν,J ion in non-adiabatic approach

We calculate decay widths of the metastable ppμ^* _ν,J molecular ion in non-adiabatic approach. The muonic molecular ion can be formed in collision of the excited pμ(2s) atoms with H₂. Then, decay of the ppμ^* _ν,J system opens a path for the muon from pμ(2s) to pμ(1s). We employ trial wave function which includes non-adiabatic terms to calculate some radiationless decay widths. The present results of the widths do not good agree with those given in our previous work, while are more close to recent data of other researchers.     

Surface States and Spectra

Let ℤ₊ ^{d +1}= ℤ⁺×ℤ₊, let H ₀ be the discrete Laplacian on the Hilbert space l ²(ℤ₊ ^{d +1}) with a Dirichlet boundary condition, and let V be a potential supported on the boundary ∂ℤ₊ ^{d +1}. We introduce the notions of surface states and surface spectrum of the operator H=H ₀+V and explore their properties. Our main result is that if the potential V is random and if the disorder is either large or small enough, then in dimension two H has no surface spectrum on σ(H ₀) with probability one. To prove this result we combine Aizenman–Molchanov theory with techniques of scattering theory. Received: 18 September 2000 / Accepted: 21 November 2000     

Optical study of radicals (OH,O, H,N) in a needle-plate bi-directional pulsed corona discharge

In this study, analysis of optical emission spectra are used for the detection of OH (A²Σ) radicals and O (3p⁵P), H_α (3P) and N (3p⁴P) active atoms produced by the high-voltage bi-directional pulsed corona discharge of N₂ and H₂O mixture gas in a needle-plate reactor at one atmosphere. The relative vibrational populations and the vibrational temperature of N₂ (C, v') are determined. The effects of pulse peak voltage, pulse repetition rate and the added O₂ flow rate on the relative populations of OH (A²Σ) radicals and O (3p⁵P), H_α (3P) and N (3p⁴P) active atoms are investigated. It is found that when pulse peak voltage and pulse repetition rate are increased, the relative populations of those excited states radicals rise correspondingly. The relative population of OH (A²Σ) radicals decreases with increasing the flow rate of oxygen. The relative populations of O (3p⁵P), H_α (3P) and N (3p⁴P) active atoms increase with the flow rate of oxygen at first and exhibit a maximum value at about 30 ml/min. When the flow rate of oxygen is increased further, the relative populations of those excited states active atoms decrease correspondingly. The main involved physicochemical processes also have been discussed.