Experimental transition probabilities for lines arising from the 4d5p and 4d5d configurations of ZrIII

Relative transition probabilities for 120 lines arising from the 4d5p and 4d5d configurations of ZrIII were determined from measurements of emission-line intensities in a laser-produced plasma. The experiment was carried out with Cu-Zr alloy with a Zr content lower than 13% in order to have an optically thin plasma. Transition probabilities were placed on an absolute scale by using theoretical lifetimes, line-strength sum rules and Boltzmann plot. Comparison of the present experimental results with the available theoretical data is made.     

Hyperfine splitting constants in the optical transition \boldsymbol{{4{f}^{7}} {6{s}^{2}} \;{^{8}{\rm S}_{7/2}} \to {4{f}^{7}} {6{s}6{p}}\; {^{6}{\rm P}_{5/2}} \ {\rm of} \ {^{151-155}{\rm Eu}}} isotopes and hyperfine anomaly

Using the method of laser-induced fluorescence in an atomic beam we have measured the hyperfine splitting constants, A and B, of the ground and excited states of the optical transition 4f ⁷6s ^{2 8}S $_{1/2}\to 4f^{7}$ 6s6p ⁶P_5/2 (564.58 nm) for ^151???155Eu isotopes. For all isotopes, the magnetic dipole constants of the ⁶P_5/2 atomic level are determined to a precision better than 0.04%. The A and B constants for the ground state ⁸S_7/2 of the radioactive ^152,154,155Eu were obtained for the first time with a precision better than 0.5%. Our data along with previous ground state hyperfine structure measurements for the stable europium isotopes allow us to determine the hyperfine anomaly for mentioned Eu isotopes.