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1.
析相光度法测定铜(Ⅱ)的研究 总被引:3,自引:0,他引:3
本文研究了Cu-PEG-DDTC(铜试剂)(NH4)2SO4体系的析相光度法并应用于测定Cu。最宜酸度为3.6-9.0(NaAc-HAc,NH4Cl-NH3.H2O)缓冲溶液,其络合物的最大吸收位于450nm,表观摩尔吸光系数为9.05×10^3L.mol^-1.cm^-1,Cu浓度在0-30μg/L范围内服从比耳定律,铜与DDTC形成组成为1:2的稳定络合物。该方法用于铝合金中铜的测定,获得了满 相似文献
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火焰原子吸收光谱法测定鱼脑和鱼肉中铜、锌的含量 总被引:6,自引:0,他引:6
本文研究了用HNO3+HClO4(3+1)混酸消化鱼脑和鱼肉,在324.8nm波长处测定铜。在213.9nm波长处测定锌。多种离子均无干扰,RSD为0.58% ̄2.90%,加标回收率为97% ̄109%,结果令人满意。 相似文献
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原子吸收法测定人精子中锌和铜含量的研究 总被引:1,自引:0,他引:1
本文采用石墨炉原子吸收法,以NH4NO3和Mg(NO3)2混合剂作基体改进剂,测定了人精子中微量元素铜和锌。基方法的特征质量分别为10.00pgCu/0.0044A.S.,9.80PgZ/0.004A.S;平均加收率为97.42%,锌为101.91%,铜和锌的精密度分别是4.1%和4.03%。 相似文献
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ICP-AES法测定慢性乙肝患者头发中生命元素 总被引:9,自引:0,他引:9
建立了用ICP-AES法同时分析头发中多种生命元素的方法,方法的相对标准偏差为1.4% ̄4.9%,回收率介于94% ̄129%之间。测定了东莞地区159例在样大学生慢性乙肝患者头发样品中的Al、Ba、Ca、Co、Cr、Cu、Fe、Mg、Mn、Ni、Pb、Sr、Zn等十三种生命元素的含量,并和健康人比较,初步分析了头发中生命元素含量和慢性乙型肝炎的相关性。 相似文献
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本文用荧光光度法对硫酸介质中螺内酯和十二烷基硫酸钠(SDS)形成的胶束配合物的性能进行了系统研究。利用胶束的增敏增稳作用,提出了测定螺内酯的荧光光度新方法,方法线性范围宽,为1.4×10-9-4.3×10-6mol·L-1,灵敏度高,检出限为1.2×10-9mol·L-1。应用本法于片剂中螺内酯的测定,结果满意 相似文献
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铜与2-羟基-3-羧基-5-磺酸基苯重氮氨基偶氮苯反应的分光光度法研究及应用 总被引:2,自引:0,他引:2
研究了铜与2-羟基-3-羧基-5-磺酸基苯重氮氨基偶氮苯(HCSDAA)的显色反应。在Tri-tonN-101存在下和pH10.4~11.5的缓冲介质中,Cu2+与HCSDAA形成1∶2的红色配合物,其最大吸收波长是530nm,对比度为102nm,表观摩尔吸光系数为1.31×105L·mol-1·cm-1。铜在0~0.24μg/mL范围内服从比尔定律。用于铅锌矿和花生中微量铜的测定,相对误差不大于3.7%,相对标准偏差不大于1.6%(n=6)。 相似文献
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Guided-Wave Two-Dimensional Acousto-Optic Scanner Using Proton-Exchanged Lithium Niobate Waveguide 总被引:1,自引:0,他引:1
Two-dimensional scanning of a 0.6328 mum guided-light beam has been realized using noncolinear acousto-optic (AO) coplanar Bragg diffraction together with colinear AO guided-mode to substrate radiation-mode conversion in a Z-cut Xpropagation LiNbO3 proton-exchanged (PE) waveguide. The two surface acoustic (SAW) waves utilized are at the center frequencies of 500 and 200 MHz, propagating in the Y and X axes, respectively. Two-dimensional scanning of approximately 720 resolvable light beam spots, namely, 18 40 (horizontal vertical) scanning, has been demonstrated using a light beam of 1.0 mm aperture. The total number of resolvable beam spots can be greatly increased from 720 by simply utilizing SAW transducers of larger bandwidth and a light beam of greater aperture. It should also be possible to significantly increase the diffraction efficiency from 3 % by optimizing the parameters of the PE waveguide and the SAWs. 相似文献
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S. G. Nedel’ko M. A. Krysyuk A. L. Apanasenko L. N. Lymarenko Z. T. Moroz 《Journal of Applied Spectroscopy》1997,64(1):55-61
Results of a study of the effect of γ-radiation on the spectral luminescence properties of cadmium tungstate crystals doped
with silver, bismuth, and molybdenum cations are presented. Spectral characteristics of the nondnnnoped crystals are briefly
described. Absorption and photo and X-ray luminescence spectra of the crystals taken before and after exposure to γ-radiation
(5.5·104 Gy) are compared. It is found that the spectral characteristics of the crystals doped with silver, bismuth, and molybdenum
cations do not change markedly after the exposure. The relation between the type of impurity-induced defects, individual characteristics
of the impurity cations, and the character of the effect of γ-radiation on the spectral luminescence properties of impure
crystals is analyzed (preliminarily).
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 64, No. 1, pp. 55–60, January–February, 1997. 相似文献
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We measure the waveform and phase curves of short optical pulses before and after transmission over different lengths of fibers by use of the pulse analyzer with the frequency-resolved optical gating (FROG),and numerically simulate pulse evolution under the experimental conditions.The nonlinear coefficient of the fiber is given by comparing the experimental results with the numerical ones.Difference between the experiment and numerical simulation is analyzed. 相似文献
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Resonance scattering of elastic spherical shell and cylindrical shell while the surrounding fluid medium has absorption is studied. The normal mode solution derived using exact elastic theory and the separation of variables is still applicable. However, the scattering form function has to be modified for the absorbing medium, otherwise the unreasonable result would be obtained. The backscattering form function in the absorbing medium is redefined, and the form function of elastic spherical and cylindrical shell with vacuum or solid matter filled is calculated in various absorption conditions. The results show that the absorption of surrounding fluid leads to notable attenuation of the coincidence resonances in the mid-frequency, but it has a little influence on the low-frequency resonance scattering induced by the filler inside the shell. 相似文献
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A versatile and low-cost single-beam self-referenced phase-sensitive surface plasmon resonance(SPR)sensing system with ultra-high resolution performance is presented.The system exhibits a root-mean-square phase fluctuation of ±0.0028.over a period of 45 min.i.e.a resolution of±5.2×10-9 refractive index units.The enhanced performance has been achieved through the incorporation of three design elements:a true single-beam configuration enabling complete self-referencing so that only the phase change associated with SPR gets detected,a differential measurement scheme to eliminate spurious signals not related to the sensor response,and the elimination of retardation drifts by incorporating temperature stabilization in the liquid crystal phase modulato .Our design should bring the detection sensitivity of non-labeling SPR biosensing closer to that achievable by conventional fluorescence-based techniques. 相似文献
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Ta2O5 films are prepared on BK7 substrates with conventional electron beam evaporation deposition.The effects of SiO2 protective layers and annealing on the laser-induced damage threshold (LIDT) of the films are investigated.The results show that SiO2 protective layers exert little influence on the electric field intensity(EFI)distribution,microstructure and microdefect density but increase the absorption slightly.Annealing iS effective on decreasing the microdefect density and the absorption of the films.Both SiO2 protective layers and annealing are beneficial to the damage resistance of the films and the latter is more effective to improve the LIDT.Moreover,the maximal LIDT of Ta2O5 films is achieved by the combination of SiO2 protective layers and annealing. 相似文献
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Yepeng Guan 《中国光学快报(英文版)》2008,6(6)
Gray cross correlation matching technique is adopted to extract candidate matches with gray cross correla- tion coefficients less than some certain range of maximal correlation coefficient called multi-peak candidate matches. Multi-peak candidates are extracted corresponding to three closest feature points at first. The corresponding multi-peak candidate matches are used to construct the model polygon. Correspondence is determined based on the local geometric relations between the three feature points and the multi-peak candidates. The disparity test and the global consistency checkout are applied to eliminate the remaining ambiguous matches that are not removed by the local geometric relational test. Experimental results show that the proposed algorithm is feasible and accurate. 相似文献
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Byeong Ha Lee Young-Jae Kim Youngjoo Chung Won-Taek Han Un-Chul Paek 《Fiber and Integrated Optics》2001,20(5):443-455
A novel method based on fiber gratings for measuring the effective indices of fiber modes is proposed. The effective index difference between the core mode and a cladding mode was obtained by analyzing the interference fringe of a pair of cascaded long-period fiber gratings. In order to extract the core mode index from the measured index difference, an index matching oil immersion method is proposed. By analyzing the interaction between the cladding mode and the oil applied on the cladding surface, the mode order and the effective index of the involved cladding mode might be calculated. Experimental results about the interference fringe shifts induced by the oil index and the oil-applied length are also presented. 相似文献
19.
Nonlinear optical pulse compression of picosecond pulses typically requires long lengths of optical fiber and multiple components. Periodic structures, such as fiber Bragg gratings, are highly dispersive at wavelengths outside of the photonic bandgap. This implies that such gratings can be used as very short all-fiber compressors. In this paper a number of such compression schemes are reviewed involving uniform and nonuniform fiber Bragg gratings, relying on both soliton and nonsoliton compression principles. Experimental results supporting the corresponding underlying theory are also presented. Finally, an extension of one of the compression schemes is shown, which allows the generation of adjustable high-repetition rate soliton trains. 相似文献