Kinetics of shape equilibration for two dimensional islands

We study the relaxation to equilibrium of two dimensional islands containing up to 20 000 atoms by Kinetic Monte Carlo simulations. We find that the commonly assumed relaxation mechanism - curvature-driven relaxation via atom diffusion - cannot explain the results obtained at low temperatures, where the island edges consist in large facets. Specifically, our simulations show that the exponent characterizing the dependence of the equilibration time on the island size is different at high and low temperatures, in contradiction with the above cited assumptions. Instead, we propose that - at low temperatures - the relaxation is limited by the nucleation of new atomic rows on the large facets: this allows us to explain both the activation energy and the island size dependence of the equilibration time. Received 7 December 1998 and Received in final form 18 March 1999     

Sensitivity to initial conditions in the Bak-Sneppen model of biological evolution

We consider biological evolution as described within the Bak and Sneppen 1993 model. We exhibit, at the self-organized critical state, a power-law sensitivity to the initial conditions, calculate the associated exponent, and relate it to the recently introduced nonextensive thermostatistics. The scenario which here emerges without tuning strongly reminds of that of the tuned onset of chaos in say logistic-like one-dimensional maps. We also calculate the dynamical exponent z. Received: 5 November 1997 / Received in final form: 11 November 1997 / Accepted: 19 November 1997     

Apparent slip at a polymer-polymer interface

We consider a planar interface between strongly-segregated homopolymers subjected to steady shear in the plane of the interface. We develop a constitutive equation for stress relaxation in an inhomogeneous system for chains obeying Rouse dynamics. Using this equation, the interfacial viscosity for a symmetric blend is found to be in agreement with a scaling prediction due to de Gennes, where is the bead friction coefficient, b is the segment length, is the segment volume and is the Flory-Huggins interaction parameter driving the phase separation. We generalize our results to asymmetric blends and describe a phenomenological extension to entangled melts. Received: 18 August 1997 / Received in final form: 1 December 1997 / Accepted: 2 December 1997     

Evolution from BCS superconductivity to Bose condensation: analytic results for the crossover in three dimensions

We provide an analytic solution for the mean-field equations and for the relevant physical quantities at the Gaussian level, in terms of the complete elliptic integrals of the first and second kinds, for the crossover problem from BCS superconductivity to Bose-Einstein condensation of a three-dimensional system of free fermions interacting via an attractive contact potential at zero temperature. This analytic solution enables us to follow the evolution between the two limits in a particularly simple and transparent way, as well as to verify the absence of singularities during the evolution. Received: 9 May 1997 / Revised: 4 August 1997 / Accepted: 6 November 1997     

Diffusion of adsorbates on random alloy surfaces

In this work the diffusion of non-interacting adsorbates on a random AB alloy surface is considered. For this purpose a simple cubic (sc), body-centered cubic (bcc) or face-centered cubic (fcc) auxiliary metal lattice is introduced. The auxiliary lattice is truncated parallel to its (100) plane in such a way that the fourfold hollow positions of the metal surface form a regular net of adsorption sites with square symmetry. The adsorption energy of each adsorption site is determined by its own environment, i.e. by the numbers of direct A or B neighbors. The Monte-Carlo method has been utilized to simulate surface diffusion of adsorbates on such energetically heterogeneous alloy surfaces and to calculate the tracer, jump and chemical diffusion coefficients. The chemical diffusion coefficient was calculated via two different approaches: the fluctuation and the Kubo-Green method. The influence of energetical heterogeneities on the surface diffusion is largely pronounced at low temperatures and low surface coverages, where most of the adatoms are trapped by deep adsorption sites. It was found that at low temperatures the sequential occupation of the different types of adsorption sites can be observed. Received: 24 October 1997 / Accepted: 17 December 1997     

Effect of hydrodynamic flow on kinetics of nematic-isotropic transition in liquid crystals

We investigate kinetics of nematic-isotropic transition by solving the hydrodynamic equations for the nematic tensor order parameter and the fluid velocity in two space dimension (x-y plane). Numerical results indicate that nematic directors tend to align parallel to the x-y plane when hydrodynamic flow is incorporated. Late stage growth exponents, for the correlation length and for the number of topological defects, are not significantly altered by hydrodynamic flow. However, in contrast to the case without flow, the relation holds well, which may indicate the validity of dynamical scaling for the case with hydrodynamic flow. Received: 8 September 1997 / Received in final form: 23 October 1997 /Accepted: 3 November 1997     

Monte Carlo simulations of high-moment - low-moment transitions in Invar alloys

We have reproduced magneto-volume effects typical for Invar alloys by examining a spin-analogous model which describes coupled spatial and magnetic degrees of freedom and, additionally, chemical disorder. Constant pressure Monte Carlo simulations of this model show an almost vanishing thermal expansion over a broad range of temperatures below ,a softening of the bulk modulus and the absence of a sharp peak in the specific heat at the magnetic phase transition as observed in Fe₆₅Ni₃₅ Invar. Received: 9 September 1996 / Revised: 23 May and 23 September 1997 / accepted: 3 September 1997     

Quantum fluctuations and ground state of weakly interacting helix spin chains in a magnetic field

Ferromagnetic spin chains of a hexagonal lattice coupled by a weak antiferromagnetic interaction J₁ develop a helix arrangement if the intrachain antiferromagnetic NNN exchange J₂ is sufficiently large. We show that the classical minimum energy spin configuration is an umbrella when an external magnetic field is applied. The scenario is dramatically changed by quantum fluctuations. Indeed we find that the zero point motion forces the spins in a plane containing the magnetic field so that classical expectation is deceptive for our model. Our result is obtained by controlled expansion in the low field-long wavelength modulation limit. Received: 9 September 1997 / Revised: 15 October 1997 / Accepted: 17 November 1997     

Low frequency dielectric spectroscopy of the Peierls-Mott insulating state in the deuterated copper-DCNQI systems

We report a detailed characterization of an unique 3-fold commensurate insulating state in single crystals of the organic – inorganic d hybrid Cu(DMe-DCNQI)₂ systems with deuterated and partially deuterated DCNQI ring, by means of low-frequency dielectric spectroscopy. A broad relaxation mode of strength centred at kHz is observed in the hysteresis temperature region in which the insulating phase coexists with metallic islands. At lower temperatures, outside the nucleation range, the relaxation narrows, approaching a Debye-like form for an overdamped response of a system with a single degree of freedom. Both, the relaxation strength and the mean relaxation time () are much larger than that expected for single-particle excitations. These features suggest the origin of the dielectric relaxation as an intrinsic property of the N = 3 charge density wave state. Received 1 December 1999 and Received in final form 5 April 2000     

Mesoscopic charge density wave in a magnetic flux

The stability of a Charge Density Wave (CDW) in a one-dimensional ring pierced by a Aharonov-Bohm flux is studied in a mean-field picture. It is found that the stability depends on the parity of the number N of electrons. When the size of the ring becomes as small as the coherence length , the CDW gap increases for even N and decreases for odd N. Then when N is even, the CDW gap decreases with flux but it increases when N is odd. The variation of the BCS ratio with size and flux is also calculated. We derive the harmonics expansion of the persistent current in a presence of a finite gap. Received: 16 September 1997 / Received in final form: 12 November 1997 / Accepted: 13 November 1997     

Buffer-gas loaded magnetic traps for atoms and molecules: A primer

Over the past three years we have developed the technique of buffer-gas cooling and loading of atoms and molecules into magnetic traps. Buffer-gas cooling relies solely on elastic collisions (thermalization) of the species-to-be-trapped with a cryogenically cooled helium gas and so is independent of any particular energy level pattern. This makes the cooling technique general and potentially applicable to any species trappable at the temperature of the buffer gas (as low as 240 mK). Using buffer-gas loading, paramagnetic atoms (europium and chromium) as well as a molecule (calcium monohydride) were trapped at temperatures around 300 mK. The numbers of the trapped atoms and molecules were respectively about 10¹² and 10⁸. The atoms and molecules were produced by laser ablation of suitable solid precursors. In conjunction with evaporative cooling, buffer-gas loaded magnetic traps offer the means to further lower the temperature and increase the density of the trapped ensemble to study a large variety of both static (spectra) and dynamic (collisional cross-sections) properties of many atoms and molecules at ultra-low temperatures. In this article we survey our main results obtained on Cr, Eu, and CaH and outline prospects for future work. Received 2 November 1998 and Received in final form 19 February 1999     

Stabilizing co-continuous polymer blend morphologies with ABC block copolymers

We suggest that ABC triblock copolymers provide a convenient and effective route to emulsifying blends of A and C homopolymers into co-continuous morphologies over a wide range of compositions. Direct transitions between disordered tricontinuous phases (“ABC microemulsions”) and spatially-periodic tricontinuous phases (e.g. gyroid or double-diamond cubic phases) should be possible in appropriately formulated alloys. We envision a broad range of potential applications to thermoplastic and thermoset polymeric materials. Received: 4 June 1997 / Revised: 17 September 1997 / Accepted: 13 October 1997     

Fermi liquid theory: a renormalization group approach

We show how Fermi liquid theory results can be systematically recovered using a renormalization group (RG) approach. Considering a two-dimensional system with a circular Fermi surface, we derive RG equations at one-loop order for the two-particle vertex function in the limit of small momentum () and energy () transfer and obtain the equation which determines the collective modes of a Fermi liquid. The density-density response function is also calculated. The Landau function (or, equivalently, the Landau parameters F _l ^s and F _l ^a ) is determined by the fixed point value of the -limit of the two-particle vertex function (). We show how the results obtained at one-loop order can be extended to all orders in a loop expansion. Calculating the quasi-particle life-time and renormalization factor at two-loop order, we reproduce the results obtained from two-dimensional bosonization or Ward Identities. We discuss the zero-temperature limit of the RG equations and the difference between the Field Theory and the Kadanoff-Wilson formulations of the RG. We point out the importance of n-body () interactions in the latter. Received: 27 June 1997 / Received in final form: 17 December 1997 / Accepted: 26 January 1998     

Surface effects in field-induced smectic transitions

We study the surface behavior of a semi-infinite smectogenic sample bounded by a solid wall, in the presence of an external electric field. Our analysis is performed in the framework of a Landau-de Gennes theory. For the sake of simplicity, we consider only the case in which, in the absence of field and surfaces, a direct isotropic to smectic-A transition occurs, while in the presence of the electric field a nonspontaneous nematic phase appears. Two new surface phases are identified, namely a parasmectic and a surface-induced smectic phase. The shifts in the transition temperatures and the critical behavior of the surface states are analyzed. Received: 25 August 1997 / Accepted: 23 January 1998     

The new identity for the scattering matrix of exactly solvable models

We discovered a simple quadratic equation, which relates scattering phases of particles on Fermi surface. We consider one-dimensional Bose gas and XXZ Heisenberg quantum spin chain. Received: 4 December 1997 / Accepted: 17 March 1998     

Monte-Carlo study of correlations in quantum spin chains at non-zero temperature

Antiferromagnetic Heisenberg spin chains with various spin values (S=1/2,1,3/2,2,5/2) are studied numerically with the quantum Monte-Carlo method. Effective spin S chains are realized by ferromagnetically coupling n=2S antiferromagnetic spin chains with S=1/2. The temperature dependence of the uniform susceptibility, the staggered susceptibility, and the static structure factor peak intensity are computed down to very low temperatures, . The correlation length at each temperature is deduced from numerical measurements of the instantaneous spin-spin correlation function. At high temperatures, very good agreement with exact results for the classical spin chain is obtained independent of the value of S. For the S=2 chain which has a gap , the correlation length and the uniform susceptibility in the temperature range are well predicted by the semi-classical theory of Damle and Sachdev. Received: 23 December 1997 / Revised and Accepted: 11 March 1998     

Dynamics of selfavoiding tethered membranes. I. Model A dynamics (Rouse model)

The dynamical scaling properties of selfavoiding polymerized membranes with internal dimension D are studied using model A dynamics. It is shown that the theory is renormalizable to all orders in perturbation theory and that the dynamical scaling exponent z is given by . This result applies especially to membranes (D=2) but also to polymers (D=1). Received: 5 September 1997 / Accepted: 17 November 1997     

Magnetothermal instabilities in an organic superconductor

We have studied the occurrence of magnetothermal instabilities in a single crystal during field sweep magnetization experiments, equivalent to short time relaxation studies. We find instability behaviour in good agreement with a recent model by Mints, for a non-linear E(J) characteristic. In particular, we find that a decrease of the dynamic relaxation rate, characterizing the effective activation energy, precedes the unstable regime. We point out formal analogies between such instabilities and the general predictions for flux avalanches. Received: 11 December 1997 / Revised: 15 January 1998 / Accepted: 31 March 1998