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本文首次研究了Al80Mn14Si6合金在静高压下准晶相得形成。利用静高压熔态淬火方法,在压力2.8和3.1 GPa下得到淬火的Al-Mn-Si样品。电子和X射线衍射实验表明,高压淬火样品中含有准晶二十面体相和非晶相。X射线衍射实验还表明,高压淬火样品经350 ℃退火一小时基本上没有发生变化;而经过500 ℃退火一小时后,准晶相晶化为α-Al73Si10Mn17相。另外,电子衍射实验表明,高压淬火后样品中还存在其它中间亚稳相。本文还讨论了静高压熔态淬火方法的适用性。 相似文献
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静高压(4.5 GPa)下Al6Mn合金熔态淬火(冷却速度约为102 ℃/s),得到Al6Mn合金的高压淬火样品。X射线分析表明:Al6Mn合金的高压淬火样品中含有准晶二十面体相、Al6Mn相及Al的面心立方相;与常压结果相比,高压淬火方法的冷却速率可比常压的低约3个数量级的条件下产生准晶二十面体相。其晶化温度与急冷甩带的相近。对静高压(2.5 GPa)下Al6Mn准晶条带样品的晶化过程进行了研究。X射线分析表明:静高压下Al6Mn准晶条带样品的晶化过程中,出现了一种新的未知亚稳相——准晶向晶体转化中的一种中间过渡态,具有类T相形式;与常压结果比较,高压下准晶相晶化温度提高。 相似文献
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LIAO ShuZhi GUI XuChun ZHANG Chun PENG HaoJun XIE HaoWen OUYANG YiFang & ZHANG BangWei Key Laboratory of Low Dimensional Quantum Structures Quantum Control of Ministry of Education 《中国科学G辑(英文版)》2009,52(10):1593-1600
The forming ability of quasicrystal phase has a relationship with the atomic bond factors based on differences in atom size and electron factors.Usually,those factors or their combination are used to describe the forming ability,stability of alloys,etc.In this paper,the quasicrystal alloy forming abilities for the fifth and sixth transition metals(Y,Zr,Nb,Mo,Ru,Rh,Pd and La,Hf,Ta,W,Re,Os,Ir,Pt) based alloys have been studied by the size factor and the atomic parametric function.It has been found that an ell... 相似文献
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The theory of crystallization of quasicrystal structures that does not use the concept of multidimensional crystallography for describing the quasicrystal order has been proposed. It has been shown using the structure of the MnSiAl octagonal quasicrystal as an example that the coordinates of the sites in the corresponding quasicrystal lattice can be calculated by conditional minimization of the Landau free energy. The abandonment of the unconditional minimization of the free energy has been justified by special features of the local atomic order in the considered structure. The proposed theory gives a new physical meaning to the traditional concepts of multidimensional crystallography and can also be used for explaining the formation of quasicrystal structures with other quasicrystal lattices. 相似文献
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D. V. Olenev É. I. Isaev Yu. Kh. Vekilov 《Journal of Experimental and Theoretical Physics》1998,86(3):550-558
Electron spectra and wave functions of icosahedral quasicrystals have been investigated in the tight-binding approximation
using the two-fragment structural model (the Amman-MacKay network) with “central” decoration. A quasicrystal has been considered
as a limiting structure in a set of optimal cubic approximants with increasing lattice constants. The method of level statistics
indicates that the energy spectrum of an icosahedral quasicrystal contains a singular (nonsmooth) component. The density of
electron states has been calculated for the first four optimal cubic approximants of the icosahedral quasicrystal, and the
respective Lebesgue measures of energy spectra of these approximants have been obtained. Unlike the case of a one-dimensional
quasiperiodic structure, the energy spectrum of an icosahedral quasicrystal does not contain a hierarchical gap structure
typical of the Cantor set of measure zero in a one-dimensional quasicrystal. Localization of wave functions in an icosahedral
quasicrystal has been studied, and their “critical” behavior has been detected. The effect of disorder due to substitutional
impurities on electron properties of icosahedral quasicrystals has been investigated. This disorder makes the electron spectrum
“smoother” and leads to a tendency to localization of wave functions.
Zh. éksp. Teor. Fiz. 113, 1009–1025 (March 1998) 相似文献
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Structure of the Al---Rh---Cu decagonal quasicrystal has been studied by high-resolution electron microscopy. The high-resolution structure image shows an aperiodic tiling composed of three kinds of subunits, namely flattened hexagon, crown and five star. Therefore, a structural model of the Al---Rh---Cu decagonal quasicrystal has been constructed in a unit-cell approach, in which the atom arrangements in the subunits have been proposed. It is known that the phase has two layers in a period of 0.4 nm along the unique tenfold axis according to the previous study by electron diffraction method. The ideal model of the Al---Rh---Cu decagonal quasicrystal is proposed as periodic stacking of the layers with quasiperiodic tessellation of the three kinds of subunits, in each layer the two-colour Penrose tiling is obtained if different atom decorations for the same shape subunits are distinguished by white and black colours. Calculated images reproduces well the contrast features of the observed images, which means that the present model is basically correct. Structural relationship between the Al---Rh---Cu decagonal quasicrystal and the previously reported Al---Ni---Co decagonal quasicrystal, which has also a period of 0.4 nm, has also been discussed. 相似文献
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P. P. Parshin M. G. Zemlyanov G. Kh. Panova A. A. Shikov R. A. Brand B. Grushko 《Journal of Experimental and Theoretical Physics》2009,109(4):645-651
The atomic dynamics of an Al71.3Ni24Fe4.7 decagonal quasicrystal has been investigated using the isotopic contrast method for inelastic neutron scattering. The partial
vibrational spectra of the Ni, Fe, and Al atoms and the spectrum of the thermal vibrations of the alloy have been reconstructed
directly from the experimental data without any model assumptions. The cutoff energies and the positions of the main features
of the spectra have been determined. It has been revealed that the average binding energy of the nickel atoms in the quasicrystal
under investigation is lower than that of the iron atoms and the vibrational spectrum of the aluminum atoms is noticeably
harder than the spectrum of the pure metal. The results obtained for the d-AlNiFe decagonal quasicrystal have been compared with the previously published data for an i-AlCuFe icosahedral quasicrystal. 相似文献
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G. Kh. Panova M. G. Zemlyanov P. P. Parshin A. A. Shikov R. A. Brand 《Physics of the Solid State》2010,52(4):771-775
The specific heat of decagonal Al71.3Ni24.0Fe4.7 and icosahedral Al62Cu25.5Fe12.5 quasicrystals and the Al55.0Si7.0Cu25.5Fe12.5 cubic phase approximating the structure of the icosahedral alloy has been studied in the temperature range 4.2–40.0 K. All
the three compounds exhibit low coefficients of the electronic heat capacity and pronounced deviations of the low-temperature
lattice heat capacity from a cubic temperature law in the range 5–10 K. The results obtained by the thermodynamic method and
inelastic neutron scattering have been compared and analyzed. It has been established that, at energies ɛ < 14 meV, the spectral
density of thermal vibrations in the icosahedral quasicrystal is substantially higher than those in the cubic approximant
and in decagonal quasicrystal. 相似文献
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The band structure of three-dimensional cubic approximants of a photonic quasicrystal has been determined by numerical calculation. The approximants of different orders appear to have large, almost isotropic, band gaps in a wide range of relative permittivity values. The existence of the complete band gap in the photonic quasicrystal with the six-dimensional bcc lattice is shown. 相似文献
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Nanocrystalline Al64Cu23Fe13 icosahedral quasicrystal has been obtained by milling of solid quasicrystal precursors prepared by arc-melt. The local structure around Fe atoms was studied by Mössbauer spectroscopy using a quadrupole splitting distribution method. Mössbauer results of annealed and milled samples show the existence of a broadened distribution of Fe sites which is associated to intrinsic disorder. The structural characterization was determined using x-ray diffraction. The average grain-size of the nanostructured quasicrystal, obtained from the line broadening of the X-ray diffraction peaks, was estimated to be of the order of 10 nm for a sample milled by 5 h. 相似文献
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P. P. Parshin M. G. Zemlyanov R. A. Brand D. Pavlyuchkov J. Ollivier 《Physics of the Solid State》2010,52(7):1492-1498
The atomic dynamics of the Al0.550Si0.070Cu0.255Fe0.125 alloy with the structure that approximates the structure of an icosahedral quasicrystal with a similar chemical composition
has been investigated using inelastic neutron scattering. The partial vibrational spectra of copper, iron, and aluminum atoms
and the total spectrum of thermal vibrations of the compound have been directly reconstructed from the experimental data for
the first time. A combined analysis of the results obtained and the data on the atomic dynamics of the i-AlCuFe icosahedral quasicrystal has been performed. 相似文献