共查询到19条相似文献,搜索用时 187 毫秒
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具有巨介电常数的CaCu3Ti4O12陶瓷是一种理想的高储能密度电容器材料.本文以草酸为沉淀剂、以乙酸铵为调节pH值的定量缓冲剂,获得制备CaCu3Ti4O12陶瓷的简化共沉淀法.确定了pH=30为制备前驱粉料的最佳反应条件.通过显微分析和介电性能测量,发现在1040℃—1100℃范围内,随着烧结温度的提高,陶瓷的品粒尺寸增大,非线性系数上升,电位梯度和介电损耗下降,1100℃烧结的试样tanδ最低达到0.04.认为CaCu3Ti4O12陶瓷介电损耗包含直流电导分量、低频松弛损耗和高频松弛损耗.低频松弛活化能为0.51 eV.,对应于晶界处的Maxwell-Wagner松弛极化;高频松弛过程活化能为0.10 eV,对应晶粒内部的氧空位缺陷.烧结温度的升高导致晶界电阻下降. 相似文献
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对比分析了几种可输出圆波导TE01模激励器的仿真设计结果。结果表明,利用行波功分结构实现矩形波导TE10模到4路矩形波导TE10模的等幅同相功分,进而合成转换成圆波导TE01模的转换过程,可在较宽的频带范围内,实现圆波导TE01模的高效激励。以中心频率9.40 GHz仿真设计的圆波导TE01模激励器,在中心频率上的传输效率超过99.9%;在9.08~9.61 GHz的频率范围内,传输效率大于99%。实验测量结果表明,所加工激励器在较宽的频带范围内,传输损耗优于-0.2 dB,与仿真结果的差异主要来自于波导壁面的欧姆损耗和波同转换结构;器件工作频带内平坦特性良好,有利于开展测量工作。 相似文献
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在77—553K范围内的不同温度下测量了金属玻璃(Fe0.8Ni0.15,Cr0.05)78Si8B14的起始磁导率减落。测量结果表明,减落的温度关系表现为一个具有单一弛豫峰的不对称谱。在273K下考察了减落的动力学行为。用Hesse-Rubartsch方法拟合动力学曲线得到一个左右不对称的单峰激活能谱,最可几激活能大约为1.40eV。考察了减落的退火效应及退火动力学行为,结果表明,在宽的温度范围内,减落呈现明显的退火效应,而且退火动力学行为近似服从lnt动力学。
关键词: 相似文献
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E. Colavita M. De Crescenzi L. Papagno L.S. Caputi G. Chiarello R. Scarmozzino R. Rosei 《Solid State Communications》1982,41(7):545-548
The electronic properties of the amorphous and sintered Fe80B20 alloys have been studied by electron energy loss spectroscopy. A correlation among energy loss data and X-ray absorption near edge structures has been attempted.Structure-related effects in the electronic properties of Fe80B20 alloy have been found and discussed. 相似文献
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根据实验研究成果提出纳米晶合金软磁性能受其介观结构影响的观点,建立了Fe基纳米晶合金的球状介观结构模型,分别求出只有交变磁场或交变磁场和静磁场作用时纳米晶粒球的频率函数——D函数.分析表明,两种D函数都是复变函数,其实部Re(D)为纳米晶电感性质和电容性质的反映,虚部Im(D)为纳米晶电阻性质的反映,据此建立了Fe基纳米晶合金介观结构的等效RLC并联模型.由该模型求得合金产生极值巨磁电阻的条件为vextGMI=v|Re(D)=0,决定因素有μ,σ,ω,R和Hex及微观磁结构.
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Fe基纳米晶合金
等效RLC并联模型
球状介观结构模型
频率函数 相似文献
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PbO-PbF2-B2O3 glasses containing different concentrations of FeO have been prepared. The glasses are characterized by X-ray diffraction and differential thermal analysis. The dielectric properties viz., dielectric constant, loss, conductivity, over a moderately wide range of frequency and temperature and dielectric breakdown strength have been investigated. The results of these studies have been analyzed in the light of different oxidation states of iron with the aid of the data on IR, ESR, optical absorption and magnetic susceptibility measurements. The analysis shows that iron ions exist mainly in Fe3+ state, occupy tetrahedral positions and increase the insulating strength of the glass if FeO is present in smaller concentrations. However, if FeO is present in higher concentrations in the glass matrix, (i) the dielectric relaxation intensity has been observed to increase, (ii) the intensity and the half width of the ESR signal has been observed to decrease and (iii) the value of magnetic moment (evaluated from magnetic susceptibility) has been observed to drop to a value of 4.6 μB from 5.7 μB. From these results it has been concluded that in this concentration range, iron ions exist mainly in divalent state. 相似文献
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Giant magnetoimpedance (GMI) effect has been measured in a glass-coated amorphous (Co0.93Fe0.7)63Ni10Si11B16 microwire as a function of DC magnetic field and up to the frequency of 11 MHz. The sample shows single peak GMI characteristics within the whole range of frequency. The domain structure of the above sample has been changed by applying tensile stresses up to 603 MPa and current annealing with a DC current of 50 mA for various time durations, and the corresponding effect on GMI has been studied in detail. A maximum change of 8.85% in MI of the as-quenched sample has been observed around a frequency of 5.05 MHz. Application of an external tensile stress reduces the GMI value by increasing the inner core domain, whereas heat treatment of the sample enhances the same. The square-shaped magnetic hysteresis loop of the as-quenched sample helps us understanding the MI results. 相似文献
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The structural, elastic, and electronic properties of a series of icosahedral phases, such as boron subcarbides B12C3 and B13C2, subnitride B12N2, and suboxide B12O2, have been studied in the framework of the SCC-DFTB method. It has been found that the B12C2 and B13C2 phases manifest metal-like properties, while B12C3 and B12O2 are semiconductors. The estimates have shown that the insertion of 2p atoms (C, N, or O) into intericosahedral pores of elemental boron can cause both a decrease in its elastic modulus (an increase
in the compressibility of B12N2) and a sharp increase in the modulus B (in subcarbides B12C3 and B12BCC). On the other hand, the insertion of 2p atoms into α-B12 will favor an increase in its hardness (suboxide B12O2 will have a maximum hardness). 相似文献
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The substitution of iron for cobalt in crystalline Co3B and Co78B22 and Co72Si2B26 glasses has been studied by Mössbauer spectroscopy. In both crystalline and amorphous states, iron preferentially replaces those cobalt atoms which have two boron nearest neighbours. 相似文献
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The electronic structure of hexagonal Gd3Co11B4 compound has been studied by X-ray photoemission spectroscopy (XPS) and ab initio self-consistent tight binding linear muffin tin orbital (TB LMTO) method. We have found a good agreement between the experimental XPS valence band spectra and theoretical LMTO calculations. Results showed that the Gd3Co11B4 compound is ferrimagnetic with the calculated total magnetic moment M=14.29 μB/f.u. The values of the magnetic moments on Co atoms strongly depend on the local environment. We have also compared the electronic structure and magnetic properties of Gd3Co11B4 compound with those of Nd3Co11B4 compound. 相似文献