Colligative Properties of Solutions: I. Fixed Concentrations

Using the formalism of rigorous statistical mechanics, we study the phenomena of phase separation and freezing-point depression upon freezing of solutions. Specifically, we devise an Ising-based model of a solvent--solute system and show that, in the ensemble with a fixed amount of solute, a macroscopic phase separation occurs in an interval of values of the chemical potential of the solvent. The boundaries of the phase separation domain in the phase diagram are characterized and shown to asymptotically agree with the formulas used in heuristic analyses of freezing-point depression. The limit of infinitesimal concentrations is described in a subsequent paper.     

Droplet Shapes for a Class of Models in \mathbb{Z}^2 at Zero Temperature

In this work we consider the Wulff construction at zero temperature for a class of Gibbs models and study the shape of the obtained droplets. Considering zero temperature we avoid all difficulties connected with the competition between energy and entropy. It allows us to study a quite wide class of models which provides a variety of shapes. The motivations of the study come from attempts to describe isotropic properties of some models on 2D lattice at zero temperature. The studied models are binary (the spin space is 0,1) with a ferromagnetic behavior such that the potential functions are not equal to zero only for some tiles with size 3×3. In fact, we study herein droplet shapes of a subclass of the ferromagnetic models with potential functions as mentioned above. This subclass of models is defined by a condition called regularity. We call the model classified here as having regular micro-boundaries. Several examples of non-regular models are also presented.     

Large deviations for the 2D ising model: A lower bound without cluster expansions

We show that a lower large-deviation bound for the block-spin magnetization in the 2D Ising model can be pushed all the way forward toward its correct Wulff value for all >_c.     

A microscopic justification of the Wulff construction

We report results about a rigorous microscopic justification of the Wulff construction for the two-dimensional Ising model at low temperatures and under periodic boundary conditions. The idea of the proof is sketched.     

Magnetic Properties of Transverse Ising Model under a Time Oscillating Longitudinal Field

A transverse Ising spin system, in the presence of time-dependentlongitudinal field, is studied by the effective-field theory (EFT). Theeffective-field equations of motion of the average magnetization are givenfor the simple cubic lattice (Z = 6) and the honeycomb lattice (Z = 3).The Liapunov exponent λ is calculated for discussing the stability of the magnetization and it is used to determine the phase boundary. Thedynamic phase transition diagrams in h₀/ ZJ -Γ/ZJ plane and in h₀/ZJ-T/ZJ plane have been drawn, and there is no dynamical tricritical point on the dynamic phase transition boundary. The effect of the thermal fluctuations upon the dynamic phase boundary has been discussed.     

正则黑洞熵与相变

应用隧道效应对黑洞Hawking辐射研究得到的辐射谱,对非旋转黑洞的正则熵进行讨论.所得熵遵守Bekenstein-Hawking 面积定律,并带有修正项,主要修正项与面积的对数成正比,另有与黑洞热容量有关的修正项.利用所给出的正则熵,对黑洞的相变进行讨论,得到当黑洞的热容量出现发散时,正则熵在该处并不出现复数,由此认为此相变为二级相变. 关键词： 正则系综 量子修正 黑洞相变     

Existence and Order of the Phase Transition of the Ising Model with Fixed Magnetization

Properties of the two dimensional Ising model with fixed magnetization are deduced from known exact results on the two dimensional Ising model. The existence of a continuous phase transition is shown for arbitrary values of the fixed magnetization when crossing the boundary of the coexistence region. Modifications of this result for systems of spatial dimension greater than two are discussed.     

The theory of melting in heteropolymers. II. Correlated chains

Equations are derived for the calculation of the ground-state melting curves for polynucleotide sequences with correlation between the nearest neighbors. The case of arbitrary correlated sequences is also considered. The effect of correlations in the sequence on the width and on the intrinsic fine structure of melting curves is discussed.Work supported in part by NSF Material Research Laboratory at Case Western Reserve University.     

Equilibrium Phase Transitions in Coupled Map Lattices: A Pedestrian Approach

A class of piecewise linear coupled map lattices with simple symbolic dynamics is constructed. It can be solved analytically in terms of the statistical mechanics of spin lattices. The corresponding Hamiltonian is written down explicitly in terms of the parameters of the map. The approach follows the line of recent mathematical investigations. But the presentation is kept elementary so that phase transitions in the dynamical model can be studied in detail. Although the method works only for map lattices with repelling invariant sets some of the conclusions, i.e., the role of local curvature of the single site map and properties of the nearest neighbour coupling might play an important role for phase transitions in general dynamical systems.     

Thermodynamics properties of an anisotropic Ising antiferromagnet in both external longitudinal and transverse fields

We have studied the anisotropic two-dimensional nearest-neighbor Ising model with competitive interactions in both uniform longitudinal field H$H$ and transverse magnetic field Ω$\Omega$. Using the effective-field theory (EFT) with correlation in cluster with N=1$N=1$ spin we calculate the thermodynamic properties as a function of temperature with values H$H$ and Ω$\Omega$ fixed. The model consists of ferromagnetic interaction _Jx$J_x$ in the x$x$ direction and antiferromagnetic interaction _Jy$J_y$ in the y$y$ direction, and it is found that for H/_Jy∈[0,2]$H/J_y\in [0,2]$ the system exhibits a second-order phase transition. The thermodynamic properties are obtained for the particular case of λ=_Jx/_Jy=1$\lambda =J_x/J_y=1$ (isotropic square lattice).     

Application of bond-moving renormalization-group approach to fractal lattices

We investigate the application of the Migdal-Kadanoff bond-moving renormalization group (RG) approach to fractal lattices. We find the following two results: first, for inhomogeneous interaction lattice models, bond moving involving inequivalent bonds is unsuitable because it violates the condition <Δ>=0 (Δ is the perturbation potential resulting from moving the bonds); second, the condition <Δ>=0 does not uniquely determine the way to move bonds; different choices of bond moving yield different RG recursion relations and corresponding fixed points, which makes the conclusions concerning the phase transition quite uncertain.     

Higher-order susceptibilities of the regular and the random Ising model on the Cayley tree. I

Explicit expressions for the fourth-order susceptibility (⁴), the fourth derivative of thebulk free energy with respect to the external field, are given for the regular and the random-bond Ising model on the Cayley tree in the thermodynamic limit, at zero external field. The fourth-order susceptibility for the regular system diverges at temperature T _c ⁽⁴⁾ = 2k _B ^–1 J/ln{1+2/[(z–1)^3/4–1]}, confirming a result obtained by Müller-Hartmann and Zittartz [Phys. Rev. Lett. 33:893 (1974)]; Herez is the coordination number of the lattice,J is the exchange integral, andk _B is the Boltzmann constant. The temperatures at which ⁽⁴⁾ and the ordinary susceptibility (²) diverge are given also for the random-bond and the random-site Ising model and for diluted Ising models.     

Magnetic Properties of Spin-1/2 Ising Superlattice

Using the effective-field theory we studied the magnetic properties of a spin-1/2 Ising supedattice, which consist of three different ferromagnet materials. The magnetic behavior of this superlattice is examined. The critical temperature and the compensation temprature of the system are studied as a function of the exchange interactions between the nearest-neiboring spins across the interface and in the intraface. Temperature dependence of magenetizations is also given.     

Super-sensitivity in Dynamics of Ising Model with Transverse Field: From Perspective of Franck-Condon Principle

We study the role of Franck-Condon (F-C) principle in the dynamics of a central spin system, which is coupled to an Ising chain in transverse field. The transition process of energy levels caused by the excited central spin is studied to manifest the quantum critical effect through the Franck-Condon principle. The super-sensitivity of this quantum critical system is demonstrated clearly from the properties of Franck-Condon factors. We analytically show how spin numbers, coupling strength and order parameter of the Ising chain sensitively effect on the energy level populations in dynamical evolution near the critical point. This super-sensitivity and criticality are explicitly displayed in absorption spectrum.     

Critical Behavior of Spatial Evolutionary Game with Altruistic to Spiteful Preferences on Two-Dimensional Lattices

Self-questioning mechanism which is similar to single spin-flip of Ising model in statistical physics is introduced into spatial evolutionary game model. We propose a game model with altruistic to spiteful preferences via weighted sums of own and opponent's payoffs. This game model can be transformed into Ising model with an external field. Both interaction between spins and the external field are determined by the elements of payoff matrix and the preference parameter. In the case of perfect rationality at zero social temperature, this game model has three different phases which are entirely cooperative phase, entirely non-cooperative phase and mixed phase. In the investigations of the game model with Monte Carlo simulation, two paths of payoff and preference parameters are taken. In one path, the system undergoes a discontinuous transition from cooperative phase to non-cooperative phase with the change of preference parameter. In another path, two continuous transitions appear one after another when system changes from cooperative phase to non-cooperative phase with the prefenrence parameter. The critical exponents ν, β, and γ of two continuous phase transitions are estimated by the finite-size scaling analysis. Both continuous phase transitions have the same critical exponents and they belong to the same universality class as the two-dimensional Ising model.     

Surface order large deviations of phase interfaces for the continuum Widom-Rowlinson model in high density limit

We establish a surface order large deviation principle characterising, in the phase coexistence region, the exponential decay rates for the probabilities of macroscopic fluctuations of phase-separating interfaces for the continuum Widom-Rowlinson binary gas, with the thermodynamic and high fugacity limits taken simultaneously. The large deviation rate function is given by an isotropic surface energy functional and hence it attains its minimum for balls which are the most favourable shapes of ‘droplets’ of dominated phase within the ‘ocean’ of dominating phase.     

A non-equilibrium Ising model of turbulence

We introduce a model of interacting lattices at different resolutions driven by the two-dimensional Ising dynamics with a nearest-neighbor interaction. We study this model both with tools borrowed from equilibrium statistical mechanics as well as non-equilibrium thermodynamics. Our findings show that this model keeps the signature of the equilibrium phase transition. The critical temperature of the equilibrium models corresponds to the state maximizing the entropy and delimits two out-of-equilibrium regimes, one satisfying the Onsager relations for systems close to equilibrium and one resembling convective turbulent states. Since the model preserves the entropy and energy fluxes in the scale space, it seems a good candidate for parametric studies of out-of-equilibrium turbulent systems.     

Phase transitions and relaxation characteristics of Quantum Magnets and Quantum Glasses

An overview is presented of the phase changes as well as certain relaxation characteristics of model quantum magnets, magnetic glasses and proton glasses. Although the systems considered are quite varied, they are connected by the common themes of tunneling, transverse Ising model, long-ranged interactions and above all, the occurrence of quantum phase transitions. Because the interactions are long-ranged, mean-field theory is eminently suitable for analyzing both the equilibrium and nonequilibrium properties. Wherever pertinent, detailed comparisons with experimental data have been presented.     

Phase Diagram of Transverse Spin-2 Ising Model with Longitudinal Crystal Field

The transverse spin-2 Ising ferromagnetic model with a longitudinal crystal field is studied within the mean-field theory. The phase diagrams and magnetization curves are obtained by diagonalizing the Hamiltonian Hi of the Ising system numerically, and the first order-order phase transitions, the first order-disorder phase transitions, and the second-order phase transitions are discussed in details. Reentrant phenomena occur when the value of the transverse field is not zero and the reentrant diagram is given.     

Applications of the Yang-Lee-Ruelle theory to hard-core lattice gases

The grand-partition-function-zero method is applied to lattice systems of rigid molecules, based on the algebraic technique of Ruelle. Consideration of small collections of lattice molecules, through this approach, provides rigorous delineation of regions of the complex activity plane which are free of zeros of the grand partition function, and hence free of thermodynamic singularities. Two conjectures, as yet unproved, are offered, which greatly reduce the computational effort required in using the technique. A simple proof is provided for the absence of physical phase transitions in monomerdimer systems, and bounds are obtained on the locations of the transitions of other lattice gases.Research supported in part by National Science Foundation Grant GP-17026.