Palladium-like XeIX-CeXIII spectra: Effective interaction and radiative constants

A semiempirical least squares method is used to determine the wave functions for the intermediate coupling between the 4d ⁹5s, 4d ⁹5p, and 4d ⁹5d levels in the XeIX-CeXIII spectra and to calculate the radiative lifetimes of the 4d ⁹5p and 4d ⁹5d levels in these spectra.     

Configuration interaction and radiative constants in spectra of argon-like Sc IV-Fe IX ions

The probabilities of the 3p ⁵3d, 3p ⁵4s?3p ⁶, 3p ⁵4p, 3s3p ⁶3d electric dipole transitions and radiative lifetimes of the 3p ⁵3d, 3p ⁵4p, 3p ⁵4s, and 3s3p ⁶3d levels are calculated for the Sc IV–Fe IX isoelectronic sequence.     

Analysis of the spectrum of the Zn-like Kr VII ion: Highly excited 4<Emphasis Type="Italic">p</Emphasis>4<Emphasis Type="Italic">d</Emphasis> and 4<Emphasis Type="Italic">p</Emphasis>5<Emphasis Type="Italic">s</Emphasis> configurations

The spectrum of the Zn-like Kr VII ion, excited in a capillary discharge and recorded with a high resolution in the wavelength range of 300–1000 Å, was studied. Previously performed identification of the transitions from the levels of the 4s4f, 4s5s, 4s5p, and 4s5d configurations is confirmed and extended, and the energies of these levels are specified. The (4p ²+4s4d)?4p4d and (4p ²+4s5s)?4p5s transitions are identified for the first time, and the energies of all the levels of the 4p4d and 4p5s configurations are determined. The results of the analysis performed are confirmed by semiempirical calculations in terms of the Hartree-Fock method. These results are also shown to conform to the experimental data obtained for lighter ions of the Zn I isoelectronic sequence.     

Energy levels of ions of silver and rhodium isoelectronic sequences with <Emphasis Type="Italic">Z</Emphasis> < 86

The method of extrapolation of the parameter of a model potential for states of one electron (4f, 5s, 5p, 5d, 5f) above the core 1s ²2s ²2p ⁶3s ²3p ⁶3d ¹⁰4s ²4p ⁶4d ¹⁰ and one vacancy (4d ⁹) in the same core is applied to calculate the energy levels in the silver and rhodium isoelectronic sequences with the maximum nuclear charge Z = 86. The energy levels of Ag-and Rh-like ions were used for the calculation of the energies of resonance transitions to the ground state ¹ S ₀ in Pd-like ions. Good agreement between the theoretical and calculated energies of the resonance transitions in Pd-like ions indicates the reliability of the results obtained.     

Radiative transition probabilities in ions of the silver isoelectronic sequence

The wave functions of one-electron states above the 4d ¹⁰ core have been calculated within the relativistic perturbation theory with a zero-order model potential. The wavelengths and probabilities of electric dipole transitions in an Ag-like ion have been calculated for the 5s-5p, 5p-5d, 5d-5f, and 4f-5d transitions. The data obtained are compared with the results of calculations by the relativistic Hartree-Fock method and within the relativistic many-body perturbation theory. The theoretical results are compared with experimental data on the lifetimes of energy levels in Ag-like ions.     

VUV-luminescence and excitation spectra of the heavy trivalent rare-earth ions in fluoride matrices

VUV 4f ⁿ → 4f^n?15d transitions of Gd³⁺, Er³⁺, Tm³⁺, and Lu³⁺ in fluoride matrices have been analyzed with high-resolution luminescence and excitation spectroscopy. In trifluorides, strong electron-phonon coupling has been found. In the other matrices, the luminescence spectra clearly yield zero-phonon lines and phonon replica, indicating intermediate coupling. The energies of the zero-phonon lines observed are compared with theoretical predictions. Near the threshold of f → d excitations, some of the excitation spectra yield sharp structures which cannot be explained with phonon replica but will be discussed in terms of the energy levels of the 4f^n?15d configuration.     

The probabilities of radiative transitions and lifetimes of levels in the spectra of Cu XX,La IV

The probabilities of radiative electric dipole transitions 2p ⁵3p, 2p ⁶–2p ⁵3s, and 2p ⁵3d in the spectrum of neon-like copper Cu XX and 5p ⁵6p, 5p ⁶–5p ⁵6s, 5p ⁵7s, and 5p ⁵5d in the spectrum of xenon-like lanthanum La IV are calculated. The wave functions of the intermediate coupling were found from the wellknown experimental energy levels by the least-squares method (LSM). To transfer to an absolute scale the radial integrals for the transitions calculated in the form of a length on the Hartree–Fock functions have been used. By summing the calculated probabilities of the transitions, the lifetimes of the levels of configurations 2p ⁵3s, 2p ⁵3p, and 2p ⁵3d in the spectrum of Cu XX and levels of configurations 5p ⁵6s, 5p ⁵6p, and 5p ⁵7s in the spectrum of La IV have been obtained.     

Measurement of isotope shifts of gadolinium levels by laser-induced fluorescence spectroscopy

The results of isotope shift measurements for the gadolinium atom both in a hollow cathode lamp and in an atomic beam are described. Using laser-induced fluorescence spectroscopy, the measurements were performed for four transitions, which are related to the configurations 4f⁷5d6s²⁹D to 4f⁷5d6s6p⁹D and 4f⁷5d6ss6p⁹FD.     

Hyperfeinstruktur-Untersuchungen im Rhenium-I-Spektrum

By optical means (i.e. hollow cathode, Fabry-Perot-interferometer and spectrograph) the hyperfine structure of 15 transitions in the Re-I spectrum was investigated. This permits to state the hfs coupling constantsA, B for 15 levels belonging to the configurations (5d ⁵) 6s ², (5d ⁵) 6s 6p, (5d ⁵) 6s 7s, (5d ⁶) 6s, (5d ⁶) 6p and (5d ⁴) 6s ² 6p. It was found that the (5d ⁵) 6s ^{2 6} S _5/2 ground state, too, shows a small hfs. Of its magnetic splitting both size and sign could be determined (A _0,185,187=?2,2±0,4 mK); for a possible quadrupole splitting upper limits were obtained. Estimates of the quadrupole moments resulted inQ _185,187?2,9b. — In the case of two levels (x ⁶ P _7/2 andy ⁶ F _11/2) the hfs analysis raises doubts as to their classification.     

Excitation of even levels of erbium atoms without a change in the number of 4<Emphasis Type="Italic">f</Emphasis> electrons

The excitation of even levels of erbium atoms by slow electrons that occurs without a change in the number of electrons in the 4f shell is experimentally studied. The levels investigated belong to the 4f ¹²6s7s, 4f ¹²5d6s, 4f ¹²6s6d configurations. The cross sections measured at an electron energy of 30 eV lie within the range (0.2–18) × 10^?18 cm².     

Highly excited and autoionizing states in the spectrum of triply ionized titanium Ti(IV)

The spectrum of Ti(IV) excited in a vacuum spark was investigated in the range 250–900 Å with high resolution. Eighty-four lines were measured and identified as transitions from the 3p⁶ns, 3p⁶np, and 3p⁶nf configurations, where n ≤ 8, ≤ 10, and ≤ 8, respectively, and from the 3p⁵3d² and 3p⁵3d⁴s configurations. The lines due to the transitions from the autoionizing levels of the 3p⁵3d² and 3p⁵3d⁴s configurations were also observed and their widths were measured. The experimental data were compared with the results obtained by calculations using the Hartree-Fock method and semiempirical calculations.     

Manifestation of the Coster-Kronig effect in the near-threshold electron-impact excitation of the Cd<Superscript>+</Superscript> ion

The near-threshold portions of the energy dependences of the effective excitation cross sections of the resonance transition 4d¹⁰5p²P_1/2° → 4d¹⁰5s²S_1/2 and the two-electron forbidden transition 4d⁹5s²²D_5/2 → 4d¹⁰5p²P_3/2° in the spectrum of the Cd⁺ ion were investigated by the spectroscopic method in crossed electron and ion beams. In the region of energy splitting of the ²P° and ²D levels, a significant resonance contribution of the autoionizing states of cadmium (decaying during the Coster-Kronig process) to the effective excitation cross sections of the noted transitions was revealed for the first time. It is found that the resonance contribution manifests itself much more strongly for the forbidden transition in comparison with the more intense resonance transition; i.e., the manifestation of the Coster-Kronig effect in the electron excitation of ions depends strongly on the cross section of the direct process. It is ascertained that, during the Coster-Kronig process, the main contribution to the resonance excitation of both the resonance and the two-electron forbidden spectral transitions is from the low-lying terms of the series of autoionizing states 4d¹⁰5p(²P_3/2°)ns, md and 4d⁹(²D_3/2)5s²ns, md, which are in the splitting region of the ²P_{1/2, 3/2}° and ²D_{5/2, 3/2} levels, rather than from the high-lying atomic autoionizing states of cadmium, which are located near the ionization limits (corresponding to the and ²P_3/2° and ²D_3/2 levels).     

Effect of spin crossovers on the Mott-Hubbard transition at high pressures

The effect of spin crossovers in d _n terms on the effective Hubbard parameter (U _eff) determining the gap between the lower and upper Hubbard bands is analyzed using a many-electron approach to describe the electron structure of Mott insulators. A new mechanism of the insulator-metal transition is established for d ⁵ ions, which is related to a decrease in U _eff caused by spin crossover. For other ions, the U _eff value is either independent of pressure (d ², d ⁴, d ⁷) or it exhibits nonmonotonic growth (d ³, d ⁶, d ⁸).     

Theory of the muonic hydrogen-muonic deuterium isotope shift

Corrections of the α³, α⁴, and α⁵ orders are calculated for the Lamb shift of the 1S and 2S energy levels of muonic hydrogen μp and muonic deuterium μd. The nuclear structure effects are taken into account in terms of the charge radii of the proton r _p and deuteron r _d for one-photon interaction, as well as in terms of the electromagnetic form factors of the proton and deuteron for the case of one-loop amplitudes. The μd-μp isotope shift for the 1S-2S splitting is found to be equal to 101003.3495 meV, which can be treated as a reliable estimate when conducting the corresponding experiment with an accuracy of 10^?6. The fine-structure intervals E(1S)-8E(2S) in muonic hydrogen and muonic deuteron are calculated.     

Observation of high efficiency of Raman scattering in the process of the three-photon ionization of samarium atom

Very high efficiency of Raman scattering on samarium atoms in the process of three-photon ionization has been detected. An intense maximum attributed to the one-photon transition 4f ⁶5d6s ⁹ H ₂ → 4f ⁵5d6s ^{2 7} D ₃° between two excited states is observed in the dependence of the yield of Sm⁺ ions on the laser-radiation frequency. The 4f ⁶5d6s ⁹ H ₂ state is populated owing to the spontaneous Raman scattering 4f ⁶6s ^{2 7} F ₃ + ω ? ν → 4f ⁶5d6s ⁹ H ₂.     

Spontaneous Raman scattering upon resonant three-photon ionization of a samarium atom

The manifestation of spontaneous Raman scattering upon the three-photon ionization of a samarium atom has been investigated. The dependence of the Sm⁺ yield on the laser frequency, along with the peaks due to the two-photon excitation of bound states from different levels of the 4f ⁶6s ^{2 7} F ground term, exhibits a strong peak due to single-photon excitation of the 4f ⁵5d6s ^{2 7} D°₃ state from the 4f ⁶5d6s ⁹ H ₂ excited state. The 4f ⁶5d6s ⁹ H ₂ state was populated as a result of spontaneous Raman scattering. The large amplitude of the observed peak indicates a high efficiency of this process. The estimations performed indicate that the probability of resonant ionization through an excited state populated due to spontaneous Raman scattering can be comparable with the probability of three-photon ionization through the two-photon intermediate resonance. The necessary conditions for implementing this channel of resonant three-photon ionization are formulated.     

4<Emphasis Type="Italic">p</Emphasis><Superscript>5</Superscript>4<Emphasis Type="Italic">d</Emphasis><Superscript>2</Superscript> configuration in the spectra of rubidium-like Ru VIII and Rh IX ions

The spectra of ruthenium and rhodium excited in a low-inductive vacuum spark have been obtained using a vacuum grazing-incidence spectrograph with a grating of 3600 lines/mm 3 m in radius in the range of 180–350 Å. The bidium-like spectra of Ru VIII and Rh IX were analyzed. Ten spectral lines of the 4p ⁶4d-4p ⁵4d ² transitions are identified and six energy levels in the 4p ⁵4d ² configuration with an excited internal electron were found for each ion for the first time.     

Radiative lifetimes of the levels in the Ba III spectrum

The radiative lifetimes of the 5p ⁵ (6s+5d), 5p ⁵ (6p+4f), and 5p ⁵5f levels in the spectrum of the Ba III ion are calculated. The wave functions of the intermediate coupling are found from the experimental energy levels by the method of least squares. The radial transition integrals are calculated by the Hartree-Fock method.     

Spectrum of calcium-like copper Cu X

A copper spectrum has been excited in a vacuum spark and recorded in the range from 80 to 200 Å on high-resolution vacuum spectrographs. The 3d ²?(3d4p + 3d4f + 4p ⁵4d ³) transitions in the spectrum of ninetimes ionized copper (Cu X) have been investigated. Atomic calculations by the Hartree-Fock method with semiempirical correction made it possible to identify 64 new spectral lines. The energies of the corresponding levels are determined.     

Calculation of Spectra of Neutrons and Charged Particles Produced in a Target of a Neutron Generator

An algorithm for calculating the spectra of neutrons and associated charged particles produced in the target of a neutron generator is detailed. The products of four nuclear reactions ³H(d,n)⁴He, ²H(d,n)³He, ²H(d,p)³H, and ³He(d,p)⁴He are analyzed. The results of calculations are presented in the form of neutron spectra for several emission angles and spectra of associated charged particles emitted at an angle of 180° for a deuteron initial energy of 0.13 MeV.