共查询到20条相似文献,搜索用时 15 毫秒
1.
Bharat P. Kapgate Chayan Das Amit Das Debdipta Basu Uta Reuter Gert Heinrich 《Journal of Sol-Gel Science and Technology》2012,63(3):501-509
Silica particles were generated and grown in situ by sol–gel method into rubber blends comprised of natural rubber (NR) and acrylonitrile butadiene rubber (NBR) at various blend ratios. Silica formed into rubber matrix was amorphous in nature. Amount of in situ silica increased with increase in natural rubber proportion in the blends during the sol–gel process. Morphology studies showed that the generated in situ silica were nanoparticles of different shapes and sizes mostly grown into the NR phase of the blends. In situ silica filled NR/NBR blend composites showed improvement in the mechanical and dynamic mechanical behaviors in comparison to those of the unfilled and externally filled NR/NBR blend composites. For the NR/NBR blend at 40/60 composition, in particular, the improvement was appreciable where size and dispersion of the silica particles into the rubber matrix were found to be more uniform. Dynamic mechanical analysis revealed a strong rubber–in situ silica interaction as indicated by a positive shift of the glass transition temperature of both the rubber phases in the blends. 相似文献
2.
Silica packed epoxy networks are prepared in two steps via in situ, solvent free sol–gel processing of tetraethoxysilane in
liquid epoxy monomer and curing the mixture with a flexible diamine afterwards. The influence of filler content and processing
conditions on the mechanical properties and the fracture behavior is studied by means of the static mechanical analysis and
AFM characterization of the pristine and the fractured polymer surfaces, and a mechanism to enhance polymer strength and toughness
is proposed. The in–situ evolution and packing of silica nanostructures into epoxy networks influences the overall morphology
and performance of polymers under high stress. It is found that smaller silica domains distributed at the molecular level
cause efficient crack distribution by absorbing energy and thus improve the strength and toughness of silica packed epoxy
polymers. 相似文献
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Betul Akkopru Akgun Nathan P. Mellott Caner Durucan 《Journal of Sol-Gel Science and Technology》2012,62(2):240-251
Silver containing silica (Ag–SiO2) thin films with and without aluminum (Al) were prepared on soda-lime-silica glass by spin coating of aqueous sols. The coating
sol was formed through mixing tetraethyl orthosilicate [Si(OC2H5)4]/ethanol solution with aqueous silver nitrate (AgNO3) and aluminum nitrate nonahydrate [(AlNO3)3·9H2O] solutions. The deposited films were calcined in air at 100, 300 and 500 °C for 2 h and characterized using x-ray diffraction,
UV-visible and x-ray photoelectron spectroscopy. The effect of Al incorporation and calcination treatment on microstructure
and durability of the films, and chemical/physical state of silver in the silica thin film have been reported. The bactericidal
activity of the films was also determined against Staphylococcus aureus via disk diffusion assay studies before and after chemical durability tests. The investigations revealed that the optical,
bactericidal properties and chemical durability of Ag–SiO2 films can be improved by Al addition. The Al-modified Ag–SiO2 thin films do not exhibit any coloring after calcination in the range of 100–500 °C, illustrating that silver is incorporated
within the silica gel network in ionic form (Ag+). Al incorporation also improved the overall durability and antibacterial endurance of Ag–SiO2 thin films. 相似文献
5.
A comparative study on the physical and optical properties of silica nanoparticles prepared by sol–gel has been carried out.
Post-modification of as-synthesized silica nanoparticles produced organo-functionalized silica nanoparticles slightly increased
in size (~20%) and relatively high aggregation. However, in situ method produced sixfold bigger functionalized particles with
good dispersion and less aggregation. Higher organic content was observed for in situ modified nanosilica, leading to a higher
surface hydrophobicity that improved compatibility and dispersion in preparation of silica-polymer nanocomposite. Furthermore,
in situ and post-modified nanosilica demonstrated a distinct optical activity, photoluminescence and UV compared to the unmodified
nanoparticles. 相似文献
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One-pot synthesis of organo-silica hybrids with high thermal properties via a simple sol–gel process
Javanbakht Fatemeh Razavi Bahareh Salami-Kalajahi Mehdi Roghani-Mamaqani Hossein Ommati Masoud 《Journal of Thermal Analysis and Calorimetry》2020,140(5):2267-2274
Journal of Thermal Analysis and Calorimetry - Organic–inorganic hybrid composites have received much attention of scientists in the recent years due to the notable improvement of thermal... 相似文献
8.
Tin oxide (SnO2) nanoparticles were synthesized by the reaction of SnCl4·5H2O in methanol, ethanol and water via sol–gel method. The samples were characterized by X-ray diffraction (XRD), Fourier transform
infrared, Scanning electron microscopy and Transmission electron microscopy. The optical properties of the as-prepared samples
were investigated. The XRD analysis showed well crystallized tetragonal SnO2 can be obtained and the crystal sizes were 3.9, 4.5 and 5 nm for the sample calcined at 400 °C for 2 h. It was found that
solvents played important roles in the particle size effect of nanocrystalline SnO2. 相似文献
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Chunming Lin Yanhua Song Fei Gao Hongguang Zhang Ye Sheng Keyan Zheng Zhan Shi Xuechun Xu Haifeng Zou 《Journal of Sol-Gel Science and Technology》2014,69(3):536-543
Uniform Eu3+-doped SiO2 nanorods were synthesized through a simple sol–gel method using cetyltrimethylammonium bromide (CTAB) as surfactant template and tetraethylorthosilicate as silicon source. X-ray diffraction, energy-dispersive X-ray spectroscopy, Fourier transform infrared spectrum, scanning electron microscope (SEM), transmission electron microscopy, and photoluminescence spectra were employed to characterize the products in detail. The nanorods have good uniformity and their diameters and lengths are in the range of 200–300 and 500–700 nm through the SEM images, respectively. The formation of the nanorods was studied by taking SEM images after different aging time. The experimental results indicate that CTAB plays a crucial role in the formation of the silica nanorods. The luminescence of Eu3+-doped SiO2 nanorods is dominated by red-emission around 612 nm due to intra-atomic 4f → 4f (5D0 → 7F2) transition of Eu3+ ions. Furthermore, the effect of doping concentrations of Eu3+ ions on the luminescence was investigated. 相似文献
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Perullini Mercedes Jobbágy Matías Bilmes Sara A. Torriani Iris L. Candal Roberto 《Journal of Sol-Gel Science and Technology》2011,59(1):174-180
Silica matrices synthesized from a pre-hydrolysis step in ethanol followed by alcohol removal at low pressure distillation,
and condensation in water, are suitable for encapsulation of biomolecules and microorganisms and building bioactive materials
with optimized optical properties. Here we analyze the microstructure of these hydrogels from the dependence of I(q) data acquired from SAXS experiments over a wide range of silica concentration and pH employed in the condensation step. From
the resulting data it is shown that there is a clear correlation between the microscopic parameters—cluster fractal dimension
(D), elementary particle radius (a) and cluster gyration radius (R)—with the attenuation of visible light when the condensation step proceeds at pH < 6. At higher pHs, there is a steep dependence
of the cluster density (~R
D−3) with the condensation pH, and non-monotonous changes of attenuance are less than 20%, revealing the complexity of the system.
These results, which were obtained for a wide pH and silica concentration range, reinforce the idea that the behavior of gels
determined in a restricted interval of synthesis variables cannot be extrapolated, and comparison of gelation times is not
enough for predicting their properties. 相似文献
13.
Aparna V. Deshpande Jayraj R. Rane Laxman V. Jathar 《Journal of Sol-Gel Science and Technology》2009,49(3):268-276
Glass samples are prepared with different amount of glycerol as drying control chemical additive (DCCA) via acid catalysed
sol–gel method. These samples are given solvent treatment namely rinse and dip with methanol while drying of the sample. In
rinse treatment solid sample is rinsed with small amount of methanol while in dip treatment sample is dipped for 5 h in methanol.
Comparative studies of these treated samples containing varied DCCA concentration are carried out by measuring optical transmission,
mechanical strength and bulk density. Various instrumental techniques used for analysis are FTIR, DTA-TGA, XRD, SEM and TEM.
The untreated samples take long time to dry up and to come out of the cuvette and show very less transmission in UV region
which is much enhanced by solvent treatment. On the basis of this study, the solvent treated glass samples with DCCA amount
8 ml in the composition used are found to have the maximum UV transmission, good mechanical strength and may be useful as
silica gel host matrices for solid state dye lasers and other applications. The UV transmission reported in the present studies
is 90% in 337 nm region, which is the wavelength of N2 laser pumping. 相似文献
14.
Nataly Carolina Rosero-Navarro Pawel Figiel Roman Jedrzejewski Anna Biedunkiewicz Yolanda Castro Mario Aparicio Sergio Antonio Pellice Alicia Durán 《Journal of Sol-Gel Science and Technology》2010,54(3):301-311
The aim of this work was to study the effect of the incorporation of cerium nitrate in a silica-methacrylate sol–gel hybrid
matrix reinforced with silica nanoparticles. Sols, coatings and powders have been studied, focusing specially in the determination
of the redox ratio Ce3+/Ce4+ and films structure. Sols have been characterised using viscosity measurements and FT-IR spectroscopy, and powders and coatings
obtained with different Ce contents through UV–Vis and FT-IR spectroscopy, TGA, TEM, AFM and FE-SEM. The goal was to reach
the best compromise between maximum cerium concentration and coating stability to better understand the mechanisms acting
in active anti-corrosive processes. 相似文献
15.
M. Jafarzadeh I. A. Rahman C. S. Sipaut 《Journal of Sol-Gel Science and Technology》2009,50(3):328-336
A modified preparation of silica nanoparticles via sol–gel process was described. The ability to control the particle size
and distribution was found highly dependent on mixing modes of the reactants and drying techniques. The mixture of tetraethoxysilane
and ethanol followed by addition of water (Mode-A) produced monodispersed powder with an average particle size of 10.6 ± 1.40 nm
with a narrow size distribution. The freeze drying technique (FD) further improved the quality of powder. In addition, the
freeze dried samples have shown unique TGA decomposition steps which might be related to the well-defined structure of silica
nanoparticles as compared to the heat dried samples. DSC analysis showed that FD preserved the silica surface with low shrinkage
and generated remarkably well-order, narrow and bigger pore size and pore volume and also large endothermic enthalpies (ΔH
FD = −688 J g−1 vs. ΔH
HD = −617 J g−1) that lead to easy escape of physically adsorbed water from the pore at lower temperature. 相似文献
16.
Cristina Lavinia Nistor Dan Donescu Alain Perichaud Wael Ballout Marius Ghiurea 《Journal of Sol-Gel Science and Technology》2011,57(2):164-171
The sol–gel synthesis strategies combined with the templated growth of organic–inorganic hybrid networks provide access to
an immense new area of innovative multi-functional advanced materials. One possible way to prepare such new advanced materials
is to encapsulate liquid active agents (such as monomers, dyes, catalysts and hardeners) in microcapsules. Silica microcapsules
of tetraethylortosilicate (TEOS) and 3-(trimethoxysilyl)propyl methacrylate (MPTS) were prepared in a precursor-monomer/NH4OH water microemulsion system. Trimethylolpropane triacrylate (TMPTA)—a trifunctional monomer useful in manufacturing of coatings,
inks and adhesives—and a corresponding photoinitiator (DAROCUR 1173) were entrapped inside the obtained microcapsules. MPTS
was used to increase compatibility between TMPTA and the sol–gel precursors. As stability agent we added a “home made” product
resulted from functionalization of poly (ethylene glycol) methyl ether (MPEG) with (3-isocyanatopropyl) triethoxysilane (NCOTEOS).
Were obtained microcapsules containing incorporated monomer and having average particle size in range of 0.5–50 μm. Thermal
analysis, morphology study and the increase of the silica microcapsules average diameter, measured by DLS technique confirm
the monomer encapsulation. 相似文献
17.
Jieyang Huang Peng Zhang Xu Wang Longbo Luo Jie Gao Chaorong Peng Xiangyang Liu 《Journal of Sol-Gel Science and Technology》2013,66(2):193-198
Crystalline silica in cristobalite phase was successfully prepared at a relatively low temperature of 800 °C by calcinating polyimide/silica hybrid films under ambient air. X-ray photoelectron spectroscopy measurements show that the product is silica after calcination. It is found that the crystallinity is dependent on the removing rate and the strength of the interaction between polyimide and silica. The presence of polyimide plays an important role in the growth of silica. Calcination to remove polyimide with rapid heating results in lower crystallinity compared with calcination with slow heating. For samples with the same content of silica, the crystallinity changes with the strength of the interaction between polyimide and silica molecules. 相似文献
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Kiyofumi Katagiri Jumpei Kamiya Kunihito Koumoto Kei Inumaru 《Journal of Sol-Gel Science and Technology》2012,63(3):366-372
A facile approach, based on polyelectrolyte-mediated electrostatic adsorption of a water-soluble titanium complex on colloidal templates and hydrothermal treatment, is presented for the formation of hollow titania (TiO2) and strontium titanate (SrTiO3) spheres. Monodispersed silica gel particles were prepared by the sol?Cgel method and adopted as core templates. Deposition of a water-soluble titanium complex, titanium (IV) bis(ammoniumlactato)dihydroxide (TALH), on the silica gel particles was carried out via the layer-by-layer assembly technique. Hollow spheres were successfully formed from the core?Cshell particles. The silica gel particles used as core templates dissolved during hydrothermal treatment because of the particles?? undeveloped siloxane network. In addition, the hydrothermal treatment induced crystallization of the hollow shells. Therefore, the hydrothermal treatment played two roles; removal of the silica templates and crystallization of the hollow shells. When deionized water was used, hollow TiO2 spheres were obtained. Hollow SrTiO3 spheres could also be formed when an aqueous solution of Sr(OH)2 was used. The approach presented here could be exploited as a novel and sustainable approach for the fabrication of a range of different inorganic hollow spheres. 相似文献