强紫外激光在空气中长程传输受激旋转拉曼散射效应

 采用瞬态受激旋转拉曼散射（SRRS）模型，详细考虑了激光脉冲波形、介质的非线性极化、泵浦光的衰减、斯托克斯光的非线性放大以及拉曼线宽等诸多因素，对强紫外激光束在空气中长程传输过程产生的SRRS效应进行了研究。讨论了产生SRRS效应的阈值条件，详细分析了SRRS效应对激光光束质量的影响。     

Efficient rotational Raman conversion of XeCl laser radiation in H2

2 is investigated with a XeCl laser. It is shown that energy conversion to rotational Stokes radiation can be efficiently obtained by properly choosing the focusing geometry of pump radiation and the pressure of the Raman medium even at moderate pulse energies. Energy conversion to the first rotational Stokes at 313.8 nm with efficiencies as high as 38% is obtained with a circularly polarised XeCl pump beam of 10-mJ energy focused in 30 bar of H₂. The spectral and optical characteristics of the pump and the rotational Stokes radiation are analysed. Received: 29 May 1996/Revised version: 7 March 1997     

位相畸变对强紫外激光在空气中长程传输的影响

 采用瞬态受激旋转拉曼散射（SRRS）模型,详细考虑了激光脉冲的位相变化、时间波形、泵浦光的衰减、斯托克斯光的非线性放大以及初始的随机斯托克斯散射场等诸多因素,研究了空间位相畸变对空气中长程传输过程中产生的SRRS效应的影响。研究结果表明：位相畸变对阈值条件和时间特性影响较小,而对光束质量影响较为明显;随着位相畸变的增大,光束的能量分布变得极不均匀,光束的光强对比度也明显变大,从而使激光光束质量变差,而且当传输距离达到阈值条件后,随着传输距离的增加,光束质量将进一步变差。     

受激旋转拉曼散射效应对基频光光束质量的影响

 采用瞬态受激旋转拉曼散射(SRRS)和空间相位扰动模型，定量分析了泵浦光强度和脉冲宽度对基频光在空气长程传输过程中产生的SRRS效应的阈值距离和转换效率的影响，讨论了泵浦光空间相位畸变对长程传输后的基频光光束质量的影响。研究结果表明：SRRS效应的阈值距离随着泵浦光强度和脉宽的增大而变短；空间相位畸变对斯托克斯光和泵浦光的光强分布存在一定影响，对斯托克斯光相位分布的影响比对泵浦光相位的影响大；SRRS效应的存在将导致基频光光束质量明显变差，对谐波转换效率产生明显影响。     

受激旋转拉曼散射对强紫外激光相位的影响

 利用瞬态受激旋转拉曼散射（SRRS）模型及相位畸变模型，对具有空间相位畸变的强紫外激光束在空气中长程传输的SRRS效应进行了研究。详细讨论了低频和中高频空间相位畸变对SRRS阈值条件、斯托克斯光转换效率、剩余泵浦光和斯托克斯光相位的影响。研究结果表明，泵浦光的初始相位畸变对斯托克斯光相位畸变的影响较剩余泵浦光的更为明显；高频相位畸变对转换效率影响较低频相位畸变更大； SRRS效应阈值随低频相位畸变的增大而减小，随高频相位畸变的增大而增大。     

Intracavity Raman conversion for 16-μm Stokes pulse generation in para-hydrogen

16-μm Stokes pulses were directly generated for the first time to our knowledge by an intracavity configuration for the para-hydrogen Raman laser. We have analyzed Stokes field growth using a focused gain model and designed a pump/Stokes cavity to satisfy CO₂ pump power and pulse duration requirements for Raman oscillation. The CO₂ laser oscillation with circular polarization was realized by seeding externally circularly polarized CO₂ radiation. An output energy of 2.4 mJ was obtained with the output coupler of 0.5% transmittance, which indicated that 420 mJ of Stokes pulse energy was stored inside the cavity. This suggests that a much higher energy can be extracted by the optimization of cavity parameters. Received: 18 November 1998 / Published online: 26 May 1999     

Effect of buffer gas on the generation of eye-safe 1.54 μm radiation using the stimulated Raman scattering technique in CH4

Experimental results on the generation of 1.54 μm eye-safe radiation in pure CH₄, CH₄:He and CH₄:Ar mixtures pumped by the fundamental of an Nd:YAG laser, using the stimulated Raman scattering (SRS) technique, are described. A decrease in the energy conversion efficiency and degradation in the beam quality of S₁ was observed in pure CH₄ at high pump energies. This problem was overcome in CH₄:He and CH₄:Ar mixtures. Compared with the first Stokes (1.54 μm) energy conversion efficiency in pure CH₄, at a pump energy of 126 mJ, an enhancement of 50% in energy conversion efficiency was observed in the CH₄:Ar mixture (60% argon concentration) and as much as 100% in the CH₄:He mixture (60% helium concentration). The use of these buffer gas mixtures improved the spatial beam quality of the Stokes radiation considerably and also resulted in raising the pump threshold for optical breakdown of the Raman gain medium.     

Effect of buffer gas on the generation of eye-safe 1.54 μm radiation using the stimulated Raman scattering technique in CH4

Experimental results on the generation of 1.54 μm eye-safe radiation in pure CH₄, CH₄:He and CH₄:Ar mixtures pumped by the fundamental of an Nd:YAG laser, using the stimulated Raman scattering (SRS) technique, are described. A decrease in the energy conversion efficiency and degradation in the beam quality of S₁ was observed in pure CH₄ at high pump energies. This problem was overcome in CH₄:He and CH₄:Ar mixtures. Compared with the first Stokes (1.54 μm) energy conversion efficiency in pure CH₄, at a pump energy of 126 mJ, an enhancement of 50% in energy conversion efficiency was observed in the CH₄:Ar mixture (60% argon concentration) and as much as 100% in the CH₄:He mixture (60% helium concentration). The use of these buffer gas mixtures improved the spatial beam quality of the Stokes radiation considerably and also resulted in raising the pump threshold for optical breakdown of the Raman gain medium.     

Ultrahigh efficiency laser wavelength conversion in a gas-filled hollow core photonic crystal fiber by pure stimulated rotational Raman scattering in molecular hydrogen

We report on the generation of pure rotational stimulated Raman scattering in a hydrogen gas hollow-core photonic crystal fiber. Using the special properties of this low-loss fiber, the normally dominant vibrational stimulated Raman scattering is suppressed, permitting pure conversion to the rotational Stokes frequency in a single-pass configuration pumped by a microchip laser. We report 92% quantum conversion efficiency (40 nJ pulses in 2.9 m fiber) and threshold energies (3 nJ in 35 m) more than 1 x 10(6) times lower than previously reported. The control of the output spectral components by varying only the pump polarization is also shown. The results point to a new generation of highly engineerable and compact laser sources.     

真空度对强紫外激光在空气中长程传输的影响

 采用瞬态受激旋转拉曼散射(SRRS)模型，并充分考虑非线性介质分子密度、增益系数、泵浦光的衰减、斯托克斯光的非线性放大以及初始的随机斯托克斯散射场等因素，研究了空气真空度对强紫外激光在空气长程传输过程中产生的SRRS效应的影响。结果表明，真空度对SRRS效应的阈值传输距离和Stokes光的转换效率的影响较大，随着真空度的提高，Stokes光的转换效率将降低，产生SRRS效应的阈值传输距离将增大。因此，在实际工作中，可以采用真空度较高的激光传输环境来抑制SRRS效应的产生，以减小入射泵浦光能量的衰减并提高光束质量。     

The stimulated Raman scattering competition between solute and solvent in Rhodamine B solution

The competition between the stimulated resonance Raman scattering (SRRS) of Rhodamine B (RhB) and the stimulated Raman scattering (SRS) of ethanol (C₂H₅OH) is observed at the RhB in C₂H₅OH solution. For different concentrations of the solution, the peak wavelengths of the SRRS, the amplified spontaneous emission (ASE), the fluorescence and the absorption of RhB are different. The SRRS of RhB and the SRS of C₂H₅OH are simultaneously generated when the concentration of the solution is 10^-5 mol/L and the energy of the excitation laser is 20.4 mJ. Otherwise, only either the SRRS of RhB or the SRS of C₂H₅OH is generated. The SRRS can be amplified by the ASE gain when the SRRS is near the peak of the ASE, and the peak wavelength of the SRRS coincides with the wavelength of the maximal intensity ASE.     

Stimulated resonance Raman scattering of Rhodamine B

Stimulated resonance Raman scattering (SRRS) of the Rhodamine B (RhB) in the methanol (CH₃OH) or ethanol (C₂H₅OH) solutions have been observed. SRRS from RhB can be distinguished from the amplified spontaneous emission (ASE) of RhB with increasing the input laser energy. When the RhB is dissolved in the methanol or ethanol (10^?3 mol/L), the RhB have the different peak wavelengths of SRRS, ASE, fluorescence and absorption, respectively. SRRS can be amplified by the ASE gain when the SRRS is near the peak of the ASE, and the peak wavelength of SRRS coincides with the maximal intensity wavelength of ASE.     

发散光长程空气传输受激转动拉曼散射效应

研究强激光长程空气传输受激转动拉曼散射(SRRS)效应,寻求抑制措施是高功率固体激光驱动器建造中需要解决的关键问题之一。采用数值模拟的方法研究了发散光长程空气传输SRRS效应的演化规律,通过几何近似理论推导了该效应有效建立时的强度距离乘积阈值和抑制判据。结果表明:发散光长程空气传输SRRS效应的建立速度小于平行光,二者阈值有理论关系;能够有效抑制SRRS效应的发散角设计判据由光束口径、激光强度及安全传输距离决定。     

Focusing effects in nonlinear resonant four-wave mixing (RFWM) MIR and FIR generation

Summary The influence of pump beam geometry in a NH₃ superradiant Raman FIR laser with RFWM generation of MIR emission has been analysed. We have observed that, in general, MIR radiation is emitted in a stimulated configuration, so pump and MIR beam overlap is basically important to exhibit an efficient RFWM. In particular, strong focusing, also in the presence of self-focusing, shows a lowering of the threshold of Raman FIR emission, as expected, plus a reduction of RFWM MIR emission. COMB-Arrich., CRE Frascati.     

Tunable infrared generation using the 6s−5d Raman transition in caesium vapour

Coherent infrared radiation tunable between 1.6 and 3.2 μm was generated with a pulsed dye laser by 6s−5d _5/2 stimulated electronic Raman scattering in caesium vapour. We describe a technique using thermal dissociation to reduce the density of caesium dimers in a heat-pipe oven, which produced a factor of 7 reduction in Raman threshold. The threshold displayed a marked dependence on pump bandwidth.     

Infrared stimulated Raman generation: Effects of gain focussing on threshold and tuning behaviour

It is shown that for generation of infrared radiation by stimulated Raman scattering, the diffraction spread of the Stokes wave can have a significant effect on the threshold. Compared with an analysis in which gain focussing is neglected, the threshold powers may be much higher with a corresponding reduction in tuning range. The design of a Raman oscillator is considerably influenced by these diffraction effects, and also it is found that the Stokes wave is subject to frequency-pulling which is dependent on the pump power.     

Relation of pump-beam quality and conversion efficiency in the Raman downward conversion

To investigate the full conversion of pump power to the Stokes waves in stimulated Raman scattering with a single-pass cell, unconverted pump energies have been analyzed in detail in relation to the first Stokes, second Stokes and first anti-Stokes energies. Adoption of a long focusing configuration with a high-pressure cell was found to be effective but insufficient to suppress the four-wave mixing effect, because a small amount of pump energy always remained undepleted. Comparison of the results using pump beams of various spectral and spatial mode characteristics from alexandrite and Nd:YAG lasers revealed that the spatial mode quality was the most critical parameter for full depletion of a pump pulse.     

Stimulated Raman scattering and spontaneous Raman solitons in ammonia

In this study we report the first observation of spontaneous Raman solitons in stimulated Raman scattering (SRS) by the gas NH₃. The scattered radiation is called Stokes radiation. Raman solitons are of considerable interest, because their existence can be explained by quantum-mechanical fluctuations of the electromagnetic field in vacuum. We have observed spontaneous Raman solitons in a forward SRS configuration for two different molecular transitions of NH₃, the laser emissions at 58 μm and 72.6 μm wavelength. These are optically pumped by 10 μm CO₂-laser pulses with a duration of 100 ns and an energy of 150 mJ. Spontaneous Raman solitons are short spikes in the pump pulse which occur during its depletion. Their origin is the rapid π phase change of the Stokes seed. In contrast to other laboratories we have used single-pass cells. Thus, we have succeeded in observing multiple spontaneous Raman solitons during one pump pulse. Previous experiments with multi-pass cells never showed multiple solitons. Since multiple spontaneous Raman solitons have already been reported in an earlier experiment with a single-pass cell filled with hydrogen at high pressure, we conclude that such multiple Raman solitons can be observed mainly in this type of gas cell. Subsequently, we have performed statistical measurements on the delay time and the height of the spontaneous Raman solitons in the depleted pump pulse for the 58 μm-NH₃ emission. We have compared these statistics with theory and equivalent experimental results of other laboratories. They are in good agreement with the assumption that quantum-mechanical fluctuations are the origin of spontaneous Raman solitons. The most recent theories postulate that the origin of the formation of spontaneous Raman solitons can be explained by the rapid π phase change of the Stokes seed as well as that of the laser or polarization wave. Therefore, we have determined the phase of the spontaneous Raman solitons relative to the depleted pump pulse. Although, such changes of sign of the relative phase have already been observed in an earlier SRS experiment with hydrogen at high pressure, we did not detect any in our experiment. Therefore, we conclude that in this experiment the π phase change occurs in the Stokes or polarization wave.     

Two-photon interaction of coherent radiation with a thin film of resonant atoms

The problem of the interaction of an ultrashort optical pulse and a thin film of resonant atoms under the conditions of two-photon absorption, third-harmonic generation, and the inverse effect of the latter on the pump pulse via Raman scattering is studied. The fact that the field acting on an atom differs from the macroscopic field in the film is also taken into consideration. It is shown that the polarization of the film undergoes dynamic relaxation even in the absence of irreversible relaxation, suppressing Rabi oscillations and establishing stationary values of the populations of the resonant energy levels and of the polarization of the film at the pump and the third-harmonic frequencies. Zh. éksp. Teor. Fiz. 115, 30–42 (January 1999)