Droplet velocity and acceleration measurements in dense sprays by laser flow tagging

The feasibility of liquid-phase velocity measurements in dense sprays by 2D laser-based flow tagging is demonstrated. Velocity measurements in dense sprays are difficult with conventional techniques because of the high number densities of droplets, the optical thickness of the medium, and multiple light-scattering effects. The present flow-tagging technique is based on phosphorescent tracer molecules, which are excited by a grid of pulsed ‘write’ laser beams. The motion of the tagged droplet groups can be observed by a CCD camera in this way. In addition, multiple consecutive velocity measurements are performed by ‘droplet-group tracking’. This yields the acceleration along the trajectory of individual groups of droplets in unsteady sprays. Received: 5 June 2000 / Revised version: 28 July 2000 / Published online: 6 September 2000     

Stereoscopic flow-tagging velocimetry

A laser-based method for measuring the three components of the velocity in a plane simultaneously and instantaneously without seed particles is presented. This is achieved by combining a laser flow-tagging technique with stereoscopic detection, in which the tagged flow is viewed from two different directions. A single CCD camera is employed for this purpose by using a new optical detection system. The flow tagging is performed by two consecutive laser pulses, i.e., “write” and “read” laser pulses. The write laser creates a grid of tracer molecules (NO) by inducing a photodissociation process. The three-dimensional motion of the tracer molecules is measured by a thick read laser sheet. Received: 22 July 1999 / Revised version: 5 August 1999 / Published online: 30 September 1999     

High repetition rate planar laser induced fluorescence of OH in a turbulent non-premixed flame

Received: 1 February 1999 / Revised version: 17 February 1999     

Simultaneous multiple-line Raman/Rayleigh/LIF measurements in combustion

It is demonstrated that multiple 1D Raman scattering, Rayleigh scattering, and laser-induced fluorescence (LIF) measurements can be performed simultaneously. This can be used for quasi-2D (or quasi-3D) single-shot measurements of multiple species and the temperature in turbulent reacting and non-reacting flows. The technique has the potential to yield more precise information than most competitive planar imaging approaches in combustion. For example, it can be used to overcome Raman/LIF interference problems in technical flames. This is achieved by a new optical set-up that makes use of an imaging spectrograph combined with fiber optics. Received: 13 October 1999 / Revised version: 26 November 1999 / Published online: 27 January 2000     

Heteroepitaxial growth of oxides on sapphire induced by laser radiation in the solid–liquid interface

2 O₃, Fe₂O₃ and MnO₂ on sapphire from an aqueous solutions of either CrO₃, FeCl₃, or KMnO₄, respectively, under laser irradiation of the interface sapphire/liquid. The interface is exposed through the sapphire substrate to the radiation of a copper vapor laser (wavelength of 510 nm). The etching of sapphire is accompanied by the deposition of oxide films, which are shown to grow epitaxially on the sapphire substrate, while the deposition of the polycrystalline oxide film occurs on a glass substrate under the same experimental conditions. Similarly, the epitaxial growth of cubic Fe₂O₃ and orthorhombic MnO₂ is observed, though their crystallographic structure is different from the hexagonal structure of sapphire. Received: 26 June 1997/Accepted: 7 July 1997     

Large scale correlations for energy injection mechanisms in swirling turbulent flows

We report an experimental study of large scale correlations in the power injected in turbulent swirling flows generated in the gap between two coaxial rotating disks. We measure the pressure fluctuations on the blades of one disk, as well as the pressure drop between the leading and the trailing edges of the rotating blades, i.e. the local drag force. Measurements at different positions on one blade and on two successive blades display a correlation length much larger than the ones usually expected in turbulent flows. The time lag for which the correlation between two points is maximum, strongly depends on the global flow configuration. These results help us to understand the statistical properties of the injected power fluctuations in turbulent swirling flows. Received 2 September 1999     

An analysis of the destabilizing curvature effects on the turbulent flow over a rotating cylinder

An analysis based on the available experimental data and second-order closures is made for a turbulent shear flow over a rotating cylinder in a quiescent fluid. The near-wall behaviour of the non-linear model for the pressure-strain correlation proposed by Speziale, Sarkar and Gatski [J. Fluid Mech. 245, 227 (1991)] is enlarged; and the methodology proposed by Lai and So [J. Fluid Mech. 221, 641 (1990)] is adopted to take into account the wall-effects. The radial profile of the curvature parameter, R_s, is examined in connection with the logarithmic law. It is shown that the log-layer is associated to the region where the mean velocity profile, V, is related to the power of the radial distance as Computations reveal that this region corresponds to the state with the most destabilizing curvature effects; which can be chararacterized by the minimum value of the parameter B _c =2R _s (1+2R _s ), and not that one of the parameter B=2R _s (1+2R _s )/(1+R _s )² firstly introduced by Bradshaw [J. Fluid Mech. 36, 171 (1969)] and extensively used to characterize the turbulence structure in curved flows. Received 9 December 1997     

Scaling of global momentum transport in Taylor-Couette and pipe flow

We interpret measurements of the Reynolds number dependence of the torque in Taylor-Couette flow by Lewis and Swinney [Phys. Rev. E 59, 5457 (1999)] and of the pressure drop in pipe flow by Smits and Zagarola [Phys. Fluids 10, 1045 (1998)] within the scaling theory of Grossmann and Lohse [J. Fluid Mech. 407, 27 (2000)], developed in the context of thermal convection. The main idea is to split the energy dissipation into contributions from a boundary layer and the turbulent bulk. This ansatz can account for the observed scaling in both cases if it is assumed that the internal wind velocity introduced through the rotational or pressure forcing is related to the external (imposed) velocity U, by with and for the Taylor-Couette (U inner cylinder velocity) and pipe flow (U mean flow velocity) case, respectively. In contrast to the Rayleigh-Bénard case the scaling exponents cannot (yet) be derived from the dynamical equations. Received 9 September 2000     

Ultraviolet and visible Raman spectroscopy characterization of diamond–like carbon film growth by pulsed laser deposition

Laser-induced removal of flash from heat sinks in integrated circuit (IC) packages has been studied. It is found that flash can be effectively removed from heat sinks in plastic IC packages by laser deflashing. An optical microscope, an α-step surface profiler and X-ray photoelectron spectroscopy are used to analyze the deflashing efficiency. Laser deflashing of IC packages is based on laser ablation of flash materials. With an increase of laser fluence, the ablation rate increases. The laser fluence is selected between the ablation threshold of flash materials and that of heat-sink materials. An acoustic wave is generated by laser ablation of flash materials. Acoustic wave detection is used to monitor the surface cleanness during laser deflashing and to determine the ablation threshold of flash materials. Received: 18 April 2001 / Accepted: 14 September 2001 / Published online: 17 October 2001     

Measurement of gas jet flow velocities using laser-induced electrostrictive gratings

We used time-resolved light scattering of cw probe laser radiation from laser-induced electrostrictive gratings for the determination of flow velocities in air at room temperature. Some possibilities of the technique have been experimentally demonstrated with submerged planar air jets in atmosphere, both for accumulated and single-shot measurements. The range of investigated flow velocities was 5–200 m/s. The method of data treatment and of the estimate of the experimental parameters is described. Received: 8 Febuary 2000 / Revised version: 2 May 2000 / Published online: 2 August 2000     

Tailored ablation processing of advanced biomedical hydroxyapatite by femtosecond laser pulses

The micromachining of hydroxyapatite (HAp) is highly important for orthopedics and dentistry, since human bone and teeth consist mainly of HAp. We demonstrate ultrashort Ti:sapphire laser ablation of HAp, using pulse-widths of 50 fs, 500 fs, and 2 ps at a wavelength of 820 nm and at 1 kpps. The crucial medical issue is to preserve the chemical properties of the machined (ablated) surface. If the chemical properties of HAp change, the human bone or tooth cannot re-grow after laser processing. Using X-ray photoelectron spectroscopy, we observe chemical properties of HAp ablated in air. The HAp is ablated at laser fluences of 3.2 J/cm² (6.4×10¹³ W/cm² at 50 fs), 3.3 J/cm² (6.6×10¹² W/cm² at 500 fs), and 9.6 J/cm² (4.8×10¹² W/cm² at 2 ps), respectively. As a result it is found that the ablated surface is unchanged after laser ablation over the pulse-width range used in this experiment. Received: 7 October 2002 / Accepted: 20 January 2003 / Published online: 28 May 2003 RID="*" ID="*"Corresponding author. Fax: +81-45/566-1533, E-mail: obara@obara.elec.keio.ac.jp     

Laser-diagnostic multi-species imaging in strongly swirling natural gas flames

Within the TECFLAM group a standard swirl burner is investigated, both experimentally using optical and probe measurements and by simulations using different modeling attempts. The present study is focused on the laser-based investigation of the NO distribution within the reacting flow field of a strongly swirling, confined 150-kW natural gas flame. Simultaneous quantitative measurements of NO- and OH-concentration fields by laser-induced fluorescence imaging (LIF) and temperature distribution (Rayleigh scattering) are performed. Mixing properties of the unburned gases are investigated for the isothermal and the combusting flow using tetrahydrothiophene (THT) as a new fluorescing tracer. These measurements show which areas are sufficiently mixed allowing for the application of planar Rayleigh thermometry. Areas where THT-LIF interferes with OH-LIF detection are localized and omitted from data evaluation. The data is analyzed yielding global scalar fields for comparison with model simulations and correlations between the different measured scalars are investigated showing an almost linear correlation of NO concentration and temperature within the swirl flame whereas no apparent correlation between NO and OH concentration was found. Received: 20 April 2000 / Revised version: 16 May 2000 / Published online: 20 September 2000     

Raman-Rayleigh-LIF measurements of temperature and species concentrations in the Delft piloted turbulent jet diffusion flame

We report a series of Raman-Rayleigh-LIF measurements in two turbulent natural-gas jet diffusion flames produced by the Delft piloted jet diffusion flame burner. The main objective of the Raman-Rayleigh-LIF measurements was to obtain detailed information on the major species concentrations in the flames. The measurements provide simultaneous data on temperature, the concentrations of the major species and the radicals OH and NO and mixture fraction. The application of the Raman technique in the undiluted natural-gas flames proves to be very challenging because of the high fluorescence interference levels. The interference contributions to the recorded Raman signals are identified and subtracted using empirical correlations between the Raman signals and the signals on fluorescence interference monitor channels. The calibration and data reduction of the Raman-Rayleigh and LIF signals are discussed in detail. The resulting dataset compares excellently with data from previous experiments. Because the Raman-Rayleigh-LIF data provide quantitative concentrations and accordingly quantitative mixture fractions, they form a valuable and useful extension of the existing database for the Delft piloted jet diffusion flame burner. Received: 19 October 1999 / Revised version: 31 January 2000 / Published online: 7 June 2000     

13CO2/12CO2 isotopic ratio measurements using a difference frequency-based sensor operating at 4.35 micrometers

A portable modular gas sensor for measuring the ¹³C/¹²C isotopic ratio in CO₂ with a precision of 0.8‰(±1σ) was developed for volcanic gas emission studies. This sensor employed a difference frequency generation (DFG)-based spectroscopic source operating at 4.35 μm (∼2300 cm^-1) in combination with a dual-chamber gas absorption cell. Direct absorption spectroscopy using this specially designed cell permitted rapid comparisons of isotopic ratios of a gas sample and a reference standard for appropriately selected CO₂ absorption lines. Special attention was given to minimizing undesirable precision degrading effects, in particular temperature and pressure fluctuations. Received: 16 April 2002 / Revised version: 28 May 2002 / Published online: 21 August 2002 RID="*" ID="*"Corresponding author. Fax: +1-713/5245237, E-mail: fkt@rice.edu     

Analytical Interaction of the Acoustic Wave and Turbulent Flame

A modified resonance model of a weakly turbulent flame in a high-frequency acoustic wave is derived analytically. Under the mechanism of Darrieus-Landau instability, the amplitude of flame wrinkles, which is as functions of the expansion coefficient and the perturbation wave number, increases greatly independent of the stationary＇ turbulence. The high perturbation wave number makes the resonance easier to be triggered but weakened with respect to the extra acoustic wave. In a closed burning chamber with the acoustic wave induced by the flame itself, the high perturbation wave number is to restrain the resonance for a realistic flame.     

Oxygen-distribution imaging with a novel two-tracer laser-induced fluorescence technique

We introduce a new technique for imaging oxygen concentrations in fuel/air mixtures that takes advantage of the different responses of toluene and 3-pentanone to collisional quenching by molecular oxygen. Since laser-induced fluorescence signals from both tracers upon excitation at 248 nm are spectrally well separated, simultaneous detection is possible. The technique is first applied to instantaneous imaging in turbulent mixing processes of interacting seeded air and nitrogen flows. Received: 1 August 2001 / Revised version: 29 October 2001 / Published online: 29 November 2001     

Mechanism of and method to avoid discoloration of stainless steel surfaces in laser cleaning

2 O₃. Based on Auger Electron Spectroscopy analyses and optical microscopic observations, γ-Fe₂O₃ and Fe₃O₄ are formed on the stainless steel surface in laser cleaning in the air. Since laser can induce high temperature rise in stainless steel surfaces, the above phenomenon can be explained by a thermochemical reaction between oxygen in the air and the stainless steel. With increasing laser fluences, the temperature rise in the irradiated area of stainless steel surface increases, which enhances oxygen diffusion into the surface and oxidation reaction within the irradiated area. In order to avoid discoloration of stainless steel surfaces, a vacuum system was used to reduce the oxidation reaction between oxygen and stainless steel. Received: 7 June 1996/Accepted: 30 September 1996     

Quantitative laser-induced fluorescence of CH in atmospheric pressure flames

Absolute number densities of the CH radical were determined in a partially premixed methane/air flame (equivalence ratio was 1.36) at atmospheric pressure by exciting a predissociating level via the CH B–X(1,0) transition using a quasi-linear laser-induced fluorescence scheme. The peak number density was (1.0±0.4)×10¹³ cm^-3 or 2.4±1 ppm at 1900 K, with a flame-front width of 250 μm (FWHM). Rotational energy transfer must be considered for correct laser-induced fluorescence signal interpretation. Competition between optical pumping and rotational relaxation in both excited and ground states produces a signal that varies almost linearly with laser pulse energy even for large pumping rates. For these conditions, the population of the initial ground-state rotational level is depleted by optical pumping, and rotational energy transfer collisions rapidly repopulate the level during the laser pulse. Deviations from linear behavior are less than 20%. The effects of spatial resolution and polarization of the fluorescence on the absolute measurements are also discussed. Received: 27 March 2002 / Revised version: 22 August 2002 / Published online: 15 November 2002 RID="*" ID="*"Present address: Lam Research Corporation, Fremont, CA 94538, USA RID="**" ID="**"Present address: Mechanical Engineering, Eindhoven University of Technology, 5600 MB Eindhoven, The Netherlands RID="***" ID="***"Present address: Mechanical Engineering Dept., Stanford University, Stanford CA 94305, USA RID="****" ID="****"Corresponding author. Fax: +1-650/859-6196, E-mail: smith@mplvax.sri.com     

The mechanism of nanostructuring upon nanosecond laser irradiation of a STM tip

Received: 20 April 1998/Accepted: 2 June 1998     

Scaling in large Prandtl number turbulent thermal convection

We study the scaling properties of heat transfer Nu in turbulent thermal convection at large Prandtl number Pr using a quasi-linear theory. We show that two regimes arise, depending on the Reynolds number Re. At low Reynolds number, NuPr ^-1/2 and Re are a function of RaPr ^-3/2. At large Reynolds number NuPr ^1/3 and RePr are function only of RaPr ^2/3 (within logarithmic corrections). In practice, since Nu is always close to Ra ^1/3, this corresponds to a much weaker dependence of the heat transfer in the Prandtl number at low Reynolds number than at large Reynolds number. This difference may solve an existing controversy between measurements in SF₆ (large Re) and in alcohol/water (lower Re). We link these regimes with a possible global bifurcation in the turbulent mean flow. We further show how a scaling theory could be used to describe these two regimes through a single universal function. This function presents a bimodal character for intermediate range of Reynolds number. We explain this bimodality in term of two dissipation regimes, one in which fluctuation dominate, and one in which mean flow dominates. Altogether, our results provide a six parameters fit of the curve Nu(Ra, Pr) which may be used to describe all measurements at Pr≥0.7. Received 27 February 2002 / Received in final form 29 May 2002 Published online 31 July 2002