Thermodynamic instability of disperse media isolated from external actions

The evolution of the structure of a medium containing disperse elements (the drops in a weakly viscous fluid, rigid spheres in glycerin, and air pores in a gel) is studied experimentally in the case where the gradient temperature and the concentration fields are absent in the system, and the medium is isolated from the influence of an external force field (including gravity forces). It is shown that these systems are nonequilibrium: if the initial distance between disperse particles is of the order of their sizes, the particles approach until they come in contact (coagulation) irrespective of the scale of the system. Lavrent’ev Institute of Hydrodynamics, Siberian Division, Russian Academy of Sciences, Novosibirsk 630090. Translated from Prikladnaya Mekhanika i Tekhnicheskaya Fizika, Vol. 40, No. 3, pp. 53–58, May–June, 1999.     

An unsymmetric constitutive equation for anisotropic viscoelastic fluid

A continuum constitutive theory of corotational derivative type is developed for the anisotropic viscoelastic fluid–liquid crystalline (LC) polymers. A concept of anisotropic viscoelastic simple fluid is introduced. The stress tensor instead of the velocity gradient tensor D in the classic Leslie–Ericksen theory is described by the first Rivlin–Ericksen tensor A and a spin tensor W measured with respect to a co-rotational coordinate system. A model LCP-H on this theory is proposed and the characteristic unsymmetric behaviour of the shear stress is predicted for LC polymer liquids. Two shear stresses thereby in shear flow of LC polymer liquids lead to internal vortex flow and rotational flow. The conclusion could be of theoretical meaning for the modern liquid crystalline display technology. By using the equation, extrusion–extensional flows of the fluid are studied for fiber spinning of LC polymer melts, the elongational viscosity vs. extension rate with variation of shear rate is given in figures. A considerable increase of elongational viscosity and bifurcation behaviour are observed when the orientational motion of the director vector is considered. The contraction of extrudate of LC polymer melts is caused by the high elongational viscosity. For anisotropic viscoelastic fluids, an important advance has been made in the investigation on the constitutive equation on the basis of which a series of new anisotropic non-Newtonian fluid problems can be addressed. The project supported by the National Natural Science Foundation of China (10372100, 19832050) (Key project). The English text was polished by Yunming Chen.     

Effect of convection on the stability of a liquid with a nonuniformly distributed heavy admixture

The effect of the transverse temperature gradient on the stability of steady motion of a viscous incompressible liquid in a plane vertical layer bounded by two infinite solid surfaces is studied. The motion of the liquid is caused by sedimentation of heavy solid spherical particles distributed nonuniformly across the layer and by the horizontal temperature gradient. Spectra of decrements of small normal perturbations are calculated for different particle sizes and different degrees of nonuniformity of the distribution of admixture particles. The stability of a steady flow of the liquid with an admixture decreases with increasing temperature gradient and increasing particle radius and increases with a tendency of the particles to a uniform distribution. Chelyabinsk State University, Chelyabinsk 454021. Translated from Prikladnaya Mekhanika i Tekhnicheskaya Fizika, Vol. 41, No. 5, pp. 180–187, September–October, 2000.     

Experimental investigation of pulsed stretching of cavitating media

A class of media whose structure develops into a foam state during pulsed volume stretching because of unrestricted growth of cavitational bubbles was determined experimentally. Among such media are low-viscosity Newtonian liquids, and disperse liquid media (emulsions, suspensions, and gels) with a low-viscosity liquid matrix. The results obtained are important for the development of a generalized rheological model for cavitating media. Lavrent'ev Institute of Hydrodynamics, Siberian Division, Russian Academy of Sciences, Novosibirsk 630090. Translated from Prikladnaya Mekhanika i Tekhnicheskaya Fizika, Vol. 39, No. 5, pp. 122–125, September–October, 1998.     

Motion and heat and mass transfer in a disperse admixture in turbulent nonisothermal jets of a gas and a low-temperature plasma

The motion and heat and mass transfer of particles of a disperse admixture in nonisothermal jets of a gas and a low-temperature plasma are simulated with allowance for the migration mechanism of particle motion actuated by the turbophoresis force and the influence of turbulent fluctuations of the jet flow velocity on heat and mass transfer of the particle. The temperature distribution inside the particle at each time step is found by solving the equation of unsteady heat conduction. The laws of scattering of the admixture and the laws of melting and evaporation of an individual particle are studied, depending on the injection velocity and on the method of particle insertion into the jet flow. The calculated results are compared with data obtained with ignored influence of turbulent fluctuations on the motion and heat and mass transfer of the disperse phase. __________ Translated from Prikladnaya Mekhanika i Tekhnicheskaya Fizika, Vol. 49, No. 3, pp. 95–108, May–June, 2008.     

Charging and coagulation of water aerosols with a small admixture of highly radioactive droplets

The mechanism of electrocoagulation of water aerosols with a small admixture of highly radioactive droplets is examined. A corresponding mathematical model describing the processes of ionization, electrization and coagulation of radioactive water aerosols is developed. The time dependence of the ion concentration and the charge and concentration of the nonradioactive droplets and of the charge and radius of the radioactive droplets is numerically investigated for a number of typical aerosols. It is shown that the electrocoagulation process may lead to an increase in the radius of the droplets from 5–10 to 30–40μm in ≃10⁴ sec ≃3 h and, consequently, may play a significant part in the development of aerosols with a droplet radius of up to 20μm, when gravitational coagulation is unimportant. Moscow. Translated from Izvestiya Rossiiskoi Akademii Nauk, Mekhanika Zhidkosti i Gaza, No.2, pp. 90–96, March–April, 1994.     

Stability of small radial oscillations of a spherical layer of liquid

An isothermal spherical layer of a viscoelastic liquid described by the one-parameter Maxwell model is considered. When the model parameter is taken equal to zero, a model of a purely viscous Newtonian fluid is obtained. The stability of the spherical layer of liquid with respect to small radial perturbations of the velocity and pressure is investigated for both types of liquids. Leningrad. Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 5, pp. 170–171, September–October, 1988.     

An approximate solution for the Couette–Poiseuille flow of the Giesekus model between parallel plates

An approximate analytical solution is derived for the Couette–Poiseuille flow of a nonlinear viscoelastic fluid obeying the Giesekus constitutive equation between parallel plates for the case where the upper plate moves at constant velocity, and the lower one is at rest. Validity of this approximation is examined by comparison to the exact solution during a parametric study. The influence of Deborah number (De) and Giesekus model parameter (α) on the velocity profile, normal stress, and friction factor are investigated. Results show strong effects of viscoelastic parameters on velocity profile and normal stress. In addition, five velocity profile types were obtained for different values of α, De, and the dimensionless pressure gradient (G).     

Effect of Relaxation and Retardation Time on Peristaltic Transport of the Oldroydian Viscoelastic Fluid

The influence of relaxation and retardation time on peristaltic transport of an incompressible Oldroydian viscoelastic fluid by means of an infinite train of sinusoidal waves traveling along the walls of a two-dimensional flexible channel is investigated. A perturbation solution is obtained for the case in which the amplitude ratio (wave amplitude to channel half-width) is small. The results show that the values of the mean axial velocity of an Oldroydian viscoelastic fluid is smaller than that for a Newtonian fluid. The reflux phenomena are discussed. It is found that the critical reflux pressure gradient decreases with increasing retardation time and increases with increasing relaxation time. Numerical results are reported for different values of the physical parameters of interest. __________ Translated from Prikladnaya Mekhanika i Tekhnicheskaya Fizika, Vol. 46, No. 6, pp. 86–95, November–December, 2005.     

Shock-wave-initiated lifting of particles from a cavity

The dynamics of particles of the disperse phase in a turbulent gas flow in planar shock waves sliding along a solid surface with a trapezoid cavity is examined numerically. Lifting of particles from the cavity walls is calculated in the approximation of a rarefied gas suspension. It is shown that the intensity of the transient shock wave and the initial positions of particles have a significant effect on the particle-lifting properties. The height of particle lifting is found to nonmonotonically depend on the initial streamwise coordinate and shock-wave Mach number. It is shown that zones of aggregation and subtraction of particles may be formed at the cavity bottom. __________ Translated from Prikladnaya Mekhanika i Tekhnicheskaya Fizika, Vol. 48, No. 1, pp. 24–34, January–February, 2007.     

Evolution of perturbations on the surface of a viscoelastic liquid

The stability of a layer of a viscoelastic liquid on an inclined plane is studied within the framework of the model with a time-dependent “memory” in the presence of surface tension. It is shown analytically and numerically that these flows can be stable or unstable depending on the Reynolds number. Profiles of the free surface are found as functions of the Reynolds and Weber numbers. Translated from Prikladnaya Mekhanika i Tekhnicheskaya Fizika, Vol. 41, No. 3, pp. 86–91, May–June, 2000.     

A Model for Flow and Deformation in Unsaturated Swelling Porous Media

A thermomechanical theory for multiphase transport in unsaturated swelling porous media is developed on the basis of Hybrid Mixture Theory (saturated systems can also be modeled as a special case of this general theory). The aim is to comprehensively and non-empirically describe the effect of viscoelastic deformation on fluid transport (and vice versa) for swelling porous materials. Three phases are considered in the system: the swelling solid matrix s, liquid l, and air a. The Coleman–Noll procedure is used to obtain the restrictions on the form of the constitutive equations. The form of Darcy’s law for the fluid phase, which takes into account both Fickian and non-Fickian transport, is slightly different from the forms obtained by other researchers though all the terms have been included. When the fluid phases interact with the swelling solid porous matrix, deformation occurs. Viscoelastic large deformation of the solid matrix is investigated. A simple form of differential-integral equation is obtained for the fluid transport under isothermal conditions, which can be coupled with the deformation of the solid matrix to solve for transport in an unsaturated system. The modeling theory thus developed, which involves two-way coupling of the viscoelastic solid deformation and fluid transport, can be applied to study the processing of biopolymers, for example, soaking of foodstuffs and stress-crack predictions. Moreover, extension and modification of this modeling theory can be applied to study a vast variety of problems, such as drying of gels, consolidation of clays, drug delivery, and absorption of liquids in diapers.     

Specific features of microparticle deformation upon impact on a rigid barrier

Based on experimental data and numerical modeling, it is shown that a lamina of melted metal of thickness of order0.01 d, in which the temperature is close to the melting point of the particle material, can be formed upon high-speed impact (v ₀≈500–1200 m/sec) of a fine metal particle (d=1–50 μm) on a rigid undeformable barrier near the contact surface. Institute of Theoretical and Applied Mechanics, Siberian Division, Russian Academy of Sciences, Novosibirsk 630090. Translated from Prikladnaya Mekhanika i Tekhnicheskaya Fizika, Vol. 41, No. 1, pp. 204–209, January–February, 2000.     

Rheology of SiO2/(acrylic polymer/epoxy) suspensions. I. Linear viscoelasticity

Linear viscoelastic properties of SiO₂/(AP/EP) suspension with various SiO₂ volume fractions (ϕ) in a blend of acrylic polymer (AP) and epoxy (EP) were investigated at various temperatures (T). The AP/EP contained 70 vol.% of EP. The SiO₂ particles were treated with epoxy silane coupling agent. The effects of the SiO₂ particles are more pronounced in the terminal zone: a transition from viscoelastic liquid (ϕ ≤ 30 vol.%) to viscoelastic solid (ϕ ≥ 40 vol.%) was observed which can be interpreted as a critical gelation occurring at a critical particle content and critical gel temperature. The SiO₂/(AP/EP) systems exhibited a critical gel behavior at ϕ ≅ 35 vol.% and T ≅ 100°C characterized with a power–law relationship between the storage and loss moduli (G ^′ and G ^″) and frequency (ω); G ^′ = G ^″/tan(nπ/2) ∝ ω ⁿ . The critical gel exponent (n) was estimated to be about 0.45. The gelation occurred with increasing T.     

Gas-dynamic spraying. An experimental study of the spraying process

We present results of an experimental study of the specific features of the gas-dynamic formation of coatings from metallic powders (d_p<50 μm) on substrates of various materials depending on the particle velocity (200–1200m/sec), the jet temperature (300–700K), and other parameters. Results of a prospecting study of the implementation of the methods of particle acceleration in supersonic (M=2.0–3.0) rectangular nozzles are described. The rate of bond formation in a cold particle-cold substrate contact occurring in gas-dynamic spraying is estimated within the framework of the concepts applied in analysis of gas-dynamic spraying. Institute of Theoretical and Applied Mechanics, Siberian Division, Russian Academy of Sciences, Novosibirsk 630090. Translated from Prikladnaya Mekhanika i Tekhnicheskaya Fizika, Vol. 39, No. 2, pp. 182–188, March–Apil, 1998.     

Scale-up criterion of turbulent flows of dilute polymer solutions and a generalized dependence of the friction coefficient

Dilute polymer solutions that reduce turbulent friction are treated as viscoelastic liquids for which, in addition to the Reynolds number, the scale-up criteria include the Deborah or elasticity number. Introduction of a generalized (viscoelastic) Reynolds number makes it possible to reduce the experimental curves for the drag coefficients obtained in pipes of various diameters at different and concentrations to a unified dependence. St. Petersburg. Translated from Izvestiya Rossiiskoi Akademii Nauk, Mekhanika Zhidkosti i Gaza, No. 4, pp. 191–196, July–August, 1998.     

Rheological properties of disperse systems at low shear stresses

Three-dimensional network structures can be built up in disperse systems due to long-range colloidal interactions between the dispersed particles. The rheological behaviour of such coagulation structures has been studied by means of creep and recovery experiments at low shear stresses, i.e. by measuring the shear strain as a function of time under constant stress and after removal of stress. Measurements of this type give insight into the elastic and viscous deformations and the retardation times necessary to reach equilibrium or steady-state conditions.Results obtained with dispersions of pigments in polymer solutions and with monodisperse polymer latexes indicate the existence of an equilibrium state at low shear stresses with a predominant elastic deformation and a high viscosity suggesting that the disperse systems investigated do not behave exactly as rigid gels but apparently exhibit a dynamic equilibrium of structural break-down and formation under applied stress. This behaviour is approximately described by a 4-parameter-model with an instantaneous and a steady-state compliance, one retardation time, and a viscosity.At higher shear stresses thixotropic structural break-down occurs resulting in a transition from the rheological behaviour described here to a liquid-like state with a comparatively low viscosity. In this stress range the viscoelastic properties become strongly time-dependent.These measurements give evidence of the presence of two types of deformation: an instantaneous, purely elastic deformation attributable to the unperturbed coagulation structure and the creep-recovery behaviour of an elastic liquid apparently related to the breaking and re-forming of bonds.     

Thermocapillary motion of a liquid with a free surface with nonlinear dependence of the surface tension on the temperature

The present note considers two problems concerning the thermocapillary motion, due to the existence of a temperature gradient, of a weightless liquid with a parabolic dependence of the surface tension on the temperature. These problems admit self-similar solutions (in the generalized sense) within the framework of the Navier-Stokes equations. It is noted that the solution may not be unique. Moscow. Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 5, pp. 132–137, September–October, 1988.     

Spherical particle sedimentation along an inclined plane at small reynolds numbers

At small Reynolds numbers, the gravity-driven motion of a solid spherical particle along an inclined plane in a Newtonian liquid initially at rest was studied experimentally. A comparison of the experiment with the calculations showed that motions both with and without particle-plane contact may occur. The latter cannot be explained within the Stokes approximation. Moscow. Translated from Izvestiya Rossiiskoi Akademii Nauk, Mekhanika Zhidkosti i Gaza, No. 4, pp. 129–136, July–August, 1998.