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1.
A novel mono‐component intumescent flame retardant named pentaerythritol phosphate melamine salt (PPMS)‐hybrid bismuth oxide (PPMS‐Bi2O3) was synthesized and carefully characterized by FTIR, 1H NMR, 31P NMR, SEM‐EDS, and TG analyses. Then, PPMS‐Bi2O3 was utilized as flame retardant for epoxy resins (EPs), and the thermal stability, flame retardancy, and smoke suppression properties of EP composites were investigated. TG results show that PPMS‐Bi2O3 is more conducive to enhance the thermal stability and char forming ability of EP composites compared with the same addition of PPMS or the mixture of PPMS and Bi2O3, and this positive effect is enhanced with the increasing Bi2O3 content. Cone calorimeter test reveals that the PPMS‐Bi2O3 can effectively reduce the heat release and smoke production in comparison with PPMS or the mixture of PPMS and Bi2O3 due to the formation of a more compact and intumescent char against fire, as judged by digital photographs and SEM images. EDS analysis indicates that the combination PPMS and Bi2O3 by hydrogen bonds promotes to generate more phosphorus‐rich and aromatization structures in the condensed phase that enhance the barrier effect and anti‐oxidation ability of the char, thus imparting higher flame retardant and smoke suppression efficiencies to EP composites.  相似文献   

2.
A series of flame retardant epoxy resins (EPs) containing phosphorus‐containing oligomeric silsesquioxane are prepared, and an interesting blowing‐out effect is detected in flame retardant EPs. The temperature profiles show that blowing‐out effect slows the heat transfer from the fire to the unburned matrix; furthermore, this blowing‐out effect can even take away some heat from the surface zone by the spurting gases. The thermo gravimetric analyzer and Fourier transform infrared spectrometer result shows that the spurting gases during the blowing‐out effect have a high content of CO2, which could reduce the combustion capability of the jetting gases. The flame retardancy of these EPs is tested by limit oxygen index and UL‐94. The incorporation of 2.5 wt% phosphorus‐containing oligomeric silsesquioxane into EP gives a remarkable blowing‐out effect, which results in a significant enhancement of limit oxygen index value and UL‐94 rating. The flame retardancy mechanism of blowing‐out effect is quite different from the traditional mechanisms. The char strength and morphology of EP composites are also investigated to explain the mechanism of the blowing‐out effect. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

3.
In this work, a DOPO‐based imidazolone derivative named DHI was synthesized using DOPO, 5‐amino‐2‐benzimidazolinone and 4‐hydroxybenzaldehyde as raw materials. The chemical structure of DHI was characterized by 1H‐NMR, 31P‐NMR and Fourier transform infrared spectra (FTIR). Then, a series of different flame‐retardant epoxy resin (EP) thermosets were prepared by mixing flame retardant DHI. The thermal properties of the cured EPs was investigated by thermogravimetry analysis (TGA) and differential scanning calorimeter (DSC), and the results showed the thermal stability and glass transition temperature (Tg) of the cured EP modified with DHI declined slightly compared with that of neat EP. The limited oxygen index (LOI) and UL94 test results exhibited DHI imparted good flame retardancy to EP. The EP‐4 (phosphorus content of 1.25%) possessed a LOI value of 36.5% and achieved a V‐0 rating. Furthermore, the peak of heat release rate (PHRR) and total heat release rate (THR) of EP‐4 decreased by 38.7% and 24.5%, respectively. Excitedly, the total smoke production (TSP) of EP‐4 sample declined by 62.5%, which meant DHI also made EP obtain excellent smoke suppression property. Moreover, the flame‐retardant mechanism was studied by scanning electron microscopy (SEM) and pyrolysis‐gas chromatography/mass spectrometry (Py‐GC/MS). It was reasonable inferred that DHI could not only promote EP to form dense char layer in condensed phase, but also restrain combustion in gaseous phase through catching the free radicals sourced from the degradation of EP.  相似文献   

4.
A novel activated carbon spheres (ACS)@SnO2@NiO hierarchical hybrid architecture was first synthesized and applied for enhancing the flame retardancy of epoxy (EP) resin via a cooperative effect. Herein, using activated carbon microspheres as the template, SnO2 and NiO nanospheres were successively anchored to it by a sedimentation‐calcination strategy. The well‐designed ACS@SnO2@NiO significantly enhanced the flame retardancy for consistency of EP composites, as demonstrated by thermogravimetric and cone calorimeter experiments. For instance, the incorporation of 2 wt% ACS@SnO2@NiO decreased by 15.5% maximum in the total smoke production, accompanying the higher graphitized char layer. In addition, the synergetic mechanism of flame retardancy between ACS@SnO2@NiO and aluminum hypophosphite (AHP) was investigated. The obtained sample satisfied the UL‐94 V‐0 rating with a 5.0 wt% addition of AHP and ACS@SnO2@NiO (the ratio of the mass fraction of AHP to ACS@SnO2@NiO is 4.5:0.5). Notably, the incorporation of AHP and ACS@SnO2@NiO resulted in a significant decrease in the fire hazard properties of EP resin; for instance, 4.5AHP‐0.5ACS@SnO2@NiO/EP resulted in a maximum decrease of 32.4% in the total smoke production as compared with that of pure EP resin. It should be noted that the improved flame‐retardant performance for the EP composites is primarily attributed to the synergistic effect of ACS@SnO2@NiO and AHP in promoting the formation of residual char in the condensed phase.  相似文献   

5.
A novel flame retardant containing cellulose, phosphorus and ferrum complex (Cell‐P‐Fe) was successfully synthesized and then it was used as flame retardants in epoxy resins (EP). Due to the present of acid sources and carbon sources, the Cell‐P‐Fe exhibits improved thermal stability and flame retardant properties. The EP/Cell‐P‐Fe composites with 10 wt% of Cell‐P‐Fe show remarkably improved LOI and UL‐94 values compared with the flame retardants without ferrum. At the loading of 10.0 wt% flame retardants, the char yield for EP/Cell‐P‐Fe composites increased to 29.1 wt%, indicating the improved thermal stability at high temperature. Moreover, thermogravimetric analysis, morphology of char residues and FTIR results demonstrate that stable char layers are formed on the surface of the composites during the combustion, attributing to the catalytic carbonization effect of Fe and phosphorus and the present of cellulose as carbon source. The stable char layers, which can protect the underlying materials from heat and oxygen, play an important role in the flame retardancy enhancement.  相似文献   

6.
《先进技术聚合物》2018,29(1):641-648
To explore the component synergistic effect of boron/phosphorus compounds in epoxy resin (EP), 3 typical boron compounds, zinc borate (ZB), boron phosphate (BPO4), and boron oxide (B2O3), blended with phosphaphenanthrene compound TAD were incorporated into EP, respectively. All 3 boron/phosphorus compound systems inhibited heat release and increased residue yields and exerted smoke suppression effect. Among 3 boron/phosphorus compound systems, B2O3/TAD system brought best flame‐retardant effect to epoxy thermosets in improving the UL94 classification of EP composites and also reducing heat release most efficiently during combustion. B2O3 can interact with epoxy matrix and enhance the charring quantity and quality, resulting in obvious condensed‐phase flame‐retardant effect. The combination of condensed‐phase flame‐retardant effect from B2O3 and the gaseous‐phase flame‐retardant effect from TAD effectively optimized the action distribution between gaseous and condensed phases. Therefore, B2O3/TAD system generated component synergistic flame‐retardant effect in epoxy thermosets.  相似文献   

7.
Graphene‐polyaniline/nickel hydroxide ternary hybrid (RGO‐PANI/Ni(OH)2) was synthesized and incorporated into epoxy resin (EP) to improve the fire retardant property. Thermogravimetric analysis results showed that the RGO‐PANI/Ni(OH)2 nanohybrid could catalyze the thermal degradation of epoxy matrix that was essential to trigger the char formation. The char yield of the RGO‐PANI/Ni(OH)2/EP composite was improved compared with that of the samples with graphene and polyaniline only. With 3.0‐wt% RGO‐PANI/Ni(OH)2, significant reduction in peak heat release rate (40%) and peak smoke production rate (36%) was observed in the cone calorimeter tests. Thermogravimetric analysis/infrared spectrometry (TG‐IR) results indicated that the flammable volatiles of the RGO‐PANI/Ni(OH)2/EP composite was reduced compared with those of the EP and RGO‐PANI/EP. The superior flame retardant and smoke suppressant behaviors of the RGO‐PANI/Ni(OH)2 nanohybrid over RGO‐PANI were attributed to the combination of good barrier effect of graphene with catalytic ability of char formation of PANI and metal hydroxide.  相似文献   

8.
A triazine ring‐containing charring agent (PEPATA) was synthesized via the reaction between 2,6,7‐trioxa‐l‐phosphabicyclo‐[2.2.2]octane‐4‐methanol (PEPA) and cyanuric chloride. It was applied into intumescent flame retardant epoxy resins (IFR‐EP) as a charring agent. The effect of PEPATA on fire retardancy and thermal degradation behavior of IFR‐EP system was investigated by limited oxygen index (LOI), UL‐94 test, microscale combustion calorimetry (MCC), thermogravimetric analysis (TGA) and thermogravimetric analysis/infrared spectrometry (TG‐IR). The glass transition temperatures (Tg) of IFR‐EP systems were studied by dynamic mechanical analysis (DMA). The LOI values increased from 21.5 for neat epoxy resins (EPs) to 34.0 for IFR‐EP, demonstrating improved flame retardancy. The TGA curves showed that the amount of residue of IFR‐EP system was largely increased compared to that of neat EP at 700 °C. The new IFR‐EP system could apparently reduce the amount of decomposing products at higher temperatures and promotes the formation of carbonaceous charred layers that slowed down the degradation. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

9.
Through addition reaction of Schiff‐base terephthalylidene‐bis‐(p‐aminophenol) ( DP‐1 ) and diethyl phosphite (DEP), a novel phosphorus‐modified epoxy, 4,4'‐diglycidyl‐(terephthalylidene‐bis‐(p‐aminophenol))diphosphonate ether ( EP‐2 ), was obtained. An modification reaction between EP‐2 and DP‐1 resulted in an epoxy compound, EP‐3 , possessing both phosphonate groups and C?N imine groups. The structure of EP‐2 was characterized by Fourier transform infrared (FTIR), elemental analysis (EA), 1H, 13C, and 31P NMR analyses. The thermal properties of phosphorus‐modified epoxies cured with 4,4'‐diaminodiphenylmethane (MDA) and 4,4'‐diaminodiphenyl ether (DDE) were studied by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). The activation energies of dynamic thermal degradation (Ed) were calculated using Kissinger and Ozawa's methods. The thermal degradation mechanism was characterized using thermogravimetric analysis/infrared spectrometry (TG‐IR). In addition, the flame retardancy of phosphorus‐modified epoxy thermosets was evaluated using limiting oxygen index (LOI) and UL‐94 vertical test methods. Via an ingenious design, phosphonate groups were successfully introduced into the backbone of the epoxies; the flame retardancy of phosphorus‐modified epoxy thermosets was distinctly improved. Due to incorporation of C?N imine group, the phosphorus‐modified epoxy thermosets exhibited high thermal stabilities; the values of glass‐transition temperatures (Tgs) were about 201–210°C, the values of Ed were about 220–490 kJ/mol and char yields at 700°C were 49–53% in nitrogen and 45–50% in air. These results showed an improvement in the thermal properties of phosphorus‐modified epoxy by the incorporation of C?N imine groups. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

10.
《先进技术聚合物》2018,29(7):2147-2160
Layered double hydroxides (LDHs) are emerging as a new and green high‐efficient flame retardant. But LDHs aggregate seriously because of their hydrophilicity, which affect deeply the mechanical and flame retardant properties of their composites. For the first time in this paper, microencapsulated LDHs (MCLDHs) with melamine‐formaldehyde (MF) resin were prepared by microencapsulation technology to enhance their compatibility and dispersion within epoxy resin (EP). The mechanical and flame retardant performances of EP/MCLDH composite were studied by comparing with EP/LDH composite. Results showed that the water contact angle of MCLDHs increased from 8.9° to 122.1°, which indicated good compatibility. The particle size of MCLDHs decreased sharply, and more than one‐third were up to submicron scale, which can be conducive to dispersion. Moreover, the tensile strength and elongation at break of EP/MCLDHs with different flame retardant contents were higher than those of EP/LDHs. And the addition of MCLDHs increased the glass transition temperature (Tg) of EP/MCLDHs, which meant a strong interfacial interaction. Besides, compared with EP/LDHs, the limiting oxygen index values of EP/MCLDHs were higher, and its peak of heat release rate and total heat release decreased by 16.3% and 5.5% respectively. EP/MCLDHs achieved from V‐1 to V‐0 rate with the increasing content of MCLDHs from 20% to 30%, while LDHs/EP never passed tests. In the process of heating, H2O, CO2, and NH3 released from MCLDHs formed gaseous phase, and the remaining dense char layers and oxides produced condensed phase, which played an important role in inhibiting combustion.  相似文献   

11.
A novel phosphorus-containing oligomeric flame retardant, poly(DOPO substituted hydroxyphenyl methanol pentaerythritol diphosphonate) (PDPDP) was synthesized and applied to flame retarded epoxy resins. The thermal degradation behaviors of flame retarded epoxy composites with PDPDP were investigated by thermogravimetric analysis (TGA), thermogravimetric analysis/infrared spectrometry (TG-FTIR) and direct pyrolysis-mass spectrometry (DP-MS) techniques. The identification of pyrolysis fragment ions provided insight into the flame retardant mechanism. The results showed that the mass loss rate of the EP/PDPDP composites was clearly lower than pure EP when the temperature was higher than 300 °C in air or nitrogen atmosphere. The results also suggested that the main decomposition fragment ions of the EP/PDPDP composite were H2O, CO2, CO, benzene, and phenol. The incorporation of PDPDP can reduce the release of combustible gas and induce the formation of char layer, hence the fire potential hazard was reduced.  相似文献   

12.
Black phosphorus (BP) has been attractive for many research groups as its promising properties. However, the poor air stability of BP has limited its practical applications. To simultaneously address this problem and improve the flame retardancy of BP in epoxy resin (EP), a surface coordination strategy was proposed. Herein, a titanium ligand (denoted as TiL4) was designed to coordinate BP nanosheets, which can occupy the lone pair electrons of BP. The Ti–P coordination contributed to the improvement of ambient stability of BP. The serious degradation was observed from pure BP owing to the oxidation. Whereas, the surface coordination can impede the ambient degradation rate of BP by 74.07%. With the addition of 1.5 wt% TiL4@BP, the char yield of EP nanocomposites was increased by 20.55% due to the catalytic charring effect of TiL4@BP. The incorporation of 1.5 wt% TiL4@BP can reduce the peak of heat release rate and total heat release values of EP by 29.41% and 23.32%. The EP/TiL4@BP 1.5 also can pass the UL-94 V-0 rating, and its value of limiting oxygen index was enhanced by 13.60%. The improvement in the flame retardancy of BP in EP can be largely ascribed to synergistic catalytic charring effects between BP and TiL4. The condense and compact char layer can act as a physical barrier to restrict the exchange of pyrolytic products and the transfer of heat. In addition, the free radical quenching effect of BP nanosheets also accounted for the excellent flame retardant performance of EP. This work proposed a reference for synchronically obtaining the improvement for the air stability and flame retardant performance of BP.  相似文献   

13.
In order to improve the flame retardant of polylactide (PLA), the synergistic effect of graphitic carbon nitride (g‐C3N4) with commercial‐available flame retardants melamine pyrophosphate (MPP) and 9,10‐dihydro‐9‐oxa‐10‐phosphaphenanthrene‐10‐oxide (DOPO) was investigated. The PLA composites containing 5 wt% g‐C3N4 and 10 wt% DOPO had a highest limited oxygen index (LOI) value of 29.5% and reached the V‐0 rating of UL‐94 test. The cone calorimeter tests exhibited that DOPO had a better synergistic effect with g‐C3N4 than MPP to improve flame retardancy of PLA. The peak heat release rate (pHRR) and total heat release (THR) of PLA composites containing 10 wt% DOPO could be reduced by 25.2% and 23.6%, respectively, as compared with those of pure PLA. The presence of rich phosphorus element and aromatic groups in DOPO contributed to obtain continuous compact char layer and increase the graphitization level of char residues, thereby, resulting in improving the flame retardancy of PLA together with g‐C3N4. In addition, the incorporation of DOPO can serve as a plasticizer to reduce the complex viscosity, improving the processability of PLA composites.  相似文献   

14.
A highly cross‐linked poly (cyclotriphosphazene‐resveratrol) microsphere (PRV) was synthesized by using hexachlorocyclotriphosphazene (HCCP) and bio‐based resveratrol (REV) as raw materials, and the obtained PRV microspheres were applied to improve the flame retardancy and mechanical property of epoxy resin (EP). The TGA results showed that the PRV microsphere is an excellent charring agent and the char yield is as high as 62% at 800°C. The incorporation of PRV makes the initial degradation earlier yet significantly increases the char residue of EP composites. Moreover, the introduction of PRV microspheres into EP greatly promoted the flame retardancy performance. Under 3% of addition of PRV microspheres, the peak heat release rate (PHRR) and total heat release (THR) were decreased by 58.3% and 29.6%, respectively, the limited oxygen index (LOI) value was increased to 29.7% from 25.3% of pure EP. In addition, because of the uniform distribution in EP matrix and the enhancing effect of PRV microspheres, the mechanical properties including tensile modulus of EP composites were strengthened. PRV microspheres in this paper provide a possibility to synthesize a dual functional filler, which acts as both flame retardant and strengthening agent.  相似文献   

15.
A novel curing and flame‐retardant agent (PEPA‐TMAC) was successfully synthesized. The chemical structure was characterized by Fourier transform infrared spectroscopy (FTIR) and nuclear magnetic resonance (NMR). Use of PEPA‐TMAC as part of the curing agent in combination with another anhydride for a commercial epoxy resin (EP) was studied. Results of differential scanning calorimetry (DSC) indicated that PEPA‐TMAC was an effective curing agent for EP. The dynamic mechanical analysis (DMA) results showed that the glass transition temperature (Tg) and cross‐linking density (Ve) of EP composites exhibited an increase trend with the addition of PEPA‐TMAC. The limiting oxygen index (LOI) value of EP composites reached 26.9%, and the cone calorimeter results indicated that peak heat release rate (PHRR), total heat release (THR), smoke produce rate (SPR), and total smoke produce (TSP) remarkably decreased with increasing PEPA‐TMAC content. TGA data showed that the addition of PEPA‐TMAC greatly increased the amount of residual char during combustion. The morphology of the residual char was studied by SEM and showed that the addition of PEPA‐TMAC greatly increased the stability of EP composites. The thermogravimetric analysis (TGA), energy‐dispersive X‐ray spectroscopy (EDS), and FTIR results revealed the flame‐retardant mechanism that PEPA‐TMAC can promote the formation of charred layers with the phospho‐carbonaceous complexes in the condensed phase during burning of EP composites.  相似文献   

16.
Molybdenum trioxide (MoO3) microrods, nanofibers, and nanoplates were synthesized via the hydrothermal method and high‐temperature calcination method, respectively. Then the MoO3 was added into polyurethane elastomer, respectively. The flame retardancy and smoke suppression of the composites added with different MoO3 were studied by thermal gravimetric analysis, cone calorimeter, and smoke density. The results show that the three kinds of MoO3 with different morphologies could promote the formation of char and possess flame retardancy and smoke suppression, and MoO3 nanofibers exhibit a higher degree of flame retardancy, and 1 wt% addition could make the peak heat release rate of polyurethane elastomer composites reduce from 881.6 kW m?2 for a pure sample to 343.4 kW m?2, a decrease by 61.0%. As for smoke suppression, MoO3 nanoplates possess the best smoke suppression; 5 wt% could decrease a pure sample's smoke density by 41.3% from 361 to 212. Moreover, the char residue of composites after combustion was analyzed by Raman spectra and X‐ray photoelectron spectroscopy, and the flame retardancy and smoke suppression mechanisms of MoO3 were discussed.  相似文献   

17.
A series of CeO2‐loaded titania nanotubes (CeO2‐TNTs) hybrid materials with different CeO2 loadings were synthesized by co‐precipitation method and then incorporated into epoxy resin (EP) to prepare CeO2‐TNTs flame‐retardant epoxy nanocomposites. Structure and morphology characterization indicated the successful synthesis of CeO2‐TNTs. The effect of CeO2‐TNTs with different CeO2 loading capacity on the flame retardance of EP was compared and analyzed by the thermogravimetric analysis, Cone and Raman. The results showed that CeO2 loading could increase the carbon residue of nanocomposites, reduce the peak heat release rate (PHRR) and total heat release (THR), and improve the fire safety of EP. The residual carbon content of EP/0.1CeO2‐TNTs sample at 700°C reached 19.8% with the lowest degradation rate, and the PHRR and THR were reduced to 680 kW/m2 and 32.9 MJ/m2, respectively. Such a significant improvement in flame‐retardant properties for EP could be attributed to the protective effect of CeO2‐TNTs.  相似文献   

18.
Establishing a phosphorus‐free strategy to fabricate high‐performance thermosetting resins owning outstanding thermal resistance, good flame retardancy, and smoke suppression is important for sustainable development. Herein, a unique phosphorus‐free hybrid (BN@CeO2) was synthesized through chemically grafting cerium oxide (CeO2) on surface of exfoliated boron nitride (BN) nanosheet with the aids of γ‐aminopropyltriethoxysilane and polydopamine coating, which was then embedded into bisphenol A cyanate ester (BCy) resin to fabricate new BN@CeO2/BCy composites with high thermal resistance. Compared with BCy resin, the BN@CeO2/BCy composite with 4 wt% BN@CeO2 not only has delayed initial ignition time by 23 seconds but also severally shows 58.1%, 23.1%, and 44.4% lower smoke produce rate, total heat release, and peak heat release rate. The study on mechanism behind outstanding flame retardancy reveals that the improved heat resistance and flame retardancy of BN@CeO2/BCy composite are attributed to multiply effects induced by BN@CeO2 and its interaction with BCy resin; specifically, these effects come from BN (physical barrier) and CeO2 (free radical trapping effect and catalytic char layer formation) as well as those from the synergistic effect of BN and CeO2. These excellent comprehensive properties of BN@CeO2/BCy composites demonstrate that BN@CeO2 is an environment‐friendly and synergistic modifier for developing heat‐resisting thermosetting resins with outstanding flame retardancy and smoke suppression.  相似文献   

19.
Cellulose microcrystalline (CMC), a linear polysaccharide with glucosidic bond, was successfully extracted from bamboo powder and modified by 3‐aminopropyltriethoxy silane coupling agent (KH550) to prepare KH550‐CMC. The prepared KH550‐CMC, in association with ammonium polyphosphate (APP), was introduced into epoxy resin (EP) by casting process to obtain flame retardant composites. The fire performance evaluation indicated that the presence of 10‐phr APP and 5‐phr KH550‐CMC in EP achieved the maximal LOI value of 28.9%, passed the UL‐94 V‐0 rating, and significantly decreased the peak heat release rate from 1055 kW/m2 of neat EP to 286 kW/m2. The improved fire performance is due to the improvement of dispersity of CMC in EP matrix and formation of better char layer, thus protecting the matrix effectively. Moreover, the introduction of KH550‐CMC could also partly eliminate the negative influence of flame retardants on the mechanical properties of EP composites due to the strengthening effect of CMC and better interfacial compatibility after modification with KH550.  相似文献   

20.
《先进技术聚合物》2018,29(10):2665-2673
A phosphazene derivative flame retardant with a highly cross‐linked microsphere structure, named poly(cyclotriphosphazene‐c‐sulfonyldiphenol) (PCPS) microspheres, were synthesized by 1‐pot reaction and then applied on flame retarded epoxy (EP) resin. The microstructure and chemical composition of PCPS microspheres were characterized using scanning electron microscopy, transmission electron microscopy, and element mapping. The thermal stability of PCPS microspheres and PCPS/EP composites was explored through thermogravimetric analysis. Thermogravimetric data showed that the PCPS microspheres have excellent thermal stability, and the char yield is about 43% at the end of 800°C. The incorporation of PCPS microspheres significantly increased the char yield of PCPS/EP composites. The flammability was investigated by limited oxygen index tests and cone calorimeter. The limited oxygen index value of PCPS/EP composite was increased to 29.8 from 26.6 when 3 wt% of PCPS microspheres was added. Compared with neat EP, the flame retardancy was greatly improved. The peak heat release rate and smoke production rate of PCPS/EP composites were reduced by 45.0% and 43.6%, respectively. The mechanical properties including tensile strength and modulus were both improved due to the enhancement of PCPS microspheres. The PCPS microspheres act as a dual function for improving both the flame resistance and mechanical strength of PCPS/EP system.  相似文献   

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