共查询到18条相似文献,搜索用时 181 毫秒
1.
研究了沉积在液体基底(硅油)表面金薄膜中的带状有序结构和自组装现象.实验结果表明:在一定条件下,生长在硅油表面的金薄膜中可形成一种特征的有序结构,它是由近似矩形状的畴块拼接而成的;相邻畴块的长度近似相等,但宽度一般不同,因而具有特征长度为101—102μm数量级的准周期结构.进一步的实验发现:此类带状有序结构是由薄膜中特征内应力所引起的物质相互挤压而形成的.另外,对此类具有近似自由支撑边界条件的薄膜中的内应力形成机理进行了研究.
关键词:
薄膜
有序结构
内应力
自组装 相似文献
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利用直流溅射方法在液体基底(硅油)表面成功制备出金属铁薄膜系统,研究了其生长机理及特征的表面有序结构.实验发现铁薄膜的生长过程与液相基底表面非磁性金属薄膜的情况类似,基本服从二阶段生长模型.连续铁薄膜中可观测到尺寸巨大的圆盘形有序结构,其生长演化与溅射功率、沉积时间和真空环境中的生长时间等实验条件密切相关.实验证明,此类有序结构是在薄膜内应力作用下,铁原子及原子团簇在液体表面自由扩散迁移,并最终在硅油基底表面某些区域成核凝聚所致.在较大溅射功率和沉积时间条件下,圆盘外部区域的铁薄膜中形成周期分布的波纹褶皱,其波长约为10 μm,波峰基本与圆盘的边界平行.进一步研究表明:在沉积过程中,由于沉积铁原子的局域能量作用,导致硅油的表面层结构发生改变而形成一聚合物层;在随后的冷却过程中,聚合物层的强烈收缩使铁薄膜处于很大的压应力场中,促使薄膜起皱形成波纹结构.
关键词:
液体基底
铁薄膜
生长机理
有序结构 相似文献
3.
沉积在液相基底表面磁性薄膜的形成机理和特性研究 总被引:2,自引:0,他引:2
采用气相沉积方法在硅油基底表面成功制备了一种具有近似自由支撑的新型铁薄膜系统,并研究了其生长机制、内应力分布以及低温磁特性.实验发现,此类铁薄膜的生长机制与沉积在液相基底表面非磁性薄膜的情况类似,即服从二阶段生长模型.在固定基底温度的条件下,当沉积速率较小时,可制得近似透明的连续铁薄膜,薄膜中呈现明显的特征尺寸达10^2μm数量级的带状准周期有序结构,它是由铁薄膜样品中内应力释放时所引起的薄膜板块间相互挤压而逐渐形成的.当沉积速率较大时,制得的连续铁薄膜呈金属色.实验发现,在临界温度Tc=10—15K附近,具有金属色的铁薄膜样品的矫顽力Hc有一明显的极大值峰.研究表明,这一奇异的矫顽力特性与液相基底表面铁薄膜中的原子团簇尺寸分布、无序的薄膜表面磁各向异性以及团簇间的磁性相互作用等因素有关. 相似文献
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An unusual form of ordered stress relief patterns is observed in a nearly free sustained aluminum film system deposited on liquid substrates by the therm~l evaporation method. The edge effects on the growth of the ordered patterns are systematically studied. It is found that the patterns initiate from the film edges, preexisting ordered patterns, or other imperfections of the film. When the patterns extend in the film regions, they decay gradually and finally disappear. If they develop along the boundaries, however, the sizes are almost unchanged over several millimeters. The stress relief patterns look like rectangular waves in appearance, which are proven to evolve from sinusoidal to triangular waves gradually. The morphological evolution can be well explained by the general theory of buckling of plates. 相似文献
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A nearly free sustained copper (Cu) film system has been successfully fabricated by thermal evaporation deposition of Cu atoms on silicone oil surfaces, and a characteristic ordered pattern has been systematically studied. The ordered pattern, namely, band, is composed of a large number of parallel key-formed domains with different width w but nearly uniform length L; its characteristic values of w and L are very susceptible to the growth period, deposition rate and nominal film thickness. The formation mechanism of the ordered patterns is well explained in terms of the relaxation of the internal stress in the films, which is related to the nearly zero adhesion of the solid-liquid interface. By using a two-time deposition method, it is confirmed that the ordered patterns really form in the vacuum chamber. 相似文献
13.
Undoped and Al-doped 3C-SiC films are deposited on Si(100) substrates by low-pressure chemical vapour deposition. Effects of aluminium incorporation on crystallinity, strain stress, surface morphology and growth rate of SiC films have been investigated. The x-ray diffraction patterns and rocking curves indicate that the crystallinity is improved with aluminium doping. Raman scatting patterns also demonstrate that the strain stress in SiC films is released due to the incorporation of Al ions and the increase of film thickness. Furthermore, due to the catalysis of surface reaction which is induced by trimethylaluminium, the growth rate is increased greatly and the growth process varies from three-dimensional island-growth mode to step-flow growth mode. 相似文献
14.
I. John Berlin L.V. Maneeshya Jijimon K. Thomas P.V. Thomas K. Joy 《Journal of luminescence》2012,132(11):3077-3081
Al doped ZrO2 thin films were deposited on quartz substrates by sol–gel dip coating technique. X-ray diffraction pattern showed the deterioration of the crystallinity of the films with increase in Al doping concentration due to the formation of stress in the film. Scanning electron microscope images showed crack free surface. An average transmittance of >80% (in UV–vis region) was observed for all samples. Optical band gap was found to vary as a function of doping concentration. Photoluminescence spectra of the films exhibited an increase in the emission intensity with increase in Al doping concentration which is due to the increase in oxygen vacancies in the Al doped films. The “Blueshift” and “Redshift” of the PL spectra with increase in Al concentration originates from the change of stress in the films. The enhancement of PL intensity in the Al doped ZrO2 thin films make it suitable for generation of solid state lighting in light emitting diode. 相似文献
15.
Byeong-Yun Oh Jeong-Hwan KimJin-Woo Han Dae-Shik Seo Hwan Soo JangHo-Jin Choi Seong-Ho BaekJae Hyun Kim Gi-Seok HeoTae-Won Kim Kwang-Young Kim 《Current Applied Physics》2012,12(1):273-279
Structural, electrical, and optical properties of atomic layer-controlled Al-doped ZnO (ZnO:Al) films grown by atomic layer deposition (ALD) on glass substrates were characterized at various growth temperatures for use as transparent electrodes. The Al atomic content in ZnO:Al films increased due to the reduced ZnO film growth rate with increasing temperature. The preferred orientation of ZnO:Al films was changed, and the optimum condition for best crystallinity was identified by varying the growth temperature. Furthermore, the carrier concentration of free electron was increased by substituting the Zn sites with Al atoms in the crystal, resulting from monolayer growth based on alternate self-limiting surface chemical reactions. The electrical resistivity of ZnO:Al film grown by ALD at 225 °C reached the lowest value of 8.45 × 10−4 Ω cm, with a carrier mobility of 9.00 cm2 V−1 s−1 and optical transmittance of ∼93%. This result demonstrates that ZnO:Al films grown by ALD possess excellent potential for applications in electronic devices and displays as transparent electrodes and surface passivation layers. 相似文献
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Fournée V Sharma HR Shimoda M Tsai AP Unal B Ross AR Lograsso TA Thiel PA 《Physical review letters》2005,95(15):155504
We have investigated by scanning tunneling microscopy the growth of Bi and Ag thin films on the fivefold surface of Al63Cu24Fe13 and Al72Pd19.5Mn8.5 quasicrystal, respectively. For both systems, we observe the formation of islands with magic height, corresponding to the stacking of a specific number of atomic layers. We interpret this unusual growth morphology in terms of quantum size effects, arising from the confinement of the electron within the film. The magic island heights are thus a direct manifestation of the electronic structure of the quasicrystalline substrates. 相似文献
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J.J. Ding 《Applied Surface Science》2010,256(13):4304-1266
Al-doped ZnO (ZnO:Al) thin films with different Al contents were deposited on Si substrates using the radio frequency reactive magnetron sputtering technique. X-ray diffraction (XRD) measurements showed that the crystallinity of the films was promoted by appropriate Al content (0.75 wt.%). Then the ZnO:Al film with Al content of 0.75 wt.% was annealed in vacuum at different temperatures. XRD patterns revealed that the residual compressive stress decreased at higher annealing temperatures. While the surface roughness of the ZnO:Al film annealed at 300 °C became smoother, those of the ZnO:Al films annealed at 600 and 750 °C became rougher. The photoluminescence (PL) measurements at room temperature revealed a violet, two blue and a green emission. The origin of these emissions was discussed and the mechanism of violet and blue emission of ZnO:Al thin films were suggested. We concluded that the defect centers are mainly ascribed to antisite oxygen and interstitial Zn in annealed (in vacuum) ZnO:Al films. 相似文献
18.
The oxidation of the (100), (110) and (111) surfaces of the intermetallic compound FeAl has been investigated using LEED and XPS. On all three surfaces, oxidation at room temperature leads to the formation of an amorphous oxide film on top of an Al-depleted interlayer. The film growth can be divided into two regions of differing kinetics, i.e. the initial formation of a closed oxide film and a subsequent thickening. In the first region, the oxygen-uptake rate varies significantly with surface orientation, while in the thickening regime the uptake is the same for all surfaces. The maximum thickness as well as the composition of the oxide films were found to depend on the initial oxidation rate. At higher oxidation temperatures, ordered oxide films of around 5–8 Å in thickness are formed, very similar to those observed on NiAl. Photoemission spectra from these ordered phases showed evidence for Al atoms in two different chemical environments, i.e. the well-known oxide species in the interior of the film and an additional species present at the oxide/alloy interface. 相似文献