可激发气体分子声弛豫过程振动模式能量转移速率计算

研究可激发气体中振动模式能量转移速率和声弛豫过程形成的关系,将单一气体Tanczos弛豫方程理论[J.Chem.Phys.25,439(1956)]扩展应用于混合气体中振动模式的振动-振动(V-V)和振动-平动(V-T)能量转移速率的计算。在室温下CO₂,CH₄,CL₂,N₂和O₂组成的多种混合气体中,振动模式能量转移速率的计算结果表明:对于多个振动模式所形成的声复合弛豫过程,各振动模式的声激发能可由V-V能量转移相互耦合后传递给具有最快V-T转移速率的最低振动频率振动模式,再通过该振动模式的V-T转移退激发形成主弛豫过程。这种选择最快转移路径的声激发量弛豫方式,造成了大多数可激发气体中声弛豫吸收谱的实测数据只存在一个吸收峰的现象。从而提供了一个可通过计算微观振动能量转移速率分析混合气体声弛豫过程形成机理的理论模型。     

Calculation of vibrational energy transition rates in acoustic relaxation processes for excitable gas molecules

To research the correlation between vibrational energy transition rates and acoustic relaxation processes in excitable gases, the vibrational relaxation theory provided by Tanczos [J.Chem. Phys. 25, 439(1956)] is applied to calculate the energy transition rates of VibrationalVibrational(V-V) and Vibrational-Translational(V-T) energy transfer in gas mixtures. The results of calculation for the multi-relaxation processes in various gas mixtures, consisting of carbon dioxide, methane, chlorine, nitrogen, and oxygen at room temperature, demonstrate that the acoustic energy stagnated in every vibrational mode is coupled with each other through V-V energy exchanges. The vibrational excitation energy will relax through the V-T de-excitation path of the lowest mode because of its fastest V-T transition rate, resulting in that only one absorption peak can be measured for most of excitable gas mixtures. Thus, an effective model is provided to analyze how the vibrational energy transition rates affect the characteristics of acoustic relaxation processes and acoustic propagation in excitable gas mixtures.     

Experimental studies of applications of time-reversal acoustics to noncoherent underwater communications

The most difficult problem in shallow underwater acoustic communications is considered to be the time-varying multipath propagation because it impacts negatively on data rates. At high data rates the intersymbol interference requires adaptive algorithms on the receiver side that lead to computationally intensive and complex signal processing. A novel technique called time-reversal acoustics (TRA) can environmentally adapt the acoustic propagation effects of a complex medium in order to focus energy at a particular target range and depth. Using TRA, the multipath structure is reduced because all the propagation paths add coherently at the intended target location. This property of time-reversal acoustics suggests a potential application in the field of noncoherent acoustic communications. This work presents results of a tank scale experiment using an algorithm for rapid transmission of binary data in a complex underwater environment with the TRA approach. A simple 15-symbol code provides an example of the simplicity and feasibility of the approach. Covert coding due to the inherent scrambling induced by the environment at points other than the intended receiver is also investigated. The experiments described suggest a high potential in data rate for the time-reversal approach in underwater acoustic communications while keeping the computational complexity low.     

The pecularities of ultrasonic equipment design for stabilization of dispersed structures of alumosilicic reagents for wastewater treatment

Acoustic fields formed during operation of ultrasonic reactors with waveguides of following types: rod-type, cylindrical with rectangular protrusions and tubular were calculated and measured. The influence of distribution of acoustic fields arising from the operation of waveguide systems of three different types on the efficiency of ultrasonic activation of alumosilicic flocculant-coagulant and magnetite intended for water purification was investigated. It was shown that regardless of the equipment used on an industrial scale it is possible to reactivate the alumosilicic flocculant-coagulant even after the shelf life period of it passed, however in case of activation of magnetite the use of a bigger reactor in inefficient.In case of industrial scale processes, the choice of the correct reactor design is of significant importance, since it allows to reduce the required processing time, and, as a result, the energy consumption of the processes. The advantages of tubular waveguide systems include the possibility of processing large volumes of liquid. The high efficiency and uniformity of the excited ultrasonic fields can lead to reduction of operating costs. In case of smaller flows, the waveguide system with rectangular protrusions allowed to obtain better results.Our work illustrates the dependence of the success of a specific method on the choice of the waveguide and the size of the reactor during upscale.     

Process monitoring using ultrasonic sensor systems

Continuous in-line measurement of substance concentration in liquid mixtures is valuable in improving industrial processes in terms of material properties, energy efficiency and process safety. Ultrasonic sensor systems meet the practical requirements of a chemical sensor quite well. Currently ultrasonic sensor systems are widely used as acoustic chemical sensors to measure concentration of selected substances or to monitor the course of polymerisation, crystallisation or fermentation processes. Useable acoustic properties for the characterisation of liquid mixtures are sound velocity, sound absorption and acoustic impedance. This contribution will give a short overview of the state of the art and several trends for the use of ultrasonic sensor systems in process applications. Novel investigations show the very promising possibility to analyse liquid multi-phase mixtures like suspensions, emulsions and dispersions.     

Reconstruction of an acoustical image using an ‘acousto-electronic’ lens device

Present acoustic imaging apparatuses give only a virtual image of the insonified object. Several studies have been conducted in order to pick up the information from such an image, such as holography and computer data processing. These techniques are very involved, and so simpler processing systems have been analysed in our laboratory in order to reconstruct a true image. Our first system used optical processing of the acoustic echo. In this paper, a second, acousto-electronic, system is described, which enables like the first the attainment of very high image rates in the B-scan mode.     

Inelastic tunneling in a double quantum dot coupled to a bosonic environment

Coupling a quantum system to a bosonic environment always give rise to inelastic processes, which reduce the coherency of the system. We measure energy-dependent rates for inelastic tunneling processes in a fully controllable two-level system of a double quantum dot. The emission and absorption rates are well reproduced by Einstein's coefficients, which relate to the spontaneous emission rate. The inelastic tunneling rate can be comparable to the elastic tunneling rate if the boson occupation number becomes large. In the specific semiconductor double dot, the energy dependence of the inelastic rate suggests that acoustic phonons are coupled to the double dot piezoelectrically.     

Performance of a quarter-wavelength particle concentrator

A series of devices have been investigated which use acoustic radiation forces to concentrate micron sized particles. These multi-layered resonators use a quarter-wavelength resonance in order to position an acoustic pressure node close to the top surface of a fluid layer such that particles migrate towards this surface. As flow-through devices, it is then possible to collect a concentrate of particulates by drawing off the particle stream and separating it from the clarified fluid and so can operate continuously as opposed to batch processes such as centrifugation. The methods of construction are described which include a micro-fabricated, wet-etched device and a modular device fabricated using a micro-mill. These use silicon and macor, a machinable glass ceramic, as a carrier layer between the transducer and fluid channel, respectively. Simulations using an acoustic impedance transfer model are used to determine the influence of various design parameters on the acoustic energy density within the fluid layer and the nodal position. Concentration tests have shown up to 4.4-, 6.0- and 3.2-fold increases in concentration for 9, 3 and 1 microm diameter polystyrene particles, respectively. The effect of voltage and fluid flow rates on concentration performance is investigated and helps demonstrate the various factors which determine the increase in concentration possible.     

Applications of sonochemistry in Russian food processing industry

In food industry, conventional methodologies such as grinding, mixing, and heat treatment are used for food processing and preservation. These processes have been well studied for many centuries and used in the conversion of raw food materials to consumable food products. This report is dedicated to the application of a cost-efficient method of energy transfer caused by acoustic cavitation effects in food processing, overall, having significant impacts on the development of relatively new area of food processing such as food sonochemistry.     

Comparison of energy consumptions between ultrasonic, mechanical, and combined soil washing processes

Vigorous physical effects including micro-jet and micro-streaming can be induced in heterogeneous systems by acoustic cavitation. This can be useful for the removal of pollutants from contaminated soil particles. In this study, the diesel removal efficiencies in ultrasonic, mechanical, and combined soil washing processes have been compared considering the electrical energy consumptions for these processes. The combined process showed synergistic effects for both removal efficiency and effective volume also has the advantage of a short operation time compared to the sequential processes. Thus the ultrasonic soil washing process with mechanical mixing is considered a promising technology for industrial use.     

Matching a transducer to water at cavitation: acoustic horn design principles

High-power ultrasound for several decades has been an integral part of many industrial processes conducted in aqueous solutions. Maximizing the transfer efficiency of the acoustic energy between electromechanical transducers and water at cavitation is crucial when designing industrial ultrasonic reactors with large active volumes. This can be achieved by matching the acoustic impedances of transducers to water at cavitation using appropriately designed ultrasonic horns. In the present work, a set of criteria characterizing the matching capabilities of ultrasonic horns is developed. It is shown that none of the commonly used tapered-shape horns can achieve the necessary conditions. An analytical method for designing five-element acoustic horns with the desirable matching properties is introduced, and five novel types of such horns, most suitable for practical applications, are proposed. An evaluation of the horns' performance is presented in a set of experiments, demonstrating the validity of the developed theoretical methodology. Power transfer efficiency increase by almost an order of magnitude is shown to be possible with the presented horn designs, as compared to those traditionally utilized.     

Piecewise coherent mode processing of acoustic data recorded on two horizontally separated vertical line arrays

Motivated by measurements made in the 2004 Long-Range Ocean Acoustic Propagation Experiment (LOAPEX), the problem of mode processing transient acoustic signals collected on two nearby vertical line arrays is considered. The first three moments (centroid, variance, and skewness) of broadband distributions of acoustic energy with fixed mode number (referred to as modal group arrivals) are estimated. It is shown that despite the absence of signal coherence between the two arrays and poor high mode number energy resolution, the centroid and variance of these distributions can be estimated with tolerable errors using piecewise coherent mode processing as described in this paper.     

激光声信号的频谱特性

构建了激光声实验测量系统,利用脉冲激光聚焦击穿水介质产生声信号,由水听器将声信号转换成电信号并送入数字存储示波器。分析了激光声信号的时频域数学模型,实验研究了激光声信号的频域能量分布,以及激光器重复频率和激光声信号频谱特性的关系。结果表明:激光声信号能量主要集中在200 kHz内,其中100~200 kHz内的能量所占比例约50%。激光声信号的幅频响应极大值点可以受到激光器重复频率的控制。     

激光声信号的频谱特性

构建了激光声实验测量系统,利用脉冲激光聚焦击穿水介质产生声信号,由水听器将声信号转换成电信号并送入数字存储示波器。分析了激光声信号的时频域数学模型,实验研究了激光声信号的频域能量分布,以及激光器重复频率和激光声信号频谱特性的关系。结果表明:激光声信号能量主要集中在200 kHz内,其中100~200 kHz内的能量所占比例约50%。激光声信号的幅频响应极大值点可以受到激光器重复频率的控制。     

Liquid crystal thermography and true-colour digital image processing

In the last decade thermochromic liquid crystals (TLC) and true-colour digital image processing have been successfully used in non-intrusive technical, industrial and biomedical studies and applications. Thin coatings of TLCs at surfaces are utilized to obtain detailed temperature distributions and heat transfer rates for steady or transient processes. Liquid crystals also can be used to make visible the temperature and velocity fields in liquids by the simple expedient of directly mixing the liquid crystal material into the liquid (water, glycerol, glycol, and silicone oils) in very small quantities to use as thermal and hydrodynamic tracers. In biomedical situations e.g., skin diseases, breast cancer, blood circulation and other medical application, TLC and image processing are successfully used as an additional non-invasive diagnostic method especially useful for screening large groups of potential patients. The history of this technique is reviewed, principal methods and tools are described and some examples are also presented.     

A computer simulation study of compressor tuning phenomena

Basic thermofluid processes of a positive displacement compressor are strongly dependent upon the acoustic behavior of the manifolds. The tuning process of such a compressor is fairly complex as increases in the mass flow rate may not correspond with higher energy efficiencies. In this paper a computer simulation program is described, which includes the manifold back pressure effect, developed to investigate and explain the tuning phenomena for a single or two-cylinder reciprocating compressor. A symmetric suction manifold system for a two-cylinder refrigeration compressor has been considered as the example case in this tuning study. Results for flow efficiency, energy efficiency, and pressure pulsations at the valve exit are presented in terms of the acoustic natural frequencies of the manifold system. Predicted results compare reasonably well with experimental data. Based on this study, it is possible to choose optimal manifold dimensions which will provide higher efficiencies with lower pressure pulsations.     

A power ultrasonic technology for deliquoring

Solid-liquid separation is a topic of permanent interest in many areas such as mineral recovery, food processing and sewage disposal. The adequate application of high-intensity ultrasonic fields may contribute to improve the efficiency of conventional deliquoring processes. Deliquoring refers to removal of liquid from a product without changing its phase.Different effects are involved in the application of high-intensity ultrasound for deliquoring, the most important of which are: the alternating acoustic stresses, the radiation pressure, the acoustic streaming, interface instabilities and cavitation. One of the main advantages of the ultrasonic energy in deliquoring processes is its ability to release the strongly bound moisture.This paper deals with the application of an ultrasonic procedure for deliquoring of slurries in which a high-intensity vibration, homogeneously distributed, is directly applied to the wet particulate material. The vibration travels through the solid-liquid medium and the rapid series of alternative compressions and rarefactions produce a kind of "sponge effect" which favours the migration of moisture through natural or acoustically created channels.The obtained results show that the new technique is very promising to assist filtration processes for solid-liquid separation of highly concentrated suspensions of fine particles.     

Energy relaxation by hot carriers in wurtzite GaN epilayers

In this paper, we report hot carrier energy relaxation processes studied by acoustic phonon emission in wurtzite GaN epilayers, using the heat pulse technique. In this method, the carriers were heated up by means of short (≈ 10 ns) voltage pulses and emitted phonons were detected by Al bolometers biased at their superconducting transition. Obtained phonon signals indicate that the optical phonon emission threshold has not been reached and longitudinal acoustic and transverse acoustic modes can be clearly resolved. This paper specifically concentrates on the electron temperature dependence of the energy relaxation rates and compares the experimental results with the existing theory.     

Scattering light by short acoustic pulses in a crystalline collinear cell and coherent processing of ultra-high frequency radio-wave electronic pulses

We present the study of collinear light scattering by relatively short acoustic pulses in birefringent crystals providing that both the acoustic attenuation and spreading the acoustic beam are allowed for. The exact and closed analytical model for the phenomenon described is developed. The peculiarities of collinear acousto-optical interaction in the cells made of lithium niobate single crystal are considered for the traveling-wave regime. The feasibility of applying such an effect to perform a coherent optical processing of ultra-high frequency (UHF) radio-wave electronic pulses is analyzed and the corresponding opto-electronic algorithm is elaborated. The results of preliminary experiments, exhibiting an opportunity for the data processing in anti-radar system, are presented.     

Broadband planar nearfield acoustic holography based on one-third-octave band analysis

Planar nearfield acoustic holography (PNAH) is usually based on narrow-band, single frequency analysis, which is time consuming when the source behavior over a broad frequency range is of interest, as is the case with many industrial sources. In this paper a method, broadband planar nearfield acoustic holography based on one-third-octave band analysis (BPNAH), is described. Data relating to the complex band pressure on the hologram is obtained by combining the root-mean-square pressure corresponding to a one-third-octave band with the phase of the pressure corresponding to a single frequency line. Numerical simulations and measurements show that the BPNAH method allows a significant reduction in processing time, while keeping a similar accuracy to the conventional reconstruction, which is based on the summation of frequency by frequency in the corresponding band. As a simple, time-saving and robust technique, the BPNAH method is particularly well adapted to industrial studies.