Sxaps spectra of pyrolytic graphite as a function of the angle of incidence of the incoming electrons

Soft X-ray appearance potential (SXAPS) spectra of pyrolytic graphite as a function of the angle of incidence of the incoming electrons have been measured to obtain information about surface plasmon excitation. Plasmons can be coupled with a core hole and two slow electrons above the Fermi level or with a fast incoming electron. In the last case angular dependent plasmon excitation can be observed. Coupling with the fast incoming electron is observed, but band structure effects cannot be neglected to explain the observed structure. Measurements were performed on clean and hydrogen-contaminated pyrolytic graphite. A signal increase over the whole spectrum was observed after hydrogen contamination, probably due to a rearrangement of the surface lattice structure. Bombardment of the surface with electrons of 2 keV gave a decrease in spectral intensity probably due to surface damage.     

Comparison of light rare earths N4,5-level soft X-ray and auger electron appearance-potential spectra

Appearance-potential Spectroscopy (APS) probes the binding energy of core levels and local conduction band states of atoms in the surface region. Soft X-ray APS (SXAPS) and Auger electron APS (AEAPS), respectively, measure the differential X-ray fluorescence and secondary electron yields as a function of incident electron energy. We have obtained the N_4,5-level SXAPS and AEAPS spectra of La, Ce, Pr, Nd and Sm metals. Both spectra exhibit multiplet structure below the expected 4d excitation threshold and a broad, 10–20 eV wide peak above the threshold followed by small peaks of decreasing intensity. The data are used to gain an understanding of the decay mechanism following the excitation of the core levels in these spectroscopies. The strong similarity observed between the SXAPS and AEAPS indicates that the characteristic emission and not the bremsstrahlung dominates the spectral lineshape in APS.     

Electronic structure of lithium graphite

X-ray photoemission spectra of vacuum cleaved LiC₆, prepared from highly oriented pyrolytic graphite, provide a direct measure of the filling of the graphite π bands by electrons from Li. The resulting Fermi energy shift is in agreement with recent band structure calculations and indicates near unity charge transfer from Li. Core level spectra exhibit shifts compatible with the expected charge transger and line shapes showing strong asymmetries resulting from the metallic character of this compound.     

On the electronic structure of graphite

Comprehending investigations of the electronic structure of polycrystalline as well as monocrystalline graphite have been performed by means of X-ray emission, self absorption and X-ray induced photoemission techniques. On the basis of these combined investigations a model for the determination of the relative cross sections for the photoemission process has been established and applied to graphite, where it yields _s / _p =32. The anisotropy and polarization of the CK-radiation of monocrystalline graphite is discussed in terms of the binding properties of the graphite lattice. The predictions are verified by measurements of the CK-emission employing a crystal monochromator which acts simultaneously as a nearly perfect analyzer for the polarization of the monochromatized radiation. By means of the self absorption technique the unoccupied part of the conduction band has been investigated.     

Hard X-ray photoelectron spectroscopy from 5-14.5 keV

Photoemission spectroscopy at high energies can be used to probe bulk electronic states. We used a specially designed high-voltage retarding lens and a commercial Perkin-Elmer PHI 10-360 hemispherical electron analyzer to investigate the core and valence band region of Au, YBa₂Cu₃O_7−δ and highly oriented pyrolytic graphite samples with hard X-rays in the energy range 5-14.5 keV. The overall instrumental resolution obtained at 8 keV was 218 meV. The photo ionization cross-sections for Au 5d and 6s excitations were determined experimentally. In comparison with published calculations for atomic cross-sections neglecting corrections for angular anisotropy, the values we find are twice as large for the 5d and an order of magnitude larger for the 6s (conduction band) level. Our results demonstrate the feasibility of bulk sensitive valence band spectroscopy with high resolution at high brilliance X-ray sources such as the ESRF. The measured cross-sections provide important input for improving current theoretical models.     

On the influence of oxygen on the valence band shape of carbon measured by XPS

XPS-spectra of the valence band of pyrolytic graphite with different amounts of contamination by oxygen have been investigated. The strong influence of oxygen on the XPS-spectra is discussed in terms of adsorbed as well as chemisorbed oxygen. A carbon valence band shape free from distortion by oxygen is presented.     

Manifestation of auger processes in C1s-satellite spectra of single-walled carbon nanotubes

Using the equipment of the Russian-German beamline of the synchrotron radiation at the BESSY II electron storage ring, satellite spectra accompanying the C1s core lines in the cases of single-walled carbon nanotubes and highly ordered pyrolytic graphite have been measured with a high energy resolution. The Auger spectra corresponding to shaking of the valence system of carbon by the core vacancy have been found and investigated. The Auger spectra of the studied single-walled carbon nanotubes and highly ordered pyrolytic graphite are caused by annihilation of the excited π* electron with a hole in the π subband. It has been established that the electron states in the conduction band have 3π* (gT, K, M) symmetry; i.e., they correspond to flat 3π* subband, which is localized by 12–13 eV above the Fermi level. It has been revealed that the general regularities of the distribution of electron states in the valence system insignificantly change during its shake-up by the excited core.     

Theory for the 2p-shell sxaps for the 3d-transition metals

The 2p-shell Soft X-Ray Appearance Potential Spectra (SXAPS) of the 3d-transition metals have been described as a scattering process whereby both the impinging and the 2p-core electrons go into the empty conduction band states above the Fermi level (E_F) of the metals. It is shown that the resonant contribution to the ordinary bremsstrahlung emission process can be of comparable importance to the usual characteristic one.     

A spectroscopic study of CNx formation by the keV N2 irradiation of highly oriented pyrolytic graphite surfaces

Amorphous carbon nitride (CN_x) thin layer, formed by the keV N₂⁺ irradiation of highly oriented pyrolytic graphite, has been investigated using X-ray photoelectron and raman spectroscopies, and time-of-flight secondary ion mass spectrometry. C1s X-ray photoelectron spectroscopy (XPS) peak separations indicate that C-N bonds form over and above the graphite fragmentation previously obtained on Ar⁺ irradiation. N1s XPS peak separations indicate three components. Their attributions, and the resultant CN_x structure, are confirmed by angle-resolved XPS and TOF-SIMS analyses.     

Soft X-ray appearance potential spectroscopy (SXAPS) study of TiO2(1 1 0)-1 × 2 and (0 0 1)-1 × 1 surfaces

A soft X-ray appearance potential spectroscopy (SXAPS) apparatus with high sensitivity was built to measure non-derivative spectra. SXAPS spectra (non-derivative) of Ti 2p and O 1s for TiO₂(1 1 0)-1 × 2 and (0 0 1)-1 × 1 surfaces have been measured using low incident currents (about 10 μA/cm²) and a photon counting mode. Density of empty states on Ti and O sites are deduced by self-deconvoluting the spectra. The self-deconvoluted SXAPS spectra are qualitatively similar to those measured by X-ray absorption spectroscopy (XAS). The Ti 2p_3/2 spectrum shows two strong peaks which correspond to t_2g and e_g states. For the O 1s spectrum two strong peaks near the threshold are also found which can be ascribed to O 2pπ and O 2pσ states. These results suggest that the spectra almost obey the dipole selection rule, so-called the “approximate dipole selection rule”. The SXAPS spectra of Ti 2p and O 1s for the (1 1 0) and (0 0 1) surfaces resemble qualitatively, which is consistent with the XAS results. The spectra measured on the (1 1 0)-1 × 2 surface at an incident angle of 45° off normal to the surface and on the (1 1 0) surface sputtered by Ar ions indicate that SXAPS is very sensitive to the surface electronic states.     

Spin splitting in HgTe/CdHgTe (013) quantum well heterostructures

The electron transport and cyclotron resonance in a one-sided selectively doped HgTe/CdHgTe (013) heterostructure with a 15-nm quantum well with an inverted band structure have been investigated. The modulation of the Shubnikov-de Haas oscillations has been observed, and the spin splitting in zero magnetic field has been found to be about 30 meV. A large Δm _c/m _c ≃ 0.12 splitting of the cyclotron resonance line has been discovered and shown to be due to both the spin splitting and the strong nonparabolicity of the dispersion relation in the conduction band.     

Correlation of selected core-level spectroscopies

Spectral characteristics representing the distribution of unoccupied conduction-band states in the 3d transition-series metals Fe, Co, Ni and Cu, obtained using soft X-ray absorption (SXA), bremsstrahlung isochromat (BI) and characteristic isochromat (CI) methods, are related mathematically to those found in soft X-ray appearance-potential Spectroscopy (SXAPS) on the basis of the one-electron band approximation. These mathematical relationships are used to compute SXAPS spectra from reported experimental data obtained by the SXA, BI and CI methods. For the metals considered, the correlations between the computed and experimental SXAPS spectra are found to be good. The observed discrepancies are attributed to differences in the selection rules of the excitation processes, to the effect of the core vacancy on the final state, and to many-body phenomena which are not included in the simplified one-electron band model.     

The density of unoccupied electronic states in copper

The density of unoccupied electronic states in Cu has been measured employing soft X-ray appearance-potential spectroscopy (SXAPS). The L_III le     

Band reject filtration of the excitation spectrum at energy dispersive X-ray spectroscopy of weak signals

The possibility of the efficient band reject filtration of the continuous X-ray excitation spectrum in the energy range E ≥ 8 keV is demonstrated. This makes it possible to strongly increase the sensitivity of energy dispersive X-ray spectroscopy at detecting of weak fluorescence lines. Spectral rejection is implemented by transmitting a primary beam through highly oriented pyrolytic graphite with given structural parameters. Diffraction extinction in pyrolytic graphite ensures the possibility of reducing the intensity by more than 20 dB and rejecting the spectral band with a width of ~1 keV. The reduction of statistical fluctuations of the background of elastically scattered radiation is achieved when the bottom of the formed spectral valley is adjusted to the analyzed fluorescence line. The proposed scheme of band reject filtration also allows the suppression of intense characteristic lines in the primary and scattered radiation spectra.     

Critical point energies from appearance potential spectra of cobalt,nickel, and copper

Structural features in soft X-ray appearance potential spectra (SXAPS) of cobalt, nickel, and copper previously assigned to collective excitations are shown to be due to corresponding structure in the s-p like density of states of these metals. By reference to theoretical work the critical points in the f.c.c. Brillouin zone responsible for these features are identified and experimental critical point energies are derived and compared to various band structure calculations.     

Specific features of the electronic structure of the CeCu<Subscript>6</Subscript>, CePd<Subscript>3</Subscript>, CeSi<Subscript>2</Subscript>, and CeF<Subscript>3</Subscript> systems

The electronic structure of cerium systems, the hybridization of 4 f and outer-shell electrons, and the influence of the position of the localized 4 f level with respect to the Fermi level E _F in the conduction band have been investigated. The CeCu₆, CePd₃, CeSi₂, and CeF₃ systems have been studied using X-ray photoelectron spectroscopy. The densities of states have been calculated by the tight-binding linearized muffin-tin orbital method within the atomic sphere approximation, which takes into account the covalent character of bonds and the nonspherical distribution of the electron density. The results obtained from the calculations of the total density of states are in good agreement with the valence band X-ray photoelectron data for the systems under investigation. It has been shown that the differences in the properties of the cerium systems are determined by the specific features of their electronic structure. A strong interatomic interaction is characteristic of heavy-fermion systems.     

Electronic structure of Al2O3 from electron energy loss spectroscopy

The electronic structure of Al₂O₃ has been studied by electron energy loss spectroscopy (ELS), and an energy level model of both filled and empty states has been constructed from the ELS and available optical data. For the high temperature pyrolytic α-polycrystalline Al₂O₃ films, the transitions are assumed to originate at the two principal peaks in the valence band density of states and the O(2s) core state, and to terminate on two peaks within the conduction band density of states. We also report energy loss spectra due to excitations out of the deeper Al(2p), Al(2s), Al(1s), and O(1s) core levels. The excitations originating at the Al(2p), Al(2s), and Al(1s) core levels terminate on levels in the conduction band and on an exciton lying about 1 eV below the conduction-band edge.     

MBE GaAs1-xSbx/GaAs应变层量子阱的光调制反射光谱

本文采用光调制反射光谱技术研究了MBE GaAs_1-xSb_x/GaAs应变层量子阱。通过实验分析和理论上对受应力作用后能带结构的估算,确认在这一系统中流体静压力作用引起的能带结构变化主要出现在导带上,同时也证实了GaAs_1-xSb_x/GaAs应变层量子阱属于第Ⅱ型量子阱结构。实验结果与理论估算符合很好。 关键词：     

X-ray C K-emission band spectra of graphite fluoride

X-ray C K-emission band spectra of graphite fluoride were measured for the first time by the use of the electron beam excitation. The problem of first importance in obtaining X-ray spectra was the decomposition of graphite fluoride induced by electron beams. The decomposition of the samples during the measurements was controlled by moving the samples at a constant rate. The spectra thus measured showed strong high energy satellite bands. Peak positions of these satellites were 5 eV and 8 eV higher relative to that of the main band. Each satellite was considered to be attributable to the CF and CF₂ bonding, respectively. A similar spectrum was obtained from graphite fluoride, (C₂F)_n. Owing to the zig-zag form of the C-C bond, the polarization of the C K-emission bands of well-ordered flaky graphite fluorides was not observed distinctly.