Polarization spectroscopy of the E0g+-B0u+ band system of Br2

The E-B (0_g⁺-0_u⁺) band system of Br₂ has been investigated at Doppler-limited resolution using polarization labeling spectroscopy. Merged E state data for the three naturally occurring isotopes in the range v_E = 0–16, expressed in terms of the constants for ⁷⁹Br₂, are (in cm^?1) Y_0,0 = 49 777.962(54), Y_1,0 = 150.834(22), Y_2,0 = ?0.4182(28), Y_3,0 = 6.6(11) × 10^?4, Y_0,1 = 4.1876(28) × 10^?2, Y_1,1 = ?1.607(16) × 10^?4, and Y_0,2 = 1.39(39) × 10^?8. The bond distance is $\text{r}{}_{\mathrm{<mtext>e</mtext>}}\text{= 3.194}\text{A}\text{?}$, and the diabatic dissociation energy to $\text{Br}{}^{\mathrm{+}}\text{(}{}^3\text{P}{}_2\text{) +}\text{Br}{}^{\mathrm{?}}\text{(}{}^1\text{S}{}_0\text{)}\text{is 34 700 cm}{}^{\mathrm{?1}}$.     

Vibrational spectra and force constants of symmetric tops: High resolution spectra of monoisotopic H3SiCl in the 2200-cm−1 region and rovibrational analysis of the ν1 and ν4 fundamentals

The gas phase infrared spectra of monoisotopic H₃Si³⁵Cl and H₃Si³⁷Cl have been studied in the $\text{ν}{}_1\text{ν}{}_4$ region near 2200 cm^?1 with a resolution of 0.012 and 0.04 cm^?1, respectively, and rotational fine structure for ΔJ = ±1 branches has been resolved. In addition, some information on ν₃ + ν₄ of H₃Si³⁵Cl near 2750 cm^?1 has been obtained. ν₁ and ν₄ are weakly coupled by Coriolis x, y resonance, $\text{B}\text{Ω}{}_{14}\text{ζ}{}_{14}\text{～ 2 × 10}{}^{\mathrm{?3}}\text{cm}{}^{\mathrm{?1}}$, only the upper states K′ = 2, l = 0 and K′ = 1, l = ?1 being substantially affected. Local perturbation due to rotational l(±1, ±1)-type resonance with ν₃ + ν₅⁺¹ + ν₆⁺¹ and ν₃ + ν₅⁺¹ + ν₆^?1 is revealed in the ΔK = +1 and ?1 branches, respectively. From a fit of the experimental line positions, standard deviations of 1.4 and 3.8 × 10^?3 cm^?1, respectively, to a model with five interacting levels conventional excited state parameters and interaction constants have been obtained. In $\text{H}{}_3\text{Si}{}^{35}\text{Cl}\text{H}{}_3\text{Si}{}^{37}\text{Cl}$ the fundamentals are ν₁, $\text{2201.94380(15)}\text{2201.9345(7)}$ and ν₄, $\text{2209.63862(8)}\text{2209.6254(2)}\text{cm}{}^{\mathrm{?1}}$, respectively. Q branches of the “hot” band (ν₃ + ν₄) ? ν₃ and of ν₄ of the ²⁹Si and ³⁰Si species have been detected.     

Ω− produced in K−p reactions at 4.2 GeV/c

Forty $\text{Ω}{}^{\mathrm{?}}$ events have been observed in a large (133 events/βb) experiment at 4.2 GeV/c incident K^? momentum. Thirty nine of the events come from the three-body reaction $\text{K}{}^{\mathrm{?}}\text{p}\text{→Ω}{}^{\mathrm{?}}\text{K}{}^{\mathrm{+}}\text{K}{}^0$. The $\text{Ω}{}^{\mathrm{?}}$ is mainly produced in the forward hemisphere (direction of the incident K^?). The lifetime is measured to be τ = (0.75 _+0.14?0.11 × 10^?10 sec substantially less than the Particle Data Group value of (1.3 _?0.3^+0.2) × 10^?10 sec. The mass is determined to be 1671.7 ± 0.6 MeV, in good agreement with other determinations. The decay asymmetry parameter α (for the decay mode $\text{Ω}{}^{\mathrm{?}}\text{→ Λ}\text{K}{}^{\mathrm{?}}$) is found to be ?0.2 ± 0.4.     

SIMS,AES, work function and flash desorption measurements of the CO adsorption on NiCu alloy surfaces

The chemisorption of CO on Cu, Ni and CuNi alloy surfaces was examined by SIMS, work function measurements and desorption spectroscopy. Using a dynamic SIMS technique the M⁺, M⁺₂, MCO⁺ and M₂CO⁺ emission at different temperatures (100–400 K) was measured as a function of CO exposure. In agreement with the work function and desorption experiments an increase of M⁺ and MCO⁺ emission due to the CO adsorption on Cu was found only at low temperatures (100–190 K). On the Ni surface an increase of Ni⁺, NiCO⁺ and Ni₂CO⁺ was measured up to 400 K. The adsorption of CO on CuNi alloy surfaces — as derived from the work function measurements — can be described by the assumption of two different states of adsorbed carbon monoxide. They can be characterized by different binding energies and from sign and magnitude different work function changes. These states were interpreted as adsorption at Ni or Cu sites of the alloy surfaces, respectively. To a certain extent the SIMS results from the alloy surfaces are incompatible with the work function measurements and desorption spectroscopy and the SIMS studies on the pure metals. A Cu⁺ emission with comparable intensity to the Ni⁺ emission was found for alloys with bulk concentrations of 60 and 40 at% Cu at 300 K. The ratio $\text{Ni}{}^{\mathrm{+}}\text{Cu}{}^{\mathrm{+}}$ was nearly independent of CO pressure and temperature. The measured ratios of $\text{Cu}{}^{\mathrm{+}}{}_2\text{(}\text{Cu}{}^{\mathrm{+}}\text{+}\text{Ni}{}^{\mathrm{+}}\text{)}$, $\text{Ni}{}^{\mathrm{+}}{}_2\text{(}\text{Cu}{}^{\mathrm{+}}\text{+}\text{Ni}{}^{\mathrm{+}}\text{)}$ and $\text{CuNi}{}^{\mathrm{+}}\text{(}\text{Cu}{}^{\mathrm{+}}\text{+}\text{Ni}{}^{\mathrm{+}}\text{)}$ with values about 10^?2 can be explained the basis of a statistical arrangement of Cu and Ni atoms in the alloy surface. The intensities of the MCO⁺ emissions are 10² times smaller than the corresponding values of the pure metals. No emission of M₂CO⁺ was found on CuNi during CO adsorption.     

Search for 4n IN π− double charge exchange reactions with heavy nuclei

A search for the existence of the tetraneutron has been made using the double charge exchange reaction $\text{π}{}^{\mathrm{?}}\text{+}{}^{208}\text{Pb}\text{→}{}^4\text{n + π}{}^{\mathrm{+}}\text{+}$ residuals for ⁴n production and the capture process in the same target, ${}^{208}\text{Pb}\text{+}{}^4\text{n}\text{→}{}^{212}\text{Pb}\text{+ γ}$, for the ⁴n detection. No event has been found, giving an upper limit for the product of the production cross section σ_p, the detection cross section σ_d and the ⁴n lifetime τ. Assuming 10^?18 ≦ τ ≦ 10^?9 sec it follows that σ_pσ_dτ ≦ 2.5 × 10^?65cm⁴ sec with 90 % confidence, and for $\text{τ ≧ 10}{}^{\mathrm{?9}}\text{sec}\text{, σ}{}_{\mathrm{<mtext>p</mtext>}}\text{σ}{}_{\mathrm{<mtext>d</mtext>}}\text{≦ 2.5 × 10}{}^{\mathrm{?56}}\text{cm}{}^4$ with 90 % confidence. The magnitude of this value is comparable to the experimental limit of the ⁴He(π^?, π⁺)⁴n cross section.     

Weak decays of the charmed baryon C0+ and the inclusive yield of Λ and p

We calculate the decay rates of the charmed baryon state C₀⁺(2.26) into 25 two body and quasi two body states involving baryons and mesons with $\text{J}{}^{\mathrm{P}}\text{=}\text{1}\text{2}{}^{\mathrm{+}}\text{,}\text{3}\text{2}{}^{\mathrm{+}}\text{, 0}{}^{\mathrm{?}}\text{and}\text{1}{}^{\mathrm{?}}$. These modes yield a width of Γ = 16.3 × 10¹²s^?1and an inclusive yield of $\text{Λ/}\text{p}\text{? 40\%}$.     

A study of valency changes of vanadium ions in Al2O3 by γ irradiation

The effect of γ irradiation at 300 K on the concentrations of vanadium ions V³⁺, V⁴⁺ and V²⁺ in Al₂O₃ has been studied quantitatively, using three techniques: optical absorption (V³⁺), low temperature thermal conductivity measurements (V⁴⁺) and EPR (V²⁺). Several single crystals of Al₂O₃ doped with vanadium in a large range of concentration $\text{(2.8 × 10}{}^{18}\text{? 1.3 × 10}{}^{20}\text{at.}\text{cm}{}^3\text{)}$ have been measured. The evolution of the respective concentrations by γ irradiation as a function of the total vanadium content C is quite different in the two regions $\text{C< 1.2 × 10}{}^{19}\text{at.}\text{cm}{}^3$ and C larger than this value. A consistent analysis of the results has nevertheless been achieved, leading to the determination of the absolute concentrations of the three ions in the as-received and γ irradiated states for all samples with $\text{C<4.2 × 10}{}^{19}\text{at.}\text{cm}{}^3$ (room temperature annealing is observed above this value). The concentrations of V⁴⁺ and V²⁺ ions are always small, but V⁴⁺ ions are more stable: they are present in the as-received state at a level of 1% of the total concentration and a maximum value of $\text{/}\text{?}\text{2.3 × 10}{}^{18}\text{at.}\text{cm}{}^3$ is observed in the γ irradiated state; on the other hand there are less than 4.7 × 10¹⁵V²⁺ ions per cm³ in the as-received state and the maximum value is only $\text{4.2 × 10}{}^{17}\text{at.}\text{cm}{}^3$. Charge transfer between V ions only is not sufficient to explain the experimental results and other defects must be involved in the γ irradiation effect.     

Direct observations of the behavior of single silicon atoms on a metal surface

The behavior of single silicon adatoms on the W {110} plane has been successfully studied for the first time. Single atom diffusion parameters are found to be E_d = 0.70 ± 0.07 eV, and $\text{d}{}_0\text{= 3.08 × 10}{}^{\mathrm{?4}}\text{× 10}{}^{\mathrm{\pm 1.28}}\text{solcm}{}^2\text{s}$. The field desorption behavior of Si atoms is similar to that of metal adatoms. SiSi adatom-adatom interaction shows nonmonotonic distance dependence, but the repulsive region around 3.2 Å is much weaker than those found in metal adatom interactions.     

The rotational spectrum of the X 2Σ+ state of the SrF radical using laser microwave optical double resonance

The pure rotational spectrum of the $\text{X}{}^2\text{Σ}{}^{\mathrm{+}}$ state of the gaseous SrF radical has been measured using microwave optical double resonance (MODR) techniques. The analysis fully confirms the recent dye laser excitation spectrum and rotational assignment of the $\text{B}{}^2\text{Σ}{}^{\mathrm{+}}\text{-X}{}^2\text{Σ}{}^{\mathrm{+}}$ system. Transitions were measured in both the v″ = 0 and v″ = 1 states to give values of B_e″ = 0.250533 cm^?1, α_e″ = 1.546 × 10^?3 cm^?1 and γ″ (spin-rotation) = 2.49 × 10^?3 cm^?1. General qualitative features of MODR in ²Σ⁺ states are treated and suggested improvements for obtaining experimental hyperfine constants are discussed. The more precise ground state constants are merged with the B-X optical analysis to obtain a more accurate set of constants for both states.     

Energy levels of interstitial manganese in silicon

Interstitial manganese in silicon can exist in four charge states which imply single acceptor and double donor behaviour. The corresponding level scheme with the acceptor level ($\text{Mn}{}^{\mathrm{<mtext>?</mtext><mtext>0</mtext>}}$) at E_c-0.13eV, the first donor level ($\text{Mn}{}^{\mathrm{<mtext>0</mtext><mtext>+</mtext>}}$) at E_c?0.45eV and the second donor level (Mn^+/++) at E_v+0.30eV is established through EPR-controlled Hall measurements. Another deep donor level at E_c?0.54eV is produced by the donor acceptor pair (MnB) whereas a more shallow one around E_c-0.28eV was already attributed to a Mn₄-cluster.     

Positron production by muon neutrinos BEBC filled with a neon-hydrogen mixture

For e⁺ energy > 0.3 GeV and 10 GeV < visible energy < 100 GeV we find that: (i) $\text{? = (v}{}_{\mathrm{\mu }}\text{+}\text{Ne}\text{→ μ}{}^{\mathrm{?}}\text{e}{}^{\mathrm{+}}\text{)/(v}{}_{\mathrm{\mu }}\text{+}\text{Ne}\text{→ μ}{}^{\mathrm{?}}\text{) = (0.41 ± 0.15)\%}$; (ii) 1.2 ± 0.5 neutral strange particles are produced per μ^?e⁺ event; (iii) the lifetime of possible positron-parent particles is < 3 × 10^?10 s (90% C.L.); (iv) the cross section for direct e⁺ production via the neutral current is < 0.2 times that via the charged current (90% C.L.); (v) the cross section for producing heavy leptons, L⁺, decaying into e⁺ … is < 0.7 × 10^?3 times that for μ^?production, implying M(L⁺) > 10 GeV.     

Study of neutrino-indiced dimuon events in gargamelle at CERN SPS

This letter reports a study of 117 opposite-sign and 41 like-sign dimuons, in a wide-band neutrino exposure of Gargamelle at CERN SPS. No signal is found in the μ^?μ^? channel. The μ^?μ⁺ channel is found to be dominated by D-meson production and decay. There is evidence in these events for missing energy which may be interpreted as an unseen neutrino. The V⁰ multiplicities, K⁰/event=0.53_?0.20^+0.25and Λ/event=0.03_?0.04^+0.06 show only evidence for charmed meson production. Information on the D-meson fragmentation function is presented. In a specific model, a rate $\text{σ}\text{(μ}{}^{\mathrm{?}}\text{μ}{}^{\mathrm{+}}\text{)}\text{σ(μ}{}^{\mathrm{?}}\text{)}\text{=(0.72±0.14×10}{}^{\mathrm{?2}}$ is found, independent of the energy. An investigation of these events for visible D-decays sets a limit on the life-time τ_D<0.8 ×10^?12s at 90% C.L.     

Observation of proton emission following thermal neutron capture in 34.5 d 84Rb

Using a target prepared by on-line isotope separation, thermal neutron capture in ⁸⁴Rb (I^π = 2^?) has been shown to induce proton emission to the ground state (0⁺) and first excited state (2⁺) of ⁸⁴Kr. The branching ratio was measured as $\text{Γ}{}_{\mathrm{<mtext>p</mtext>}}\text{(0}{}^{\mathrm{+}}\text{)}\text{Γ}{}_{\mathrm{<mtext>p</mtext>}}\text{(2}{}^{\mathrm{+}}\text{)}\text{= 4.7 ± 0.7}$, favouring a $\text{3}\text{2}{}^{\mathrm{?}}$ assignment of the capturing state without excluding $\text{5}\text{2}{}^{\mathrm{?}}$, and the (n_th, p) cross section as 12 ± 2 b. The energy available for the process was determined to be 3.45 ± 0.01 MeV, in agreement with other mass data in the region.     

The spectroscopic study of excitation and ionization in the collision of two metastable atoms

Collisions between two excited atoms leading to an increase in the excitation energy of the particles have been under investigation. All measurements were made in the afterglow of gas-discharge plasma. The cross sections of the following reactions have been determined: $\text{Hg}\text{(6}{}^3\text{P}{}_{012}\text{) +}\text{Hg}\text{(6}{}^3\text{P}{}_{012}\text{) →}\text{Hg}{}^7\text{+}\text{Hg}\text{(6}{}^1\text{S}{}_0\text{),}\text{He}{}_{\mathrm{m}}\text{(2}{}^{\mathrm{1,3}}\text{S}\text{) +}\text{Xe}{}_{\mathrm{m}}\text{(}{}^3\text{P}{}_{\mathrm{0,2}}\text{) → (}\text{Xe}{}^{\mathrm{+}}\text{)}{}^1\text{+}\text{He}{}_0\text{+}\text{e}$. The cross section of the first reaction for different transitions lies in the region (2?35) × 10^?15 cm² and the cross section of the second, in (0.2?2.4) × 10^?16 cm². Possible systematic errors and the role of cascade transitions are discussed. Cross sections of the Penning reaction He_m + Xe₀ → He₀ + Xe⁺ + e have also been measured. The result is σ (2³S) = (1.4 ± 0.2) × 10^?15 cm², σ (2¹S) = (1.2 ± 0.3) × 10^?15 cm².     

The ground state of methane 12CH4 through the forbidden lines of the ν3 band

High resolution spectra of the ν₃ band of methane, ¹²CH₄, were recorded by using a “third generation vacuum Fourier interferometer”; a large pressure range (from 0.009 to 10 Torr) with a sample path fixed at eight meters was used, enabling observation of transitions with intensity ratios as low as $\text{1}\text{10 000}$. More than 350 forbidden transitions of the ν₃ band, including about 125 transitions of the Q⁺ branch, were unambiguously identified. Of the 277 transitions retained for computations, one-hundred have 11 ≤ J ≤ 16. From combination difference relations using pairs of transitions having the same upper state energy level (forbidden-allowed and forbidden-forbidden pairs were used), 276 independent differences between ground state energy levels could be determined with uncertainties of about 0.001 cm^?1.These data yielded the following values for the ground state structure constants of ¹²CH₄ along with their standard deviations (in cm^?1): $\text{β}{}^{\mathrm{o}}\text{hc}\text{=5.2410356±0.0000096}$, $\text{γ}{}^{\mathrm{o}}\text{hc}\text{=(?1±0.00074) 10}{}^{\mathrm{?4}}$, $\text{π}{}^{\mathrm{o}}\text{hc}\text{=(5.78±0.18) 10}{}^{\mathrm{?9}}$, $\text{?}{}^{\mathrm{o}}\text{hc}\text{=(?1.4485±0.0023) 10}{}^{\mathrm{?6}}$, $\text{?}{}^{\mathrm{o}}\text{hc}\text{=(1.768±0.126) 10}{}^{\mathrm{?10}}$, $\text{ξ}{}^{\mathrm{o}}\text{hc}\text{=(?1.602±0.067) 10}{}^{\mathrm{?11}}$, Thus, for the first time, the scalar constant π⁰ has been evaluated and ir values have been obtained for the two tetrahedral constants ?⁰ and ξ⁰; furthermore, these values are in very good agreement with the ones recently determined from radiofrequency data, i.e., in cm^?1: $\text{?}{}^{\mathrm{o}}\text{hc}\text{=(?1.45061±0.00014) 10}{}^{\mathrm{?6}}$, $\text{?}{}^{\mathrm{o}}\text{hc}\text{=(1.7634±0.0068) 10}{}^{\mathrm{?10}}$, $\text{ξ}{}^{\mathrm{o}}\text{hc}\text{=(?1.5432±0.0040) 10}{}^{\mathrm{?11}}$ From these values, the 276 differences can be reproduced with an overall rms deviation equal to 0.0009 cm^?1.Finally, the ground state energies of ¹²CH₄ have been calculated for J ≤ 16.     

Baroemf in the metal—superionic-metal system: AgAg4RbJ5Ag

It is shown that the application of pressure to one of the electrodes of the AgAg₄RbJ₅Ag system causes a flow of Ag⁺ ions into a region of lower pressure, thus giving rise to baroemf. The value of the baroelectric coefficient is determined by the volume-to-charge ratio of “metallic” ion: $\text{α =}\text{v}{}_0\text{e}\text{= (8?9) × 10}{}^{\mathrm{?11}}\text{V Pa}{}^{\mathrm{?1}}$, which agrees quite well with the measured values of (7–9) × 10^?11 V Pa^?1. Freshly prepared samples exhibit a non-equilibrium enhancement of baroemf, so that α differs somewhat from the above value.     

Static structure factor of gaseous helium

The static structure factor of helium gas has been measured at densities of 3.45 × 10^?3, 2.66 × 10^?3 and $\text{1.95 × 10}{}^{\mathrm{?3}}\text{moles}\text{cm}{}^3$ at a temperature of 4.995 K. The results are in qualitative agreement with the limited theoretical work available.     

Polarizabilities of shallow donors in silicon

Capacitance measurements on N-type As, P, and Sb-doped Si samples have been made between 4.2 and 1.35°K, from 0.3 to 100 kHz as a function of (N_D ? N_A) [high purity to 2.7 × 10¹⁸/cm³]. From the dielectric constant variation with (N_D ? N_A) donor polarizabilities α_AS, α_P, and α_Sb are found respectively to be $\text{1.0±0.1, 2.4±0.4,}\text{and}\text{3.1±0.3 × 10}{}^5\text{A}\text{?}{}^3$.     

Lithium mobility in the layered oxide Li1−xCoO2

The Li⁺-ion chemical diffusion coefficient in the layered oxide Li_0.65CoO₂ has been measured to be $\text{D}\text{?}\text{= 5 × 10}{}^{\mathrm{?12}}$ m² s^?1 by three independent techniques: (1) from the Warburg prefactor, (2) from the transition frequency for semi-infinite to finite diffusion lengths in steady-state ac-impedence measurements and (3) from a modified Tubandt method that uses ac-impedance data to distinguish interfacial and surface-layer resistances from the bulk resistance of the sample. This value and a small increase in D? with (1 ? x) in Li_1?xCoO₂, 0.45 < (1 ? x) < 0.80, compare favorably with the $\text{D}\text{?}\text{= 5}\text{to}\text{7 × 10}{}^{-12}\text{m}{}^2\text{s}{}^{-1}$ obtained by Honders for this system with pulse techniques. A qualitative discussion is presented as to why this composition dependence and why D? for this system is a factor of five larger than that for Li⁺-ion diffusion in Li_xTiS₂.     

Investigation of like-sign dimuon production in neutrino and antineutrino reactions

290 events of the type νFe→μ^?μ^?X and 53 events from the reaction $\text{ν}\text{Fe→μ}{}^{\mathrm{+}}\text{μ}{}^{\mathrm{+}}\text{X with}\text{E}{}_{\mathrm{\nu }}\text{>30}\text{GeV}$ and muon momenta p_μ>6.5GeV/c have been observed in the CDHS detector. After subtracting the background from charged-current processes with one π or K meson of the hadronic shower decaying into $\text{μ}{}^{\mathrm{?}}\text{ν}\text{(or μ}{}^{\mathrm{+}}\text{μ)}$, we obtain for neutrinos a rate of prompt like- sign dimuon production of (3.4±1.8)×10^?5 relative to the rate of charged-current events with the same cuts, or (4.1 ± 2.2)% relative to the prompt μ^?μ⁺ rate, and for antineutrinos the corresponding relative rates (4.3±2.3)×10^?5 and (4.2 ± 2.3)%. A possible explanation for the events is charm pair production at a level of 10^?3 relative to all charged-current reactions.