Energies and orbital sizes for some Rydberg and valence states of the nitrogen molecule

Accurate SCF computations are reported on the Rydberg states of N₂ of electron configurations $\text{---1π}{}_{\mathrm{u}}{}^3\text{2π}{}_{\mathrm{u}}$, $\text{---1π}{}_{\mathrm{u}}{}^3\text{3σ}{}_{\mathrm{u}}$, and ---3σ_g2π_g, also on the valence states of the configuration $\text{---1π}{}_{\mathrm{u}}{}^3\text{1π}{}_{\mathrm{g}}$. The Rydberg state calculations supplement those of Lefebvre-Brion and Moser. A comparison is made between the $\text{---1π}{}_{\mathrm{u}}{}^3\text{2π}{}_{\mathrm{u}}$ states and the parallel set of states of the $\text{1π}{}_{\mathrm{u}}{}^3\text{1π}{}_{\mathrm{g}}$ configuration. This comparison shows a sharp difference in the ¹Σ⁺ states of the two configurations, the ¹Σ⁺ state being very high in the latter but relatively low in the former configuration. Recknagel coefficients are given for the several states of the two configurations; as expected, these are much smaller for the $\text{1π}{}_{\mathrm{u}}{}^3\text{2π}{}_{\mathrm{u}}$ configuration. Also, the ¹Δ state is relatively lower for the latter configuration.     

Spectrum and structure of the He2 molecule: Characterization of the singlet and triplet states associated with the UAO's 4s, 4dσ, 4dπ, and 4dδ

The emission spectrum of the He₂ molecule has been rephotographed in the ～4000–～5700 Å region and the $\text{4d(}{}^3\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{+}}\text{,}{}^3\text{Π}{}_{\mathrm{u}}\text{,}{}^3\text{Δ}{}_{\mathrm{u}}\text{) → 2pπ}{}^3\text{Π}{}_{\mathrm{g}}$, $\text{4d(}{}^1\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{+}}\text{,}{}^1\text{Π}{}_{\mathrm{u}}\text{,}{}^1\text{Δ}{}_{\mathrm{u}}\text{) → 2pπ}{}^1\text{Π}{}_{\mathrm{g}}$, $\text{4s}{}^3\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{+}}\text{→ 2pπ}{}^3\text{Π}{}_{\mathrm{g}}$ and $\text{4s}{}^1\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{+}}\text{→ 2pπ}{}^1\text{Π}{}_{\mathrm{g}}$ transitions analyzed. The 4dδj³Δ_u, 4dπj³Π_u, $\text{4dσj}{}^3\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{+}}$ and $\text{4sh}{}^3\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{+}}$ states have been characterized through v = 2 and the 4dδJ¹Δ_u, 4dπJ¹Π_u, $\text{4dσJ}{}^1\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{+}}$, and $\text{4sH}{}^1\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{+}}$ states for v = 0. The term levels for these perturbed and l-uncoupled states have been confirmed (a) by analyses of bands with common levels from Δv = 0, ±1 sequences and (b) by analyses of the transitions between the above states from 4d and 4s and the $\text{c}{}^3\text{Σ}{}_{\mathrm{g}}{}^{\mathrm{+}}$ and $\text{C}{}^1\text{Σ}{}_{\mathrm{g}}{}^{\mathrm{+}}$ states associated with 3pσ. Molecular constants are reported which have been partially corrected for the effects of l-uncoupling and the homogeneous perturbations between the state pairs J, H and j, h.     

The spectrum of HeAr+

Two band groups near 1450 Å, first observed by Tanaka, Yoshino, and Freeman (J. Chem. Phys.62, 4484–4496 (1975)) in discharges through mixtures of helium and argon and assigned by them to the HeAr⁺ ion, were studied under high resolution. Like the similar spectrum of HeNe⁺ previously investigated, the spectrum of HeAr⁺ is a charge transfer spectrum. The upper state B²Σ⁺ of both band groups is derived from $\text{He}{}^{\mathrm{+}}\text{(}{}^2\text{S) +}\text{Ar}\text{(}{}^1\text{S)}$ while the two lower states $\text{A}{}_2{}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ and X²Σ⁺ are derived from $\text{He}\text{(}{}^1\text{S) +}\text{Ar}{}^{\mathrm{+}}\text{(}{}^2\text{P)}$. All three states are very weakly bound, the two lower states even more weakly than the upper state. Unlike HeNe⁺ most of the HeAr⁺ bands are violet shaded. In the longward band group each band shows only three branches while in the shortward group there are four. The former observation shows that the $\text{A}{}_2{}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ state behaves like a ²Σ^? state with γ_v ≈ 0. The B, D, γ, p, and ΔG values of all states were evaluated. While the B_v values of upper and lower states are nearly equal, the D_v values are quite different and this difference accounts for the violet shading of most of the bands even when B′_v is slightly smaller than B″_v; it also accounts for some of the extraheads and linelike features in the rotational structure. As in HeNe⁺ the ${}^2\text{Π}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}$ component of ²Π was not observed.     

The spectrum of HeNe+

Discharges through mixtures of helium and neon show two band groups near 4250 and 4100 Å as first observed by Druyvesteyn. These bands, assigned to the HeNe⁺ ion by Tanaka, Yoshino, and Freeman, have been studied under high resolution and have been fairly completely analyzed. The upper state of the transition is a very weakly bound state resulting from $\text{He}{}^{\mathrm{+}}\text{(}{}^2\text{S) +}\text{Ne}\text{(}{}^1\text{S}{}_0\text{)}$. There are two lower states resulting from the two components of $\text{Ne}{}^{\mathrm{+}}\text{(}{}^2\text{P) +}\text{He}\text{(}{}^1\text{S}{}_0\text{)}$. The upper of these two (${}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$) is also very weakly bound while the lower of the two, the ²Σ⁺ ground state, has a dissociation energy of 0.69 eV and an r_e value of 1.30 Å. All bands in both band groups show four branches designated R_ff, Q_ef, Q_fe, and P_ee. From their analysis the rotational constants in the various vibrational levels of the three electronic states have been determined. While no spin splitting in the B²Σ⁺ state has been found the ground state X²Σ shows a very large spin splitting and the $\text{A}{}_2{}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ state a very large $\text{Ω-type}$ doubling. The vibrational numberings in all these states were established by the study of the spectrum of ³HeNe⁺. At the same time the hyperfine structure observed in all lines of ³HeNe⁺ confirmed the nature of the upper state B²Σ⁺ as resulting from He⁺ + Ne, i.e., by charge exchange from the ground state. The ${}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ component of the ²Π state has not been observed, presumably because of low intensity.     

Rotational bands in 195, 197Tl

High-spin states in ^{195, 197}Tl have been populated with (α, xn) reactions and studied by means of in-beam γ-ray and e^? spectroscopic methods. Complementary studies of the decay of ^{195, 197}Pb to ^{195, 197}Tl have been carried out. Several new features have been observed in these nuclei. The $\text{9}\text{2}{}^{\mathrm{?}}$ bands of ^{195, 197}T1. extended to $\text{27}\text{2}{}^{\mathrm{(?)}}$ and $\text{29}\text{2}{}^{\mathrm{(?)}}$, respectively, show a quenching of energy spacings between the $\text{23}\text{2}{}^{\mathrm{?}}$, $\text{25}\text{2}{}^{\mathrm{?}}$, $\text{27}\text{2}{}^{\mathrm{(?}}$ and $\text{29}\text{2}{}^{\mathrm{(?}}$ states. This has been interpreted as resulting from the coupling of a $\text{h}{}_{\mathrm{<mtext>9</mtext><mtext>2</mtext>}}$ proton to the ($\text{π}\text{h}{}^{\mathrm{?2}}{}_{\mathrm{<mtext>11</mtext><mtext>2</mtext>}}\text{)}{}_{\mathrm{8+,\; 10+}}$ configurations in the core nuclei ^{194, 196}Hg. Furthermore, positive-parity bands based on $\text{15}\text{2}{}^{\mathrm{+}}$ states were established up to the $\text{35}\text{2}{}^{\mathrm{(+)}}$ and $\text{29}\text{2}{}^{\mathrm{(+)}}$ states in ^{195, 197}Tl respectively. Probably these bands originate from the coupling of a h${}_{\mathrm{<mtext>9</mtext><mtext>2</mtext>}}$ proton to a broken neutron pair. This pair consists of a rotation-aligned $\text{i}{}_{\mathrm{<mtext>13</mtext><mtext>2</mtext>}}$ neutron and a low-j neutron in the $\text{P}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$, $\text{P}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}$ or $\text{f}{}_{\mathrm{<mtext>5</mtext><mtext>2</mtext>}}$ shell. It is known to constitute the 5^? bands in ^{194, 196}Hg.     

Predissociation and Λ-doubling in the even-parity Rydberg states of the nitrogen molecule

Predissociations in the y¹Π_g and $\text{x}{}^1\text{Σ}{}_{\mathrm{g}}{}^{\mathrm{?}}$ Rydberg states of N₂ (configurations $\text{1π}{}_{\mathrm{u}}{}^{\mathrm{?1}}\text{4pσ}$ and $\text{1π}{}_{\mathrm{u}}{}^{\mathrm{?1}}\text{3pπ}$, respectively) and their likely causes, are discussed. Peaking of rotational intensity at unusually low J values, without sharp breaking off, is interpreted as due to case c^? or case cⁱ predissociation. Λ doubling in the y state, attributed to interactions with the $\text{x}{}^1\text{Σ}{}_{\mathrm{g}}{}^{\mathrm{?}}$ state and with another, ¹Σ⁺, state of the same electron configuration as x, is analyzed. From this analysis the location of the (unobserved) ${}^1\text{Σ}{}_{\mathrm{g}}{}^{\mathrm{+}}$ state, here labeled x′, is obtained. It is concluded that the predissociation in the Π⁺ levels of the y state is an indirect one mediated by the interaction with x′ coupled with predissociation of x′ by a ${}^3\text{Σ}{}_{\mathrm{g}}{}^{\mathrm{?}}$ state dissociating to ${}^4\text{S +}{}^2\text{P}$ atoms: combined, however, with perturbation of the y state by the k¹Π_g Rydberg state (configuration $\text{3σ}{}_{\mathrm{g}}{}^{\mathrm{?1}}\text{4dπ}$), whose Π⁺ levels are completely predissociated.     

The interaction of 33 MeV polarised helions with 30Si

Distributions of cross sections and analysing powers have been measured over the range ～ 14°–100° c.m. for the $\text{(}{}^3\text{H}\text{,}{}^3\text{He), (}{}^3\text{H}\text{,}{}^4\text{He), (}{}^{\mathrm{<mtext>3</mtext><mtext>H</mtext>}}\text{,}{}^2\text{H)}$ reactions at 33.4 MeV incident e using a ～ 95 % enriched ³⁰Si target. Phenomenological optical-model analyses of the elastic-scattering data have been carried out. A DWBA analysis of the inelastic-scattering data for the 2.24 MeV (2⁺) and 5.49 MeV (3^?) states of ³⁰Si has yielded values of the deformation β₂ and β₃. The j-dependence of the analysing powers for the (³He, ⁴He) and (³He, ²H) reactions has identified the 6.71 MeV level of ²⁹Si as a $\text{5}\text{2}{}^{\mathrm{+}}$ state, and a level near 9.5 MeV in ³¹P as a possible $\text{7}\text{2}{}^{\mathrm{?}}$ state. Spectroscopic factors for ten states in ²⁹Si and seven states in ³¹P have been deduced and are compared with other work. The extent to which the data defines the ³He spin-orbit potential is discussed.     

3Σu−-3Σu+ coupling in the O2B3Σu− predissociation

The role of $\text{B}{}^3\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{?}}\text{-2}{}^3\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{+}}$ spin-orbit mixing in the O₂ Schumann-Runge predissociation is investigated. The $\text{2}{}^3\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{+}}$ state is found to cross the $\text{B}{}^3\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{?}}$ state near 2.0 Å with an interaction matrix element of approximately 55 cm^?1. This state contributes to the widths of the Bv ≥ 6 levels, but introduces only small level shift perturbations. When the partial widths due to the ${}^3\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{?}}\text{-}{}^3\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{+}}$ interaction are added to the previously calculated widths due to the ⁵Π_u, ³Π_u, and ¹Π_u states, reasonable agreement is obtained with experimental measurements on O¹⁶O¹⁶ and O¹⁸O¹⁸. The possibility of non-Lorentzian line profiles and the dependence of the width on rotational quantum number is investigated. The approximation of the spin-orbit matrix element by its value at the crossing point is shown to be a good approximation for calculating the second difference perturbations.     

N2+ bound quartet and sextet state potential energy curves

Potential energy curves for the ${}^4\text{Σ}{}^{\mathrm{+}}{}_{\mathrm{u}}$, ${}^4\text{Π}{}_{\mathrm{g}}$ and ${}^6\text{Σ}{}^{\mathrm{+}}{}_{\mathrm{g}}$ states of N⁺₂ that dissociate to N (${}^4\text{S}{}^0$) and $\text{N}{}^{\mathrm{+}}\text{(}{}^3\text{P)}$, have been determined from a complete active space self-consistent field calculation. The ${}^6\text{Σ}{}^{\mathrm{+}}{}_{\mathrm{g}}$ state is found to be significantly bound (D_e = 2.68 eV) with a minimum at 1.72 Å.     

Energy levels of low lying triplet states of N2 from infrared emission studies

A theoretical model used to describe the $\text{B′}{}^3\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{?}}$ and B³Π_g states of N₂ is presented. Using recently acquired high resolution spectra of the $\text{B′}{}^3\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{?}}\text{→ B}{}^3\text{Π}{}_{\mathrm{g}}$ (0-0) band, rotational energy levels of the v = 0 vibrational levels of these two states are generated with this model. These levels are in excellent agreement with those obtained using a combination differences technique. The precision of the model generated levels is 0.01 cm^?1. The previously unpublished rotational levels of Dieke and Heath for the $\text{A}{}^3\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{+}}$, B³Π_g and C³Π_u states are referenced to the $\text{N}{}_2\text{X}{}^1\text{Σ}{}_{\mathrm{g}}{}^{\mathrm{+}}$ (v = 0, J = 0) ground level and tabulated here. Estimates of the precision of their work are made.     

Matthiessen's rule and its variation for cyclotron resonance width in two and three dimensions

Based on the proper connected diagram expansion, we calculated cyclotron resonance widths Γ_n associated with neighboring Landau states (n, n +1) for free electrons in interaction with more than one kind of impurities. In 3D usual Matthiessen's rule Γ_n=Γ⁽¹⁾_n+Γ⁽²⁾_n+…where Γ⁽ⁱ⁾_n represent widths calculated separately for each kind, is obtained. In 2D a new rule: is obtained.     

The spectrum and structure of the He2 molecule: Characterization of the triplet states associated with the UAO's 4pσ, 5pσ, and 6pσ

The emission spectrum of the He₂ molecule has been rephotographed in the ～3200–4100 Å region and the $\text{4pσ g}{}^3\text{Σ}{}_{\mathrm{g}}{}^{\mathrm{+}}\text{→ 2s a}{}^3\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{+}}$, $\text{5pσ k′}{}^3\text{Σ}{}_{\mathrm{g}}{}^{\mathrm{+}}\text{→ 2s a}{}^3\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{+}}$, and $\text{6pσ n}{}^3\text{Σ}{}_{\mathrm{g}}{}^{\mathrm{+}}\text{→ 2s a}{}^3\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{+}}$ transitions analyzed. The g, k′, and n states, which have not been reported previously, are characterized through v = 1, 2, and 1, respectively. Several small accidental perturbations have been observed in the rotational manifolds of the k′ and n states.     

Vibrational spectra and force constants of symmetric tops: High resolution spectra of monoisotopic H3SiCl in the 2200-cm−1 region and rovibrational analysis of the ν1 and ν4 fundamentals

The gas phase infrared spectra of monoisotopic H₃Si³⁵Cl and H₃Si³⁷Cl have been studied in the $\text{ν}{}_1\text{ν}{}_4$ region near 2200 cm^?1 with a resolution of 0.012 and 0.04 cm^?1, respectively, and rotational fine structure for ΔJ = ±1 branches has been resolved. In addition, some information on ν₃ + ν₄ of H₃Si³⁵Cl near 2750 cm^?1 has been obtained. ν₁ and ν₄ are weakly coupled by Coriolis x, y resonance, $\text{B}\text{Ω}{}_{14}\text{ζ}{}_{14}\text{～ 2 × 10}{}^{\mathrm{?3}}\text{cm}{}^{\mathrm{?1}}$, only the upper states K′ = 2, l = 0 and K′ = 1, l = ?1 being substantially affected. Local perturbation due to rotational l(±1, ±1)-type resonance with ν₃ + ν₅⁺¹ + ν₆⁺¹ and ν₃ + ν₅⁺¹ + ν₆^?1 is revealed in the ΔK = +1 and ?1 branches, respectively. From a fit of the experimental line positions, standard deviations of 1.4 and 3.8 × 10^?3 cm^?1, respectively, to a model with five interacting levels conventional excited state parameters and interaction constants have been obtained. In $\text{H}{}_3\text{Si}{}^{35}\text{Cl}\text{H}{}_3\text{Si}{}^{37}\text{Cl}$ the fundamentals are ν₁, $\text{2201.94380(15)}\text{2201.9345(7)}$ and ν₄, $\text{2209.63862(8)}\text{2209.6254(2)}\text{cm}{}^{\mathrm{?1}}$, respectively. Q branches of the “hot” band (ν₃ + ν₄) ? ν₃ and of ν₄ of the ²⁹Si and ³⁰Si species have been detected.     

Core polarization for M2 transitions in odd-A tin isotopes

The reduced M2 transition probabilities $\text{11}\text{2}{}^{\mathrm{?}}{}_1\text{→}\text{7}\text{2}{}^{\mathrm{+}}{}_1$ in the odd-A isotopes ^109–121Sn are found to reveal a specific behaviour. B(M2) values are calculated in the framework of the quasiparticlephonon model. The coupling of a quasineutron with the 2⁺, 3^? and 2^? one-phonon core excitation is taken into account. Inclusion of all one-phonon 2^? states up to 24 MeV in the wave functions of the excited states $\text{11}\text{2}{}^{\mathrm{?}}{}_1\text{and}\text{7}\text{2}{}^{\mathrm{+}}{}_1$ reduces the theoretical B(M2) values by 3–4 times as compared to the single-particle values. The specific B(M2) dependence on the mass number appears to be due to the pairing effect.     

Measurement of Debye-Waller factors by Raman scattering from inter-term excitons and exciton-multiphonon states in FeF2

We have observed inter-term Raman scattering from ⁵T_2g→⁵E_g Frenkel excitons in antiferromagnetic FeF₂. It differs qualitatively from previously observed intra-term scattering in a sharply reduced zero-phonon cross section and the appearance of relatively strong exciton-phonon scattering. Since the Raman process is fully allowed, it is possible to measure excited state Debye-Waller factors, D, and we find $\text{D(Λ}{}_3{}^{\mathrm{+}}\text{+ Λ}{}_4{}^{\mathrm{+}}\text{,}{}^5\text{E}{}_{\mathrm{g}}\text{) = 0.04}$ and $\text{D(Λ}{}_1{}^{\mathrm{+}}\text{,}{}^5\text{E}{}_{\mathrm{g}}\text{) = 0.03}$.     

Charmed baryon pair production in e+e− annihilation

Cross sections for charmed baryon pair production near threshold in e⁺e^? annihilation are calculated using pole-dominated form factors modified to take intoccount continuum effects. When the C₀⁺$\text{C}$₀^? production cross section is normalized with the help of data for $\text{e}{}^{\mathrm{+}}\text{e}{}^{\mathrm{?}}\text{→}\text{p}\text{X}$ it is found that the total charmed baryon production cross $\text{(}\text{C}{}_0\text{C}{}_0\text{,}\text{C}{}_1\text{C}{}_1\text{,}\text{C}{}_1\text{C}{}_1{}^1\text{+}\text{C}{}_1{}^1\text{C}{}_1\text{,}\text{C}{}_1{}^1\text{C}{}_1{}^1\text{)}$ reaches a peak value of approximately 2.7 nb at √s = 5 GeV.     

Two-quasiproton states in 168Er studied by the 169Tm(t, α)168Er reaction

The ${}^{169}\text{Tm}\text{(}\text{t}\text{, α)}{}^{168}\text{Er}$ reaction has been studied using 17 MeV polarized tritons from the Los Alamos National Laboratory tandem Van de Graaff accelerator. The α-spectra were analyzed with a Q3D magnetic spectrometer. The overall energy resolution was typically ~ 15 keV (FHWM) and angular distributions of cross sections and analyzing powers were obtained for levels up to ~ 2.7 MeV. The fact that spins and parities for all levels up to ? 2 MeV were previously known from an extensive series of (n, γ) studies made it possible to determine specific two-quasiproton structures for many bands from the present results. The K^π = 2⁺ γ-vibrational band was found to have a large $\text{3}\text{2}{}^{\mathrm{+}}\text{[411]}{}_{\mathrm{<mtext>p</mtext>}}\text{+}\text{1}\text{2}{}^{\mathrm{+}}\text{[411]}{}_{\mathrm{<mtext>p</mtext>}}$ admixture, consistent with the predicted microscopic composition of this phonon, but no $\text{5}\text{2}\text{[413]}{}_{\mathrm{<mtext>p</mtext>}}\text{?}\text{1}\text{2}{}^{\mathrm{+}}\text{[411]}{}_{\mathrm{<mtext>p</mtext>}}$ component was observed. The K^π = 0₄⁺ band at 1833 keV has ～ 25% of the $\text{1}\text{2}{}^{\mathrm{+}}\text{[411]}{}_{\mathrm{<mtext>p</mtext>}}\text{?}\text{1}\text{2}{}^{\mathrm{+}}\text{[411]}{}_{\mathrm{<mtext>p</mtext>}}$ two-quasiproton strength. This is in excellent agreement with the Soloviev model but is inconsistent with the interacting boson model, in which the K^π = 0₄⁺ band is composed almost completely of multiphonon configurations that should not be populated in a single-nucleon transfer reaction. The $\text{K}{}^{\mathrm{\pi }}\text{= 4}{}^{\mathrm{?}}\text{,}\text{7}\text{2}{}^{\mathrm{?}}\text{[523]}{}_{\mathrm{<mtext>p</mtext>}}\text{+}\text{1}\text{2}{}^{\mathrm{+}}\text{[411]}{}_{\mathrm{<mtext>p</mtext>}}$ two-quasiproton and the $\text{K}{}^{\mathrm{\pi }}\text{= 4}{}^{\mathrm{?}}\text{,}\text{7}\text{2}{}^{\mathrm{+}}\text{[633]}{}_{\mathrm{<mtext>n</mtext>}}\text{+}\text{1}\text{2}{}^{\mathrm{?}}\text{[521]}{}_{\mathrm{<mtext>n</mtext>}}$ two-quasineutron states are mixed strongly with each other, but the two K^π = 3^? bands composed of antiparallel couplings of the same particles are not. A good qualitative explanation of this mixing pattern is provided in terms of the effective neutron-proton interaction.     

The infrared part of the C2 Phillips system (2.3–0.9 μm)

Line positions and molecular constants for the 0-0, 1-0, 2-0, 0-1, 2-1, 3-1, 0-2, 1-2, and 4-2 bands of the C₂ Phillips system ($\text{A}{}^1\text{Π}{}_{\mathrm{u}}\text{-X}{}^1\text{Σ}{}_{\mathrm{g}}{}^{\mathrm{+}}$) are reported. Among them, five bands have not been reported previously. Rotational perturbations have been observed in the previously unobserved v = 1 level of the $\text{A}{}^1\text{Π}{}_{\mathrm{u}}$ state. This state is perturbed by the $\text{c}{}^3\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{+}}$ state which was discovered by Ballik and Ramsay. These observations provide new information regarding the perturbing state. In particular, the minimum of the potential energy for the $\text{c}{}^3\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{+}}$ state has been found to be at 9227.4 cm^?1 instead of 13 310 cm^?1, which was the previous T_e value for this electronic state.