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4-Acetamido-2,4,6-trideoxy-D,L-arabino-hexopyranose, a desmethyl analog of N-acetyl-L-hoTantosamine, the glycosidic residue of the cardenolide HoTarosine A and holantosines C and D, has been prepared via a novel intramolecular rearrangement of an amino alcohol and has been characterized by single-crystal X-ray diffraction. 相似文献
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Treatment of bafilomycin A1 with mercuric chloride resulted in a regioselective intramolecular oxymercuration. Reduction with triphenyltin hydride gave 7,10-anhydro bafilomycin A1 characterized by a single crystal X-ray analysis. 相似文献
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Heteropolyblueisthereducedproductofthepoly oxometalates.Ithasattractedmuchattentionbecauseofitsnovelstructure ,uniquepropertiesandpotentialap plicationsinthefieldsofcatalysis ,pharmaceuticalchemistryandfunctionalmaterials .1 3 Atearlystage ,heteropolybluewa… 相似文献
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NBS bromination of the ketobromohydrin 2 produces a dibromohydroxy ketone with bromination occurring exclusively at the secondary α-position of the ketone. 相似文献
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Thomas R. Ward Luigi M. Venanzi Alberto Albinati Francesca Lianza Tobias Gerfin Volker Gramlich Gerardo M. Ramos Tombo 《Helvetica chimica acta》1991,74(5):983-988
The preparation of the optically pure tritertiary phosphine (RRR)-MeSi(CH2P(t-Bu)Ph)3 (2) is reported. The route followed involves deprotonation of optically pure (R)-P(BH3)Me(t-Bu)PH (2) the reaction of the resulting carbanion with MeSiCl3, followed by removal with morpholine of the BH3-protecting groups from the triertiary phosphine-borane 3 . The latter's X-ray crystal structure and that of [Rh(NBD)((RRR)- 1 ]TOf)( 4 ), are also rported. Furthermore, it is shown that the separation of the racemic phosphine-borane 2 can be conveniently carried out using medium-pressure liquid chromatgrapy with cellulose-riacetate as a chiral stationary phase. 相似文献
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Antonio L. Llamas-Saiz Concepción Foces-Foces Christophe Fontenas José Elguero 《Molecules Online》1998,2(2):76-81
The crystal structure of the title compound has been determined by X-ray diffraction. The N and O atoms are involved in chains of hydrogen bonds, running through the whole crystal, which show proton disorder in a 1:1 ratio. This implies an inversion in the sense of the hydrogen bond network and the presence of inversion centers in the structure. Each molecule is engaged in two unconnected chains building sheets of molecules. An analysis of packing modes of NH-pyrazoles containing at least another hydrogen bond donor or acceptor site in the substituents has been performed. 相似文献
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Yoon Hee Lee Shim Sung Lee 《Journal of inclusion phenomena and macrocyclic chemistry》2001,39(3-4):235-239
The novel 1,12-dithia macrocycles based on dibenzo substituents,5 (S2O3), 6 (S3O2) and 7 (S2O4) have been synthesized by cesium carbonatepromoted ring closure reactions of 2,2'-(ethylenedioxy)bis(benzyl chloride), 3, with the appropriate dithiols under high dilution condition in reasonable yields. The structures of macrocycles 6 and 7 have been characterized by X-ray crystallography. 相似文献
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David J. Leaver Andrew B. Hughes Anastasios Polyzos Jonathan M. White 《Journal of carbohydrate chemistry》2013,32(8-9):379-385
We report the crystal structures of two galactosylacetylenes: 3,7-anhydro-4,5,6,8-tetra-O-benzyl-1,1,2,2-tetradehydro-1,2-dideoxy-1-C-(trimethylsilyl)-D-glycero-L-mannooctitol (7) and 3,7-anhydro-4,5,6,8-tetra-O-benzyl-1,1,2,2-tetradehydro-1,2-D-glycero-L-mannooctitol (8). A short overview of the synthetic chemistry used to obtain these targets is mentioned. 相似文献
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1INTRODUCTI0NCarvedilol,1-(4-carbazolyloxy)-3-[2-methoxyphenoxy)ethylaminoj-2-propanol,isanewgblockingandvasodilatingagent"'.IthadsynthesizedbyF.Wiedemannetalt23.Howeverthereportaboutcrystalstructureofcarvedilolhasnotbeenseen.Inthispaper,wediscussthecrystalstructureofthecarvedilolsynthe-sized[2ibythereacti0nof4-(2,3-ex0xypropoxy)-carbazoleand2-(2-methoxyphe-noxy)ethylamine.Sinceknowledgeofthemolecularandcrystalstructureofcarvedil0lwasconsideredusefulforunderstandingthemechanismoftheactio… 相似文献
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1 INTRODUCTION In the last decade the chemistry of ferrocene and the design of new compounds containing fer- rocene have received much attention, associated with the utility of these compounds in many fields such as organic synthesis, homogeneous cata… 相似文献
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