Depolarization of luminescence of polyatomic molecules in the gas phase as a method of determining the efficiency of collisional transfer of angular momentum

The theory of collisional depolarization of luminescence of extended polyatomic molecules in rarefiedgases is considered. The interrelation between the frequency of collisions, the relaxation time of the angular momentum, and the cross section of the luminescence depolarization is established, and the dependence of these parameters on the efficiency of an abrupt change in the angular momentum is calculated. The use of the theory of collisions of solids in the Enskog approximation made it possible to take into account the effect of the shape and mass of colliding molecules on the degree of depolarization. It is established that, in terms of this theory, there exists a limiting efficiency of an abrupt change in the angular momentum, which, however, does not attain the value proposed in the model of strong collisions (Jdiffusion). The dependence of the depolarization of luminescence of 1,4-di-(2-5-p-tolyloxazolyl) benzene molecules on the concentration of a buffer gas (argon) is measured. It is found that about five collisions with Ar atoms are required for randomization of the angular momentum of these molecules.     

Collisional depolarization of fluorescence of polyatomic molecules in the gas phase by excited state quenchers

A new method of extracting information on the efficiencies of quenching of an excited state and collisional reorientation from the data on the fluorescence depolarization of molecular vapors by quenchers of the excited state is proposed. The method does not involve collisional cross sections and fluorescence lifetimes. From the experimental data on the depolarization of polarized luminescence of para-quaterphenyl and 2-(4′-dimethylamine) phenyl-5-phenyloxydiazole by oxygen and nitrogen, the ratios of the constants of the excitedstate quenching and orientation randomization (fluorescence depolarization) by oxygen are obtained. For these molecules, the probabilities of the excited-state quenching q and orientation randomization s per collision with oxygen molecules are determined (q=0.25±0.04 and s=0.13±0.04 for para-quaterphenyl and q=0.2±0.04 and s=0.21±0.04 for 2-(4′-dimethylamine)phenyl-5-phenyloxydiazole). The self-quenching of fluorescence of perylene vapors, with the probability 0.28 per collision, is found.     

Azimuthal anisotropy of the emission of fragments and relativistic particles in collisions between iron nuclei of momentum 2.5 GeV/<Emphasis Type="Italic">c</Emphasis> per nucleon and photoemulsion nuclei

The azimuthal anisotropy of the emission of fragments and relativistic particles in collisions between ⁵⁶Fe nuclei of momentum 2.5 GeV/c per nucleon and photoemulsion nuclei is measured. For semicentral collisions at impact-parameter values in the range 0.12 ≤ b/b_max ≤ 0.70, charged fragments and relativistic particles are predominantly emitted in the direction orthogonal to the nuclear-reaction plane. The azimuthal-asymmetry parameter P₂ for fragments whose charge numbers are Z = 1, 2 and Z ≥ 3 takes values of, respectively, ?0.192±0.057, ?0.28±0.07, and ?0.39±0.12. Evaporated b particles have an isotropic azimuthal distribution.     

Using ion imaging to analyze higher-order moments of the angular distributions of photofragments

We investigate the effect of the hexadecapole (K=4) polarization moment on the spatial distributions of angular momenta for atoms produced during the photodissociation of diatomic or triatomic molecules by polarized radiation. We derive general expressions for the angular distributions of the atomic density matrix for K = 2, 4 and expressions for the corresponding anisotropy parameters that contain all information on the photodissociation dynamics. We show that these anisotropy parameters can be experimentally determined by using ion imaging. We consider oxygen atoms in the ¹ D ₂ state aligned with respect to the orbital angular momentum as an example and provide ion images of the signals that correspond to the population of the atomic magnetic sublevels ¦m¦ = 0, 1, 2. We show the contributions from the second-and fourth-rank state multipoles to the angular distributions of the atomic density matrix to be comparable in magnitude and significantly different in form.     

Vector correlations in the F + HD reaction

A theoretical study of the orientation of product rotational angular momenta for two chemical reaction channels: F + HD(ν _r = 0, j _r = 0) → HF(ν, j) + D and F + HD(ν _r = 0, j _r = 0) → DF(ν, j) + H at a E _coll = 78.54 meV collision energy was performed. Angular momentum orientation was described on the basis of irreducible tensor operators (state multipoles) expressed through anisotropy transfer coefficients, which contained quantum-mechanical scattering T matrices determined on the basis of exact solutions to quantum scattering equations obtained using the hyperquantization algorithm. The possibility of the existence of substantial orientation of the angular momentum of reaction products j in the direction perpendicular to the scattering plane was demonstrated. The dependences of differential reaction cross sections and state multi-poles on the ν and j quantum numbers were calculated and analyzed. A experimental scheme based on the multiphoton ionization method was suggested. The scheme can be used to detect predicted reaction product angular momentum orientation.     

Dependence of the differential cross sections for radiative-collisional excitation of metastable atomic states on the polarization of radiation

We calculate the total and differential cross sections for radiative-collisional excitation of the metastable 2¹S state of He atoms at collisions with Ne atoms in external radiation fields of various frequencies and polarizations. The calculations are performed for a thermal collision energy of E = 10^?3 atomic units and light intensity of I = 1 MW cm^?2, which corresponds to a single photon absorption by a quasi-molecule during the collision. Both the differential and total cross sections are shown to depend strongly on the relative orientation of the radiation polarization vector and the initial relative velocity vector of the colliding atoms. We analyze the azimuthal scattering asymmetry related to the orientation of the angular momentum of the absorbed photon.     

Stochastic model of angular distributions of fragments originating from the fission of excited compound nuclei

The anisotropy of angular distributions of fission fragments and the average multiplicity of prescission neutrons were calculated within a stochastic approach to fission dynamics on the basis of three-dimensional Langevin equations. This approach was combined with a Monte Carlo algorithm for the degree of freedom K (projection of the total angular momentum I onto the fission axis). The relaxation time τ _K in the coordinate K was considered as a free parameter of the model; it was estimated on the basis of a fit to experimental data on the anisotropy of angular distributions. Specifically, the relaxation time τ _K was estimated at 2 × 10^?21 s for the compound nuclei ²²⁴Th and ²²⁵Pa and at 4 × 10^?21 s for the heavier nuclei ²⁴⁸Cf, ²⁵⁴Fm, and ²⁶⁴Rf. The potential energy was calculated on the basis of the liquid-drop model with allowance for finiteness of the range of nuclear forces and for the diffuseness of the nuclear surface. A modified one-body viscosity mechanism featuring a coefficient k _s that takes into account the reduction of the contribution from the wall formula was used to describe collective-energy dissipation. The coefficient k _s was also treated as a free parameter and was estimated at 0.5 on the basis of a fit to experimental data on the average prescission multiplicity of neutrons.     

Coulomb Problem for <Emphasis Type="Italic">Z</Emphasis> &gt; Z<Subscript>cr</Subscript> in Doped Graphene

The dynamics of charge carriers in doped graphene, i.e., graphene with a gap in the energy spectrum depending on the substrate, in the presence of a Coulomb impurity with charge Z is considered within the effective two-dimensional Dirac equation. The wave functions of carriers with conserved angular momentum J = M + 1/2 are determined for a Coulomb potential modified at small distances. This case, just as any two-dimensional physical system, admits both integer and half-integer quantization of the orbital angular momentum in plane, M = 0, ±1, ±2, …. For J = 0, ±1/2, ±1, critical values of the effective charge Z_cr(J, n) are calculated for which a level with angular momentum J and radial quantum numbers n = 0 and n = 1 reaches the upper boundary of the valence band. For Z < Z_cr (J, n = 0), the energy of a level is presented as a function of charge Z for the lowest values of orbital angular momentum M, the level with J = 0 being the first to descend to the band edge. For Z>Z_cr (J, n = 0), scattering phases are calculated as a function of hole energy for several values of supercriticality, as well as the positions ε₀ and widths γ of quasistationary states as a function of supercriticality. The values of ε₀* and width γ* are pointed out for which quasidiscrete levels may show up as Breit–Wigner resonances in the scattering of holes by a supercritical impurity. Since the phases are real, the partial scattering matrix is unitary, so that the radial Dirac equation is consistent even for Z > Z_cr. In this single-particle approximation, there is no spontaneous creation of electron–hole pairs, and the impurity charge cannot be screened by this mechanism.     

The analysis of <Emphasis Type="Italic">π</Emphasis><Superscript>−</Superscript>-meson spectra in semicentral CC and CTa collisions at a momentum of 4.2 GeV/<Emphasis Type="Italic">c</Emphasis> per nucleon in terms of light-front variables

The inclusive spectra of pions produced in CC and CTa collisions at a momentum of 4.2 GeV/c per nucleon are analyzed in terms of light-front variables ξ and ζ. The phase space of the secondary pions is divided into two parts with very different angular and momentum distributions. In one of these parts, the thermal equilibrium assumption seems to be in good agreement with the data. Corresponding temperatures T are extracted, and their dependence on (A_PA_T)^1/2 is studied: T decreases linearly with increasing (A_PA_T)^1/2. The results are compared with the predictions of the quark-gluon string model (QGSM). The QGSM satisfactorily reproduces the experimental data.     

Measurement of polarization angular coefficients in <Emphasis Type="Italic">Z</Emphasis> boson leptonic decays with ATLAS at the LHC

This paper presents the complete set of polarization angular coefficients A _0?7 describing lepton angular distributions in Z boson decay, which were measured at the ATLAS experiment in proton–proton collisions with the energy √s = 8 TeV. Theoretical values for the difference A ₀ ? A ₂ calculated in the fixed-order QCD perturbation theory O(α _s ² ), demonstrate significant deviation from the measured data, which indicates the necessity of taking into account higher order corrections. The evidence of nonzero coefficients A _5,6,7 was obtained for the first time, in accordance with theoretical calculations in O(α _s ² ) approximation. Measurement of the polarization angular coefficients A _i is important for subsequent precision measurement of parameters of the electroweak model at the LHC, such as the sine of Weinberg electroweak mixing angle sin² θ _W and the W boson mass.     

Frustrated antiferromagnetism in the Sr<Subscript>2</Subscript>YRuO<Subscript>6</Subscript> double perovskite

The spins of Ru⁵⁺ ions in Sr₂YRuO₆ form a face-centered cubic lattice with antiferromagnetic nearest neighbor interaction J≈25 meV. The antiferromagnetic structure of the first type experimentally observed below the Néel temperature T _N =26 K corresponds to four frustrated spins of 12 nearest neighbors. In the Heisenberg model in the spin-wave approximation, the frustrations already cause instability of the antiferromagnetic state at T=0 K. This state is stabilized by weak anisotropy D or exchange interaction I with the next-nearest neighbors. Low D/J～I/J～10^?3 values correspond to the experimental T _N and sublattice magnetic moment values.     

<Emphasis Type="Italic">z</Emphasis>-Scaling and high-<Emphasis Type="Italic">p</Emphasis><Subscript><Emphasis Type="Italic">T</Emphasis></Subscript> particle production in hadron-hadron and hadron-nucleus collisions at high energies

The general features of particle production in hadron-hadron and hadron-nucleus collisions at high energy and transverse momentum using the concept of z-scaling are reviewed. z-Presentation of experimental data on the inclusive cross sections obtained at ISR, SPS, and Tevatron is presented and its properties are discussed. It is argued that the properties reflect the fundamental symmetries such as self-similarity, locality, and fractality. z-Scaling is used to predict particle yields in hadron-hadron and hadron-nucleus collisions at RHIC and LHC energies. The violation of z-scaling is considered as a signature of new physics phenomena.     

Corona effect in <Emphasis Type="Italic">AA</Emphasis> collisions at the LHC

Following our earlier finding based on RHIC data on the dominant jet production from nucleus corona region, we reconsider this effect in nucleus–nucleus collisions at the LHC energies. Our hypothesis was based on experimental data, which raised the idea of a finite formation time for the produced medium. At the RHIC energy and in low-density corona region, this time reaches about 2 fm/c. Following this hypothesis, the nuclear modification factor R _AA at high p _t should be independent on particle momentum, and the azimuthal anisotropy of high p _t particles, v ₂, should be finite. A separate prediction held that, at the LHC energy, the formation time in the corona region should be about 1 fm/c. New LHC data show that R _AA is not flat and is rising with p _t . We add to our original hypothesis an assumption that a fast parton traversing the produced medium loses the fixed portion of its energy. A shift of about 7 GeV from the original power law p ^?6 production cross section in pp explains well all the observed R _AA dependencies. The shift of about 7 GeV is also valid at the RHIC energy. We also show that the observed at the LHC dependence of v ₂ at high p _t and our previous predictions agree.     

Contribution of the charged Higgs boson to the production of a <Emphasis Type="Italic">tb</Emphasis> pair in hadron collisions

The contribution of the charged Higgs boson to the production of a tb pair in pp collisions at LHC is investigated. It is shown that, due to H^±-boson exchange, the total yield of tb pairs is modified significantly for small and large values of tan β. At small values of tan β, the production of right-handed t quarks is also expected, however, in contrast to what occurs in the case of only W^±-boson exchange, generating left-handed t quarks exclusively. This fact provides the possibility of separating the H^± and W^± contributions by investigating the angular distributions of products originating from top-quark decay. A detailed simulation of signal and relevant background processes is performed.     

Top-quark <Emphasis Type="Italic">p</Emphasis><Subscript><Emphasis Type="Italic">T</Emphasis></Subscript>-spectra at CMS and flavor independence of <Emphasis Type="Italic">z</Emphasis>-scaling

We present new results of analysis of top-quark differential cross sections obtained by the CMS Collaboration in pp collisions in the framework of the z-scaling approach. The spectra are measured over a wide range of collision energy \(\sqrt s = 7,8,13TeV\) and transverse momentum p _T = 30?500 GeV/c of top-quark using leptonic and jet decay modes. Flavor independence of the scaling function ψ(z) is verified in the new kinematic range. The results of analysis of the top-quark spectra obtained at the LHC are compared with similar spectra measured in \(\overline p p\) collisions at the Tevatron energy \(\sqrt s = 1.96TeV\). A tendency to saturation of ψ(z) for the process at low z and a power-law behavior of ψ(z) at high z is observed. The measurements of high-p _T is observed. The measurements of highspectra of the top-quark production at highest LHC energy is of interest for verification of self-similarity of particle production, understanding flavor origin and search for new physics symmetries with top-quark probe.     

Study of collective flow effects in CC collisions at a momentum of 4.2 GeV/<Emphasis Type="Italic">c</Emphasis> per nucleon

Directed (in-plane) flows of protons, pions, and projectile light fragments (d, t, ³He, ⁴He) have been observed by investigating the dependence of the mean transverse momentum in the reaction plane 〈p _x 〉 on the rapidity y in the c.m. system for CC collisions at a momentum of 4.2 GeV/c per nucleon. The comparison of our in-plane-flow results of protons with flow data for various projectile/target configurations was made using the scaled flow F _s = F/(A _P ^1/3 + A _T ^1/3 ). F _s demonstrates a common scaling behavior for flow values from different systems. From azimuthal distributions of protons and π^? mesons, out-of-plane (squeeze-out) flow effects have been observed and the parameter a₂ (the measure of the anisotropic emission strength) has been extracted. The quark-gluon string model reproduces the experimental results quite well.     

Inclusive deuteron production in <Superscript>16</Superscript>O<Emphasis Type="Italic">p</Emphasis> collisions at a momentum of 3.25 GeV/<Emphasis Type="Italic">c</Emphasis> per nucleon

Experimental data on inclusive deuteron production in ¹⁶Op collisions at high energies were obtained for the first time under conditions of 4π geometry. An irregularity in the momentum spectrum of deuterons in the rest frame of oxygen nuclei is found in the range 0.40 ≤ p ≤ 0.55 GeV/c, and the reasons for its appearance are discussed. The mean multiplicities of secondary fragments are correlated with the presence of deuterons in an event, these correlations being positive for fragments of charge in the range z _f ≤ 4 and negative for fragments of charge in the range 5 ≤ z _f ≤ 7. This is likely to be due to baryon-charge conservation.     

Investigation of <Emphasis Type="Italic">pn</Emphasis> correlations in <Superscript>4</Superscript>He<Emphasis Type="Italic">p</Emphasis> interactions at a momentum of 5 GeV/<Emphasis Type="Italic">c</Emphasis>

Proton-neutron correlations in ⁴Hep interactions are studied in an exclusive experiment by using a 2-m bubble chamber exposed to a 5-GeV/c beam of α particles (the kinetic energy of the protons in the nucleus rest frame is T _p = 620 MeV). Data on the production of pn pairs in 4π geometry for three channels, where it is possible to reconstruct the neutron momentum unambiguously, are used to determine the pn correlation function in ⁴Hep interactions. The experimental results are compared with the predictions of a modified Lednicky-Lyuboshitz model. The value obtained for the root-mean-square radius of the pn-emission region is R _pn = 2.1 ± 0.3 fm. The dependence of the correlation function on the modulus of the total momentum of the emitted nucleon pair and on the direction of the momentum transfer is studied. An indication that the emission of a pn pair proceeds predominantly through the production of a virtual deuteron is obtained.     

Monomer counterrotations and tunneling splitting in CO dimer by data of millimeter wave spectroscopy

Analysis of the rotational spectrum of the molecular dimer (CO)₂ measured in the millimeter wave range has been performed and four new rotational states are revealed. Three of these states are characterized by almost free rotations of both monomers in the dimer. These states have approximately the same first term σ in the expansion of the rotational energy in powers of the rotational angular momentum J for various values of the momentum projections on the dimer axis (K=0, 1, 2) and various rotational constants B. The intrinsic rotational angular momenta of CO dimers, j₁=j₂=1, are determined from the σ value. In addition, a state with K=2 is found which corresponds to one of the known shape isomers of (CO)₂. The values of the tunneling splitting for each of the new states are determined. The results indicate that previous data on the suppressed tunneling are determined by the asymmetry of internal rotations in the CO monomers rather than by the _K value.