Intersubband cyclotron resonance of holes in strained Ge/GeSi(111) heterostructures with germanium wide quantum wells and cyclotron resonance of 1<Emphasis Type="Italic">L</Emphasis> electrons in GeSi layers

The submillimeter (?ω=0.5–5 meV) magnetoabsorption spectra of strained Ge/Ge_1?xSi_x(111) multilayer heterostructures with thick Ge layers (d_Ge=300–850 Å, d_GeSi≈200 Å, x≈0.1) are investigated at T=4.2 K upon band-gap optical excitation. It is revealed that the absorption spectra contain cyclotron resonance lines of 1L electrons localized in GeSi solid solution layers (unlike the previously studied structures with thin Ge layers as quantum wells for 3L electrons). The absorption spectra of the samples with thick Ge layers (d_Ge=800–850 Å) exhibit cyclotron resonance lines of holes due to transitions from the lower Landau levels in the first quantum-well subband to the Landau levels belonging to the third and fifth higher subbands.     

A Formal Model of Berezin-Toeplitz Quantization

We give a new construction of symbols of the differential operators on the sections of a quantum line bundle L over a Kähler manifold M using the natural contravariant connection on L. These symbols are the functions on the tangent bundle TM polynomial on fibres. For high tensor powers of L, the asymptotics of the composition of these symbols leads to the star product of a deformation quantization with separation of variables on TM corresponding to some pseudo-Kähler structure on TM. Surprisingly, this star product is intimately related to the formal symplectic groupoid with separation of variables over M. We extend the star product on TM to generalized functions supported on the zero section of TM. The resulting algebra of generalized functions contains an idempotent element which can be thought of as a natural counterpart of the Bergman projection operator. Using this idempotent, we define an algebra of Toeplitz elements and show that it is naturally isomorphic to the algebra of Berezin-Toeplitz deformation quantization on M.     

A new crystalline HMX polymorph: ɛ-HMX

A new crystalline HMX polymorph, ?-HMX, was obtained. ?-HMX crystals were studied by X-ray structure analysis, optical microscopy, and differential scanning calorimetry. Their space group is P2₁/c. The unit cell parameters are a = 21.799(3) Å, b = 10.913(2) Å, c = 10.819(2) Å, and β = 97.43(2)°, V = 2552.15 ų, Z = 4. ?-HMX molecules are not equivalent in crystals and have chair conformations. The heat of the polymorphic transition of ?-HMX into the δ-polymorph was measured. The transition occurred with the intermediate formation of β-HMX. The dependence between the heats of polymorphic transitions and the densities of crystals of various HMX polymorphs was demonstrated. The character of this dependence was to a substantial extent determined by the type of HMX molecule conformation.     

X-ray structure analysis of the polycrystalline complex of copper (II) chloride with 1,5-dimethyltetrazole. Application of synchrotron radiation and laboratory diffraction data

The structure of the complex of copper (II) chloride CuCl₂ L, where L is 1,5-dimethyltetrazole, was refined with the Rietveld method using three sets of powder diffraction data obtained at laboratory diffractometers and with synchrotron radiation. The comparative analysis of the results of the structure refinement was performed; this analysis showed that the application of the laboratory data for the wavelength of X-rays λ = 1.7902 Å (CoKα radiation) provides the structural characteristics of the complex comparable in accuracy with those obtained using the synchrotron radiation for the wavelength λ = 1.5443 Å.     

Synthesis,Crystal Structure and Luminescent Properties of Some Zn(II) Schiff Base Complexes: Experimental and Computational Study

A series of Zn(II)-Schiff bases I, II and III complexes were synthesized by reaction of o-phenylenediamine with 3-methylsalicylaldehyde, 4-methylsalicylaldehyde and 5-methylsalicylaldehyde. These complexes were characterized using FT-IR, UV-Vis, Diffuse reflectance UV-Vis, elemental analysis and conductivity. Complex III was characterized by XRD single crystal, which crystallizes in the triclinic system, space group P-1, with lattice parameters a?=?9.5444(2) Å, b?=?11.9407(2) Å, c?=?21.1732(3) Å, V?=?2390.24(7) ų, D _c ?=?1.408 Mg m^?3, Z?=?4, F(000)?=?1050, GOF?=?0.981, R1?=?0.0502, wR2?=?0.1205. Luminescence property of these complexes was investigated in DMF solution and in the solid state. Computational study of the electronic properties of complex III showed good agreement with the experimental data.     

Messung derL-Auger-, Fluoreszenz- und Coster-Kronig-Ausbeuten von Gold

An apparatus is described, with which, for the first time, the spectra of Augere-lectrons and of X-rays, produced by the impact of electrons, were measured simultaneously. The electron spectrometer was a magnetic 180°-spectrometer with a half-width of 0·5%. The X-ray spectrometer was a NaJ-crystal with a photomultiplier. The electron- and the X-rays were produced in metallic foils of a thickness of 50 Å by the impact of 55-keV-electrons. The knownK-fluorescence-yields of copper and selenium were used to determine the various yields for theL-shells of gold. TheL-fluorescence-yields areω _L1 =0·08±0·01;ω _L2 =0·26±0·03;ω _L3 =0·24±0·02.     

Zur Isomerie des Tl197

Tl^197m was produced by the (α, 4n) reaction on Au¹⁹⁷ using 49 MeVα particles. The following results were obtained: Half-lifeT _1/2=(0.55±0.02) sec; energy of the isomeric level (607±4) keV, determined directly by summing up the cascade transitions in a well-type scintillator; energy of the isomeric transition (222±2) keV; conversion coefficients of this transitionα _K222=0.41±0.05 andα _tot222=2.1±0.2, indicating anE3 multipolarity; energy of the second transition (385±3)keV; conversion coefficientsα _K385=0.09±0.03 andα _tot385<0.1. This transition was identified asE2 with aM1 admixture of 20 to 30%. Spins and parities are 1/2⁺, 3/2⁺ and 9/2^? for the ground state, the 385 keV state and the 607 keV isomeric state, respectively, in disagreement with the extreme single-particle model. If this model were correct, anotherM1 transition should appear. No furtherM1 transition having an energy greater than theL-shell binding energy of T1 was observed.     

Structural transformations of K<Subscript>3</Subscript>H(SO<Subscript>4</Subscript>)<Subscript>2</Subscript> crystals with variations in temperature

Single crystals of the K₃H(SO₄)₂ compound are investigated using X-ray diffraction on Xcalibur S and Bruker diffractometers. The structure of the low-temperature monoclinic phase is refined (space group C2/c, z = 4, a = 14.698(1) Å, b = 5.683(1) Å, c = 9.783(1) Å, β = 103.01(1)°, T = 293 K, Bruker diffractometer), the structural phase transition is revealed, and the structure of the high-temperature trigonal phase is determined (space group R \(\bar 3\) m, z = 3, a = 5.73(1) Å,c = 21.51(1) Å,T = 458 K, Xcalibur diffractometer).     

Micrometer-scale deformation jumps at different stages of creep in solids

Laser interferometry is used to study micrometer-scale creep-strain nonuniformities (jumps) that occur during compression of metals (Ag, Al, Bi, Cu, Pb, Sn, Zn) and LiF: Mg crystals. The strain rate is found to vary periodically. The average magnitude of deformation L over one period and the variation of L with the total strain are determined. Correlations are found to exist between L and the Mg content in the LiF crystals, between L and the grain size in the metals, and between the magnitude of small jumps and the Burgers vector in the metals.     

Structure and electrophysical properties of ferrocobaltites <Emphasis Type="Italic">Ln</Emphasis>BaFeCoO<Subscript>5 + δ</Subscript> (<Emphasis Type="Italic">Ln</Emphasis> = Tb,Dy, Ho,Y)

The ferrocobaltites LnBaFeCoO^{5 + δ} (Ln = Tb, Dy, Ho, Y) have been synthesized, and the parameters of their crystal structure have been determined. The thermal expansion, electrical resistivity ρ, and thermopower S of the synthesized compounds have been investigated in air at temperatures in the range from 300 to 1100 K. The compounds have a tetragonal structure (symmetry space group P4/mmm) with the unit cell parameters a = 3.9000 Å and c = 7.5922 Å (Ln = Tb, δ = 0.31), a = 3.8973 Å and c = 7.5679 Å (Ln = Dy, δ = 0.34), a = 3.8970 Å and c = 7.5507 Å (Ln = Ho, δ = 0.28), and a = 3.9029 Å and c = 7.5538 Å (Ln = Y, δ = 0.25). The ferrocobaltites under investigation are p-type semiconductors, and their electrical resistivity ρ and thermopower S decrease in the sequence Tb → Ho → Y → Dy (at room temperature). The linear thermal expansion coefficient of the LnBaFeCoO^{5 + δ} phases in the vicinity of the temperatures ranging from 465 to 535 K increases from (1.15?1.23) × 10^?5 to (1.73?1.93) × 10^?5 K^?1. The parameters of charge transfer in these ferrocobaltites have been determined. It has been found that an increase in the temperature leads to an increase in the excitation energy of charge carriers and a decrease in the activation energy of charge carrier transfer.     

A theoretical investigation of the effect of water on the structure and fluorescence spectra of L-tryptophan

Fluorescence spectra of two long-wavelength electron transitions S₀ ← ¹L_b and S₀ ← ¹L_a in uncharged and zwitterionic forms of L-tryptophan (Trp) in aqueous solution and in the complex of Trp with water molecule were calculated using the Frank–Condon approximation. Geometric parameters of Trp in electronically excited states were determined, and the vibrational structure of vibronic spectra was analyzed. It was shown that the relative position of structural fragments of alanine (R-Ala) and indole (R-In) could have a determining effect on the fluorescence and formation of the vibrational structure of electronic spectra. The increase of the rotation angle between the R-Ala and R-In, which depends on the Trp environment, results in the Trp fluorescence originating only from the singlet excited state ¹L_a.     

Fermi Surface Topology in the Case of Spontaneously Broken Rotational Symmetry

The relation between the broken rotational symmetry of a system and the topology of its Fermi surface is studied for the two-dimensional system with the quasiparticle interaction f(p, p') having a sharp peak at |p ? p'| = q₀. It is shown that, in the case of attraction and q₀ = 2p_F the first instability manifesting itself with the growth of the interaction strength is the Pomeranchuk instability. This instability appearing in the L = 2 channel gives rise to a second order phase transition to a nematic phase. The Monte Carlo calculations demonstrate that this transition is followed by a sequence of the first and second order phase transitions corresponding to the changes in the symmetry and topology of the Fermi surface. In the case of repulsion and small values of q₀, the first transition is a topological transition to a state with the spontaneously broken rotational symmetry, namely, corresponding to the nucleation of L ? π(p_F/q₀ ? 1) small hole pockets at the distance p_F ? q₀ from the center and the deformation of the outer Fermi surface with the characteristic multipole number equal to L. At q₀ → 0, when the model under study transforms to the two-dimensional Nozières model, the multipole number characterizing the spontaneous deformation is L → ∞, whereas the infinitely folded Fermi curve acquires the Hausdorff dimension D = 2 which corresponds to the state with the fermion condensate.     

Microwave photoresistance of a two-dimensional electron gas in a ballistic microbar

The effect of millimeter microwave radiation on the electron transport of two-dimensional (2D) ballistic microbars formed on the basis of individual GaAs quantum wells at a temperature of T = 4.2 K in magnetic fields B < 0.6 T has been investigated. Differences have been revealed in the magnetic field dependences of the microwave photoresistance of a 2D electron gas in Hall bars with a length L and a width W for the cases L, W > l _p and L, W < l _p , where l _p is the electron mean free path for momentum. The microwave photoresistance in macroscopic bars (L, W > l _p ) is a periodic alternating function of the inverse magnetic field; in microbars (L, W < l _p ), it is a periodic positive function of 1/B. The experimental results indicate that the mechanisms of the microwave photoresistance of a 2D electron gas are different for macroscopic and microscopic bars.     

Das Kernquadrupolmoment des Mn55

With a recording photoelectric Fabry-Perot spectrometer and an atomic-beam light source the hyperfine structure of the Mn I-resonance linesλ=4031 Å,λ=4033 Å,λ=4034 Å (3d ⁵4s ² a ⁶ S _5/2?3d ⁵4s4p z ⁶ P _7/2,5/2,3/2 ⁰)and of the inter-combination linesλ=5395 Å andλ=5433 Å (3d ⁵4s ² a ⁶ S _5/2?3d ⁵4s4p z ⁸ P _7/2,5/2 ⁰) was measured. Furthermore the resonance lines have been measured with a pulsed atomic-beam in absorption. In this case the quotient (I ₀(ν)?I(ν))/I ₀(ν) was recorded, whereI(ν)=I ₀(ν) exp(?α(ν)d) is the observed intensity with absorption andI ₀(ν) the intensity of the light source. From the hyperfine structure splitting the value of the electric quadrupole moment of Mn⁵⁵ was derived to be:Q(Mn⁵⁵)=+(0.35±0.05)·10^?24 cm².     

Solid–liquid phase transition in a Gibbs monolayer of melissic acid at the n-hexane–water interface

A sharp phase transition from a crystalline state with the area per molecule A = (17 ± 1) Ų to a liquid state with A = (23 ± 1) Ų at the n-hexane–water interface in a Gibbs monolayer of melissic acid has been revealed in data of X-ray reflectometry with the use of synchrotron radiation.     

Das Auger-Spektrum derL III- Schale von Wismut

A thin Bi layer is irradiated by X-rays so thatL-Auger electrons are emitted. A magnetic lens spectrometer is used to measure the electron spectrum. Energy, transition, and relativ intensity are given for 14 lines. Under the most favourable conditions the number ofL _III ionisations is about ten times that ofL _II ionisations. In this case only a small intensity ofL _II-Auger electrons is superposed on theL _III-Auger spectrum. The ratiod of intensities of line groupL _III M N to line groupL _III M M is found by extrapolation to bed=0·46±0·02. This combined with earlier results gives anL _III-Auger yielda ₃= 0·64±0·04. TheL _III fluorescenc yield isω ₃=0·36±0·04, correspondingly. A further application of the experimental method is described.     

Thin ferroelectric Nd-doped BiFeO<Subscript>3</Subscript> films with orthorhombic structure

X-ray diffraction and Raman spectroscopy of epitaxial Nd-doped bismuth ferrite films on MgO substrates reveal their orthorhombic symmetry Fmm2 (a = 7.914 Å, b = 7.913 Å, and c = 7.937 Å).     

Hall-Petch analysis for temperature and strain rate dependent deformation of polycrystalline lead

A dislocation pile-up analysis of the Hall-Petch constant k _ε for the tensile deformation of polycrystalline lead over a wide range of temperature T and at two strain rates has been made. The predicted and experimental Hall-Petch dependencies k _ε ² = f (T) are in good agreement. Lower than predicted k _ε values at very low temperatures are attributed to the high curvature of grain boundaries which experience high localized plasticity and consequent shear banding.     

Scaling of the conductance and resistance of square lattices with an exponentially wide spectrum of the resistances of links

The conductance G? and \(\overline {{G^{ - 1}}} \) resistance average over realizations of disorder have been calculated for various sizes of square lattices L. In contrast with different direction of change in the two quantities at percolation in lattices with the binary spread of conductances of links (g _i = 0 or 1), it has been found that the mean conductance and resistance of lattices decrease simultaneously with an increase in L in the case of an exponential distribution of local conductances g _i = exp(?kx_i), where x _i ∈ [0,1] are random numbers. When L is smaller than the disorder length L₀ = bk^v, G?(L) and \(\overline {{G^{ - 1}}} \)(L) are proportional to L^?n with n = k/5 and k/6, respectively. A similar behavior is characteristic of the distributions of conductances of links, which simulate a transition between the open and tunneling regimes in semiconducting lattices of antidots created in a two-dimensional electron gas.     

Numerical analysis of electronic conductivity in graphene with resonant adsorbates: comparison of monolayer and Bernal bilayer

We describe the electronic conductivity, as a function of the Fermi energy, in the Bernal bilayer graphene (BLG) in presence of a random distribution of vacancies that simulate resonant adsorbates. We compare it to monolayer (MLG) with the same defect concentrations. These transport properties are related to the values of fundamental length scales such as the elastic mean free path L _e , the localization length ξ and the inelastic mean free path L _i . Usually the later, which reflect the effect of inelastic scattering by phonons, strongly depends on temperature T. In BLG an additional characteristic distance l ₁ exists which is the typical traveling distance between two interlayer hopping events. We find that when the concentration of defects is smaller than 1%–2%, one has l ₁ ≤ L _e ? ξ and the BLG has transport properties that differ from those of the MLG independently of L _i (T). Whereas for larger concentration of defects L _e <l ₁ ? ξ, and depending on L _i (T), the transport in the BLG can be equivalent (or not) to that of two decoupled MLG. We compare two tight-binding model Hamiltonians with and without hopping beyond the nearest neighbors.