Temperature dependent ultrasonic properties of aluminium nitride

Hexagonal wurtzite structured aluminium nitride has been characterized by the theoretical calculation of ultrasonic attenuation, ultrasonic velocity, higher order elastic constants, thermal relaxation time, acoustic coupling constants and other related parameters in temperature range 200-800 K for wave propagation along the unique axis of the crystal. Higher order elastic constants of AlN at different temperatures are calculated using Lennard-Jones potential for the determination of ultrasonic attenuation. A decrease in ultrasonic velocity with temperature has been predicted, which is caused by reduction in higher order elastic constants with temperature. The temperature dependent ultrasonic properties have been discussed in correlation with higher order elastic constants, thermal relaxation time, thermal conductivity, acoustic coupling constants and thermal energy density. Anomalous behaviour of the attenuation is found at 400 K. On the basis of attenuation, the ductility and performance of AlN have been studied.     

On the propagation of linear transverse acoustic waves in isotropic media with mechanical relaxation phenomena due to viscosity and a tensorial internal variable: II. Some cases of special interest (Poynting-Thomson,Jeffreys, Maxwell,Kelvin-Voigt,Hooke and Newton media)

The propagation of linear transverse acoustic waves in isotropic media in which mechanical relaxation phenomena occur was considered in a previous paper. In particular expressions for the velocity and attenuation of the waves were obtained and the limiting cases of waves with high and low frequencies were discussed. In the present paper we investigate the propagation of linear transverse acoustic waves in Poynting-Thomson, Jeffreys, Maxwell, Kelvin-Voigt, Hooke and Newton media. We show that the dispersion relations for these waves may be considered as degeneracies of the dispersion relation which we derived in the general case of a viscoanelastic medium with memory. In particular we investigate the explicit dependence of the dispersion relations on the thermodynamic parameters and the phenomenological coefficients.     

Ultrasonic wave propagation in IIIrd group nitrides

The ultrasonic attenuation in hexagonal structured (wurtzite) third group nitrides (GaN, AlN and InN) has been evaluated at 300 K for an ultrasonic wave propagating along the unique axis of the crystal. Higher order elastic constants of these materials are calculated using the Lennard-Jones potential for the determination of ultrasonic attenuation. The ultrasonic velocity, Debye average velocity, thermal relaxation time and acoustic coupling constant are evaluated along the z-axis of the crystal using the second order elastic constants and other related parameters. The contributions of the elastic constants, thermal conductivity, thermal energy density, ultrasonic velocity and acoustic coupling constant to the total attenuation are studied. On the basis of the ultrasonic attenuation, it can be concluded that the AlN is more ductile than either GaN or InN at 300 K. Orientation dependent characterization has been achieved by calculation of the orientation dependent ultrasonic velocity, Debye average velocity and thermal relaxation time for the materials.     

A thermodynamic discussion of the possibility of singular yield conditions in plasticity theory

A generalization is given of the author's theory for plasticity phenomena. The generalization leads to the possibility that the yield surface has singularities. From the theory a formula may be derived which is analogous to a formula proposed by Koiter for plastic flow in media with singular yield surfaces. The possibility of elastic relaxation phenomena in the preplastic range is included in the developed formalism.     

Nonlinear wave processes in porous waterlike media containing a system of capillaries partially filled with a viscous liquid

A nonlinear dynamic state equation of waterlike porous material that contains a system of cylindrical capillaries partially filled with viscous liquid was received. It is shown that an acoustic nonlinearity of such media contains the relaxation elastic and inelastic components due to the nonlinear dependence of the capillary and viscous pressure in fluid on the capillary diameter. For the medium, theoretical study of such nonlinear phenomena as generation of the second harmonic and a difference frequency wave, self-demodulation of high-frequency pulses as well as the change in the propagation velocity and absorption coefficient of a test wave being under an action of static loading have been carried out. The frequency dependences of medium nonlinearity parameters for these processes were determined.     

Effect of periodic corrugation,reinforcement, heterogeneity and initial stress on Love wave propagation

This paper investigates the impact of corrugated boundary surfaces, reinforcement on the propagation of Love-type wave in prestressed corrugated heterogeneous fiber-reinforced layer resting over a void pores half-space. The heterogeneity in the upper corrugated layer is caused due to exponential variation in the elastic constants with respect to the space variable pointing positively downwards. The dispersion equation in the complex form has been derived using method of separation of variables. The real and imaginary parts of the complex dispersion equation were separated and found in well agreement with the classical Love wave equation. Also, the attenuation of the Love waves has been discussed. The study reveals that such a medium transmits two fronts of Love waves. The first front depends upon the change in volume fraction of the pores and the second front depends upon the modulus of rigidity of the elastic matrix of the medium. The substantial influence of corrugation parameters, reinforcement, undulatory parameter, initial stress, heterogeneity parameter and position parameter on the phase velocity, and attenuation of Love-type wave have been observed and depicted by means of graph. It has been observed that the phase velocity decreases with the increase in initial stress parameters, heterogeneity, and reinforcement in upper layer.     

A model for the propagation of nonlinear dispersive strain waves in a solid with defect clusters

A model for the propagation of nonlinear dispersive one-dimensional longitudinal strain waves in an isotropic solid with quadratic nonlinearity of elastic continuum is developed with taking into account the interaction with atomic defect clusters. The governing nonlinear dispersive-dissipative equation describing the evolution of longitudinal strain waves is derived. An approximate solution of the model equation was derived which describes asymmetrical distortion of geometry of the solitary strain wave due to the interaction between the strain field and the field of clusters. The contributions of the finiteness of the relaxation times of cluster-induced atomic defects to the linear elastic modulus and the lattice dissipation and dispersion parameters are determined. The amplitudes and width of the nonlinear waves depend on the elastic constants and on the properties of the defect subsystem (atomic defects, clusters) in the medium. The explicit expression is received for the sound velocity dependence upon the fractional cluster volume, which is in good agreement with experiment. The critical value of cluster volume fraction for the influence on the strain wave propagation is determined.     

Rayleigh wave propagation along the boundary of a non-Newtonian fluid-saturated porous medium

The Frenkel-Biot theory is used to study the reflection of elastic waves from the boundary of a non-Newtonian (Maxwell) fluid-saturated porous medium. The velocity and attenuation of a Rayleigh surface wave propagating along the boundary of the medium are determined. Two models of a fluid-saturated porous medium are used for calculation: with pore channels of a fixed diameter and with a lognormal distribution of pore channels in size. The results of calculations show that, when the fluid in the porous medium is characterized by a small Deborah number (i.e., exhibits non-Newtonian properties), the velocity of Rayleigh waves exhibits a considerable frequency dispersion. The results also suggest that, in principle, it is possible to estimate the Deborah number from the measured frequency dispersion of the Rayleigh wave velocity.     

Wave propagation in 2D elastic composites with partially debonded fibres by the null field approach

Time-harmonic plane wave propagation in a two-dimensional (2D) elastic matrix with partially debonded elastic fibres of nonclassical cross-section is investigated. The modified null field approach, taking into account the asymptotic behaviour of the solution at the interface crack-tips, is exploited to obtain the numerical results for a single scatterer. The effective medium approach based on Foldy's approximation is applied to estimate the average dynamic parameters of the composites containing randomly distributed partially debonded fibres of dilute concentration. Numerical results concern the longitudinal wave dispersion and attenuation owing to scattering by both randomly oriented and aligned fibres. The effects of the fibre shape, debonding (interface crack) size and direction of wave incidence on the effective P-wave velocity and attenuation coefficient are analysed.     

Rayleigh wave at the boundary of an inhomogeneous nonlinear viscoelastic half-space

In the approximation of weak nonlinearity and weak viscosity of the medium, we obtain an equation describing the spectral density of the particle horizontal velocity for a Rayleigh wave propagating along the boundary of a half-space. The coefficients of nonlinear interaction between the wave harmonics are found on the assumption that the third-order elastic moduli arbitrarily depend on the depth. We find expressions for the complex correction to the wave frequency due to small relaxation corrections to the elastic moduli and small variations in the medium density, which arbitrarily depend on the depth as well. The imaginary part of this correction to the frequency determines the decay of the linear Rayleigh wave due to small relaxation corrections to the elastic moduli arbitrarily dependent on the depth. Using numerical simulation (with allowance for the interaction of 500 harmonics), we study distortions of an initially harmonic Rayleigh wave for a particular dependence of variations in the nonlinear moduli on the depth. An integral equation is derived for the nonlinear elastic moduli as functions of the depth. It is shown that for independent spatio-temporal distributions of the viscous moduli, functions determining the dependence of the viscosity on the depth are described by an analogous integral equation. __________ Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Radiofizika, Vol. 50, No. 3, pp. 212–226, March 2007.     

Influence of static and dynamic internal actions on elastic nonlinear properties of a granulated unconsolidated medium

We have studied the influence of external static (pressure) and dynamic (caused by an elastic wave with a finite amplitude) actions on the linear and nonlinear elastic properties of a granulated unconsolidated medium, which was simulated by steel spheres with diameters of 2 and 4 mm. We have analyzed the equation of state for such a medium taking into account the presence of weakly and strongly deformed contacts between individual spheres. We have obtained expressions for the elasticity coefficient and second- and third-order nonlinear elastic parameters, and we have experimentally studied the influence of external static pressure on their values. We have measured the dependence of the velocity of elastic waves on external static pressure and the probing signal amplitude. In the studied medium, a number of structural phase transitions were observed, related to rearrangement of the packing of spheres, which were caused by both static and dynamic actions. The structural phase transition was accompanied by an anomalous change in the nonlinear elastic parameters of the medium and the velocity of elastic waves. We have analyzed the results based on the Hertz theory of contact interaction.     

线性黏弹性各向异性介质速度频散和衰减特征研究

地层岩石既非各向同性的,也非完全弹性的,正确地描述波在地层中的传播需要搞清楚岩石的各向异性和黏弹性特征.针对裂缝性地层的裂缝发育方位问题,建立具有任意方位角的方位各向异性黏弹性本构关系.使用均匀平面简谐波分析方法研究其频散关系,得到Christoffel方程,进而获得均匀平面波的复速度、相速度、衰减系数和品质因子的表达式.通过黏弹性方位各向异性页岩和砂岩进行模拟,研究了波场在地层中的传播特征,如相速度、衰减系数和品质因子等随频率、方位和入射角的变化关系 关键词： 黏弹性 各向异性 相速度 衰减系数 品质因子     

各向异性渗流条件下弹性波的传播特征

研究了弹性波在非均匀裂纹孔隙介质中的传播特性,建立了各向异性喷射流模型.当弹性波通过裂纹孔隙介质时,由于波的扰动及裂纹和孔隙几何结构的不一致,导致在裂纹内部及裂纹与周边孔隙之间同时存在着流体压力梯度.此时的弹性波波动响应中包含着裂纹内连通性特征和背景孔隙渗透率信息.流体的动态流动过程使得介质的等效弹性参数为复数(非完全弹性),并且具有频率依赖性.当弹性波为低频和高频极限时,介质为完全弹性;当处于中间频段时,波有衰减和频率依赖.裂纹孔隙介质的各向异性连通性(渗透率)对应着各向异性特征频率(当渗流长度等于非均匀尺度时的弹性波频率),波的传播受到裂纹内连通性的影响.在一定频段内,随着裂纹厚度的增加,将出现第二峰值,峰值大小同时受到裂纹厚度和半径的影响.     

Relaxation and resonance ultrasound attenuation by Jahn-Teller centers in a GaAs:Cu crystal

The interaction of ultrasound with Cu_Ga4As in a GaAs:Cu crystal has been experimentally studied. The temperature dependences of the attenuation of all normal ultrasonic modes propagating in the ??110?? direction both in doped copper and in nominally pure gallium arsenide crystals have been measured. In the GaAs:Cu crystal, the attenuation peak has been revealed for a transverse wave polarized along the ??110?? axis whose elastic shifts correspond to the symmetry of the tetragonal mode of the Jahn-Teller effect. The temperature dependence of the attenuation of this wave indicates that two types of attenuation??relaxation and resonance??occur. The constructed temperature dependence of the relaxation time indicates that tunneling through the potential barrier between the minima of the adiabatic potential energy is the main relaxation mechanism at temperatures below 10 K. Tunneling splitting estimated from experimental data is in good agreement with the theoretical estimate.     

Ultrasonic self-calibrated method applied to monitoring of sol-gel transition

In many industrial processes where online control is necessary such as in the food industry, the real time monitoring of visco-elastic properties is essential to ensure the quantity of production. Acoustic methods have shown that reliable properties could be obtained from measurements of velocity and attenuation. This paper proposes a simple, real time ultrasound method for monitoring linear medium properties (phase velocity and attenuation) that vary in time. The method is based on a pulse echo measurement and is self-calibrated. Results on a silica gel are reported and the importance of taking into account the changes of the mechanical loading on the front face of the transducer will be shown. This is done through a modification of the emission and reception transfer parameters. The simultaneous measurement of the input and output currents and voltages enables these parameters to be calculated during the reaction. The variations of the transfer parameters are in the order of 6% and predominate other effects. The evolution of the ultrasonic longitudinal wave phase velocity and attenuation as a function of time allows the characteristic times of the chemical reaction to be determined. The results are well correlated with the gelation time measured by rheological method at low frequency.     

Properties of photocured epoxy resin materials for application in piezoelectric ultrasonic transducer matching layers

This paper describes the acoustic properties of a range of epoxy resins prepared by photocuring that are suitable for application in piezoelectric ultrasonic transducer matching layers. Materials, based on blends of diglycidyl ether of Bisphenol A and 1,4-cyclohexanedimethanol diglycidyl ether, are described. Furthermore, in order to vary the elastic character of the base resin, samples containing polymer microspheres or barium sulfate particles are also described. The acoustic properties of the materials are determined by a liquid coupled through transmission methodology, capable of determining the velocity and attenuation of longitudinal and shear waves propagating in an isotropic layer. Measured acoustic properties are reported which demonstrate materials with specific acoustic impedance varying in the range 0.88-6.25 MRayls. In the samples comprising blends of resin types, a linear variation in the acoustic velocities and density was observed. In the barium sulfate filled samples, acoustic impedance showed an approximately linear variation with composition, reflecting the dominance of the density variation. While such variations can be predicted by simple mixing laws, relaxation and scattering effects influence the attenuation in both the blended and filled resins. These phenomena are discussed with reference to dynamic mechanical thermal analysis and differential scanning calorimetry of the samples.     

Frequency dependence of acoustic properties of aqueous glucose solutions in the VHF/UHF range

The bioultrasonic spectroscopy system was employed for measurements of velocity and attenuation coefficient of glucose solutions in the VHF/UHF range. The relation between the slope of the square of velocity and the relaxation parameters, and the relation between the frequency exponent on attenuation coefficient and the relaxation parameters are investigated. In order to carry out numerical calculations, a model for a single relaxation process is employed, wherein the attenuation coefficient is expressed as (A/( 1 + (f/falpha)2) + B)f2 where falpha is the attenuation relaxation frequency, and A and B are constants. The numerical calculations show that the slope of the square of the velocity is determined uniquely by the velocity relaxation frequency fv and v(infinity)2 - v(0)2 where v0 is the zero-frequency velocity and v(infinity) is the infinite-frequency velocity, and that the frequency exponent on the attenuation coefficient is determined uniquely by falpha and A/B. For experimental considerations, the velocities and the attenuation coefficients of 5, 15, and 25% concentration aqueous solutions of glucose were measured in the frequency range 20 to 700 MHz. The data for the 5 and 15% aqueous solutions can be explained using the single relaxation model. However, the data for the 25% aqueous solution suggest the existence of multirelaxation processes.     

Influence of the surrounding pressure on acoustic properties of slightly compressible porous media permeated with air-filled bubbles

The effective wave velocity, attenuation, and nonlinear properties of slightly compressible porous media permeated with air-filled bubbles are studied numerically by employing the nonlinear Hooke’s law for different surrounding pressures. Numerical simulations show that the acoustic properties of porous media are greatly affected by the surrounding pressure if the shear modulus of the elastic medium is very small due to the fact that the acoustic wave propagation in porous media are strongly influenced by the nonlinear oscillation of bubbles; moreover, the oscillation of a bubble depends on the equilibrium bubble radius, which is affected by the surrounding pressures. Published in Russian in Akusticheskiĭ Zhurnal, 2006, Vol. 52, No. 4, pp. 490–496. The text was submitted by the authors in English.     

无限流体中孔隙介质圆柱周向导波的传播特性

为研究无限大流体约束的孔隙圆柱中周向导波的传播规律,分析孔隙参数对导波传播特性的影响,建立了无限流体中孔隙介质圆柱的理论模型,利用孔隙介质弹性波动理论,建立了周向导波频散方程,通过数值模拟计算得到无限流体中孔隙介质圆柱的频散曲线,探讨了圆柱半径和孔隙参数对导波传播特性的影响,并对导波的衰减特性进行了分析;通过数值计算,得到了周向导波的时域波形,讨论了孔隙参数对波形的影响.结果表明,孔隙介质圆柱半径的改变影响圆柱尺度,孔隙度的改变影响孔隙介质中体声波的波速,都对周向导波频散曲线产生一定的影响,所得到的频散曲线特征及衰减曲线与时域波形吻合.研究结果对开展无限流体中孔隙介质圆柱的超声无损评价提供了一定的理论参考.