A Variational Principle for Thermodynamical Waves

When the dissipative processes are dominant in the system, the assumption of local equilibrium holds good and the space time evolution of irreversible system can be described by the variational principle of GYARMATI. However when imposed changes in the state variables are fast, the system can not be in a state of local equilibrium and to define the nonequilibrium state of the system it is necessary to extend the formalism of classical irreversible thermodynamics. The wave approach of Onsagerian thermodynamics is one such pursuit and is a direct generalization of the original Onsager-Machlup proposition. An important consequence of this theory is that it leads to transport equations with finite propagation velocities, which are referred to as thermodynamical waves. In this note we endeavour to write the appropriate form of GYARMATI'S variational principle for thermodynamical waves.     

Derivation of the nonlinear hydrodynamic equations using multi-mode techniques

A general mode-mode coupling theory is developed for the microscopic mass, energy and momentum densities of a simple classical fluid. A projection operator method is employed to derive a generalized Langevin equation that contains nonlinearities of all orders with both convective and dissipative terms. A general nonequilibrium ensemble average, which contains local equilibrium as a special case, is employed to derive nonlinear transport equations that are nonlocal in both space and time.The nonlinear Euler and Navier-Stokes equations are recovered using a factorization procedure based on an inverse system size approximation. We show that in the context of mode-mode coupling theory, nonlinearities of all orders must be retained to derive the full nonlinear transport equations. We also slow that the space and time dependent nonequilibrium pressure and transport coefficients are functions of the nonequilibrium mass and internal energy densities. The thermodynamic closure relationships follow as a natural consequence of mode-mode coupling theory. For a system linearly displaced from equilibrium we demonstrate the role of the corrections to our factorization approximation in renormalizing the transport coefficients.     

Non-equilibrium thermodynamics and dissipative fluid theories

Summary Some of the available, phenomenological studies on the dissipative fluid theories have involved extending the set of independent dynamical variables. In the favourite case of a chemically inert fluid, one can propose to enlarge the usual hydrodynamic space both by introducing eight components of the stress deviator and the heat flux and by treating them as the fundamental variables on the same footing as the mass density and the specific internal energy. A candidate theory of this kind is based upon the quasi-linear, first-order partial differential equations for the evaluation of all variables. In this paper, the differential field equations are studied with a view to a deeper understanding of non-equilibrium thermodynamics for dissipative fluids. A characteristic feature of the endeavour is that not only it is now possible to have the differential field equations consistent with a supplementary balance law, interpreted as the equation of balance of entropy, but also possible to clarify the meaning of temperature and pressure beyond local equilibrium and to obtain the theory of thermodynamic potentials for systems ?not infinitesimally near to equilibrium?. These results are achieved via the use of the critical-point theory, as formulated by Morse, in the context of the well-known extremum property of entropy. Mathematically, the supplementary balance law is derived by exploiting the calculus of ?vertical? differential forms, and the differential field equations are defined intrinsically,i.e. without making any explicit reference to a particular coordinate system. Finally, the paper discusses some problems concerning the structure of an expression for the entropy flux.     

Projection operators in classical kinetic theory

Zwanzig's projected kinetic equation is rederived by a perturbation method. A choice of projection is proposed which, in conjunction with appropriate initial-value conditions, yields kinetic equations for the two time distribution functions of phase subsets for a system in equilibrium. These equations are generalizations of the Fokker-Planck equations in which the dissipative terms are non-Markoffian.

It is shown that exact equations for the van Hove self and distinct correlation functions are particular cases of these equations.     

Spatial correlations in nonequilibrium systems: The effect of diffusion

We show how the ideas of the fluctuation-dissipation theory can be used to calculate spatial correlations in interacting systems away from equilibrium. The only spatially dependent dissipative process considered is diffusion, and spatial correlations are generated by the nonlocal spatial dependence of the chemical potential. The results are the lowest order in a hierarchy of generalized hydrodynamic type calculations applicable to nonequilibrium systems. We derive equations for the density correlation functions at stationary state supported by diffusive fluxes and show that they have the local equilibrium form. The static correlation function is obtained from the fluctuation-dissipation theorem, which we show to be equivalent to the Ornstein-Zernike integral equation. At equilibrium we demonstrate that the dynamical structure factor obtained by these methods includes the expected wave-vector dependent diffusion constant. Finally we derive a necessary and sufficient condition for local equilibrium to obtain at a stationary state and show by explicit calculation that chemical processes can give rise to significant nonequilibrium correlations.     

Fokker-Planck equation approach to fluctuations about nonequilibrium steady states

We examine the properties of steady states in systems which interact at the boundary with a nonequilibrium environment. The examination is based on a nonlinear Fokker-Planck equation, the structure of which is determined by the fact that it also governs the time evolution of the equilibrium fluctuations of the system. The nonlinearities in the Fokker-Planck equation may have two origins: thermodynamic nonlinearities which arise if the thermodynamic potential is not a bilinear function of the state variables, and nonlinear mode coupling which arises if the transport coefficients depend on the state. While these nonlinearities have only a small effect on the equilibrium fluctuations of a system away from critical points, they are shown to be important for the determination of fluctuations about nonequilibrium steady states. In particular the state dependence of the transport coefficients may lead to deviations from local equilibrium and to a breakdown of detail balance. An explicit formula for the time correlations of fluctuations about the nonequilibrium steady state is obtained. The formula leads to long-range correlations in fluids in the presence of a temperature gradient. The result is compared with earlier approaches to the same problem. Finally, we study the linear response to external forces and obtain a generalization of the fluctuation-dissipation formula relating the response functions with the nonequilibrium correlation functions.     

Hydrodynamics and time correlation functions for cellular automata

Hydrodynamic excitations in lattice gas cellular automata are described in terms of equilibrium time correlation functions for the local conserved variables. For large space and time scales the linearized hydrodynamic equations are obtained to Navier-Stokes order. Exact expressions for the associated susceptibilities and transport coefficients are identified in terms of correlation functions. The general form of the time correlation functions for conserved densities in the hydrodynamic limit is given and illustrated by some examples suitable for comparison with computer simulation. The transport coefficients are related to time correlation functions for the conserved fluxes in a way analogous to the Green-Kubo expressions for continuous fluids. The general results are applied for a one-component fluid and several types of binary diffusion. Also discussed are the effects of unphysical slow modes such as staggered particle or momentum densities.     

Nonlinear rheological models for structured interfaces

The GENERIC formalism is a formulation of nonequilibrium thermodynamics ideally suited to develop nonlinear constitutive equations for the stress-deformation behavior of complex interfaces. Here we develop a GENERIC model for multiphase systems with interfaces displaying nonlinear viscoelastic stress-deformation behavior. The link of this behavior to the microstructure of the interface is described by including a scalar and a tensorial structural variable in the set of independent surface variables. We derive an expression for the surface stress tensor in terms of these structural variables, and a set of general nonlinear time evolution equations for these variables, coupling them to the deformation field. We use these general equations to develop a number of specific models, valid for application near equilibrium, or valid for application far beyond equilibrium.     

Nonlinear Theory of the Instability of a Modulated Electron Beam of Low Density in a Plasma. V. Excitation of Waves in Strong Dissipative Plasmas by a Monoenergetic Beam

A system of nonlinear equations derived in a previous paper which describes the evolution of the beam-plasma instability in strong dissipative plasmas is solved numerically. It is shown that there are three characteristic solutions of the system of equations: the resonant dissipative instability, the nonresonant instability with strong dissipation and the nonresonant dissipative instability. A physical interpretation of essential features of these instabilities is given. The interaction of resonant and nonresonant waves in the system electron beam-strong dissipative plasma is examined. Some conclusions for the transport problem of electron beams in strong dissipative plasmas are obtained in this paper.     

Mode coupling theory of hydrodynamics and steady state systems

We construct a formal mode coupling theory for hydrodynamic systems which includes contributions from all powers of the hydrodynamic variables. This theory is applied to nonequilibrium steady state systems. A generalization of the local equilibrium distribution is used to describe the nonequilibrium state. This distribution independently constrains all moments of the hydrodynamic variables. The infinite hierarchy of equations for the moments of the hydrodynamic variables is truncated using an inverse system size expansion. Explicit results are obtained for the time correlation functions of fluids with a linear temperature gradient or a linear shear. These results agree with previous studies of these steady states.     

光学耗散系统的准热力学模型及其在光学双稳性相变问题上的应用

本文以光学耗散系统为范例,论证在满足细致平衡原理的条件下,可以与传统热力学相平行地发展一种“准热力学”模型。然后运用此模型系统而普遍地讨论了光学双稳系统的临界现象与相变。又借助Ginzburg-Landau模型处理了光学双稳性(第二类)临界点附近的涨落与关联。将平衡热力学的Landau相变理论推广到具有双稳性并远离热平衡的耗散系统。     

Stratified quantization approach to dissipative quantum systems: Derivation of the Hamiltonian and kinetic equations for reduced density matrices

A technique for describing dissipative quantum systems that utilizes a fundamental Hamiltonian, which is composed of intrinsic operators of the system, is presented. The specific system considered is a capacitor (or free particle) that is coupled to a resistor (or dissipative medium). The microscopic mechanisms that lead to dissipation are represented by the standard Hamiltonian. Now dissipation is really a collective phenomenon of entities that comprise a macroscopic or mesoscopic object. Hence operators that describe the collective features of the dissipative medium are utilized to construct the Hamiltonian that represents the coupled resistor and capacitor. Quantization of the spatial gauge function is introduced. The magnetic energy part of the coupled Hamiltonian is written in terms of that quantized gauge function and the current density of the dissipative medium. A detailed derivation of the kinetic equation that represents the capacitor or free particle is presented. The partial spectral densities and functions related to spectral densities, which enter the kinetic equations as coefficients of commutators, are evaluated. Explicit expressions for the nonMarkoffian contribution in terms of products of spectral densities and related functions are given. The influence of all two-time correlation functions are considered. Also stated is a remainder term that is a product of partial spectral densities and which is due to higher order terms in the correlation density matrix. The Markoffian part of the kinetic equation is compared with the Master equation that is obtained using the standard generator in the axiomatic approach. A detailed derivation of the Master equation that represents the dissipative medium is also presented. The dynamical equation for the resistor depends on the spatial wavevector, and the influence of the free particle on the diagonal elements (in wavevector space) is stated.     

Note on the Kaplan–Yorke Dimension and Linear Transport Coefficients

A number of new relations between the Kaplan–Yorke dimension, phase space contraction, transport coefficients and the maximal Lyapunov exponents are given for dissipative thermostatted systems, subject to a small but non-zero external field in a nonequilibrium stationary state. A condition for the extensivity of phase space dimension reduction is given. A new expression for the linear transport coefficients in terms of the Kaplan–Yorke dimension is derived. Alternatively, the Kaplan–Yorke dimension for a dissipative macroscopic system can be expressed in terms of the linear transport coefficients of the system. The agreement with computer simulations for an atomic fluid at small shear rates is very good.     

Transport Theory and Collective Modes. I. The Case of Moderately Dense Gases

The complex spectral representation of the Liouville operator introduced by Prigogine and others is applied to moderately dense gases interacting through hard-core potentials in arbitrary d-dimensional spaces. Kinetic equations near equilibrium are constructed in each subspace as introduced in the spectral decomposition for collective, renormalized reduced distribution functions. Our renormalization is a nonequilibrium effect, as the renormalization effect disappears at equilibrium. It is remarkable that our renormalized functions strictly obey well-defined Markovian kinetic equations for all d, even though the ordinary distribution functions obey nonMarkovian equations with memory effects. One can now define transport coefficients associated to the collective modes for all dimensional systems including d = 2. Our formulation hence provides a microscopic meaning of the macroscopic transport theory. Moreover, this gives an answer to the long-standing question whether or not transport equations exist in two-dimensional systems. The non-Markovian effects for the ordinary distribution function, such as the long-time tails for arbitrary n-mode coupling, are estimated by superposition of the Markovian evolutions of the dressed distribution functions.     

Nonlinear transport and dynamics of fluctuations

The time evolution of the macroscopic variables of a system initially in a state far from thermal equilibrium is studied from a statistical mechanical point of view. Exact nonlinear transport equations for the mean values and linear nonstationary Langevin equations for the fluctuations around the mean path are derived. Connections between the dynamics of fluctuations and the transport equations are discussed. The Langevin random forces depend on the macroscopic state and they are related to the transport kernels by a fluctuation-dissipation formula.