Studying solutions at high shear rates: a dedicated microfluidics setup

The development of a dedicated small‐angle X‐ray scattering setup for the investigation of complex fluids at different controlled shear conditions is reported. The setup utilizes a microfluidics chip with a narrowing channel. As a consequence, a shear gradient is generated within the channel and the effect of shear rate on structure and interactions is mapped spatially. In a first experiment small‐angle X‐ray scattering is utilized to investigate highly concentrated protein solutions up to a shear rate of 300000 s^?1. These data demonstrate that equilibrium clusters of lysozyme are destabilized at high shear rates.     

Plastic deformation at high strain rates

In the present paper a new method, an original testing device and techniques for the study of plastic deformation in materials at high strain rates up to 2×10⁴ s^–1 achieved with the use of very short stress pulses (length within 10–20 s) are described. The suggested method of yieldpoint determination respects the effects of delayed plastic deformation in the yield point at loading by very short intensive stress pulses. The investigations were carried out in polycrystalline ARMCO-iron and low-alloyed steel, and besides on the specimens irradiated by neutrons with integral dose 1·35×10¹⁹ ncm^–2. The experimental results obtained are interpreted from the point of view of the present knowledge of the process of plastic deformation in bcc metals.     

Double-quantum dipolar recoupling at high magic-angle spinning rates

A full investigation of the possible homonuclear double-quantum recoupling sequences, based on the RN family of sequences with N < or = 20, is given. Several new RN sequences, R16(6)(5), R18(8)(5), and R18(10)(5), were applied at high magic-angle spinning rates and compared with theory. The R18(10)(5) technique can be used to recouple dipolar couplings at spinning rates up to 39 kHz, and the application of the sequence in an INADEQUATE experiment is shown for a spinning rate of 30 kHz.     

Relaxation processes in metals at high strain rates

Mathematical modeling is used for experiments involving the loading of plates by plane shock waves to study the relaxation of shear stresses during the high-rate deformation of metallic materials. It is established that the characteristic relaxation times vary broadly — from fractions of a nanosecond to several microseconds. Such variation is indicative of a change in the mechanism responsible for relaxation. As a result, there is a difference between the quasi-equilibrium shear stresses in the elastic precursor and the same stresses behind the shock front. Metallic materials remain capable of resisting plastic deformation behind the front. Structural irregularities created by high-rate deformation result in localization of plastic flow at the microscopic level, which in turn causes the parameters of the stress-strain state at this level to differ from the corresponding parameters on the macroscopic scale.Siberian Physico-Technical Institute, affiliated with Tomsk University. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 8, pp. 82–90, August, 1995.     

More on shear modulus collapse of lattices at high pressure

In his recent paper, Shear modulus collapse of lattices at high pressure, J. Phys. Cond. Matt. 16 (2004) L125, V.V. Kechin claims that the zero temperature shear modulus of a metallic solid vanishes at a high critical pressure, and the critical pressures for this shear modulus collapse lie in the range 0-250 Mbar for elemental metals. Here we demonstrate that Kechin's arguments contain an erroneous assumption, and therefore, do not prove that all metals become mechanically unstable at high pressures. Ab initio calculations and experimental results on a number of solids are analyzed to confirm our conclusion.     

Anomalous muonium relaxation rates in quartz at high temperatures

Muonium spin relaxation measurements of the \alpha‐, \beta‐, and \gamma‐tridymite phases of quartz have been carried out over a temperature range from 300 to 1250 K. Anomalous relaxation rate increases are observed which may result either from resonance coupling between the other impurity ions and defects in the lattice and the diffusing muonium, or may result from phonon interactions with the muonium quadrupole moment. This revised version was published online in August 2006 with corrections to the Cover Date.     

Temporal pitch perception at high rates in cochlear implants

A recent study reported that a group of Med-El COMBI 40+CI (cochlear implant) users could, in a forced-choice task, detect changes in the rate of a pulse train for rates higher than the 300 pps "upper limit" commonly reported in the literature [Kong, Y.-Y., et al. (2009). J. Acoust. Soc. Am. 125, 1649-1657]. The present study further investigated the upper limit of temporal pitch in the same group of CI users on three tasks [pitch ranking, rate discrimination, and multidimensional scaling (MDS)]. The patterns of results were consistent across the three tasks and all subjects could follow rate changes above 300 pps. Two subjects showed exceptional ability to follow temporal pitch change up to about 900 pps. Results from the MDS study indicated that, for the two listeners tested, changes in pulse rate over the range of 500-840 pps were perceived along a perceptual dimension that was orthogonal to the place of excitation. Some subjects showed a temporal pitch reversal at rates beyond their upper limit of pitch and some showed a reversal within a small range of rates below the upper limit. These results are discussed in relation to the possible neural bases for temporal pitch processing at high rates.     

Cooperative emission of dye molecules at high dephasing rates

The dependence of the emission of a concentrated (～10¹⁹ cm^?3 solution of Rhodamine C on the power density Φ of exciting laser radiation was studied. The emission intensity for the power density of exciting radiation above ～10²⁵ cm^?2 s^?1 was found to have a nearly quadratic dependence on the power density Φ, and this emission was interpreted as the cooperative spontaneous emission of a Dicke type. For Φ?10²⁵ cm^?2 s^?1, the emission intensity increased with increasing Φ according to the exponential law. This emission was interpreted as the amplified spontaneous emission. The spectra of cooperative emission depended on the pump radiation power only weakly. The absence of lasing in dye solutions at high concentrations, which is a well-known phenomenon, was shown to be caused by the development of the cooperative spontaneous emission and not by the concentration quenching, and the former process is more rapid than the latter.     

Deconvolution of evoked responses obtained at high stimulus rates

Continuous loop averaging deconvolution (CLAD) is a new general mathematical theory and method developed to deconvolve overlapping auditory evoked responses obtained at high stimulation rates. Using CLAD, arbitrary stimulus sequences are generated and averaged responses deconvolved. Until now, only a few special stimulus series such as maximum length sequences (MLS) and Legendre sequences (LGS) were capable of performing this task. A CLAD computer algorithm is developed and implemented in an evoked potential averaging system. Computer simulations are used to verify the theory and methodology. Auditory brainstem responses (ABR) and middle latency responses (MLR) are acquired from subjects with normal hearing at high stimulation rates to validate and show the feasibility of the CLAD technique.     

Diabatic instability of a solid deformed at high strain rates

Summary The model of a thermo-inelastic solid undergoing a very fast deformation is considered beyond the usual linear approximation. It is shown, via a stability analysis of small fluctuations, that a universal stability diagram in control parameter space exists exhibiting a complex topology but only hard-mode (acousticlike) instabilities, due to the hyperbolic nature of the governing equations. It turns out that an adiabatic homogeneous expansion against cohesion forces is no longer possible if a critical strain rate is exceeded, leading to spatial symmetry breaking towards fracture. The validity of this last result is thought to hold qualitatively irrespectively of the nature of the dissipation laws. To speed up publication, the author of this paper has agreed to not receive the proofs for correction.     

Performance of nonlinear photonic crystal devices at high bit rates

I investigate theoretically the performance limits for all-optical switching devices incorporating photonic crystals made of nonlinear materials operating at high bit rates. I compare two switching techniques--shifting of the photonic bandgap and the more traditional interferometric method enhanced by slow wave propagation in photonic crystals-and show that the latter always has an advantage. I also demonstrate that the benefits provided by the photonic crystal in the interferometer are still severely limited by the dispersion and become significant only in materials combining high nonlinearity, high index contrast, and high damage threshold.     

高导无氧铜的高压与高应变率本构模型研究

基于Y/G及G/B为常数的假设,构建了高导无氧铜的七种高压与高应变率本构模型.对于高导无氧铜进行了平面冲击波试验,采用纵向与横向锰铜应力计记录了试件中的纵向与横向应力,从而得到了屈服应力历史.用所构建的七种本构模型进行了数值模拟,并与高导无氧铜的平面冲击波试验结果进行比较.结果表明,平面冲击波载荷下高导无氧铜的屈服强度对于压力、密度、温度以及塑性应变的依赖性是本构描述的关键.而由Hopkinson试验取得的高导无氧铜高应变率本构模型,并不适合描述平面冲击波载荷下的本构特性. 关键词： 本构模型 高导无氧铜 平面冲击波试验 锰铜应力计     

Slip, yield, and bands in colloidal crystals under oscillatory shear

We study dense colloidal crystals under oscillatory shear using a confocal microscope. At large strains the crystals yield and the suspensions form shear bands. The pure harmonic response exhibited by the suspension rules out the applicability of nonlinear rheology models typically used to describe shear banding in other types of complex fluids. Instead, we show that a model based on the coexistence of linearly responding phases of the colloidal suspension accounts for the observed flows. These results highlight a new use of oscillatory measurements in distinguishing the contribution of linear and nonlinear local rheology to a globally nonlinear material response.     

Molecular dynamics study on superheating of Pd at high heating rates

Molecular dynamics simulations are employed here to study the melting and superheating behaviors of bulk Palladium at high heating rates. Quantum Sutton-Chen many body potential is used for these simulations. Being heated, the superheating and melting behavior is found to be strongly affected by the heating rate, and heating rate induced randomization during non-equilibrium heating processes is found to be the main driving force for phase transformation, and it eliminates the energy barrier for nucleation. Not only Pd crystals but also Pd crystals with defects are studied. And the upper limit of heating rate induced superheating is determined to be around 2100?K.     

Bonding of glass with femtosecond laser pulses at high repetition rates

We report on the welding of fused silica with ultrashort laser pulses at high repetition rates. Femtosecond laser pulses were focused at the interface of two optically contacted fused silica samples. Due to the nonlinear absorption in the focal volume and heat accumulation of successive pulses, the laser acts as a localized heat source at the focus position. Here, we analyze the influence of the laser and processing parameters on the amount of molten material. Moreover, we determine the achievable breaking stress by a three point bending test. With optimized parameters up to 75% of the breaking stress of the bulk material have been obtained.     

Deformation at very high strain rates of Al and ERGAL 7075

Summary Comparative examinations have been carried out on Al and ERGAL specimens deformed by compression either fast or slow. The high-strain-rate compressions were obtained by explosive. The dislocation structures have been examined by transmission electron microscopy and by Fourier analysis of the X-ray diffraction lines. Crystalline textures were also determined. After fast deformation smaller interaction energies appear among the dislocations with comparable total densities because of the accumulation in grain boundaries. The results have been interpreted by assuming that the loads which are reached in the shock and reflected wave fronts give rise to generations or multiplications of the dislocations on levels more differentiated than by slow compression.

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Riassunto Sono stati condotti esami comparativi su campioni di Al e di ERGAL deformati mediante compressione lenta o veloce. Le compressioni ad elevate velocità sono state ottenute per mezzo di esplosive. Le strutture delle dislocazioni sono state osservate con microscopia elettronica in trasmissione e analisi di Fourier delle righe di diffrazione dei raggi X. Sono state inoltre determinate le tessiture cristalline. Con densità totali di dislocazioni comparabili, dopo deformazione rapida appaiono minori energie d'interazione tra le dislocazioni stesse a causa di fenomeni di accumulo nei bordi di grano. I risultati sono stati interpretati ammettendo che i carichi raggiunti in corrispondenza delle onde d'urto, diretta e riflesse, diano luogo a generazione e moltiplicazione di dislocazioni su livelli piú differenziati che con compressione lenta.

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Резюме Проводится сравнительный анализ образцов Al и ERGAL, подвергнутых деформации сжатия либо быстро, либо, медленно. Высокая скорость деформации сжатия получается в результате взрыва. Исследуется структура дислокаций с помощью трансмисионной электронной микроскопии и с помощью Фурье-анализа линий дифракции рентгеновских лучей. Определяются кристаллические структуры. После быстрой деформации возникают небольшие энергии взаимодействия между дислокациями с соизмеримыми полными плотностями, вследствие явления аккумуляции на границах зерен. Проводится интерпретация полученных результатов, предполагая, что нагрузки приводят к образованию или размножению дислокаций на уровнях более дифференцированных, чем в случае медленного сжатия.

     

Multiscale simulations of damage of perfect crystal Cu at high strain rates

We use the molecular dynamics code, large-scale atomic/molecular massively parallel simulator (LAMMPS), to simulate high strain rate triaxial deformation of crystal copper to understand void nucleation and growth (NAG) within the framework of an experimentally fitted macroscopic NAG model for polycrystals (also known as DFRACT model). It is seen that void NAG at the atomistic scales for crystal copper (Cu) has the same qualitative behaviour as the DFRACT model, albeit with a different set of parameters. The effect of material temperature on the nucleation and growth of voids is studied. As the temperature increases, there is a steady decrease in the void NAG thresholds and close to the melting point of Cu, a double-dip in the pressure–time profile is observed. Analysis of this double-dip shows disappearance of the long-range order due to the creation of stacking faults and the system no longer has a face centred cubic (fcc) structure. Molecular dynamics simulation of shock in crystal Cu at strain rates high enough to cause spallation of crystal Cu are then carried out to validate the void NAG parameters. We show that the pre-history of the material affects the void nucleation threshold of the material. We also simulate high-strain-rate triaxial deformation of crystal Cu with defects and obtain void NAG parameters. The parameters are then used in a macroscale hydrodynamic simulation to obtain spallation threshold of realistic crystal Cu. It is seen that our results match experimental results within the limit of 20% error.     

Elastic capsules in shear flow: Analytical solutions for constant and time-dependent shear rates

We investigate the dynamics of microcapsules in linear shear flow within a reduced model with two degrees of freedom. In previous work for steady shear flow, the dynamic phases of this model, i.e. swinging, tumbling and intermittent behaviour, have been identified using numerical methods. In this paper, we integrate the equations of motion in the quasi-spherical limit analytically for time-constant and time-dependent shear flow using matched asymptotic expansions. Using this method, we find analytical expressions for the mean tumbling rate in general time-dependent shear flow. The capsule dynamics is studied in more detail when the inverse shear rate is harmonically modulated around a constant mean value for which a dynamic phase diagram is constructed. By a judicious choice of both modulation frequency and phase, tumbling motion can be induced even if the mean shear rate corresponds to the swinging regime. We derive expressions for the amplitude and width of the resonance peaks as a function of the modulation frequency.