强电离放电产生高浓度臭氧的基础理论与方法研究

论述了介质阻挡强电离放电形成方法及其产生臭氧的等离子反应过程。实现用电场强度、电子能量控制臭氧产生浓度和分解。采用α型Al2O3制成电介质薄层（230um）以及窄放电间隙（110um）的新工艺、新技术、取得折合电场强度E／n大于400Td的强电离放电,电子取得平均能量大于10eV,臭氧浓度达到250g/Nm^3,臭氧产生效率达到200g/kWh。进行实现了臭氧产生装置生产组合模块化、小型化。     

Self-bending of photorefractive solitons

Self-bending of photorefractive solitons is caused by diffusion in photorefractive crystals and becomes an important effect when the beam size is in the range of the charge carriers diffusion length. In this paper we present an experimental and numerical examination of the beam bending dependence on relevant parameters such as the applied electric field and the beam intensity. We demonstrate that the bending dependence on the electric field in the low saturation regime has the form of a square function at low values of the field and becomes linear for higher values. For stronger saturation the curve gets the form of a square root function. The bending dependence on the beam intensity has a maximum at defined intensity. The experimental data are compared with numerical simulations, giving a good qualitative agreement.     

Generation of millimeter radiation due to electric-field-induced electron-transit-time resonance in indium phosphide

The stimulated millimeter radiation from n-type indium phosphide was observed at T=4.2 K in a strong electric field. The generation is due to the appearance of negative differential conductivity near the electron-transit-time resonance and electron bundling in momentum space in a strong electric field under conditions of low-temperature scattering from optical phonons. The dependence of the radiation frequency and intensity on the electric field was experimentally measured and the radiation spectrum is presented. The experimental data satisfactorily agree with the results of numerical simulations obtained previously by the Monte Carlo method.     

All-Optical Photorefractive Effect in Carbazole-Based Azo-Side Group Polymer

We observe the photorefractivity without bias voltage or prepoling in a bifunctional photorefractive polymer. The maximum two-beam coupling gain is measured to be 126cm^-1 at zero bias voltage. The sample is considered to be poled by the photoinduced longitudinal electric field, which is formed due to the light intensity gradient along the light path. The expression of the electric field was deduced. The energy transfer direction between two writing beams and light intensity dependence of the two-beam coupling gain coefficient is predicted to be consistent with the experimental results. Furthermore, the dependence of the two-beam coupling gain coefficient on external applied electrical field is measured and this experiment verifies the existence of the photoinduced longitudinal electric field.     

Numerical modeling of ozone production in a pulsed homogeneousdischarge: a parameter study

The pulsed volume discharge is an alternative for the efficient generation of ozone in compact systems. This paper presents a parameter study of the reactions in this kind of homogeneous discharge by using a numerical model which solves plasma chemical kinetic rate and energy equations. Simulations are performed for 10^-9-10^-5 s single pulses and oxygen gas density in the range 10<300 K and normalized electric field of 1000 decreased. The maximum concentration is 3% at 10 amagat and 100 K. The results on ozone accumulation in multiple pulse discharges are presented. In contrast to the single pulse case, higher efficiency is achieved at lower gas density. This scaling can be explained by losses due to ion currents     

Macromolecular structure of cellulose studied by second-harmonic generation imaging microscopy

The macromolecular structure of purified cellulose samples is studied by second-harmonic generation (SHG) imaging microscopy. We show that the SHG contrast in both Valonia and Acetobacter cellulose strongly resembles that of collagen from animal tissues, both in terms of morphology and polarization anisotropy. Polarization analysis shows that microfibrils in each lamella are highly aligned and ordered and change directions by 90 degrees in adjacent lamellae. The angular dependence of the SHG intensity fits well to a cos2 theta distribution, which is characteristic of the electric dipole interaction. Enzymatic degradation of Valonia fibers by cellulase is followed in real time by SHG imaging and results in exponential decay kinetics, showing that SHG imaging microscopy is ideal for monitoring dynamics in biological systems.     

脉冲形状和静电场对电离率和高次谐波的影响

采用数值方法研究静电场和不同的激光脉冲对氢原子的电离率和高次谐波的影响.结果表明脉冲形状和电离率之间有着确定的关系,电离率反过来又影响了谐波谱的性质;另外,随着所加的静电场强度的增大,电离率呈上升的趋势,而谐波谱出现一个双平台的结构.     

Large optical second-order nonlinearity of poled WO3-TeO2 glass

Second-harmonic generation, one of the second-order nonlinear optical properties of thermally and electrically poled WO>(3)-TeO>(2) glasses, has been examined. We poled glass samples with two thicknesses (0.60 and 0.86 mm) at various temperatures to explore the effects of external electric field strength and poling temperature on second-order nonlinearity. The dependence of second-harmonic intensity on the poling temperature is maximum at a specific poling temperature. A second-order nonlinear susceptibility of 2.1 pm/V was attained for the 0.60-mm-thick glass poled at 250 degrees C. This value is fairly large compared with those for poled silica and tellurite glasses reported thus far. We speculate that the large third-order nonlinear susceptibility of WO>(3)- TeO>(2) glasses gives rise to the large second-order nonlinearity by means of a X((2)) = 3X((3)) E(dc) process.     

Quantum path interference in the wavelength dependence of high-harmonic generation

We investigate the dependence of the intensity of radiation due to high-harmonic generation as a function of the wavelength lambda of the fundamental driver field. Superimposed on a smooth power-law dependence observed previously, we find surprisingly strong and rapid fluctuations on a fine lambda scale. We identify the origin of these fluctuations in terms of quantum path interferences with up to five returning orbits significantly contributing.     

Correlation between Variations in the Number of Neutrons in the Atmosphere and in the Intensities of the Atmospheric Ozone Lines

We compare the data on the atmospheric radio emission in two ozone lines with resonance frequencies 96,228 and 101,736 MHz, obtained at the N. I. Lobachevsky State University of Nizhny Novgorod in 1996–2001, with the corresponding results of measuring the number of neutrons in the atmosphere, obtained at the Institute of Terrestrial Magnetism, Ionosphere, and Radio Wave Propagation (Troitsk, Moscow region) using the NM-64 monitor. It is shown that variations in both the optical depth and the intensity ratio of these lines correlate with variations in the number of neutrons. The maximum observed correlation coefficients for the optical-depth decrements of the lines amount to 0.5–0.6, which is about a factor of 1.5 higher than the maximum correlation coefficient for their intensity ratio. We analyze the dependence of the correlation coefficients on the time shift between data series for the ozone line intensity and the number of neutrons in the atmosphere. It is shown that correlation between these data series almost vanishes for a time shift of about 200 h. We discuss the features of the data on the number of neutrons in the atmosphere and the possibility of the solar origin of neutrons.     

Polarization dynamics of a monochromatic laser with linear phase anisotropy

We analyse this laser's phase diagram: the properties of its steady states when varying the linear phase anisotropy, the intensity coupling asymmetry, or the pump rate. Most interesting is a parameter window in which the laser output is a limit cycle, and not only the intensity but also the electric field polarization varies periodically. The dependence of the polarization on the laser parameters is evaluated for various states.     

Ultrasonic resonator with electrical discharge cell for ozone generation

The effect of ultrasound waves in an ultrasonic resonator cell on ozone generation by a hollow needle to plate electrical discharge enhanced by the airflow through the needle is experimentally investigated. It was found that the application of ultrasound waves increases ozone generation for discharge when the needle is negatively biased, and has no effect on ozone generation for the discharge when the needle is biased positively. We try to explain the influence of ultrasound on the discharge mechanisms.     

Photoluminescence and electric conductivity in germanium at low temperatures

We have studied the exciton and electron-hole droplet (EHD) luminescence in optically irradiated germanium at temperatures between 1.8 and 4.2 K in the presence of an electric field. Simultaneously the electric conductivity was measured. The sample material was high-purity Ge (N _A –N _D =7·10¹⁰ cm^–3) andp-doped Ge withN _A =3·10¹⁴ cm^–3. In the high-purity Ge samples the exciton and EHD-luminescence intensity decreased nearly linearly as a function of the applied electric current, whereas the dependence upon the electric field was more complicated. Our results could be explained by a model in which carrier annihilation at the contacts following a rapid drifting process plays a dominant role (drift model). In thep-doped Ge samples the current-dependence of the luminescence intensity was qualitatively similar. However, here the drift model is not strictly valid any more because of the reduced carrier mobility and the generation of additional carriers by impurity impact ionization. During variation of the electric field, the luminescence intensity and the electric current show hysteresis. Here the capture of the moving carriers by the EHD appears to play an important role, in addition to the EHD-nucleation process.     

Generation of electromagnetic waves in the terahertz frequency range by optical rectification of a Gaussian laser pulse in a plasma in presence of an externally applied static electric field

We propose a theoretical model for the generation of electromagnetic waves in the terahertz (THz) frequency range by the optical rectification of a Gaussian laser pulse in a plasma with an applied static electric field transverse to the direction of propagation. A Gaussian laser pulse can exert a transverse component of the quasi‐static ponderomotive force on the electrons at a frequency in the THz range by a suitable choice of the laser pulse width. This nonlinear force is responsible for the density oscillation. The coupling of this oscillation with the drift velocity acquired by electrons due to the applied static electric field leads to the generation of a nonlinear current density. A spatial Gaussian intensity profile of the laser beam enhances the generated THz yield by many folds as compared to a uniform spatial intensity profile.     

Azimuthal dependence of the purely nuclear diffraction for 14.4 keV resonant gamma-rays

An azimuthal dependence of the intensity of the resonant gamma-ray nuclear Bragg reflection from a sodium nitroprusside single crystal has been observed. The dependence reflects the structure of the electric field inside the crystal.     

气体放电中正柱区电场的光谱不介入诊断

基于速度调制分子离子光谱技术，提出并实现了分别通过研究分子离子光谱强度随母体分子气压变化以及光谱线宽随放电电流变化两条途径对气体放电等离子体中电场的两种光谱不介入诊断方法，两者所获得的电场吻合较好，表明速度调制分子离子光谱方法对等离子体诊断具有十分重要的意义。     

Surface band bending on clean and oxidized (110)-GaAs studied by Raman spectroscopy

We demonstrated that the measurement of a bulk phonon property, i.e. the resonantly excited symmetry forbidden LO-Raman intensity via its dependence on the surface electric field, is a comparatively easy, sensitive and high spatial resolution method to measure surface Fermi level positions in polar semiconductors as a function of e.g. cleavage conditions, oxygen exposure and doping.     

Second harmonic light scattering in paraelectric perovskites

Although one expects second harmonic generation to be absent in phases with inversion symmetry, second harmonic signals are observed in the paraelectric phase of several perovskite. We explain this frequency-doubled intensity and its temperature dependence by second harmonic scattering (SHS) due to static point defects inducing a local polarisation and dynamic fluctuations. The intensity and polarisation properties are calculated for both contributions.     

Investigation of the ozone formation process in a nanosecond microwave discharge in air and oxygen

Results are presented from an investigation of the dynamics of ozone formation in a freely localized discharge generated by a periodic train of 3-cm nanostructured microwave pulses in oxygen and air at a pressure p=3–30 Torr. Conditions for the efficient generation of ozone in air with the minimum production of nitrogen oxides are demonstrated experimentally. It is shown that when the microwave pulse repetition frequency is high, heating of the gas and the buildup of nitrogen oxides in the discharge in air reduce the ozone formation efficiency while under prolonged exposure the ozone formed initially is destroyed. The energy cost of forming ozone in oxygen and air is determined as a function of the microwave pulse length and repetition frequency and the gas pressure. The lowest energy cost of forming a single ozone molecule in these experiments is 16 eV per molecule for a discharge in air and 4 eV per molecule in oxygen. It was observed that circulating the gas through the discharge zone enhances th ozone formation efficiency. It is shown that there are optimal conditions for ozone formation as a function of the reduced electric field in the plasma. Zh. Tekh. Fiz. 67, 9–18 (March 1997)     

Electrically controlled liquid crystal fiber

We consider a cylindrical fiber whose core is a liquid crystal (LC) subject to the action of a low frequency field applied parallel to the axis of the cylinder and having initially the escaped configuration. We find the distorted textures of the nematic inside the cylinder by assuming arbitrary anchoring boundary conditions. In the optical limit we calculate the ray trajectories followed by a low intensity beam along the fiber parametrized by a low frequency electric field. Finally, we calculate exactly the spatial dependence of the transverse magnetic modes distribution in the guide, on the electric field, by using a numerical scheme. We summarize our paper and discuss our results.