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1.
利用全相对论组态相互作用理论方法,研究了类铷W37+离子从基组态3s23p63d104s24p64d经过双激发态(3s23p63d104s24p64d)-1nln′l′(n,n′=4,5)的双电子复合过程,得到了该离子在温度为1~5×104 eV范围内的总双电子复合速率系数。分析比较了不同电子激发的双电子复合速率系数,结果表明:4p电子激发的双电子复合速率系数在低温时给出了主要贡献,而3d的贡献在高温时突出。由于强组态相互作用,两电子一光子跃迁对双电子复合速率系数的贡献不可忽略,其中辐射跃迁4p54d5d5f-4p64f5d的贡献是双激发态4p54d5d5f总的双电子复合速率系数的5%。对双电子复合、辐射复合以及三体复合速率系数的比较表明,在所研究的温度范围内双电子复合速率系数最大。 相似文献
2.
Ab initio calculations of the rate coefficients for dielectronic recombination (DR) of Co-like Ag and Ta ions are performed based on Cowan's quasi-relativistic multi-configuration Hartree-Fock code. Co-like (3s 23p63d10)-1 configurations and Ni-like (3s23p63d10)-24l4l' autoionization configurations are included in the present calculation. Because of the extensive distribution of autoionization state energy levels, the DR rate coefficients cannot be reproduced or interpolated by a simple analytical formula, such as the Burgess-Merts formula, or the Hagelstein approximation. We propose to use multi-set Hagelstein parameters, which is convenient in practice and can reproduce well the ab initio calculated DR rate coefficients. 相似文献
3.
E. Behar P. Mandelbaum J.L. Schwob 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》1999,7(2):157-161
Ab initio calculations of the total dielectronic recombination (DR) rate coefficient of Ni-like barium () and tungsten () in the ground state have been performed using the HULLAC atomic code package. Resonant and nonresonant stabilizing radiative
transitions are included. Collisional transitions following electron capture are neglected. The present level-by-level calculations
include the DR contributions of all of the levels (over 17000) in the Cu-like inner-shell excited configurations 3d
9
4ln'l' (), 3p
5
3d
10
4ln'l' (), and 3s3p
6
3d
10
4ln'l' (). For both ions, the configuration complexes with a hole in the 3p inner shell contribute almost 10% to the total DR rate coefficient, while the complexes with a hole in the 3s inner shell
contribute about 1%. The converging contributions of the 3d
9
4ln'l' (n' > 9) configurations are evaluated by applying the complex-by-complex extrapolation method and are found to comprise up to about 20% of the total DR rate coefficients throughout a wide electron
temperature range. The total DR rate coefficients are fitted to an easy-to-use analytic expression which reproduces the original
data with an accuracy of about 2% or better in a very wide temperature range.
Received: 1 February 1999 相似文献
4.
Y. Zhang C. Y. Chen M. Huang Y. S. Wang Y. M. Zou 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2010,56(2):157-166
Ab initio calculations of the total dielectronic
recombination (DR) rate coefficients for thirteen ions along the NiI
isoelectronic sequence in the ground state (Kr8+, Mo14+,
Ag19+, Sn22+, Xe26+, Nd32+, Gd36+,
Yb42+, W46+, Au51+, Pb54+, At57+, and
U64+) have been performed using the flexible atomic code. The
level-by-level calculations are performed for evaluating the DR
contributions through the relevant Cu-like autoionizing inner-shell
excited 3l174l′n′′l′′ and 3l175l′n′′l′′ configuration complexes with n′′
≤15, which are associated with Δn=1 and Δn=2
core-excitations, respectively. The usual (n′′)-3 scaling
law is found to be invalid for low-Z ions. A level-by-level
extrapolation procedure is employed to obtain the contributions
through higher n′′ complexes. The decays to autoionizing
levels followed possibly by radiative cascades could enlarge the
rates at relatively high temperature by a factor up to about 23%.
For the whole isoelectronic ions the contributions from
3s23p63d9 4l′n′′l′′ dominate the total DR
rates while the contributions from the 3s23p63d9 5l′n′′l′′ configuration complexes are about 10-20% at
relatively high temperature. On the basis of the calculated results,
a general analytic formula for the total DR rate coefficients of all
the ions with 36≤Z ≤92 along the NiI isoelectronic
sequence is constructed. The comparisons of the rates obtained from
the general formula with those from the detailed calculations show
that the formula is of high precision, generally better than 3%
accuracy for electron temperatures kT≥0.1EI, where EI is
the ionization energy of the Cu-like ion. The present DR rates at
temperature above 1.0EI are larger than the previously published
data by a factor above 30%. The commonly used semiempirical formula
proposed by Burgess and modified by Merts may overestimate the rates
at high temperature by a factor of about 2 for low-Z ions. 相似文献
5.
Ultraviolet fluorescence of Nd3+ ions induced by triphotonic excitation process was studied in Nd-doped LiYF4, LiLuF4 and BaY2F8 crystals using a technique of time-resolved spectroscopy. The observed ultraviolet luminescence was due to transitions between the bottom of 4f25d configuration and 4f3 states of Nd3+ ions. Narrow emission lines superposed to the broadband emissions were observed. A detailed analysis of luminescence spectrum revealed that the narrow emissions are due to parity and spin allowed radiative transitions from the Stark levels of 4K11/2(5d) state created by the electrostatic interaction between the 5d electron and the two electrons of the 4f2 configuration. The narrow emissions are related to the high spin state (S=3/2) which gives f-f characteristics to the f-d broadband emissions. The narrow emissions superposed to the wide emission correspond to 18%, 34% and 43% of the integrated broadband emission at 262 nm observed in LiYF4, LiLuF4 and BaY2F8 crystals, respectively. Although the 5d-4f2 interaction is observed to be weaker than 5d-crystal field interaction, it is stronger enough to select only the radiative transitions from 4f25d configuration to 4f3 states that preserves the total spin S=3/2. 相似文献
6.
在自旋-轨道劈裂阵模型下,通过类铜的内壳层激发组态计算了类镍Gd的双电子复合速率系数,其中考虑了共振和非共振辐射平衡跃迁对自电离能级的影响,而忽略了因碰撞跃迁引起的电子俘获,非共振辐射平衡跃迁在低电子温度条件下主要影响双电子复合过程;本文讨论了双电子复合系数及双电子伴线强度比随电子温度的变化. 相似文献
7.
在自旋-轨道劈裂阵模型下,通过类铜的内壳层激发组态计算了类镍氙的双电子复合速率系数,其中考虑了共振和非共振辐射平衡跃迁对自电离能级的影响,而忽略了因碰撞跃迁引起的电子俘获,非共振辐射平衡跃迁在低电子温度条件下主要影响双电子复合过程;本文讨论了双电子复合系数及双电子伴线强度比随电子温度的变化. 相似文献
8.
Spectra and oscillator strengths of 3p63d9--3p53d10 and 3p63d9--3p63d84p transitions for cobalt-like Sn23+ ion
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This paper calculates the spectra and oscillator strengths for highly ionized cobalt-like Sn23+ ions 3p63d9 3p53d10,3p63d9 3p63d84p transitions by using a multi-configuration self-consistent field method program together with the proposed fitting formula.The calculations have a good agreement with observations. 相似文献
9.
Fan-Chang Meng Chong-Yang Chen Yan-Sen Wang Ya-Ming Zou 《Journal of Quantitative Spectroscopy & Radiative Transfer》2008,109(11):2000-2008
Ab initio calculation of the total dielectronic recombination (DR) rate coefficient from the ground state 3s23p63d9(J=5/2) of Co-like tungsten is performed employing the relativistic distorted-wave approximation with configuration-interaction. The DR contributions mainly come from complex series 3d84ln′l′. The complex series 3p53d10n′l′, 3p53d94ln′l′ and 3d85ln′l′ also contribute significantly to the total DR rates at relatively high electron temperatures. The l′ and n′ dependences of the partial rate coefficient are investigated. The inclusion of decays into autoionizing levels followed by radiative cascades (DAC) enlarges the total DR rate coefficients by a factor of about 10%. The level-by-level extrapolation method is developed to include DAC effects. The total DR rate coefficients are fitted to an empirical formula. It is shown that at temperatures above 2.5 keV the Burgess-Merts (BM) semiempirical formula can provide DR results with an accuracy of about 15%, whereas at electron temperatures below 100 eV it underestimates the DR rate coefficients by up to a few orders of magnitude and its temperature dependence is completely inadequate. The comparison of the results for Ni-like and Co-like tungsten shows that these two sets of DR rate coefficients are very close in magnitude at relatively high electron temperatures. 相似文献
10.
11.
The calculations of the rate coefficients for dielectronic recombination (DR) along the NiI isoelectronic sequence in the ground state Au^{51+} through Cu-like 3d^9nln′f (n,n′=4,5,6) inner-shell excited configurations are performed using the spin-orbit-split array (SOSA) model. Resonant and nonresonant radiative stabilizing transitions and decays to autoionizing levels followed by radiative cascades are included. Collisional transitions following electron capture are neglected. The trend of the DR rate coefficients and the ratio of dielectronic satellite lines intensities with the change of the electron temperature are discussed. 相似文献
12.
C.Z. Dong S. Fritzsche B. Fricke 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2003,23(1):5-13
The 17 levels of the 3
d
10
, 3
d
9
4
s and 3
d
9
4
p configurations, and the electric-dipole transitions among these levels are calculated for the three nickel-like ions Se6+, Y11+ and Sn22+ by using large-scale multiconfiguration Dirac-Fock wavefunctions. From these computations, the excitation energies and transition
probabilities as well as the lifetimes of 3
d
9
4
p levels are derived, including all dominant effects of relativity, correlation and of the rearrangement of the electron density
within the same framework. Comparison is made with the scarce number of experimental data and previous semi-empirical computations. 相似文献
13.
A. M. Tkachuk S. É. Ivanova L. I. Isaenko A. P. Yelisseyev M. -F. Joubert Y. Guyot S. Payne 《Optics and Spectroscopy》2003,95(5):722-740
Optical spectra, intensities of radiative and nonradiative transitions, and luminescence kinetics in erbium-doped potassium-lead double chloride crystals KPb2Cl5:Er3+s(KPC:Er3+) were investigated. The crystals were grown by the Bridgman-Stockbarger method. Their absorption and luminescence spectra were studied experimentally. The crystal-matrix absorption edge was determined at 80 and 300 K. Intensity parameters, radiative transition probabilities, branching ratios, and nonradiative relaxation rates were estimated by the Judd-Ofelt method. The luminescence kinetics from the emitting levels 4 G 11/2, 2 G 9/2, 4 S 3/2, and 4 F 9/2 upon selective excitation was studied. 相似文献
14.
The probabilities of the 4p 6,4p 55p→4p 5(4d+5s) radiative transitions and the radiative lifetimes of the 4p 54d,4p 55s, and 4p 55p levels are calculated semiempirically for the RbII-MoVII isoelectronic sequence. 相似文献
15.
Thermal quenching of 5d-4f luminescence from Nd3+, Er3+ and Tm3+ ions doped into KYF4 crystals has been investigated in the temperature range up to ∼750 K where this luminescence is completely quenched. The obtained temperatures of thermal quenching (Tq) are ∼270, 495, 450 K for Nd3+, Er3+, Tm3+, respectively. At high temperatures, thermal quenching of 5d-4f luminescence from Nd3+ and Er3+ is accompanied by the appearance of 4f-4f luminescence from the lower-energy 4f levels. It has been shown that the dominating mechanism of thermal quenching for Nd3+ and Er3+ ions is thermally stimulated non-radiative transitions (intersystem crossing) from the 5d states to lower-energy 4f levels, namely 2G(2)9/2 and 2F(2)7/2, respectively, whereas for the Tm3+ ion, thermally stimulated ionization of 5d electrons to the conduction band states is responsible for thermal quenching of 5d-4f luminescence. The energy gap between the lowest Tm3+ 5d level and the bottom of the KYF4 conduction band has been estimated to be 0.66 eV. 相似文献
16.
The radiative 4d 105p-4d 95p 2 transitions in the spectra of the In III, Sn IV, Sb V and Te VI, ions, belonging to the silver isoelectronic sequence, have been investigated in the range 250–600 Å with high resolution. The energies of most levels of the 4d 95p 2 configuration with J = 1/2, 3/2, and 5/2, involved in the transitions to the 4d 105p configuration, are found. Along the isoelectronic sequence, the 4d 95p 2 configuration passes from the position below the ionization limit 4d 10 in Te VI to the position above this limit in In III with corresponding autoionization effects. The autoionization widths of levels are measured. The data obtained are compared with the results of calculations by the Hartree-Fock and semiempirical methods. 相似文献
17.
A strong, sharp resonance enhancement of 4f photoemission has been observed on SmS(100) surfaces for photon energies in the region of the 4d-4f transitions at about 126 eV. The discrete final state reached via the excitation hν+4d104f6→4d94f7 autoionizes primarely via a super Coster-Kronig transition of the type 4d94f7→4d104f5 + unbound electron. Other decay channels, e.g, Sm 5p emission, as well as a surface induced binding energy shift in the Sm3+ final state are identified and discussed. 相似文献
18.
19.
Dielectronic Recombination Rate Coefficients for Nickel-like YtterbiumDielectronicRecombinationRateCoefficientsforNickel-like... 相似文献
20.
Electron energy-loss spectroscopy of ~ 200 eV electrons has been applied to the study of the electronic states of clean NiO (100) surfaces. Initial attempt has been made on the identification of observed peaks, and they are attributed to the one-electronic transitions (O2-2p → Ni2+3d, 4s and 4p; Ni2+3d → 4p, 3p → 3d and 4s), and the collective excitations (bulk plasmons of O2-2p, Ni2+3d electrons, and coupled 2p and 3d electrons). 相似文献