两带超导体LaNiC_2上临界磁场的理论分析

非中心对称超导体LaNiC_2是传统BCS超导体还是能隙存在节点又或是两带超导体,目前仍然存在争议.基于此,文章用两带Ginzburg-Landau理论分析了超导体LaNiC_2的上临界磁场随温度的变化关系,计算结果与实验结果在整个温度区间内符合得很好,说明LaNiC_2是两带超导体,和陈健等人的观点一致.文章还分析了两个不同能带对上临界磁场的影响,发现相对较小的相干长度对LaNiC_2的上临界磁场影响较大.     

Pair-Breaking Critical Current Density of Two-Band Superconductor MgB2

Temperature dependence of tbe pair-breaking critical current density of MgB2, jd（T）, is studied using a two-band Ginzburg-Landau theory. The results are shown to be in good agreement with experimental data for the superconducting magnesium diboride MgB2.     

Anisotropy of Critical Fields in MgB2： Two-Band Ginzburg-Landau Theory for Layered Superconductors

The temperature dependence of the anisotropy parameter of upper critical field γHc2(T)=H_{c2}^||(T)/H_{c2}^{\bot}(T) and London penetration depth γ_λ(T)=λ_{\perp} (T)/λ_{\bot} (T) are calculated using two-band Ginzburg-Landau theory for layered superconductors. It is shown that, with decreasing temperature the anisotropy parameter γ_{H_{c2}}(T) is increased, while theLondon penetration depth anisotropy γλ(T) reveals n opposite behavior.Results of our calculations are in agreement with experimental datafor single crystal MgB₂ nd with other calculations. Results of an analysis of magnetic field H_c1 in a single vortex between superconducting layers are also presented.     

Remarks on Small Superconducting Specimens in Magnetic Field and Measurements of the Lower Critical Field

We shall discuss the magnetic behaviors associated with the boundary effects for type-Ⅱ superconductors in general orientations. Using previous results, we speculate that the relation among the lower critical field H_c1, the thermodynamic critical field H_c and the upper critical field H_c2, namely H_c²～H_c1H_c2, is still approximately valid for general experimental orientations. More precisely, the magnitudes of H_c1, H_c and H_c2 are consistent with the formulae given for bulk superconductors when the typical size of the superconducting specimen is greater than the coherence length ε, provided the penetration depth λ is substituted by a modified value λ_m. Consequently, the criterion for observing type-Ⅱ superconducting magnetic behaviors also becomes λ_m>ε, although the London equation is still governed by λ. In the second part of the paper, we shall also suggest an experiment, based on the fact of H_c1. of superconducting thin films in parallel magnetic field being much higher than that of bulk superconductors, to measure H_c1 precisely, especially for extreme type-Ⅱ superconductors,without influence of the penetration barrier.     

Synthesis of large FeSe superconductor crystals via ion release/introduction and property characterization

Large superconducting Fe Se crystals of(001) orientation have been prepared via a hydrothermal ion release/introduction route for the first time. The hydrothermally derived Fe Se crystals are up to 10 mm×5 mm×0.3 mm in dimension. The pure tetragonal FeSe phase has been confirmed by x-ray diffraction(XRD) and the composition determined by both inductively coupled plasma atomic emission spectroscopy(ICP-AES) and energy dispersive x-ray spectroscopy(EDX). The superconducting transition of the Fe Se samples has been characterized by magnetic and transport measurements. The zero-temperature upper critical field H_(c2) is calculated to be 13.2–16.7 T from a two-band model. The normal-state cooperative paramagnetism is found to be predominated by strong spin frustrations below the characteristic temperature T_(sn), where the Ising spin nematicity has been discerned in the FeSe superconductor crystals as reported elsewhere.     

Magnetic impurities in amorphous superconductors:TKondo>Tc

Measurements of upper critical field as a function of temperature and Fe-concentration are reported for the amorphous superconductors ((Mo_.6Ru_.4)_.80G_.20)_1−cFe_c, where G is a glass-former. The linear shapes of the H_c2 vs. T curves near T_c agree well with predictions made by Matsura, Ichinose, and Nagaoka, for T_Kondo > T_c.     

掺杂对二硼化镁超导体上临界磁场的影响

采用二带Ginzburg-Landau(GL)理论模型,考虑到能带有效质量的各向异性,讨论了MgB2超导体的上临界磁场对角度、温度和相干长度的依赖关系.结果表明,替代杂质越多,上临界磁场越强,这与实验结果符合.     

Anisotropy of the upper critical field in MgB<Subscript>2</Subscript>: The two-band Ginzburg-Landau theory

The temperature dependence of the anisotropy parameter of the upper critical field \(\gamma _{H_{c2} } (T) = H_{c2}^\parallel (T)/H_{c2}^ \bot (T)\) is calculated using the two-band Ginzburg-Landau theory for layered superconductors. It is shown that the anisotropy parameter γ(T) increases with decreasing temperature. The results of the calculations are in agreement with experimental data for single crystals of MgB₂ and with other calculations.     

铁硒基超导研究新进展:高质量(Li,Fe)OHFeSe单晶薄膜

单晶薄膜形态的高温超导材料对于相关基础科学研究和应用开发都极为重要.多带的铁基高温超导体往往呈现丰富的物理现象,并具有较高的超导临界参数.特别是近年发现的插层（Li,Fe）OHFeSe超导体,无论对高温超导机理还是应用研究而言,都日益受到重视,已成为铁基家族中重要的典型材料.但是,该化合物含有OH键,加热易分解.因此,现有的常规高温成膜技术均不适用于生长该薄膜材料.为解决这一生长难题,我们最近发明了基体辅助水热外延生长法,实现了超导薄膜制备技术上的突破.本文简要介绍用此软化学成膜技术首次成功制备出（Li,Fe）OHFeSe单晶薄膜.该薄膜材料具有优良的结晶质量和较高的超导临界参数,特别是其高的临界电流密度和上临界场对应用开发有实际价值.因此,（Li,Fe）OHFeSe超导单晶薄膜的成功合成,为机理研究和应用开发分别提供了重要的实验载体和备选材料.另外,该薄膜技术也有望应用于其他功能材料的探索与合成,尤其是对常规手段难以获取的材料更具重大价值.     

Magnetic properties of the Bi1.95Sr2.05−xLaxCuOy (Bi-2201) superconducting phase

We have investigated the reversible mixed-state magnetization M of three lanthanum substituted Bi_1.95Sr_2.05−xLa_xCuO_y (Bi-2201) ceramic samples having different critical temperatures T_c ranging from 20.0 to 35.5 K. As for the Bi₂Sr₂CaCu₂O_8+δ (Bi-2212) phase, we found that anisotropy of Bi-2201 is large. A manifestation of this anisotropy is the field independent magnetization M^* observed at a temperature T^*. In the framework of the London model, and including thermal fluctuations of vortices, we found for the temperature dependence of the penetration depth λ_ab(T) = λ_ab(0)[1 − (T/T_c0)ⁿ]^−1/2, with n 1.7 and λ_ab (T = 0) 4000 Å. The estimated upper critical fields μ₀H_c2,c are of the order of 10 T. We observe a peculiar negative slope M/T at low temperature and sufficiently high external magnetic field. This feature seems to be a characteristic of the Bi-2201 phase. However, we do not know whether it is associated with the superconducting mixed-state. A small amount of magnetic impurities could also be responsible for this behavior. Finally, the behavior of the reversible magnetization of the Bi-2201 samples investigated, which are situated at the optimal and in the overdoped region, did not indicate any unusual temperature dependence for the upper critical field H_c2,c.     

FeSe基超导单晶与薄膜研究新进展:自旋向列序、电子相分离及高临界参数

FeSe基超导体的超导临界温度可大范围调控,物理现象丰富,是非常规超导机理研究的热点.由于较高的超导临界参数及易于加工等特点,FeSe基超导体在超导应用开发方面也日益受到重视.大尺寸高质量的单晶和薄膜形态的FeSe基超导材料,对于相关基础科学研究和应用开发都极为重要.作者近年来先后开发和发明了水热离子交换（ion-exchange）、离子脱插（ion-deintercalation）、基底辅助水热外延生长方法,成功解决了二元FeSe和插层（Li,Fe）OHFeSe超导体高质量单晶和薄膜的生长和物性调控难题.进而在相关物理问题的研究中取得新进展,包括发现二元FeSe中自旋向列序与超导电性密切相关,观测到（Li,Fe）OHFeSe中的电子相分离现象.此外,（Li,Fe）OHFeSe超导薄膜呈现很高的超导临界电流密度和上临界磁场,其应用前景值得关注.     

Preparation and superconducting properties of YBa2Cu4O8

Samples of YBa₂Cu₄O₈ are prepared by means of a new high oxygen pressure technique employing oxygen-HIP. Both magnetization and resistivity measurements show the superconductivity transition at 82.5 K. The lower and upper critical fields of YBa₂Cu₄O₈ are obtained from the magnetization measurements. The Ginzburg-Landau parameters, ζ(0)=17 Å, λ(0)=2400 Å, are estimated from these results.     

二带超导体上临界磁场的各向异性

采用二带Ginziburg-Landau(G-L)理论模型计算了各向异性超导体的上临界磁场,发现上临界磁场Hc2的解析式中包含序参量的各向异性和有效质量的各向异性;上临界磁场ab-面内分量Hc|2|ab、c-轴方向分量Hc|2|ab与实验数据符合;上临界磁场比率在实验许可范围之内。     

Temperature dependence of the anisotropy parameter of the LiFeAs upper critical field in the two-band Ginzburg-Landau theory

An analytical formula is obtained for the temperature dependence of the anisotropy parameter of the upper critical field of a two-band superconductor in the context of the generalized Ginzburg-Landau theory for layered superconductors. The theoretical results are compared with the experimental data for new superconductor LiFeAs.     

Fluctuating specific heat in two-band superconductors

Theory of thermal fluctuations in two-band superconductors under an essentially homogeneous magnetic field is developed within the framework of the two-band Ginzburg-Landau theory. The fluctuating specific heat is calculated by using the optimized self-consistent perturbation approach and the results are applied to analyze the thermodynamic data of the iron-based superconductors Ba_(1-x)K_xFe_2As_2 with x ~0.4, which have been suggested to have a two-band structure by recent experiments. We estimate the fluctuation strength in this material and find that the specific heat is described well with the Ginzburg number Gi = 4 · 10~(-4). The influence of interband coupling strength is investigated and the result of the two-band Gaussian approximation approach is compared.     

Ba1-xKxFe2As2单晶(Tc=38.5K)磁通钉扎力与钉扎机理研究

铁基超导体是在2008年由Hosono发现的一种新型超导材料, 由于其具有上临界场高、各向异性小、临界电流密度大等优点, 在世界范围内引起了广泛关注. 以Ba_1-xK_xFe₂As₂为代表的FeAs-122系超导体具有结构简单、合成温度低、单晶容易制备等优点, 是物理学家和材料学家关注的焦点. 本工作在获得最优化掺杂的Ba_1-xK_xFe₂As₂单晶(T_c = 38.5 K)基础上, 通过分析其在不同磁场条件下电阻温度变化关系、不同温度条件下的磁滞回线等数据, 系统的研究了Ba_1-xK_xFe₂As₂单晶磁通钉扎力和磁通钉扎机理. 研究发现Ba_1-xK_xFe₂As₂超导体具有非常高的磁通钉扎势, 其中9 T的外场条件下, 其在H//c轴和H//ab面的钉扎势分别为5800 K和8100 K, 展示出良好的应用前景; 通过进一步分析发现, 其磁通钉扎机理应是由于晶格内部的小尺寸缺陷引起的电子平均自由程变化而导致的δl钉扎.     

在二带京兹堡朗道理论下MgB2的超导参量的研究

文中通过G-L理论二带模型来研究相干长度ξ(T)、伦敦穿透深度λ(T)以及京兹堡朗道参量κ(T)=λ(T)/ξ(T)在Tc附近对温度T的依赖关系。理论计算结果与MgB2样品的实验数据符合的很好。同时与单带模型算出的结果做了对比,发现G-L理论二带模型能更精确描述MgB2的超导特性。     

THE LONGITUDINAL CRITICAL CURRENT OF A THIN FILM OF TYPE Ⅱ SUPERCONDUCTORS

The structure of the mixed state of a current-carrying thin film of ideal type II superconductors in longitudinal magnetic field is analysed. It is shown "that the lossless current flow through the films in the mixed state is possible only if H_e is larger than H_c1 (d).The curves of Longitudinal critical current obtained have complex structures and show the peak effect general.The main features of the theoretical I_c-H_e curve of the films with thickness d larger than 5λ are identical with those observed by Heaton and Rose-Innes in Nb₅₅Ta₄₅ alloys.     

Coexistence of superconductivity and antiferromagentic order in Er2O2Bi with anti-ThCr2Si2 structure

We investigated the coexistence of superconductivity and antiferromagnetic order in the compound Er₂O₂Bi with anti-ThCr₂Si₂-type structure through resistivity, magnetization, specific heat measurements and first-principle calculations. The superconducting transition temperature T_c of 1.23 K and antiferromagnetic transition temperature TN of 3 K are observed in the sample with the best nominal composition. The superconducting upper critical field H_c2(0) and electron-phonon coupling constant λ_e−ph in Er₂O₂Bi are similar to those in the previously reported non-magnetic superconductor Y2O2Bi with the same structure, indicating that the superconductivity in Er₂O₂Bi may have the same origin as in Y₂O₂Bi. The first-principle calculations of Er₂O₂Bi show that the Fermi surface is mainly composed of the Bi 6p orbitals both in the paramagnetic and antiferromagnetic state, implying minor effect of the 4f electrons on the Fermi surface. Besides, upon increasing the oxygen incorporation in Er₂O_xBi, Tc increases from 1 to 1.23 K and T_N decreases slightly from 3 K to 2.96 K, revealing that superconductivity and antiferromagnetic order may compete with each other. The Hall effect measurements indicate that hole-type carrier density indeed increases with increasing oxygen content, which may account for the variations of T_c and T_N with different oxygen content.     

Flux creep and flux flow for thallium ceramics in a pulsed magnetic field

The resistive properties of Tl-ceramics with T_c|=0=114 K were investigated in a pulsed magnetic field (B) up to 30 T and in the temperature range of 4.2 K<T<140 K. It was shown that the character of the field dependence of the resistance differs qualitatively in high-and low-temperature regions. At low (T80K) temperatures the dynamic magnetoresistance arising in the sample is analogous to that observed earlier in LaSrCuO [1] and YBaCuO [2] ceramics. This magnetoresistance is defined by the magnetic field variation rate and leads to the appearance of a minimum at the maximum of the magnetic field pulse, i.e. at . In the region of high temperatures (80 K T<T_c) or magnetic fields (at T60K) the sample resistance rises monotonically with B increase, and dynamic resistance is not observed. In this temperature range the existence of a scaling relation is shown (here B^* and T^* meet the condition k=(B^*, T^*)/ _n(T^*)=const) for the ceramics resistance (B,T), which can be represented as . An estimate for the upper critical field B_c2(0)B_o=1030±40 T is obtained.