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1.
A. I. Smirnova V. E. Maizlish N. V. Usol'tseva V. V. Bykova G. A. Anan'eva E. V. Kudrik A. V. Shirokov G. P. Shaposhnikov 《Russian Chemical Bulletin》2000,49(1):132-139
Copper tetra-4-(n-alkoxycarbonyl)phthalocyanines were synthesized, and their thermotropic and lyotropic mesomorphism at different lengths of
lateral substituents was studied. Their possibility of forming both thermotropic and lyophilic mesophases (amphotropy) was
found. The length of lateral substituents affects the type of supramolecular packing in the mesophase rather than the temperature
of the crystal→mesophase phase transition. A rarecase of the mesogeneity of disk-like compounds of the same chemical nature
possessing only four substituents is discussed.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 129–136, January, 2000. 相似文献
2.
A. I. Smirnova V. E. Maizlish N. V. Usol'tseva V. V. Bykova G. A. Anan'eva E. V. Kudrik A. V. Shirokov G. P. Shaposhnikov 《Russian Chemical Bulletin》1990,49(1):132-139
Copper tetra-4-(n-alkoxycarbonyl)phthalocyanines were synthesized, and their thermotropic and lyotropic mesomorphism at different lengths of
lateral substituents was studied. Their possibility of forming both thermotropic and lyophilic mesophases (amphotropy) was
found. The length of lateral substituents affects the type of supramolecular packing in the mesophase rather than the temperature
of the crystal→mesophase phase transition. A rarecase of the mesogeneity of disk-like compounds of the same chemical nature
possessing only four substituents is discussed.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 129–136, January, 2000. 相似文献
3.
J. G. Jegal A. Blumstein 《Journal of polymer science. Part A, Polymer chemistry》1995,33(15):2673-2680
An ionogenic main chain liquid crystalline polymer was synthesized. In contrast to previous studies the charged sites were incorporated into the flexible spacer and not into the mesogenic group. This was done through quaternization of 1,2-bis(4-pyridylethane) with a biphenyl-4,4′-nonanoxytoluenesulphonate. The polymer displayed thermotropic and lyotropic me-sophases. The thermotropic mesophase was smectic. Organic counterions such as meth-ylsulfonates and p-toluenesulfonates were found to be favorable to the development of mesophases, due to the increased solubility and lower isotropisation temperatures, when compared to bromide counterion containing polymers. Easy supercooling, dependence on thermal history, and the development of batonnet textures on cooling from the melt were also observed. © 1995 John Wiley & Sons, Inc. 相似文献
4.
There was phase separation between the anisotropic and isotropic phases in the ethyl-acetyl cellulose/dichloroacetic acid cholesteric liquid crystalline solutions .The textures of mesophase varied with the concentration. The mesophases could form the disc-like texture, oily streaks texture and texture of domains gathered randomly. In the first two textures the layers of the ordered molecular chain were perpendicular to the slide surface and the axes of the helical structure were parallel to the slide surface. 相似文献
5.
Liu Q Beier C Evans J Lee T He S Smalyukh II 《Langmuir : the ACS journal of surfaces and colloids》2011,27(12):7446-7452
We report alignment of anisotropic amphiphilic dye molecules within oblate and prolate anisotropic micelles and lamellae, the basic building blocks of surfactant-based lyotropic liquid crystals. Absorption and fluorescence transition dipole moments of these dye molecules orient either parallel or orthogonal to the liquid crystal director. This alignment enables three-dimensional visualization of director structures and defects in different lyotropic mesophases by means of fluorescence confocal polarizing microscopy and two-photon excitation fluorescence polarizing microscopy. The studied structures include nematic tactoids, Schlieren texture with disclinations in the calamitic nematic phase, oily streaks in the lamellar phase, developable domains in the columnar hexagonal phase, and various types of line defects in the discotic cholesteric phase. Orientational three-dimensional imaging of structures in the lyotropic cholesterics reveals large Burgers vector dislocations in cholesteric layering with singular disclinations in the dislocation cores that are not common for their thermotropic counterparts. 相似文献
6.
《Liquid crystals》2000,27(5):697-701
N,N'-diundecenoylbenzene-1,4-diamine (DUBDA), an amide with long symmetric aliphatic chains, is shown to exhibit monotropic thermotropic liquid crystallinity as well as lyotropic liquid crystallinity in highly polar solvents on the basis of differential scanning calorimetry, polarized optical microscopy, temperature-variable FTIR, and X-ray diffraction analysis. There are obvious differences between the two mesophases in terms of molecular stacking and driving force, although the two mesophases originate from the same molecule. In addition, a possible lamellar model for the lyotropic mesophase is proposed. 相似文献
7.
Abstract Polymerizable lipopeptides with two hydrophobic chains were synthesized and transformed into comb-like polymers by radical polymerization. The structure of dry polymerizable lipopeptides and comb-like polymers and of their aqueous solutions was determined by X-ray diffraction. Comb-like polymers exhibit both thermotropic and lyotropic properties. Three types of mesomorphic structure were resolved: smectic B, smectic A and cylindrical hexagonal. The domains of stability of the mesophases and the values of their structural parameters were established. 相似文献
8.
This study highlights the effects of amphiphile chain length and counter ions on the self-assembly and dielectric behaviour of non-aqueous lyotropic liquid crystals. Two-dimensional hexagonal mesophase is seen for short-chain length sodium dodecyl sulphate, while lamellar and multiwall lamellar mesophases are noticed for long-chain length cetyltrimethylammonium bromide and polyoxyethylene (20) sorbitan monolaurate amphiphiles in the non-aqueous domains of ethylene glycol. A strong influence of amphiphile counter ions is seen on static dielectric constant, loss factor, relaxation frequency and relaxation time of these lyotropic mixtures. Refractive indices of these lyotropic phases are also highlighted. 相似文献
9.
Polymerizable lipopeptides with two hydrophobic chains were synthesized and transformed into comb-like polymers by radical polymerization. The structure of dry polymerizable lipopeptides and comb-like polymers and of their aqueous solutions was determined by X-ray diffraction. Comb-like polymers exhibit both thermotropic and lyotropic properties. Three types of mesomorphic structure were resolved: smectic B, smectic A and cylindrical hexagonal. The domains of stability of the mesophases and the values of their structural parameters were established. 相似文献
10.
Michael A. Yandrasits Jianhua Chen Fred E. Arnold Stephen Z. D. Cheng Virgil Percec 《先进技术聚合物》1994,5(12):775-784
A series of thermotropic polyethers synthesized from 1-(4-hydroxyphenyl) - 2 - (2 - methyl - 4 - hydroxyphenyl) - ethane and α,ω-dibromo-n-alkanes with odd numbers of methylene units (MBPE-n = odd) shows monotropic mesophase behavior. In isothermal differential scanning calorimetry (DSC) experiments, two—sometimes even three—exothermic transition processes can be observed when the crystallization temperature is below the mesophase transition temperature, while only one exothermic process is present above the mesophase transition temperature. The melting behavior of the crystals grown from the mesophase and from the isotropic melt states is different. The crystals grown from the mesophase state exhibit a larger overall heat of transition and a higher transition temperature compared with those grown from the isotropic melt. This may be attributed to the molecular interfacial connections between the crystal and amorphous regions when MBPEs crystallize from the mesophase state. The difference in morphology between the crystals grown from the different states has also been studied with polarized light microscopy (PLM) and transmission electronic microscopy (TEM). The structures of the crystals grown from the different states are, however, the same, as evidenced through wide-angle X-ray diffraction (WAXD) measurements. From the banded morphology of MBPE samples observed from PLM, the defect textures observed through TEM and the results of WAXD experiments, this mesophase can be identified as a nematic liquid crystal state. 相似文献
11.
Lipopeptidic macromonomers were synthesized from bi-functional lipids by two methods and transformed into comb copolymers with lipopeptidic side chains by radical polymerization of their acrylate, methacrylate, acrylamide or methacrylamide terminal group. X-ray diffraction and differential scanning calorimetry studies showed that comb copolymers exhibit both a thermotropic and a lyotropic behaviour and present smectic and nematic mesophases. The influence of the solvent concentration, the degree of polymerization of the peptidic chains and the nature of the main chains on the structural parameters of the smectic mesophases were established in the case of copolymers with liposarcosine side chains. 相似文献
12.
通过联苯二酚(介晶基元)、取代对苯二酚(破坏结晶基元)与4,4'-二氟二苯酮的亲核取代反应合成了一系列具有液晶性的新型聚芳醚酮,采用DSC、PLM和WAXD等方法对聚合物的研究表明:联苯含量为70%时聚合物表现为向列相,联苯含量为50%时聚合物出现近晶相,在外力场作用下,向列相液晶容易形成明暗交替的条带织构. 相似文献
13.
《Liquid crystals》1997,22(4):427-443
Novel amphiphilic glucamine derivatives have been synthesized. These are N-benzoyl-1-deoxy1-methylamino-D-glucitols and N-benzoyl-1-amino-1-deoxy-D-glucitols carrying one, two or three aliphatic chains (CnH2n 1O- with n 3, 6 and 12) grafted to the benzamido group. The thermotropic mesophases of these compounds were studied by thermal polarizing optical microscopy and differential scanning calorimetry, and some also by X-ray scattering. Depending on the number and the length of the alkyl chains lamellar, bicontinuous cubic, hexagonal columnar or inverted micellar cubic mesophases were detected by analogy with lyotropic systems. In the contact region between lamellar phases of the single chain amphiphiles and micellar cubic phases of the mesomorphic triple chain compounds, hexagonal columnar phases can be induced. A hexagonal columnar phase was also induced in the contact region between a bicontinuous and a micellar cubic mesophase. The lyotropic liquid crystalline behaviour of the dodecyloxy substituted N-benzoyl-1-deoxy-1-methylamino-D-glucitols was investigated by the solvent penetration method using ethylene glycol as protic solvent. On increasing the solvent content, the double chain compound forms a cubic and a lamellar mesophase and the triple chain compound forms a hexagonal columnar lyomesophase. The dodecyloxy substituted compounds were also investigated with respect to their behaviour as thin films at the air-water interface using a Langmuir film-balance. Different types of pi/Aisotherms were observed whereby the molecular areas at collapse were determined either by the size of the carbohydrate head group (single chain compounds) or by the number of alkyl chains (double and triple chain compound). 相似文献
14.
The synthesis and characterization of lyotropic smectic amphiphilic side-on polymers are described. The amphiphile consists
of a rigid, aromatic core with two terminal ethyleneoxide chains of various lengths and is laterally attached to a polysiloxane
backbone; the length of the spacer has also been varied. The phase behavior of the monomeric amphiphiles and side-on polymers
are determined by polarizing microscopy and 2H-NMR measurements. In water, most of the low molecular weight surfactants show restricted lyotropic properties, namely lyotropic
smectic phases. The packing restriction of the amphiphiles is due to their geometric anisometry. All side-on polymers exhibit
only lyotropic smectic phases. The phase regime of the polymer mesophase with respect to the monomers depends on the spacer
length. In contrast to surfactants having a flexible hydrophobic group, these amphiphiles align spontaneously parallel to
an external magnetic field, leading to perfect lyotropic smectic monodomains.
Received: 21 May 2001 Accepted: 27 August 2001 相似文献
15.
Thomas P. Rieker 《Liquid crystals》1995,19(4):497-500
X-ray diffraction experiments on smectic A and C forming thermotropic liquid crystals reveal that the smectic layer spacing increases with the addition of organic solvents to the host material. The rate of this increase indicates the formation of an organic lyotropic lamellar liquid crystal phase in which the solvent is intercalated between the smectic layers of the host liquid crystal. 相似文献
16.
The supramolecular approach was applied to obtain a thermotropic liquid crystalline phase from the smallest possible molecules. Diaminobenzene derivatives are able to form smectic layers through a network of interconnected hydrogen bonded rings. The observed smectic A phase exhibits unusually small optical birefringence, comparable with that of lyotropic lamellar phases. 相似文献
17.
The proton magnetic resonance spectra of 1,2,5-selenadiazole together with the natural abundance 13C and 77Se satellites have been obtained and analysed in two lyotropic mesophases and in a thermotropic mesophase. The rz structure of the molecule has been obtained. 相似文献
18.
Novel 3-phenyloxy substituted propane-1,2-diol derivatives, 4-(4-n-hexyloxyphenyl)-butane-1,2-diol and 4-(trans-4-n-pyropylcyclohexyl)-butane-1,2-diol have been synthesized and their thermal behaviour has been studied. These compounds exhibit thermotropic and, after addition of water, also lyotropic liquid-crystalline behaviour. The clearing temperatures of the smectic mesophases were found to be strongly dependent on the alkyl chain length and on the structural units that link the aromatic ring to the alkyl chain and to the diol unit. The behaviour of the aromatic compounds is compared with that of the cyclohexane derivative. Thereby it has been realized that the mesophase stability of the amphiphilic diols incorporating a rigid unit is largely determined by both, the molecular geometry (molecular shape and intramolecular flexibility) and the amphiphilic structural pattern. 相似文献
19.
Liquid‐Crystalline Mesogens Based on Cyclo[6]aramides: Distinctive Phase Transitions in Response to Macrocyclic Host–Guest Interactions
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Xiaowei Li Dr. Bao Li Long Chen Jinchuan Hu Chengdanyang Wen Prof. Qingdong Zheng Prof. Lixin Wu Dr. Huaqiang Zeng Prof. Bing Gong Prof. Lihua Yuan 《Angewandte Chemie (International ed. in English)》2015,54(38):11147-11152
Producing macrocyclic mesogens that are responsive to guest encapsulation presents a significant challenge. Cyclo[6]aramides, a type of macrocycle with a hydrogen‐bond‐constrained backbone, exhibit thermotropic lamellar, discotic nematic, hexagonal, and rectangular columnar mesophases over a considerably wide temperature range, including at room temperature. Additionally, cyclo[6]aramides show unusual mesophase transitions from lamellar to hexagonal columnar phase mediated by macrocyclic host–guest (H–G) interactions between the macrocycles and alkylammonium salts. The phase transition, triggered by an organic guest engaging in H–G interactions with a macrocyclic cavity, provides a novel strategy for manipulating the properties of liquid‐crystalline materials. The crystal structure of a homologous cyclo[6]aramide reveals a disk‐shaped, near‐planar molecular backbone that facilitates intermolecular π–π stacking and leads to columnar assembly. 相似文献
20.
Novel amphiphilic block molecules consisting of a rigid 2‐phenylthiophene or 5‐phenylbithienyl core, with a polar glycerol group attached to the phenyl ring and one or two alkyl chains attached to the thiophene ring on the other side, have been synthesised by using Ni(0) and Pd(0) catalyzed coupling reactions as key steps. The thermotropic and solvent‐induced liquid crystalline behaviour of these compounds was investigated by polarising optical microscopy and X‐ray diffraction. The influence of the length, number and position of the alkyl chains, and the length of the rigid core, on their mesophase behaviour was investigated. Compounds with one alkyl chain in the terminal 5‐position on the thiophene ring form only smectic A phases, compounds with two adjacent alkyl chains attached in the 4‐ and 5‐positions of the thiophene ring exhibit thermotropic columnar mesophases, and those with two long alkyl chains attached to the 3‐ and 5‐positions form columnar LC phases only in the presence of water. Another compound containing the longer 5‐phenylbithienyl core unit and two alkyl chains attached in lateral positions to each of the thiophene rings is not mesogenic. 相似文献