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1.
用固相法制备化合物CaY1-xBO4:xE7u,研究Eu^3+在CaYBO4中的取代格位和发光特性。当Eu^3+掺杂浓度不大时,存在两具发光中心,认为是取代基质中有两个Y格位的结果:通过对Eu-O的电荷迁移激发带位置的分析,表明Eu^3+所处八面体中心格位的对称性越低,Eu-O的电荷迁移带越偏向于短波;当Eu^3+的掺杂浓度较大(X〉0.10)时,Eu^3+离子也可占据Ca^2+格位,同时Eu^2 相似文献
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应用交流阻抗,恒电流,SEM等方法,研究了Ca-SOCl2电池中CaCl2(SEI)膜的性质,不同电解质和添加剂对电极性的影响,结果表明,CaCl2SEI膜在阳极反应电阻下降,CuCl2,CuBr2可改变CaCl2沉积形态,提高阴极性能,组装的Ca-SOCl2电池可高速率放电,在50mA.cm^-2的条件下,达到了17.5mAh.cm^-2。 相似文献
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用水热同晶置换法合成了杂原子磷酸名分子筛Me-VPI-5(Me=Mg,Ti,Sn,Si)。通过水相离子交换法掺杂稀土离子,考察了高温和高压下的相变行为。讨论了相变过程对稀土离子光谱的影响,随着温度升高Eu(Ⅲ)Mg-VPI-5先转变为Eu(Ⅲ)-AlPO4-8,然后又转变成致密的磷石英相。压力对Eu(Ⅲ)光谱结构具有显著影响。随着压力增加,Eu(Ⅲ)光谱结构发生规律性变化。 相似文献
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含Eu^2+固体的荧光光谱研究及其应用 总被引:6,自引:0,他引:6
系统介绍了含Eu^2+固体的荧光光谱研究的特点和意义,综述了近年来国内外的最新研究成果及其在激光,荧光,泊激励发光,电光源材料等高技术领域的应用。评述了非掺杂含Eu^2+固体化合物荧光的研究方法,并总结了该类化合物光谱变化的某些规律。 相似文献
6.
用水热同晶置换法合成了杂原子磷酸铝分子筛Me-VPI-5(Me=Mg,Ti,Sn,Si).通过水相离子交换法掺杂稀土离子,考察了高温和高压下的相变行为.讨论了相变过程对稀土离子光谱的影响.随着温度升高,Eu(Ⅲ)Mg-VPI-5先转变为Eu(Ⅲ)-AlPO4-8,然后又转变成致密的磷石英相.压力对Eu(Ⅲ)光谱结构具有显著影响.随着压力增加,Eu(Ⅲ)光谱结构发生规律性变化. 相似文献
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利用金属蒸气法制备了四种比表面不同的树脂固载Pd-Cu燃料电池电极。X射线衍射(XRD)和透射电镜(TEM)结果表明,随着树脂比表面积增大,固载量相同的Pd-Cu电极,Pd-Cu合金的颗粒减小,因而电催化活性增大。 相似文献
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Eu^2+和Mn^2+在Sr3MgSi2O8中的光致发光研究 总被引:7,自引:1,他引:7
研究了Eu^2+和Mn^2+共激活的Sr3MgSi2O8的荧光性质。Eu^2+和Mn^2+在460nm和690nm的发射峰分别由Eu^2+的5d→4f跃迁和Mn^2+的^4T1(^4G)→^6A1g(^6S)跃迁产生。未观察到单掺杂Mn^2+的Sr3MgSi2O8的荧光发射,而掺入Eu^2+后则出现了Mn^2+的690nm光致发光峰,表明Eu^2+对Mn^2+有敏化作用。Eu^2+的荧光寿命也受M 相似文献
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固态化合物中铕的价态研究进展 总被引:2,自引:0,他引:2
介绍了近年来关于变价稀土元素Eu价态研究的最新进展,总结了Eu^2+的价态稳定和转换及其与基质结构,取代离子半径电荷,共掺杂稀土离子电子构型之间的关系和规律。 相似文献
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用溶胶-凝胶法以磷钼酸(MPA)的镍盐溶液水解钛酸四丁酯制备了NiPMo/TiO2催化剂.使用ICP、 XRD、 TG-DTA、 IR、 TPD-MS和微反应技术研究了催化剂的化学组成、热稳定性、化学吸附性质和催化反应性能.杂多钼酸盐与TiO2通过O2-在TiO2表面发生了键合.在623 K下,杂多阴离子仍保持原有的Keggin结构.CO2在Lewis酸位Ni(Ⅱ)和Lewis碱位Ni-O-Mo的桥氧协同作用下生成CO2卧式吸附态Ni(Ⅱ)←O-(CO)←(O--Ni).丙烯有多种吸附态在催化剂上吸附.在563 K、 1 MPa和空速1500 h-1的反应条件下,丙烯的摩尔转化率为3.2%,产物MAA选择性为95%. 相似文献
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Different approaches for the synthesis of 1-benzyloxypyrazin-2(1H)-one derivatives from simple amino acids have been investigated. A library of 33 precursors for the preparation of N-hydroxy pyrazinones was obtained in moderate to good yields. 相似文献
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Toward new camptothecins. Part 6: Synthesis of crucial ketones and their use in Friedländer reaction
Laurent Gavara Thomas Boisse Jean-Pierre Hénichart Adam Daïch Philippe Gautret 《Tetrahedron》2010,66(38):7544-5571
In the context of the preparation of camptothecin and luotonin A analogs, the synthesis of some key keto-precursors and their use in Friedländer condensation are described. This paper also focuses on the stability of these keto intermediates and emphasizes the major differences between indolizinones and pyrroloquinazolinones series. Noteworthy is also the report of some original structures isolated as by-products of some experiments. 相似文献
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The Langevin paramagnetic theory can’t describe the relation between magnetization of ferrofluids and applied magnetic field. The structuralization of ferrofluids, which is considered the main influence factor of the magnetization, is regarded. The part of magnetization works is deposited when the structure is forming. This action influences the magnetization of ferrofluids directly or indirectly. On the base of the “compressing” model, the Langevin function that usually describes the magnetization of ferrofluid is modified, and a well-fitted curve is obtained. An equation of the relation between the equivalent volume fraction after being “compressed” and the intensity of magnetic field is discovered, which approximately describes the process of magnetization. The relation between the approximate initial susceptibility and the volume fraction can be obtained from modified formula. 相似文献
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Rebecca J. Burton Mandy L. CrowtherNeal J. Fazakerley Shaun M. FilleryBarry M. Hayter Jason G. KettleCaroline A. McMillan Paula PerkinsPeter Robins Peter M. SmithEmma J. Williams Gail L. Wrigley 《Tetrahedron letters》2013
The highly regioselective Buchwald–Hartwig amination at C-2 of the cheap and readily accessible reagent, 2,4-dichloropyridine with a range of anilines and heterocyclic amines is described. This new methodology is robust and provides a facile access to 4-chloro-N-phenylpyridin-2-amines on 0.25 mol scale. These intermediates undergo a further Buchwald–Hartwig amination at higher temperature to enable rapid exploration of the chemical space at C-4 and to provide a library of 2,4-bisaminopyridines. 相似文献
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KMnO4-mediated oxidative CN bond cleavage of tertiary amines producing secondary amine was introduced, which was trapped by electrophiles (acyl chloride and sulfonyl chloride) to form amides and sulfonamides. The reaction could take place at mild condition, tolerating a wide range of function groups and affording products in moderate to excellent yields. 相似文献
17.
N. A. Nedolya 《Chemistry of Heterocyclic Compounds》2008,44(10):1165-1219
The review contains a concise historical account and information on the most significant researches undertaken by the staff
at the A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences on the Chemistry
of Heterocyclic Compounds.
Dedicated to Academician of the Russian Academy of Sciences B. A. Trofimov on his 70th jubilee.
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 10, pp. 1443–1502, October, 2008. 相似文献
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Regiospecific and direct imidation of the methyl C(sp3)–H bond of thioanisoles is realized under mild and metal-free conditions with N-fluorobis(benzenesulfonyl)imide as an oxidant and nitrogen source. Proposed mechanism suggests that thionium ion intermediates and a Pummerer-type reaction are involved. The imidation has advantages such as high step-economy, excellent functionality tolerance, and regiospecificity, giving structurally diverse imidation products. 相似文献
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A general synthesis of previously unknown semicarbazone-based α-amidoalkylating reagents, 4-(tosylmethyl)semicarbazones, has been developed. The synthesis involved three-component condensation of semicarbazones of aliphatic or aromatic aldehydes with the same or other aldehydes and p-toluenesulfinic acid. The scope and limitations of this reaction were investigated. The compounds obtained were demonstrated to be an efficient α-(4-semicarbazono)alkylating agents. They were reacted with H- (sodium borohydride), O- (sodium methylate), S- (sodium phenylthiolate), N- (pyrrolidine, sodium succinimide), P- (trialkyl phosphites), and C-nucleophiles (sodium diethyl malonate) to give the corresponding products of the tosyl group substitution, 4-substituted semicarbazones, including analogues of nitrofurazone. Among the prepared compounds tested in vitro for antibacterial and antifungal activity, three nitrofuryl-containing semicarbazones exhibited high biological activities with minimum inhibitory concentration (MIC) values of 8–32 μg/mL. 相似文献
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A small library of new chiral bidentate hydroxyalkyl-imidazolium salts 1 is conveniently synthesized on multi-gram scale from inexpensive and commercially available chiral pool amino acids. The corresponding carbenes, generated by deprotonation of imidazolium salts 1, in combination with palladium(II) chloride were tested in the Mizoroki–Heck coupling reaction. The most significant results in terms of yields and reactivities were achieved with low catalyst loading. The catalytic activities of these imidazolium salts were also investigated in the asymmetric addition of diethylzinc to benzaldehyde. The use of MgO nanoparticles as an additive in conjunction with these ligands played a crucial role in increasing the efficiency of these reactions. 相似文献