Low temperature selfion irradiation of quench-condensed aluminium-films

Al-films were prepared by quench-condensation from Al₂O₃-crucibles and W-boats, respectively and irradiated with 230 keV Al⁺-selfions at low temperatures (<15 K). Forsmall fluences (<5·10¹⁵ cm^–2) the irradiation induced changes of the superconducting transition temperatureT _c and the resistivity strongly depend on the chemical form of the oxygen incorporated into the films by the different preparation techniques. Forhigh fluences (>10¹⁶ cm^–2) the behavior of the irradiated films is determined only by the integral oxygen content of the layers. The results are discussed qualitatively taking into account different physical processes during irradiation.     

Low temperature self-ion irradiation of pure and granular aluminium-films

Al-films, evaporated at room temperature under different oxygen partial pressures, were irradiated with self-ions (500 keV, Al⁺⁺) at low temperature (<7 K). The observed increase of the resistivity and of the superconducting transition temperatureT _c depends strongly on the oxygen contentc ₀ present in the layers. A qualitative different behaviour of the above quantities was found for different fluence ranges of the bombarding ions. For high fluences in all cases an oxygen stabilized disorder state was obtained with correspondingT _c-increases betweenT _c=0.2 K for the purest films (c ₀0.5 at %) andT _c =1.2 K for films with c ₀=40 at %. The annealing behaviour of the irradiated films is also dependent on the oxygen contentc ₀.     

Growth and magnetic characterization of YBCO films

Summary Epitaxial films of YBa₂Cu₃O_7−x were depositedin situ on LaAlO₃ substrates using single-target 90° off-axis sputtering. The films were characterized by magnetization measurements (M vs. T, H), applying the field parallel toc-axis. The observed differences in theT _c andJ _c values are attributed to the different oxygen content in the superconducting films. Paper presented at the ?VII Congresso SATT?, Torino, 4–7 October 1994.     

Hysteresis behavior in Raman intensities in YBa2Cu3O7-y -family superconductors between T c and T o = 234 K

The intensity of the 646 cm^-1 Raman line in YBa₂Cu_3-x V _x O_7-y has been measured for cooling and heating from 77 K to 234 K. The intensity exhibits intensity hysteresis of order 20% in the cooling versus heating values between T _c = 89 K and T _o = 234 K. This effect is unexplained but is extremely similar to that reported by Ledbetter et al. for the bulk modulus and C ₁₁ elastic coefficient. In each case the hysteresis vanishes below T _c , independent of the value of T _c , which may be adjusted from 60 K to 94 K by changing oxygen concentration y. Qualitative interpretation requires that the structural phase transition near 234 K be intimately related to the superconducting transition at T _c presumably through partial ordering of oxygens.     

Oxygen content and oxide barrier thickness in granular aluminum films

Granular aluminium films were prepared by evaporation in an oxygen atmosphere. The oxygen content C_o of the films was determined by Rutherford backscattering. The superconducting transition temperature T_c is measured as a function of the oxygen concentration. From the results the thickness of the oxide barriers is derived by applying a model of spherical granula. This model is confirmed by the observed linear dependence T_c α C_o.     

Superconducting properties and structure of ion bombarded Nb layers

The influence of ion bombardment on the superconducting transition temperature T_c and the structure of thin evaporated niobium layers has been investigated as a function of ion species and layer purity. Irradiation through pure layers with neon ions and fluences of typically 1016 ions/cm² leads to relatively small T_c decreases (δT_c × 0.5 K), while in oxygen contaminated layers larger effects depending on oxygen concentration are observed. Homogeneous implantation of chemically active impurities (nitrogen, oxygen) also drastically depresses T_c reaching the detection limit of 1.2K at a concentration of 15 at. %N. The T_c depressions correlate with a lattice parameter expansion of the Nb bcc structure at a rate of about 0.1 %per 1 at. % impurity.     

Temperature dependence of the critical current density in Y-Ba-Cu-O thin films

We present a study of the temperature dependence of the critical currentJ _c of several dc magnetron sputtered thin Y-Ba-Cu-O films on single crystalline SrTiO₃, ZrO₂ and Al₂O₃ substrates. Near the critical temperature T_c it is found thatJ _c(1–T/T_c)ⁿ withn=3 for the SrTiO₃ and ZrO₂ substrates, whilen=1·3 for the Al₂O₃ substrate. The temperature dependence in our samples approximately agrees with standard theories for weak links or with the Ambegaokar-Baratoff equation.     

Superconductivity and normal electrical conductivity of amorphous lead films nucleated with molybdenum

Lead films vapor quenched onto nucleating monolayers of Mo or W exhibit strong lattice disorder and can be considered to be amorphous. The amorphous-to-crystalline transformation temperatureT _tr is indicated by a sharp drop of the electrical resistivity in the course of annealing.T _tr is found to be proportional tod ^–2 for Pb thicknessd smaller than 30 nm. The superconducting transition temperatureT _c is by 0.6 to 1 K smaller in the amorphous state than after crystallization. In both states,T _c is proportional tod ^–1. Prenucleation with about half a monolayer of Mo leads to quite the sameT _c depression as observed earlier by Strongin et al. on Pb films vapor quenched onto predeposited films of SiO, Ge or Al₂O₃. For comparison, experiments have been carried out with 2.5 nm Ge predeposits. As with Mo prenucleation, a well defined transformation temperatureT _tr of about the same value has been observed.T _c of bulk amorphous Pb can be extrapolated to be about 6.6 K.     

氧分压对Mg掺杂ZnO薄膜结晶质量和光学特性的影响

利用脉冲激光沉积技术,通过改变沉积过程中的氧气压力,在蓝宝石(0001)基片上制备了一系列ZnMgO合金.通过X射线衍射、反射和透射光谱以及室温和变温荧光光谱,对薄膜的结构和光学性能进行了系统地表征,分析了工作气压对ZnMgO合金薄膜的结晶质量及光学特性的影响.研究结果表明:随着沉积环境中氧气压力的增大,ZnMgO薄膜的结晶质量下降,富氧环境下,与蓝宝石晶格平行的ZnO晶粒的出现是导致薄膜结晶质量下降的主要原因;相对于本征ZnO,不同氧气环境下沉积的ZnMgO薄膜的紫外荧光峰均出现了不同程度的蓝移.随着工 关键词： ZnO Mg掺杂 脉冲激光沉积 薄膜生长 光学特性     

Superconductivity of thin films of lead,indium, and tin prepared in the presence of oxygen

We have studied the influence of oxygen on the superconducting properties of thin films of lead, indium and tin deposited on glass or sapphire substrates. In addition, the morphological microstructure was investigated by scanning electron microscopy. The film thickness was 1.0 μm, and the partial pressure of O₂ during the film deposition was raised up to 1×10⁻⁴ Torr. In all three materials the development of a granular structure and a strong increase in the residual electric resistivity was observed due to the O₂-treatment. Whereas in the Pb films no change of the critical temperature was found, the In films deposited on glass substrates showed a slight increase ofT _c due to the oxygen. The strongest increase ofT _c (up to 8%) was observed in the O₂-treated Sn films. These results are discussed in terms of the McMillan theory. From our measurements of the critical current densityj _c we conclude that edge pinning is dominant in the undoped films. All three materials showed a strong increase ofj _c due to the O₂-treatment which must be interpreted in terms of bulk pinning.     

Thin film synthesis and the influence of irradiation-induced defects on the superconductivity of La1.8Sr0.2CuO4

Thin superconducting films of La_1.8Sr_0.2CuO₄ have been prepared by magnetron sputter deposition and subsequent temperature treatment. The composition of the films has been determined by Rutherford backscattering and the structure by thin film X-ray diffraction. The onset of superconductivity was about 32 K and the midpoint near 28 K. Defect production in the films by He ion bombardment revealed a drasticT _c reduction with a sensitivity similar to that observed in the Chevrel phases. Oxygen implantation and subsequent annealing led to an enhancement of theT _c onset.     

Effect of Zr,Ti substitutions onT c in superconducting YBa2Cu3O7−δ system

Zr and Ti have been substituted in the system Y_1−x M _x Ba₂Cu₃O_7−δ(M=Zr, Ti,x=0.05,0.1). We find that theT _c value is unchanged, ∼90K for Zr substitutions up to 10% and in the case of Ti substitutions theT _c drops significantly. These changes may arise from their site preference.     

The influence of low-temperature annealing on the physical properties of Bi2Sr2CaCu2O y thin films

We have studied the low-temperature annealing effect on the physical properties of Bi₂Sr₂CaCu₂O _y thin films deposited on a MgO(100) substrate by rf magnetron sputtering. It is found that the characteristics of the films depend strongly on the oxygen partial pressure during re-annealing at 470°C after high-temperature annealing at 770°C in air. T_c and ρ at 300 K abruptly change for less than 20% oxygen partial pressure. A peak shift of the Bi4f core level spectrum is also observed at 0% oxygen partial pressure in an XPS measurement, which is due to the change in the ligand of the Bi atom.     

Magnetic, optical and transport properties of GaMnN films

GaMnN films with 1-3% Mn deposited on Si(100) and Al₂O₃(0001) substrates, by the technique of nebulized spray pyrolysis by employing acetylacetonate precursors, have been characterized by X-ray diffraction, photoluminescence spectra and other techniques. The films are ferromagnetic and show magnetic hysteresis. The ferromagnetic T_C increases with the Mn content, with the 3% Mn film showing a T_C of ∼250 K. Anomalous Hall effect is observed below T_C where the films exhibit a small negative magnetoresistance.     

Anisotropic optical properties of single-crystal GdBa2Cu3O7−δ

The optical spectrum of reduced-T _c GdBa₂Cu₃O_7– has been measured for polarizations parallel and perpendicular to theab plane. The sample was an oxygen-deficient single crystal with a large face containing thec axis. The polarized reflectance from this face was measured from 20–300 K in the spectral region from 30–3000 cm^–1, with 300 K data to 30000 cm^–1. Kramers-Kronig analysis was used to determine the spectral dependence of theab and thec components of the dielectric tensor. The optical properties are strongly anisotropic. Theab-plane response resembles that of other reduced-T _c materials whereas thec axis, in contrast, shows only the presence of several phonons. There is a complete absence of charge carrier response alongc aboveand belowT _c. This observation allows us to set an upper limit to the free-carrier spectral weight for transport perpendicular to the CuO₂ planes.Permanent address: Institute of Physics, CSAV, Prague, Czechoslovakia     

Effects of RE2O3 (RE = Tm, Sc, Yb) addition on the superconducting properties of ErBa2Cu3Oy

We investigated the effects of added Tm₂O₃, Sc₂O₃, and Yb₂O₃ on the superconducting properties of sintered Er123 samples. Tm₂O₃ addition caused the least T_c degradation, exhibiting a T_c above 90 K even for 17 vol% addition. Samples with added Sc₂O₃ maintained a T_c at above 90 K up to an addition of 7.2 vol%, while Yb₂O₃-containing samples showed a monotonic decrease in T_c with increased vol% of added Yb₂O₃. Tm₂O₃-containing samples exhibited a slight increase in J_c(0.1 T)/J_c(0) and had constant J_c values even for 17 vol% addition. XRD and SEM results indicate that the Tm₂O₃ is very stable in the superconducting matrix.     

Low-temperature behavior of specific heat curves in ruthenocuprate RuSr<Subscript>2</Subscript>Gd<Subscript>1.5</Subscript>Ge<Subscript>0.5</Subscript>Cu<Subscript>2</Subscript>O<Subscript>10 − δ</Subscript>: Superconducting,magnetic and crossing-point effects

Magnetic and superconducting properties of polycrystalline samples of RuSr₂Gd_1.5Ce_0.5Cu₂O_{(10 − δ)}, asprepared (by solid-state reaction) and annealed in pure oxygen at different pressure are presented. Specific heat and magnetization were investigated in the temperature range 1.8–300 K with a magnetic field up to 8 T. Specific heat, C (T), shows a jump at the superconducting transition (with onset at T ≈ 37.5 K) and a Schottky-type anomaly below 20 K. It is found that curves C(T) taken for different values of magnetic field have the same crossing point (at T _* ≈ 2.7 K) for all samples studied. At the same time, C(H) curves taken for different temperatures have a crossing point at a characteristic field H _* ≈ 3.7 T. These effects are manifestations of the crossing-point phenomenon, which is supposed to be inherent for strongly correlated electron systems.     

双层钙钛矿La1.8Ca1.2Mn2O7磁性相关I-V非线性与电输运性质

采用传统固相反应法制备了双层钙钛矿结构锰氧化物La_1.8Ca_1.2Mn₂O₇陶瓷,并用X射线粉末衍射法,扫描电镜,HL5500PC Hall效应分析仪和综合物性测量系统(PPMS)对其磁、电性质进行了表征.结果表明:经过两次高温烧结可合成具有双层Sr₃Ti₂O₇型四方结构的La_1.8Ca_1.2Mn_2<     

TG/DTA evidence of fluorine incorporation into YBa2Cu3O6⋅+δ

TG/DAT evidence to support incorporation of fluorine into superconducting orthorhombic lattice in YBa₂Cu₃O_6⋅+δ is presented. It is inferred that the F atom goes substitutionally in place of O atom in the lattice. Replacement of two oxygen atoms by four fluorine atoms did not alter theT _cof the product. By a similar replacement of two of its oxygens by fluorine atoms, the tetragonal modification of the oxide yields a product that remains non-superconducting down to 30 K.