首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献,搜索用时 578 毫秒
1.
A visible light(vis)‐sensitive photoresist based on the concept of chemical amplification was developed utilizing poly(p‐hydroxystyrene) (PHS), 2,2‐bis[4‐(2‐(vinyloxy)‐ethoxy)phenyl]propane (BPA‐DEVE) as a crosslinking agent, N‐trifluoromethylsulfonyloxy‐1,8‐naphthalimide (NIT) as a photoacid generator (PAG) and pyrromethene dyes such as 1,3,5,7,9‐pentamethylbipyrromethene difluoroborate (PRH) and 2,8‐diethyl‐1,3,5,7,9‐pentamethylbipyrromethene difluoroborate (PRE) and 3,3′‐carbonylbis(7,7′‐diethylaminocoumarin) (KCD). On irradiation with an argon ion laser, the photopolymer comprising PRH and PRE exhibited a high sensitivity of 65 and 46 mJ cm?2, respectively. It is suggested that the sensitization mechanism of the pyrromethene dye/PAG system involves singlet electron transfer. The sensitivity of the photoresist increased with the decreasing molecular weight of PHS because of the high dissolution rate. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   

2.
Poly(p-hydroxystyrene)s (PHSs) partially protected by tetrahydropyranyl (THP), PPT-x, containing 2,2′-bis(4-(2-(vinyloxy)ethoxy)phenyl)propane as a crosslinking agent were used as three-component photopolymers in combination with diphenyliodonium 9,10-dimethoxyanthracene-2-sulfonate (DIAS) as a photoacid generator. The PPT-x with a higher THP-protecting ratio was deprotected at higher temperatures than the PPT-x with a lower THP-protecting ratio. The conversions of vinyl ether compound in the photopolymer films were not related to the THP-protecting ratios in PPT-x and increased with increasing baking time. Under different THP-protecting ratios and prebaking temperatures, the PPT-x showed varying lithographic behavior between a positive-working mode and a negative-working mode. These three-component photopolymer solutions of PPT-x have good preservation stability. © 1998 John Wiley & Sons, Ltd.  相似文献   

3.
Reaction of 2-[2-(vinyloxy)ethoxy]methyl- and 2-(allyloxymethyl)oxiranes with 2-propynyl- and phenylethynylmagnesium bromides (10–55°C, 0.5–4 h) resulted in new representatives of the series of 1-organyloxy-5-hexyn-2-ols, -5-phenyl-4-pentyn-2-ols, and -3-bromo-2-propanols in 50–99% yields. During distillation the 1-[2(vinyloxy)ethoxy]-5-phenyl-4-pentyn-2-ol and -3-bromo-2-propanol transform respectively into 2-methyl-4-(3-phenyl-2-propynyl)- and 2-methyl-4-(bromomethyl)-1,3,6-trioxocanes via intramolecular cyclization involving the hydroxy and vinyloxy groups.  相似文献   

4.
A novel flexible diamine with built-in ester, amide and ether groups named terephthalic acid bis(4-{2-[2-(2-amino ethoxy)ethoxy]ethyl carbamoyl}phenyl) ester (TABE), was synthesized via two steps. Nucleophilic reaction of 4-hydroxybenzoic acid with terephthaloyl chloride in the presence of NaOH yielded terephthaloyl bis (4-oxybenzoic) acid (TOBA). The diamine (TABE) was prepared via two direct and indirect methods. In the indirect method TOBA was converted to related diacid chloride and reacted with 1,8-diamino-3,6-dioxaoctane (DADO). Direct method was achieved through the reaction of TOBA with DADO via Yamazaki method. TOBA and TABE were fully characterized and TABE was used to prepare new poly(ester amide ether amide)s through polycondensation with different diacid chlorides in the presence of trimethylchlorosilane (TMSCl). The polymers were characterized using conventional methods and their physical properties including inherent viscosity, thermal behavior, thermal stability, crystallinity, and solubility were studied. The polymers showed good thermal stability and improved solubility.  相似文献   

5.
Base-catalyzed reaction of 2-hydroxybenzaldehyde with 2-{[2-(vinyloxy)ethoxy]methyl}oxirane gave 2-{2-hydroxy-3-[2-(vinyloxy)ethoxy]propoxy}benzaldehyde in 42% yield, and subsequent condensations of the product with thiosemicarbazide and primary aliphatic amines afforded the corresponding thiosemicarbazone (yield 86%) and 1-{2-[(alkylimino)methyl]phenoxy}-3-[2-(vinyloxy)ethoxy]propan-2-ols (74–81%).  相似文献   

6.
A diamine was synthesized by two successive reactions.Nucleophilic reaction of 4-hydroxybenzoic acid with terephthaloyl chloride yielded terephthaloyl bis(4-oxybenzoic) acid.Then reaction of this compound with 1,8-diamino-3,6- dioxaoctane via Yamazaki method resulted in preparation of diamine named terephthalic acid bis(4-{2-[2-(2-amino ethoxy)ethoxy]ethyl carbamoyl}phenyl) ester.After fully characterization it was used to prepare new polyimides through polycondensation with different dianhydrides using trimethylchlorosilane.Characterization of polymers was achieved by common methods and their physical properties including inherent viscosity,thermal behavior,thermal stability,crystallinity and solubility were studied.Prepared polyimides showed improved solubility and good thermal stability.  相似文献   

7.
Three novel terpolymers, i.e. P-1, P-2 and P-3, were prepared from the terpolymerization of butyl p-styrenesulfonate (BSS), methyl methacrylate (MMA) and methacrylic acid (MAA). Thin films composed of the prepared terpolymers, 2,2-bis(4-(2-(vinyloxy)ethoxy)phenyl)propane (BVPP) and an IR dye (in case of laser scanning) were made onto an aluminum substrate. Crosslinking and de-crosslinking reactions would readily take place when the films were treated at 80 °C and 220 °C for a short period of time, respectively. Along with the chemical structural changes during thermal treatment, great solubility changes could be achieved. It was found that the crosslinked polymer matrix was more resistant to aqueous solution and insoluble in neutral water, whereas the de-crosslinked one such as P-1 matrix could become soluble in neutral water. Based on these properties, a positive-working and neutral water-developable imaging material was proposed and preliminary studies on the imaging property were conducted.  相似文献   

8.
The photochemical reaction of polymer containing vinyloxy group (P-1), which was prepared from treating poly(epichlorohydrin) with base using a phase transfer catalyst, was investigated in the presence of a photo-generated cationic catalyst (PGCC). When the polymer with PGCC was irradiated, the vinyloxy group in the polymer disappeared rapidly. The rate of disappearance of the vinyloxy group in P-1 was strongly influenced by its content in the polymer and the kind of PGCC. P-1, containing about 65 mol% of vinyloxy group, had the highest photochemical reactivity, and PGCC with PF6? and SbF6? as counterions showed higher catalytic activity than those with BF4? The photochemical reaction of P-1 involved a number of reactions such as degradation, rearrangement, and crosslinking reaction competitively; however, P-1 with less vinyloxy group than 60 mol% degraded preferentially. These results suggested that P-1 is an excellent photodegradating polymer using PGCC. The thermal degradation of P-1 was also investigated.  相似文献   

9.
To clarify the effects of the central spacer chain structure of divinyl ethers on their cationic cyclopolymerization tendencies, 1,4‐bis[(2‐vinyloxy)ethoxy]benzene ( 1 ), 1,4‐bis[(2‐vinyloxy)ethoxy]butane ( 2 ), 1,6‐bis[(2‐vinyloxy)ethoxy]hexane ( 3 ), 1,8‐bis[(2‐vinyloxy)ethoxy]octane ( 4 ), and 1,4‐bis[(4‐vinyloxy)butoxy]butane ( 5 ) were polymerized with the hydrogen chloride/zinc chloride (HCl/ZnCl2) initiating system in methylene chloride (CH2Cl2) at 0 °C at low initial monomer concentration ([M]0 = 0.15 M). The polymerizations of divinyl ethers 2 and 3 gave soluble polymers quantitatively. In contrast, the polymerizations of divinyl ethers 1 , 4 , and 5 underwent gel formation at high monomer conversion. The content of the unreacted vinyl groups of the obtained soluble polymers was measured by 1H NMR spectroscopy. Judging from the relatively low vinyl contents of the polymers produced even in the early stage of the polymerization (monomer conversion < ~20%), the cyclopolymerization occurred to some extent for 2 , 3 , and 4 . On the contrary, the polymers produced from 1 and 5 exhibited the relatively high vinyl content, indicating that the cyclopolymerization tendencies of 1 and 5 were lower than those of 2 , 3 , and 4 . These results are discussed in terms of the structural variety of the spacer chains: (1) the presence of benzene ring ( 1 vs 2 ), (2) their length ( 2 vs 3 and 4 ), and (3) the position of ether oxygen ( 4 vs 5 ). © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 40: 4002–4012, 2002  相似文献   

10.
High Tg. polymers containing both vinyloxy moiety and pendant phthalyl, 2-thiobenzoxazole or 2-thiobenzothiazole groups were synthesized by elimination reaction of poly(epichlorohydrin) with potassium hydroxide followed by substitution reaction of the obtained polymer with potassium phthalimide, potassium 2-thiobenzoxazole or potassium 2-thiobenzothiazole using tetrabutylammonium bromide as a phase transfer catalyst. The polymers containing vinyloxy moiety and pendant phthalyl or 2-thiobenzothiazole groups showed high photochemical reactivity and excellent practical photosensitivity as a positive type resist with photo-generated cationic catalyst such as 2,5-dibutoxy-4-morpholinobenzene diazonium hexafluoroanthimonate. On the other hand, the polymers had high practical photosensitivity and good resolution as a negative type resist with 2,6-di-(4′-azobenzal)-4-methylcyclohexanone as a photosensitizer.  相似文献   

11.
Base-catalyzed reaction of 2-[-(vinyloxy)alkoxy]methyloxiranes with 2-propynyl alcohol (3 wt % of t-BuOK, 60-85°C, 3-12 h) afforded first reperesentatives of the 1-[-(vinyloxy)alkoxy]-3-(2-propynyloxy)-2-propanol series in up to 99% yield. Treatment of 1-[2-(vinyloxy)ethoxy]- and 1-[2-(vinyloxy)ethoxyethoxy]-3-(2-propynyloxy)-2-propanols with trifluoroacetic acid (0.5 wt. %) in dry diethyl ether resulted in cyclization with formation of up to 96% of (2-methyl-1,3,6-trioxocan-4-yl)methyl- and (2-methyl-1,3,6,9-tetraoxacycloundecan-4-yl)methyl 2-propynyl ethers.  相似文献   

12.
The irradiation (λ > 400 nm) in air of a copolymer of phenyl vinyl ketone with 4-vinylbenzil (VBZ) containing 1.5 wt % VBZ structural units in film, followed by the thermal decomposition of the resulting pendant benzoyl peroxide groups, leads to crosslinking. The subsequent irradiation of the crosslinked polymer at 366 nm results in the cleavage of the poly(phenyl vinyl ketone) chain between the junction points of the polymer network through a Norrish type II reaction. Therefore, poly(phenyl vinyl ketone-co-4-vinylbenzil) represents a novel type of photoresist based on polymer network decrosslinking. The process involves three steps: photogeneration of peroxide, crosslinking by its thermal decomposition, and subsequent photodecrosslinking of the polymer network. This material provides positive-tone images after UV exposure (λ > 330 nm) and development in an organic medium such as isopropyl methyl ketone. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 765–771, 2004  相似文献   

13.
Butyl vinyl ether-1-amino-3-[2-(vinyloxy)ethoxy]-2-propanol cooligomer was prepared and studied as a stabilizer of mazut-coal blended fuel.  相似文献   

14.
A series of thiophene‐containing photoactive copolymers consisting of alternating conjugated and nonconjugated segments were synthesized. The 1H NMR spectra corroborated the well‐defined structures, and the copolymers not only were soluble in common organic solvents but also had high glass‐transition temperatures (ca. 130 °C) and good thermal stability up to 390 °C. Introducing aliphatic functional groups, such as alkyl or alkoxyl, into chromophores of the copolymers redshifted the photoluminescence spectra and lowered the optical bandgaps. The electrochemical bandgaps calculated from cyclic voltammetry agreed with the optical bandgaps and thus indicated that electroluminescence and photoluminescence originated from the same excited state. The energy levels (highest occupied molecular orbital and lowest unoccupied molecular orbital) of all the copolymers were lower than those of poly[2‐methoxy‐5‐(2′‐ethylhexyloxy)‐1.4‐phenylenevinylene] MEH–PPV, indicating balanced hole and electron injection, which led to improved performance in both single‐layer and double‐layer polymeric‐light‐emitting‐diode devices fabricated with these copolymers. All the copolymers emitted bluish‐green or green light above the threshold bias of 5.0 V under ambient conditions. At the maximum bias of 10 V, the electroluminescence of a device made of poly(2‐{4‐[2‐(3‐ethoxy phenyl)ethylene]phenyl}‐5‐{4‐[2‐(3‐ethoxy,4‐1,8‐octanedioxy phenyl)ethylene]phenyl}thiophene) was 5836 cd/m2. The external electroluminescence efficiency decreased with the lifetime as the polymer degraded. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 3954–3966, 2004  相似文献   

15.
Six methacrylate monomers have been synthesized for use as reactive diluents in dental composites and evaluated to investigate the relationship between molecular structure and monomer reactivity. Four were synthesized by reactions of glycidyl methacrylate (GMA) with various acids, 2‐(2‐methoxyethoxy)acetic acid ( 1 ), 2‐(2‐(2‐methoxyethoxy)ethoxy)acetic acid ( 2 ), cyanoacetic acid ( 3 ), and benzoic acid ( 4 ); others were synthesized by reactions of GMA with diethyl hydrogen phosphate ( 5 ) or methanol ( 6 ). Monomers 1 and 2 are novel, 3 seems to be novel, 4 and 6 were synthesized via a novel method, and the synthesis of 5 was described in the literature. The monomers showed high crosslinking tendencies during thermal bulk polymerizations. The photo‐, homo‐, and copolymerization behavior of the monomers with 2,2‐bis[4‐(2‐hydroxy‐3‐methacryloyloxy)phenyl]propane (Bis‐GMA) were investigated. The maximum rate of polymerizations of monomers 2 – 6 was found to be greater than triethyleneglycol dimethacrylate, Bis‐GMA, 2‐hydroxyethyl methacrylate, and glycerol dimethacrylate. For the more reactive monomers ( 2 , 3 , and 4 ), the oxygen sensitivity of polymerization was found to be low due to a hydrogen abstraction/chain transfer reaction. The computationally calculated dipole moment and lowest unoccupied molecular orbital energies indicated that there seems to be a correlation between these quantities and reactivity for ester linked monomers ( 1 – 5 ), which was also supported by 13C NMR data. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 3787–3796, 2010  相似文献   

16.
The living cationic polymerization of 4‐[2‐(vinyloxy)ethoxy]azobenzene (AzoVE) was achieved with various Lewis acids in the presence of an ester as an added base. When Et1.5AlCl1.5 was used as a catalyst, the living polymerization system was controllable by UV irradiation as a result of cis and trans isomerization of the azobenzene side groups. Furthermore, an initiating system consisting of SnCl4 and EtAlCl2 realized fast living polymerization of AzoVE. The polymerization rate of this system was 3 orders of magnitude faster than that obtained with Et1.5AlCl1.5. Poly(4‐[2‐(vinyloxy)ethoxy]azobenzene) was soluble in a diethyl ether/hexane mixture at 25 °C but became insoluble upon irradiation with UV light. This phase‐transition behavior was sensitive and reversible upon irradiation with UV or visible light and reflected the change in polarity occurring with cis and trans isomerization of the azobenzene side groups in the polymers. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 5138–5146, 2005  相似文献   

17.
The condensation of p-methoxy(ethoxy)phenylacetothioamides with acetylenedicarboxylic esters leads to two condensation products, 2-(alkoxycarbonylmethylene)-4-(4-methoxy(ethoxy)phenyl)-5-morpho-lino-3H-thiophen-3-ones and 2-(alkoxycarbonylmethylene)-4-(4-methoxy(ethoxy)phenyl)-5-alkoxy-3H-thiophen-3-ones. It was shown that the substitution of the morpholino group is intramolecular. For the jubilee of O. N. Chupakhin Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 4, pp. 541–545, April, 2009.  相似文献   

18.
In recent decades, the basic technology of pressure-sensitive adhesive (PSA) acrylics has developed into a sophisticated science. The main properties of acrylic PSAs such as tack, peel adhesion, and shear strength are determined to a large extent by the kind and quantity of crosslinking agents added to the synthesized PSAs. In order to improve their adhesive (tack, peel adhesion) and cohesive (shear strength) properties, a wide range of amino resin thermal crosslinkers are tested. An acrylic PSA based on 2-ethylhexylacrylate, n-butyl acrylate, and acrylic acid was synthesized by performing a radical polymerization in ethyl acetate. After the addition of amino resins to the acrylic PSA and carrying out thermally initiated crosslinking processes to prepare one-sided self-adhesive tapes, their properties were assessed.  相似文献   

19.
Incomparisonwithinorganicnonlinearoptic(NLO)materials,organicpolymericNLOmaterialshavemanyadvantages,suchasliablemoleculardesignandoptimization,largernonresonanceNLOcoefficiency,lowerdielectricconstant,goodworkingability,opticaltransparencyandresistancea…  相似文献   

20.
A group of new amphiphilic poly(phenylacetylene)s bearing polar oligo(ethylene oxide) pendants, poly{4‐[2‐(2‐hydroxyethoxy)ethoxy]phenylacetylene} ( 1 ), poly(4‐{2‐[2‐(2‐hydroxyethoxy)‐ethoxy]ethoxy}phenylacetylene) ( 2p ), poly(3‐{2‐[2‐(2‐hydroxyethoxy)ethoxy]ethoxy}phenylacetylene) ( 2m ), poly(4‐{2‐[2‐(2‐methanesulfonyloxyethoxy)ethoxy]ethoxy}phenylacetylene) ( 3 ), poly(4‐{2‐[2‐(p‐toluenesulfonyloxyethoxy)ethoxy]ethoxy}phenylacetylene) ( 4 ), poly(4‐{2‐[2‐(2‐trimethylsilyloxy‐ethoxy)ethoxy] ethoxy}phenylacetylene) ( 5 ), and poly(4‐{2‐[2‐(2‐chloroethoxy)ethoxy]ethoxy}phenylacetylene) ( 6 ), were synthesized with organorhodium complexes as the polymerization catalysts. The structures and properties of the polymers were characterized with IR, UV, NMR, and thermogravimetric analysis. 1 , 2p , and 2m , the three polymers containing pendants with hydroxyl groups, were oligomeric or insoluble. The organorhodium complexes worked well for the polymerization of the monomers without hydroxyl groups, giving soluble polymers 3 – 6 with a weight‐average molecular weight up to ~160 × 103 and a yield up to 99%. Z‐rich polymers 3 – 6 could be prepared by judicious selections of the catalyst under optimal conditions. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 1153–1167, 2006  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号