共查询到20条相似文献,搜索用时 15 毫秒
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JingQiang Cui JiangLi Fan XiaoJun Peng ShiGuo Sun GuiCai Chen KeXin Guo 《中国科学B辑(英文版)》2009,52(6):780-785
A new fluorescent sensor (1) for Pb2+ containing a 1,4-dicyano-2,5-bis(styryl)benzene fluorophore and 2-(N,N′-bis(carboxylmethyl))amino-1-carboxylmethoxylbenzene as receptor has been synthesized. The sensor selectively responds to
Pb2+ in the aqueous environment, and brings about similar and significant changes in one- and two-photon excited emission spectra:
λ
max red-shift from 460 (519) to 590 nm. The selective response is pH-independent in a large physiological pH range, and two-photon
action cross section (ϕδ) is 51 GM (1 GM = 1×10−50 cm4·s·photon−1·molecule−1) at 740 nm.
Supported by the National Natural Science Foundation of China (Grant Nos. 20705621 & 20706008), the National Basic Research
Project of China (Grant No. 2009CB724706), the Ministry of Education of China, Changjiang Scholars Innovative Research Team
in University (Grant No. IRT0711) and Cultivation Fund of the Key Scientific and Technical Innovation Project (Grant No. 707016) 相似文献
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A new perylene diimide (PDI) ligand (1) functionalized with a dipicolylethylenediamine (DPEN) moiety was synthesized and first
used as a colorimetric and fluorometric dual-channel sensor to specifically detect the presence of Cu2+ over a wide range of other cations. The solution of 1 (10 μmol/L) upon addition of Cu2+ displayed distinguishing pink color compared with other cations including K+, Ni2+, Ca2+, Mn2+, Na+, Sr2+, Zn2+, Co2+, Cd2+, Mg2+, Cr3+, Ag+, and Ba2+, indicating the sensitivity and selectivity of 1 to Cu2+. Thus, the advantage of this assay is that naked-eye detection of Cu2+ becomes possible. Moreover, among these metal ions investigated, only Cu2+ quenched more than half fluorescent intensity of 1. The ESI-TOF spectrum of a mixture of 1 and CuCl2 in combination of the fluorescence titration spectra of 1 (10 μmol/L) upon addition of various amounts of Cu2+ revealed the formation of a 2:1 metal-ligand complex through the metal coordination interaction.
Supported by the National Natural Science Foundation of China (Grant Nos. 20872101 & 20772086) 相似文献
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A new tripodal rhodamine B derivative 2 was designed and synthesized by tripodal trialdehyde and rhodamine B hydrazide for
the first time. This derivative could be used as a fluorescent chemosensor for the selective and sensitive determination of
copper(II) in Tris-HCl buffer and ethanol aqueous mixed media. Under the optimum conditions described herein, fluorescence
enhancement at 557/577 nm was linearly related to the concentration of copper(II) in the range of 0.10 to 10.00×10−5 mol·L−1, with a correlation coefficient of R
2=0.9964 (n=15) and a detection limit of 1.129×10−7 mol·L−1 (the relative standard deviation for five repeated measurements at 4.00×10−5 mol·L−1 Cu(II) was 2.2%). The absorbance measurements at 557 nm were linearly related to the concentration of Cu(II) in the range
of 0.50 to 25.00×10−5 mol·L−1, with a correlation coefficient of R
2=0.9948 (n=13) and a detection limit of 3.338×10−7mol·L−1.
Supported by the Foundation of the Governor of Guizhou Province, China (Grant No. 200617) and the Talented Person Foundation
of Guizhou University (Grant No. 2007039) 相似文献
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YAN LiWei YANG Li LAN JingBo & YOU JingSong Key Laboratory of Green Chemistry Technology of Ministry of Education College of Chemistry State Key Laboratory of Biotherapy West China Hospital West China Medical School Sichuan University Chengdu China 《中国科学B辑(英文版)》2009,(4)
A new perylene diimide (PDI) ligand (1) functionalized with a dipicolylethylenediamine (DPEN) moiety was synthesized and first used as a colorimetric and fluorometric dual-channel sensor to specifically detect the presence of Cu2+ over a wide range of other cations. The solution of 1 (10 μmol/L) upon ad-dition of Cu2+ displayed distinguishing pink color compared with other cations including K+,Ni2+,Ca2+,Mn2+,Na+,Sr2+,Zn2+,Co2+,Cd2+,Mg2+,Cr3+,Ag+,and Ba2+,indicating the sensitivity and selectivity of 1 to Cu... 相似文献
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A novel fluorescent tweezer was designed and synthesised to sense hydrophobic amines in aqueous solution. Association of the guest was driven by both hydrophobic effect and electrostatic interactions, with the hydrophobic interactions being dominant. The affinity and selectivity of the sensor for amine-based stimulants are reported. 相似文献
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A fluorescent sensor based on diarylethene has been designed and synthesized. The sensor not only exhibited excellent photochromic properties, but also has distinguishing ability for Ca2+ and Sr2+ from other metal ions. Upon addition of Ca2+ and Sr2+, its emission intensity enhanced 27-fold and 24-fold respectively, accompanied by the emission peak shifted from 439 nm to 484 nm for Ca2+, and to 479 nm for Sr2+. The 1:1 stoichiometry between the sensor and the two ions was confirmed by Job's plot and HRMS. The LOD for Ca2+ and Sr2+ was determined to be 9.4 × 10?8 mol L?1 and 7.2 × 10?8 mol L?1, respectively. Furthermore, the sensor was applied in the detection of Ca2+ and Sr2+ in practical samples successfully. 相似文献
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A new fluorescent chemosensor based on a helical imide as fluorophore and a cyclen moiety as ionophore was synthesized, which not only showed enhanced fluorescent responses in the presence of Zn(2+), Cd(2+), and Hg(2+) but also could simultaneously and selectively distinguish the three cations in a simulated physiological condition with the help of cysteine as an auxiliary reagent. 相似文献
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Fang-Ying Wu 《Tetrahedron letters》2006,47(50):8851-8854
A new fluorescent sensor (1) containing bis(2-pyridylmethyl)amine group as a binding moiety for Pb2+ was developed. Compound 1 shows selective response to Pb2+ over other metal ions in pH 7.0 HEPES buffer solution. The fluorescence intensity enhancement was ascribed to the complex formation between Pb2+ and 1 which blocked the photo-induced electron transfer process. 相似文献
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Membrane incorporating [Mg{(TAP)(SBn)8}] complex, (I), as ionophore with composition I:NaTPB:DOP:PVC in the ratio 10:2:133:200 (w/w) exhibits the best result for potentiometric sensing of Mg2+ ions. This gives linear potential response in the concentration range of 9.4×10−6 to 1.0×10−1 M with a slope of 29.2±0.4 mV per decade of activity of Mg2+. Standard deviation in observed values of potentials in this concentration range, from the least square fit line, found to be 2.91 mV with 90% confidence limit lying within ±0.4 mV per decade of activity. The electrode works satisfactorily in the pH range 3.5-7.8 and shows a fast response time of 13±2 s. It shows good selectivity for Mg2+ over other mono-, bi- and tri-valent cations. Only K+ and Zn2+ cause slight interference if present at concentrations ≥1.0×10−5 M. The electrode is durable and can be used over a period of 5 months with good reproducibility (∼1% error). It has been successfully used as an indicator electrode in potentiometric titration of Mg2+ against EDTA as well as for the determination of Mg2+ in simulated mixtures. 相似文献
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This paper describes a copper selective optical chemical sensor based on static quenching of the fluorescence of 2-(2′-hydroxyphenyl)benzoxazole entrapped in a poly(vinyl chloride) (PVC) membrane. The effect of the composition of the sensing membrane was studied, and experimental conditions were optimized. The sensors exhibit stable response over the concentration range from 4.0 × 10−8 M to 5.0 × 10−5 M Cu2+ at pH 4.0-6.5, and a high selectivity. The response time for Cu2+ with concentration ≤5 × 10−6 M is less than 7 min. The optode can be regenerated using 0.1 M HCl and acetate buffer solution. The sensor has been used for direct measurement of copper content in river water samples with a relative error less than 4% with reference to that obtained by atomic absorption spectrometry. 相似文献
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Yu Wu Rui Wang Ying-Le Liu Yu-Long Li Yong-Xiang He Yi-Wen Liang 《Journal of Coordination Chemistry》2018,71(9):1403-1414
A 2-D Cd(II) coordination polymer (CP), {[Cd2(L)2(4,4′-bipy)2(H2O)?7H2O]n (1), has been synthesized using 5-aminoisophthalic acid (H2L) as ligand and 4,4′-bipyridine as co-ligand. A single-crystal X-ray diffraction study shows that 1 is an infinite 2-D layer. CP 1 behaves as a highly selective and sensitive fluorescence chemosensor for detection of Hg2+ and 2,4,6-trinitrotoluene (TNT). Furthermore, possible emission quenching in 1 in the presence of nitroaromatics has been addressed with the aid of theoretical calculations. The calculations indicated that there are both electron and energy transfer processes, in addition to electrostatic interaction between 1 and nitroaromatics which contributes to the selective fluorescence quenching. 相似文献
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Kumaresh Ghosh Debasis Kar Atanu Panja Ioannis D. Petsalakis Giannoula Theodorakopoulos 《Supramolecular chemistry》2013,25(10-12):856-863
A series of pyridine-coupled benzimidazolium-based receptors 1, 2 and 3 have been designed and synthesised. In the series, only receptor 1 is structurally appealing in the selective recognition of H2PO4? in CHCl3 as well as in CH3CN over a series of other anions. The ratiometric change in emission with a triplet band at 420 nm is the distinctive feature of selective recognition of H2PO4? in CHCl3. In CH3CN, a ‘turn on’ response is selectively observed. Binding studies have been carried out using fluorescence, UV–vis, 1H NMR and 31P NMR spectroscopic techniques. Experimental results have been correlated with the theoretical findings. 相似文献
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Utilization of a spiropyran derivative in a polymeric film optode for selective fluorescent sensing of zinc ion 总被引:1,自引:0,他引:1
ZHANG Ying SHAO Na YANG Ronghua LI Ke’an LIU Feng CHAN Winghong & MO Tian . College of Chemistry Molecular Engineering Peking University Beijing China . Department of Chemistry Hong Kong Baptist University Hong Kong China 《中国科学B辑(英文版)》2006,49(3):246-255
Spiropyrans are the most studied families of func- tional materials due to their reversible structural con- version in response to external optical, chemical, and thermal stimulation[1]. Irradiation with ultraviolet light causes formation of an extended π-conjugation open form (merocyanine form) by heterolytic cleavage of the C (spiro)-O bond, which generates an intense ab- sorption in the visible region. Under the irradiating of visible light, the opened form will come back to the closed spi… 相似文献
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Ge Zhang Yangping Wen Chaoqun Guo Jingkun Xu Baoyang Lu Xuemin Duan Haohua He Jun Yang 《Analytica chimica acta》2013
A highly selective and sensitive fluorescent chemosensor suitable for practical measurement of palladium ion (Pd2+) in agricultural crops and environment samples has been successfully fabricated using polybenzanthrone (PBA). PBA was facilely electrosynthesized in the mixed electrolyte of acetonitrile and boron trifluoride diethyl etherate. The fluorescence intensity of PBA showed a linear response to Pd2+ in the concentration range of 5 nM–0.12 mM with a detection limit of 0.277 nM and quantification limit of 0.925 nM. Different compounds existing in agricultural crops and environment such as common metal ions, anions, natural amino acids, carbohydrates, and organic acids were used to examine the selectivity of the as-fabricated sensor, and no obvious fluorescence change could be observed in these interferents and their mixtures. A possible mechanism was proposed that the coordination of PBA and Pd2+ enhance the aggregation of polymer chains, which led to a significant quenching of PBA emission, and this was further confirmed by absorption spectra monitoring and transmission electron microscopy. The excellent performance of the proposed sensor and satisfactory results of the Pd2+ determination in practical samples suggested that the PBA-based fluorescent sensor for the determination of Pd2+ will be a good candidate for application in agriculture and environment. 相似文献
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Jing Cao Hai Yan Deng Chen Hui Wang Yao Xiao Ming Ren You Wei Zhang 《Supramolecular chemistry》2013,25(11):777-781
A 3,4-dimethylthieno[2,3-b]thiophene-based fluorogenic probe bearing benzo[d]-thiazole-2-thio unit (sodium 3,4-bis ((benzo[d]thiazol-2-ylthio)methyl) thieno [2, 3-b]thio-phene-2, 5-dicarboxylate) was developed as a novel fluorescent chemosensor with high selectivity towards Pb(II) over other cations tested. The new probe exhibited good water solubility and only sensed Pb(II) among metal ions examined in neutral 4-(2-hydroxyethyl)-1-piperazineethanesulfonic acid buffer solution. The selectivity and sensitivity of fluorogenic probe to Pb(II) were discussed on the basis of experimental results. 相似文献
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A new ratiometric and selective fluorescent chemosensor (1) for quantification of zinc ions in aqueous ethanol has been synthesized and investigated in this work. In an environmentally friendly media of 30% (v/v) water/ethanol and 10 mM Tris-HCl neutral buffer (pH 7.03), 1 displayed selective Zn2+ ratiometric fluorescence response, with a dynamic working range of 1.0-8.0 μM and a detection limit of 0.5 μM Zn2+. The determination of Zn2+ in synthesized water sample was also successful. 相似文献
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Azumi Higashi Naoya Kishikawa Kaname Ohyama Naotaka Kuroda 《Tetrahedron letters》2017,58(28):2774-2778
Benzofuran-2-boronic acid could be used as a fluorescent sensor for the detection of Pd2+ because it was rapidly converted to highly fluorescent derivative after mixing with Pd2+ under basic condition at room temperature. We found that dimerization of benzofuran was occurred to form fluorescent derivative by the catalytic activity of palladium. The fluorescence intensity at 360 nm increased with increasing the concentration of Pd2+. The excellent selectivity for Pd2+ was demonstrated among other metal ions. Based on this findings, we successfully applied benzofuran-2-boronic acid to develop a microplate-based assay for high-throughput measurement of Pd2+. The detection limit (blank + 3SD) for Pd2+ of the proposed assay was 9.8 nM. 相似文献