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1.
The elastic (G) and inelastic (Q ?1) properties of (Co45Fe45Zr10) x (Al2O3)100 ? x , Co x (CaF2)100 ? x , and Co x (PZT)100 ? x (x = 23–76 at %) nanocomposites obtained by ion-beam sputtering are studied in the temperature range 300–900 K. A significant rise in the Q Q ?1 (T) curve is observed at temperatures above 650 K, which is attributed to thermally activated migration of point defects under the conditions of confined geometry.  相似文献   

2.
为了确定ZrO2和(ZrO2)0.97(Bi2O3)0.03的晶体结构和原子热振动各向同性温度因子B,对该粉末晶体进行X射线衍射实验,建立了晶体结构模型,进行晶体结构分析。首先,采用共沉淀法和高温固相烧结法制备了纳米氧化锆ZrO2和(ZrO2)0.97(Bi2O3)0.03粉末晶体,接着,使用X射线测试仪对两种样品进行了衍射实验(XRD),利用Rietveld 精修方法的 RIETAN-2000程序对所得实验结果进行了晶体结构分析,获得了晶体结构参量和原子热振动各向同性温度因子B。通过Maximum Entropy Method(MEM)解析得到了粉末晶体(ZrO2)x(Bi2O3)1-x(x=1.0,0.97)的等高电子密度分布可视化图谱。结果表明,(ZrO2)0.97(Bi2O3)0.03的晶胞体积比ZrO2的晶胞体积大分别为140.6850 Å3和140.5637Å3;ZrO2晶体的原子热振动各向同性温度因子B(Zr)、BO(1)、BO(2)和 B(Bi)分别为0.690、0.269、 0.178 和 0 Å2,(ZrO2)0.97(Bi2O3)0.03晶体的分别为0.460 、0.583 、0.121 和0.581 Å2。 确定了(ZrO2)0.97(Bi2O3)0.03的晶体结构属于单斜晶系,实现了等高电子密度分布三维(3D)和二维(2D)的可视化,进一步确定了晶体结构和原子位置。  相似文献   

3.
We first demonstrate the precise Einstein-Podolsky-Rosen entanglement, which is inherent in quantum mechanics, in the context of quantum theory of complex scalar fields. We explicitly derive the entangled common eigenstates of φ1(x) - φ2(x) and П1(x) + П2(x) φ1and φ2 are two real components of the complex scalar field, and П1 and П2 are the corresponding conjugate fields) in the Fock space. The entangled eigenstates span a complete and orthonormal representation.  相似文献   

4.
Temperature-dependent, in-plane, thermoelectric power data are presented for single crystals of Ba(Fe1?x Co x )2As2 (0?≤?x?≤?0.05) and Ba(Fe1?x Rh x )2As2 (0?≤?x?≤?0.171). Given that previous thermoelectric power and angle resolved photoemission spectroscopy studies of Ba(Fe1?x Co x )2As2 delineated a rather large Co-concentration range for Lifshitz transitions to occur, and the underdoped side of the phase diagram is poorly explored, new measurements of thermoelectric power on tightly spaced concentrations of Co, 0?≤?x?≤?0.05, were carried out. The data suggest evidence of a Lifshitz transition, but instead of a discontinuous jump in thermoelectric power in the range 0?≤?x?≤?0.05, a more gradual evolution in the S(T) plots as x is increased was observed. The thermoelectric power data of Ba(Fe1?x Rh x )2As2 show very similar behavior to that of Co substituted BaFe2As2. The previously outlined Tx phase diagrams for both systems are further confirmed by these thermoelectric power data.  相似文献   

5.
利用在文章[1]中给出的强子的价夸克分布函数的解析表达式,我们讨论了电生过程的非单态分量,F_2~(ep)-F_2~(en),标度性破坏参数,以及一些其它的量。文中也给出了与实验数据的比较。在前文中,我们利用A-P方程在合理的近似下得到了强子价夸克分布函数的解析表达式。在本文中,我们用它来讨论电生中的非单态分量,F_2~(ep)-F_2~(en),标度性破坏参数以及一些其它的量。  相似文献   

6.
High resolution electron energy loss Spectroscopy (HREELS), X-ray photoelectron Spectroscopy (XPS) and low energy electron diffraction (LEED) have been used to characterize initial stages of oxidation of Si(100)2x1 and Gex Si1−x (100)2x1 surfaces. Different oxidation stages of Si were identified by measuring Si 2p core level shifts and characteristic vibrations of Si-O-Si complexes. The latter may be described in the framework of continuous random network models.Then,from the experimentally determined frequencies, force constants,average bond angles and bond lengths are determined. Complementary,marker experiments with atomic hydrogen as a probe in conjunction with HREELS were used to determine the local, atomic structure for different stages of oxidation from chemical shifts of Si-H and Ge-H stretching mode intensities, respectively.  相似文献   

7.
The optical properties of the compounds HoNi5 ? x Al x (x = 0, 1, 2) have been investigated using the ellipsometric method in the wavelength range from 0.22 to 16 μm. The electronic structure of these intermetallic compounds has been calculated in the local electron-spin density approximation with the correction for strong electronic interactions in the 4f shell of the holmium ions. The experimental dispersion dependences of optical conductivity in the region of interband light absorption have been interpreted based on the results of the calculation of the electron density of states. The plasma and relaxation frequencies of electrons have been determined.  相似文献   

8.
文中报道了 Bi_(1.9)Sb_(0.1)Sr_2Ca_2Cu_(2+x)O_y,系列的交流磁化率测量及 X 射线衍射结果,发现超导转变温度对于 Cu 的组份非常敏感,当 x=0.4时,样品在136.5K 出现抗磁性,其 X 射线衍射图中新相衍射峰较85K 超导相的峰更强,因此 Cu 的价态和配位数在形成高和 T_c 超导相中起着至关重要的作用.  相似文献   

9.
利用固相反应法制备了Nd2-2x Ca1+2x Mn2O7(x=0.0-0.9)多晶样品,通过FULLPROF程序对样品X射线衍射图谱进行了精修,样品的空间群为14/mmm.测量了样品x=0.4,0.5的磁性(5K相似文献   

10.
用活化法和迭靶技术,测量了入射氘核能量从3.2到13.3MeV范围内,Mo(d,x)~(95m)Tc,Mo(d,x)~(96g)Tc和Mo(d,x)~(97m)Tc反应的激发函数,并与复合核统计模型理论计算作了比较。  相似文献   

11.
通过调节基质组份比例,研究了SrAl2xO3x+1∶Eu2+,Dy3+(x=1~2)荧光粉晶体结构,发光性质及长余辉特性。选取硝酸锶和硝酸铝作为基质原材料,硼酸氨和氟化铝作为助溶剂,采用阳离子草酸盐共沉淀,湿法预先混合原材料及分步合成等方法,制备了亮度高、余辉长及良好粒径分布的系列长余辉发光材料。基于对样品X射线衍射(XRD)图谱,扫描电子显微镜(SEM)照片,激发、发射光谱及余辉衰减曲线分析,发现SrAl2xO3x+1∶Eu2+,Dy3+具有良好的结晶状态;随x增加,发射光谱峰值从520 nm蓝移至470 nm;衰减到可辨认发光强度0.32 mcd/m2,余辉时间可相应地从30 h延长到60 h以上。通过分析发现表现不同余辉特性的主要原因是Eu2+在基质中具有不同浓度、不同衰减寿命的蓝、绿两种发光中心造成的,其中蓝发光中心寿命明显高于绿发光中心。  相似文献   

12.
Aluminum-doped indium sulfide thin films are deposited on glass by spray pyrolysis technique. The structure and the surface morphology of these films were characterized by X-ray diffraction and atomic force microscopy. The effects of aluminum ratio z and substrate temperature T s, on the film structure and grain size are discussed. The influence of aluminum ratio on surface morphology is revealed by scanning electron microscope. Besides, energy dispersive spectrometry technique is used to compare atomic aluminum concentration in the film with aluminum ratio z in spray solution. Optical properties are studied by a spectrophotometer in the wavelength range 350–850 nm, at room temperature. Optical transmission and grain size are found to be maximal for z = 1.8 %. Moreover, band-gap energy is found to increase with aluminum ratio.  相似文献   

13.
The crystal structure and physical properties of multiferroic polycrystalline Ca(2+)-doped BiFeO(3) samples have been investigated. The present experimental investigation suggests that Bi(1-x)Ca(x)FeO(3-x/2) (x ≤ 0.1) can be considered as a solid solution between BiFeO(3) and CaFeO(2.5). The oxidation state of Fe in these materials is + 3 and charge balance occurs through the creation of oxygen vacancies. For each composition, two structural phase transitions are revealed as anomalies in the variable-temperature in situ x-ray diffraction data which is consistent with the well-established high-temperature structural transformation in pure BiFeO(3). All compositions studied show antiferromagnetic behaviour along with a ferromagnetic component that increases with Ca(2+) doping. The resistivities of the Bi(1-x)Ca(x)FeO(3-x/2) samples at room temperature are of the order of 10(9) Ω cm and decrease with increasing Ca(2+) content. Arrhenius plots of the resistivity show two distinct linear regions with activation energies in the range of 0.4-0.7 and 0.03-0.16 eV. A correlation has been established between the critical temperatures associated with the structural phase transitions and the multiferroic properties. A composition of x = 0.085 is predicted to show maximum magneto-electric coupling.  相似文献   

14.
Structural phase transitions in Cu2–x Te crystals have been investigated by high-temperature X-ray diffraction.

At room temperature Cu2Te and Cu1.90Te specimens are two-phased, i.e. they consist of an orthohombic phase with a = 7.319, b = 22.236, c = 36.458 Å and a hexagonal phase with a = 4.150, c = 7.188 Å. The changes in both compounds take place generally in the hexagonal phase with increasing temperature. At 821, 873 K they transform to a FCC phase. Monocrystals of the other compounds at room temperature crystallize in the hexagonal system and at 673, 773, 723 K, respectively, they transform to a FCC phase. It is determined that as the cation deficiency increases the crystal quality becomes better.  相似文献   

15.
杨艳敏  李佳  马洪然  杨广  毛秀娟  李聪聪 《物理学报》2019,68(4):46101-046101
运用基于密度泛函理论的第一性原理方法,对Co_2FeAl_(1–x)Si_x(x=0.25, 0.5, 0.75)系列Heusler合金的电子结构、四方畸变、弹性常数,声子谱以及热电特性进行了计算研究.结果显示, Co_2FeAl_(1–x)Si_x系列合金的电子结构均为半金属特性,向下自旋态(半导体性)均呈现良好的热电特性,并且随着硅原子浓度的增加功率因子随之增加.计算的声子谱不存在虚频,均满足动力学稳定性条件,弹性常数均满足玻恩稳定性条件,机械稳定性均良好.随着晶格常数c/a的比值变化,体系的能量最低点均出现在c/a=1处,即结构稳定性不随畸变度c/a的变化而变化,说明不存在马氏体相变.此系列合金薄膜的电子结构呈现较高的自旋极化率,在替代浓度x=0.75时自旋极化率达到100%,且当x=0.75时薄膜在畸变度c/a=1.2时存在马氏体相变.随着晶格畸变度的改变,总磁矩也发生变化,且主要由Fe和Co两种过渡金属原子的磁矩变化所决定.  相似文献   

16.
17.
A new method of analysis of the photon structure functionF 2 (x, Q 2 ) is presented. It is a generalisation of Rossi's ansatz for generating regularised solutions of the inhomogeneous Altarelli-Parisi equations which enables initial conditions in theQ 2 evolution to be incorporated. Its equivalence to the normal solution is demonstrated. It is applied in a phenomenological analysis of the data on the structure functionF 2 . It is found that the recent TPCF 2 data in the range 0.3Q 2<1.6>2 cannot be used as a starting point for a perturbative QCD analysis, despite being well described by the vector meson dominance model (VMD) and exhibiting scaling. This conclusion invalidates previous discussions of the effect of the regularisation of the asymptotic point-like QCD prediction on the sensitivity ofF 2 to the QCD mass scale , because they incorporated VMD assumptions in the perturbative region. A perturbative QCD analysis using higherQ 2 data as a starting point is presented but here the initial conditions necessarily involve more assumptions, and starting the evolution at a higherQ 2 involves an inevitable decrease in the sensitivity to .  相似文献   

18.
The post-Newtonian problem of the precession of the axis of rotation of a gyroscope rotating around the earth in relation to distant stars belongs to a number of nonclassical verifications of the consequences of the theory of gravitation with an independent determination of the post-Newtonian parameters. A generalized Fermi-Walker transport equation is constructed and the problem of precession of a gyroscope is solved for the nonregular generalized Finslerian metric gij=e2(x,y)aij, where aij signifies the Riemannian metric tensor. The result contains a contribution in addition to the usual Riemannian PPN-terms, proportional to the parameter a characterizing the dependence of on the speed of motion.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 5, pp. 91–95, May, 1989.In conclusion, the author expresses deep gratitude to G. S. Asanov (MGU) for stating the problem and valuable comments.  相似文献   

19.
考虑特征γ射线分支比、衰变常数和标准截面等修正,对带电粒子引起的核反应~(186)W(d,p)~(187)W,~(186)W(d,2n)~(186)Re,~(nat)Fe(p,x)~(56)Co和~(nat)Ti(a,x)~(51)Cr的激发函数进行了研究。全面收集了这些反应激发函数的实验测量数据,对这些实验数据进行了分析处理,应用数学方法对分析处理后的实验数据进行了拟合。经过评价,给出了50 Me V以下~(186)W(d,p)~(187)W,~(186)W(d,2n)~(186)Re,~(nat)Fe(p,x)~(56)Co和~(nat)Ti(a,x)~(51)Cr反应激发函数的推荐值。  相似文献   

20.
Single crystals of iron-containing Ba(FeAs)2 superconductors doped with phosphorus have been studied. The vortex structure has been studied by means of the decoration method. Large domains of the triangular vortex structures have been observed in the phosphorus-doped single crystals of iron-containing superconductors. The effect of doping on pinning in iron-containing superconductors has been discussed.  相似文献   

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