共查询到20条相似文献,搜索用时 31 毫秒
1.
Y.T. Chen S.U. Jen Y.D. Yao J.M. Wu G.H. Hwang T.L. Tsai Y.C. Chang A.C. Sun 《Journal of magnetism and magnetic materials》2006
Co50Fe50 films with thickness varying from 100 to 500 Å were deposited on a glass substrate by sputtering process, respectively. Two kinds of CoFe films were studied: one was the as-deposited film, and the other the annealed film. The annealing procedure was to keep the films at 400 °C for 5 h in a vacuum of 5×10−6 mbar. From the X-ray study, we find that the as-deposited film prefers the CoFe(1 1 0) orientation. Moreover, the body-centered cubic (bcc) CoFe(1 1 0) line is split into two peaks: one corresponding to the ordered body-centered tetragonal (bct) phase, and the other, the disordered bcc phase. After annealing, the peak intensity of the ordered bct phase becomes much stronger, while that of the disordered bcc phase disappears. The annealing has also caused the ordered CoFe(2 0 0) line to appear. When the amount of the ordered bct phase in Co50Fe50 is increased, the saturation magnetization (Ms) and coercivity (Hc) become larger, but the electrical resistivity (ρ) decreases. From the temperature coefficient of resistance (TCR) measurement, we learn that the bct grains in the CoFe film start to grow at temperature 82 °C. 相似文献
2.
CoPt-TiO2 nanocomposite films were synthesized by rapid thermal annealing of CoPt/TiO2 multilayers. The effects of annealing temperature, annealing time, Ag addition and TiO2 volume fraction on the microstructures and magnetic properties of the CoPt-TiO2 nanocomposite films were studied. Results showed that the ordering degree of CoPt and coercivity of CoPt-TiO2 nanocomposites increased with annealing temperature. Increasing annealing time and Ag addition were able to increase the ordering degree and coercivity of CoPt. However, complete L10-ordering of CoPt at 550 °C annealing was not realized by increasing annealing time up to 30 min and Ag addition up to 30 vol.%. Increasing TiO2 volume fraction at 700 °C annealing did not lead to the change of ordering of CoPt. However, the grain structure of the films changed slightly when TiO2 volume fraction was larger than 56%. The coercivity of the film decreased slightly with the addition of TiO2. 相似文献
3.
系统研究了衬底为SrTiO3和LaAlO3上的La0.67Ca0.33MnO3薄膜中的矫顽力随厚度和应变的变化。结构分析表明薄膜为(001)方向织构,而且薄膜中的晶粒尺寸随着薄膜厚度的减小而减小。磁测量表明矫顽力先随着膜厚的减小而增加,在t=10-25nm附近到达一极大值。随后,矫顽力随厚度的减小而降低。还得出矫顽力的大小与测量方向有关:t≥25nm (t≤10nm)时,难磁化方向的矫顽力大于(小于)易磁化方向的矫顽力。据此,我们提出:在厚膜(t≥25nm)中,矫顽力变化由畴壁钉扎机制决定;在超薄膜(t≤10nm)中,则与磁畴的形核机制有关。根据t= 5、10、25、400nm的LCMO/STO薄膜的初始磁化曲线,以及t=5,50nm的LCMO/LAO薄膜的小磁滞回线的测量,我们对薄膜中矫顽力机制作了验证,并且还讨论了钉扎和形核机制发生的非均匀区的尺寸。 相似文献
4.
In the present study, we succeeded in accelerating the L10 ordering transition of FePt thin films by employing amorphous Ni-Al as underlayers. The coercivity Hc = 5 kOe and ordering parameter S = 0.67 of FePt thin films deposited on a Ni-Al underlayer with a thickness of ∼5 nm after 380 °C annealing for 30 min are significantly higher than those Hc = 0.4 kOe and S = 0.35 of the films without the Ni-Al underlayer. The L10 ordering process of and the coercivity of FePt thin films can be significantly tuned by varying the thickness of the Ni-Al underlayer. 相似文献
5.
Naresh Kumar Richa Bhargava Amit Kumar Chawla Murtaza Bohra 《Journal of magnetism and magnetic materials》2010,322(13):1727-1730
We report on the growth of terbium iron garnet (TbIG, Tb3Fe5O12) thin films having anomalously large coercivity and in-plane easy axis of magnetization. The TbIG thin films were prepared at room temperature (RT) on Pt/Si(1 0 0) substrates by pulsed laser deposition technique. The films deposited at RT were X-ray amorphous and do not show any magnetic order. Annealing of the RT deposited film at 900 °C resulted into fully textured (532) TbIG film. Atomic force microscopy and cross-sectional scanning electron microscopy studies of the TbIG films showed good surface quality with an average surface roughness of 5.0 nm and thickness of about 300 nm, respectively. The M-H loops measured at 20 K for TbIG films, exhibit about an order of magnitude enhancement in the coercivity value (Hc) than the single crystal. In-plane and out-of-plane M-H loops revealed that the easy axis of the magnetization lies within the film’s plane. In-plane magnetization combining with large Hc value of the TbIG thin film may be of scientific interest for the possible applications. 相似文献
6.
Xingyu Mao Zhijian KeWeidong Zou Qiubao LinZhijie Qin Yan Wu 《Journal of magnetism and magnetic materials》2012,324(4):389-393
The dynamic magnetization processes of nanocrystalline Fe80Ge3Nb10B7 alloys after annealing at different temperatures are studied through the permeability spectroscopy. Three steps of crystallization are found when amorphous Fe80Ge3Nb10B7 alloys are heated from 300to 1200 K. The dominant magnetization process varies with different annealing temperatures. Domain wall bulging is the main magnetization mechanism under weak applied field. When the applied field exceeds pinning field Hp, the depinning-involved domain wall displacement occurs. Different annealing temperature results in different Hp. The lower value of μ′ and high relaxation frequency after heating at 923 and 973 K are due to the strengthened domain wall pinning and the increase of magnetocrystalline anisotropy. 相似文献
7.
We have investigated the influence of composition and annealing conditions on the magnetic properties and microstructural features of SmCox films that were prepared by sputtering and subsequent annealing. A huge in-plane coercivity of 5.6 T was obtained from an optimally annealed Sm–Co film, which was attributed to the nanometer sized polycrystalline microstructure of the highly anisotropic SmCo5 phase. Although a high density of planar defects were observed in the films that were annealed at high temperatures, they did not act as strong pinning sites for domain wall motion. The effect of Cu on [SmCo4.5(9 nm)/Cu(xnm)]10 multilayer thin films was also studied. An appropriate Cu content increased the coercivity. 相似文献
8.
Pan Mingxiang Zhang PengyueGe Hongliang Yang HangfuWu Qiong 《Journal of magnetism and magnetic materials》2012
The lean rare-earth Pr4.5Fe77−xTixB18.5 (x=0, 1, 4, 5) nanocomposite alloys were prepared by melt spinning method and subsequent thermal annealing. The effect of Ti content and annealing temperature on the magnetic properties and the microstructure of these magnets were investigated. The enhancing coercivity Hc from 211.4 to 338.2 kA/m has been observed at the optimal annealing temperature of 700 °C by the addition of 5 at% Ti in Pr2Fe14B/Fe3B alloys. It was also found that increasing Ti content leads to marked grain refinement in the annealed alloys, resulting in strong exchange-coupling interaction between the hard and the soft phases in these ribbons. In addition, the magnetization reversal behaviors of Pr2Fe14B/Fe3B nanocomposites were discussed in detail. 相似文献
9.
D.H. Wei T.S. Chin K.L. You C.C. Yu Y. Liou Y.D. Yao 《Journal of magnetism and magnetic materials》2006
L10-ordered FePt thin films prepared by molecular-beam epitaxy on MgO (0 0 1) substrate at 320 °C with different thickness of Pt buffer layer have been investigated. The out-of-plane coercivity increases with increasing thickness of Pt buffer. The maximum values of the long-range order parameter and uniaxial magnetic anisotropy energy are 0.72 and 1.78×107 erg/cm3, respectively, for films with 12 nm thick Pt buffer layer, where the c/a ratio (0.976) shows the minimum value. The reason for the enhancement in ordering is due to the proper lattice strains Pt buffer bestows on FePt layer, these strains are equal to the contraction in lattice parameter c and the expansion in a. Studies of angular-dependent coercivity revealed that the magnetization reversal behaviour shifts from a domain-wall motion dominated case towards a near rotational mode with increasing thickness of Pt buffer layer. 相似文献
10.
Nanocrystalline spinel ferrite thin films of CoxFe3−xO4 (x=0.3, 0.5, 0.8, and 1.0) have been prepared by RF sputtering on quartz substrate without a buffer layer at room temperature and annealed at the temperature range from 200 to 600 °C in air. The as-sputtered films exhibit the preferred orientation and the high magnetization and coercivity. After annealing, the preferred orientations become poor, but the magnetization and coercivity increase. The sample with a magnetization of 455 emu/cm3, a coercivity of 2.8 kOe, a remanence ratio of 0.72, and a maximum energy product of 2.4 MGOe has been obtained. The influence of Co ions and annealing temperature on the magnetic properties has been discussed. 相似文献
11.
The structure, magnetic properties and magnetostriction of Fe81Ga19 thin films have been investigated by using X-ray diffraction analysis, scanning electron microscope (SEM), vibrating sample magnetometer and capacitive cantilever method. It was found that the grain size of as-deposited Fe81Ga19 thin films is 50–60 nm and the grain size increases with increase in the annealing temperature. The remanence ratio (Mr/Ms) of the thin films slowly decreases with increase in the annealing temperature. However, the coercivity of the thin films goes the opposite way with increase in the annealing temperature. A preferential orientation of the Fe81Ga19 thin film fabricated under an applied magnetic field exists along 〈1 0 0〉 direction due to the function of magnetic field during sputtering. An in-plane-induced anisotropy of the thin film is well formed by the applied magnetic field during the sputtering and the formation of in-plane-induced anisotropy results in 90° rotations of the magnetic domains during magnetization and in the increase of magnetostriction for the thin film. 相似文献
12.
X.Q. LiX.G. Xu S.Q. YinD.L. Zhang J. MiaoY. Jiang 《Journal of magnetism and magnetic materials》2011,323(14):1914-1917
We present a systematic study on magnetic properties of co-sputtered Tb-Co2FeAl (TCFA) films. The TCFA films with suitable Tb content have perpendicular magnetic anisotropy (PMA). The PMA deteriorates with both decreasing film thickness and high temperature annealing. Under a certain thickness, the perpendicular coercivity of the TCFA films with PMA can be reduced down to 60 Oe, which is comparable with normal soft ferromagnets. After annealing at 100 °C, a large remanence squareness of 0.95 is observed in the TCFA film with 33% Tb and a thickness of 30 nm. 相似文献
13.
The amorphous Tb40(Fe49Co49V2)60 films were deposited at different sputtering powers and substrate temperatures. The microstructural and magnetic characteristics were investigated by means of field emission scan electron microscope, magnetic force microscope and vibrating sample magnetometer. Our results show that with increasing sputtering power, out-of-plane coercivity decreases monotonically while saturation magnetization has a maximum value of 231 kA/m for the sample prepared at 50 W. The as-deposited alloy films are amorphous, whereas the coercivity and saturation magnetization are strongly dependent on the substrate temperature. An out-of-plane hysteresis loop with coercivity below 22 mT and saturation magnetization over 290 kA/m is obtained combining dc power and substrate temperature. The dominant mechanism of room temperature coercivity appears to be domain wall pinning, rather than nucleation under all conditions measured. The variation of saturation magnetization is similar to that of perpendicular magnetic anisotropy with either sputtering power or substrate temperature according to the difference of magnetic domain structure. 相似文献
14.
I. Panneer Muthuselvam 《Journal of magnetism and magnetic materials》2010,322(7):767-30
We doped Ho3+ in CoFe1.95Ho0.05O4 spinel ferrite by mechanical alloying and subsequent annealing at different temperatures (600-1200 °C). We understood the structural and magnetic properties of the samples using X-ray diffraction, SEM, Thermal analysis (TGA and DTA), and VSM measurement. The samples have shown structural stabilization within cubic spinel phase for the annealing temperature (TAN)≥800 °C. Thermal activated grain growth kinetics has been accompanied with the substantial decrease in lattice strain. The gain size dependent magnetism is evident from the variation of magnetic moment, remanent magnetization and coercivity of the material. The paramagnetic to ferrimagnetic transition temperature TC (∼805 K) seems to be grain size independent in the present material. The magnetic nanograins, either single domain/pseudo-single domain (50-64 nm) or multi-domain (above 64 nm) regime, showed superparamagnetic blocking below Tm, which is below TC (805 K) and also well above the room temperature. 相似文献
15.
FePt (20 nm) films with AgCu (20 nm) underlayer were prepared on thermally oxidized Si (0 0 1) substrates at room temperature by using dc magnetron sputtering, and the films annealed at different temperature to examine the disorder–order transformation of the FePt films. It is found that the ordered L10 FePt phase can form at low annealing temperature. Even after annealing at 300 °C, the in-plane coercivity of 5.2 kOe can be obtained in the film. With increase in annealing temperature, both the ordering degree and coercivity of the films increase. The low-temperature ordering of the films may result from the dynamic stress produced by phase separation in AgCu underlayer and Cu diffusion into FePt phase during annealing. 相似文献
16.
Magnetic reversal mechanism of the Sub/AlN5 nm/[CoPt2 nm/AlN5 nm]5 nano multilayer film, which shows strong perpendicular magnetic anisotropy (Ku=6.7×106 erg/cm3), has been studied. The angle-dependent magnetic hysteresis loops of this highly perpendicular anisotropic CoPt/AlN multilayer film were measured in the present work, applying a magnetic field along different angles φ with respect to the film normal. It demonstrates that the magnetic reversal of the CoPt ultrathin layers in the CoPt/AlN multilayer film is occurred by the reversible magnetization rotation and the irreversible displacement of domain walls. The φ-dependent part of coercive field is resulted from the internal stress according to the Kondorsky and Kersten model. The φ-independent part of coercive field implies some random and isotropy pinning centers (e.g., vacancies, dislocations, grain boundaries) in the ultrathin CoPt layers. Our work is useful for coercivity control of metal/ceramics layered structures, in particular the perpendicular magnetic tunneling junctions. 相似文献
17.
Structure and magnetization of CoZrNb amorphous films prepared by DC magnetron sputtering have been studied as a function of film thickness (t), from 35 to 840 nm. Using comprehensive characterization, we show that the CoZrNb amorphous films possess a single phase and no nanocrystalline can be detected. The magnetic measurements indicate that the magnetization reversal of CoZrNb films is strongly dependent on t. That is, the coercivity is abruptly reduced to be lower than 4 Oe with t increasing from 35 to 105 nm, and then gradually decreases to ∼0.2 Oe as t increases. This coercivity transition versus t is accompanied by the strong magnetization reversal when t is larger than 105 nm. The results reveal that CoZrNb amorphous films with comparatively large film thickness (>100 nm) are suitable for sensors and anti-faked materials. 相似文献
18.
The effectiveness of nanoscale Dy2Fe14B thin films on coercivity and energy product of melt-spun ribbons of Nd2Fe14B at high temperatures was investigated. It is hypothesized that the nanoscale Dy-thin film will act as an obstacle for the nucleation of reverse domains and also maximize the energy of domain walls and thereby improve the magnetic performance at high temperatures. Pulsed laser deposition (PLD) of amorphous Dy2Fe14B layers on Nd2Fe14B melt-spun ribbons was performed for a nominal thickness of 40 nm. The coated ribbons were then annealed in environmentally controlled quartz furnace at two different cycles (750 °C for 15 min and 900 °C for 2 h) to cause crystallization. Magnetic hysteresis tests conducted at 300 and 400 K revealed that there is small but consistent improvement in the magnetic properties of the coated ribbons annealed at 750 °C for 15 min. However, higher temperature annealing (900 °C for 2 h) drastically reduced the magnetic properties. The incomplete recrystallization of amorphous structure at 750 °C for 15 min and large grain growth and formation of non-magnetic phases at 900 °C for 2 h are believed to be responsible for not meeting the expected magnetic performance. 相似文献
19.
Highly oriented films of ∼6 μm in thickness consisting of the Nd2Fe14B compound phase were obtained by a three-dimensional sputtering method at room temperature and the subsequent crystallization by annealing. The c-axis orientation and coercivity of film samples were sensitive to the sputtering parameters and annealing conditions. The optimum temperature and time for annealing were 650 °C and 30 min to show the highest coercivity without any deterioration for the orientation of Nd2Fe14B grains, and furthermore the degree of c-axis orientation was increased by decreasing the Ar gas pressure or input power for sputtering. The resultant film magnets with good magnetic properties of Br=∼1.06 T, HC=∼371 kA/m, and (BH)max=∼160 kJ/m3 were obtained under the optimized parameters for sputtering. 相似文献
20.
Strontium hexaferrite (SrFe12O19) films have been fabricated by pulsed laser deposition on Si(1 0 0) substrate with Pt(1 1 1) underlayer through in situ and post annealing heat treatments. C-axis perpendicular oriented SrFe12O19 films have been confirmed by X-ray diffraction patterns for both of the in situ heated and post annealed films. The cluster-like single domain structures are recognized by magnetic force microscopy. Higher coercivity in perpendicular direction than that for the in-plane direction shows that the films have perpendicular magnetic anisotropy. High perpendicular coercivity, around 3.8 kOe, has been achieved after post annealing at 500 °C. Higher coercivity of the post annealed SrFe12O19 films was found to be related to nanosized grain of about 50–80 nm. 相似文献