Possibility of observing magnetic macroscopic quantum tunneling using a scanning tunneling microscope

A theory describing the detection of magnetic macroscopic quantum tunneling on the basis of current fluctuations in a scanning tunneling microscope is proposed. Zh. éksp. Teor. Fiz. 112, 1011–1020 (September 1997)     

Resonance phenomena in macroscopic quantum tunneling: The small viscosity limit

We present a theoretical study of the resonant quantum behavior for a macroscopic superconducting system interacting with an external microwave at proper frequency. Here we consider a system described by a double well potential, an rf-SQUID, in the extremely underdamped regime. Numerical simulations for resonant phenomena have been performed for this system, whose parameters belong to the range typically used in the experiments. The dependence of the transition probability W on the external drive of the system, φx, can show three resonance peaks, in a small microwave frequency range. One peak is connected with the anticrossing and the other two with the external microwave frequency ν. The relative position and the height of the two lateral peaks depend on the microwave frequency. This behavior is studied here for the first time.     

Spin quantum tunneling in single molecular magnets: fingerprints in transport spectroscopy of current and noise

We demonstrate that transport spectroscopy of single molecular magnets shows signatures of quantum tunneling at low temperatures. We find current and noise oscillations as a function of bias voltage due to a weak violation of spin-selection rules by quantum tunneling processes. The interplay with Boltzmann suppression factors leads to fake resonances with temperature-dependent position which do not correspond to any charge excitation energy. Furthermore, we find that quantum tunneling can completely suppress transport if the transverse anisotropy has a high symmetry.     

Shot noise in magnetic tunnel junctions: evidence for sequential tunneling

We report the experimental observation of sub-Poissonian shot noise in single magnetic tunnel junctions, indicating the importance of tunneling via impurity levels inside the tunnel barrier. For junctions with weak zero-bias anomaly in conductance, the Fano factor (normalized shot noise) depends on the magnetic configuration being enhanced for antiparallel alignment of the ferromagnetic electrodes. We propose a model of sequential tunneling through nonmagnetic and paramagnetic impurity levels inside the tunnel barrier to qualitatively explain the observations.     

Terahertz electromagnetic waves emitted from semiconductor investigated using terahertz time domain spectroscopy

Ultrafast electromagnetic waves radiated from semiconductor material under high electric fields and photoexcited by femtosecond laser pulses have been recorded by using terahertz time domain spectroscopy (THz-TDS).The waveforms of these electromagnetic waves reflect the dynamics of the photoexcited carriers in the semiconductor material,thus,THz-TDS provides a unique opportunity to observe directly the temporal and spatial evolutions of non-equilibrium transport of carriers within sub-picosecond time scale....     

Evidence for macroscopic quantum tunneling of phase slips in long one-dimensional superconducting Al wires

Quantum phase slips have received much attention due to their relevance to superfluids in reduced dimensions and to models of cosmic string production in the early universe. Their establishment in one-dimensional superconductors has remained controversial. Here we study the nonlinear current-voltage characteristics and linear resistance in long superconducting Al wires with lateral dimensions approximately 5 nm. We find that, in a magnetic field and at temperatures well below the superconducting transition, the observed behaviors can be described by the nonclassical, macroscopic quantum tunneling of phase slips, and are inconsistent with the thermal activation of phase slips.     

Inelastic electron tunneling spectroscopy evidence for a surface chemical reaction

The inelastic electron tunnel effect has been used to show the occurence of a surface chemical reaction between an organic molecule (benzoyl chloride) dopant and the tunnel barrier of a junction (Al-oxide-Pb).     

Quantitative study of macroscopic quantum tunneling in a dc SQUID: a system with two degrees of freedom

To test whether the theory of macroscopic quantum tunneling (MQT) is applicable to systems with 2 degrees of freedom, we experimentally investigated the switching current distribution of a dc SQUID. Using sample parameters determined from measurements at T=4.2 K, we are able to make quantitative comparison to the theories from 8 mK to 4.2 K. The excellent agreement between the data and the MQT theory demonstrates that tunneling from the zero-voltage state of the dc SQUID is well described by the quantum mechanics.     

Lyophilized histidine investigated using X-ray photoelectron spectroscopy and cryogenics: Deprotonation in vacuum

Lyophilized histidine samples were investigated using X-ray photoelectron spectroscopy (XPS). Lyophilized samples were prepared from aqueous solutions at a pH in the range between ∼1.5 and ∼10, and with no further addition of electrolyte. The use of cryogenics allowed the determination of protonated to unprotonated molar ratios of sites in l-histidine, which correlates well with the dissociation constants of the residual amino acid sites. When cryogenics was not used deprotonation of the lyophilized samples occurred, where the degree and the total concentration of deprotonated sites correlates well with the formation constants and the decrease in Cl concentration, respectively. This later relation clearly indicates a correlation between deprotonation and the desorption of HCl from lyophilized samples.     

Photo-induced tunneling spectroscopy of ReS2: Dramatic increase of the quantum efficiency by chemical treatment

In this work we present a systematic study of the local photovoltaic properties of ReS₂, using a scanning tunneling microscope (STM). The tunneling junction of the STM was optically illuminated during the tunneling process. The phase sensitive detected photo-induced tunneling current (PITC) was studied as a function of wavelength and surface topography. In order to improve the performance of ReS₂ solar cells, the samples were treated with NaI/I₂ and EDTA solutions. Relative to the untreated sample, the EDTA-treated samples show an increase in the photo-induced tunneling current by a factor of 8–10 in the whole spectral range, the NaI/I-treated samples by 2–3. Two dimensional mapping of the PITC was performed on an atomic scale and compared to the surface topography.     

Structurally induced FEES from nanotips: implications for scanning tunneling spectroscopy

Recent theoretical studies and experimental data show the existence of energy levels at the apex atom of nanotips. We report here experimental measurements, by field emission electron spectroscopy (FEES), of strong modifications of the local density of states for varying atomic configurations of the nanotips. The local density of states specific to each protrusion must then be considered in interpreting scanning tunneling microscopy and scanning tunneling spectroscopy experiments with atomic resolution instead of the commonly used free-electron model.     

Diamagnetic levitation of a milligram-scale silica using permanent magnets for the use in a macroscopic quantum measurement

Verification of macroscopic quantum mechanics requires that the position measurement accuracy of mirrors of various mass scales reach the Standard Quantum Limit (SQL) derived from Heisenberg's uncertainty principle. At mg-scale, thermal noise of the suspension wire of the mirror is an issue to reach the SQL. We propose to use a magnetic levitation system consisting of permanent magnets and yokes, noting the fact that a silica mirror is diamagnetic, and have succeeded in the experimental verification to levitate a 0.1-1 mg silica mass. This is the first demonstration of the levitation system with this mass scale and this magnetic susceptibility scale using permanent magnets as far as we know. We also estimated major noise sources for a 0.1 mg silica mirror and found the noise level to be lower than the SQL at 400 Hz-18 kHz. In conclusion, the levitation system of a mg-scale mirror for the use in a macroscopic quantum measurement was realized.     

Long-distance electron tunneling in proteins: A new challenge for time-resolved spectroscopy

Long-distance electron tunneling is a fundamental process which is involved in energy generation in cells. The tunneling occurs between the metal centers in the respiratory enzymes, typically over distances up to 20 or 30 such distances, the tunneling time—i.e., the time during which an electron passes through the body of the protein molecule from one metal center to another—is of the order of 10 fs. Here the process of electron tunneling in proteins is reviewed, and a possibility of experimental observation of real-time electron tunneling in a single protein molecule is discussed.