Sensitivity of Intrinsic Permeability to Electrokinetic Coupling in Shaly and Clayey Porous Media

Classical Darcy’s law assumes that the intrinsic permeability of porous media is only dependent on the micro-geometrical and structural properties of the inner geometry of the medium. There are, however, numerous experimental evidences that intrinsic permeability of shaly and clayey porous material is a function of the fluid phase used in the experiments. Several pore-scale processes have been proposed to explain the observed behavior. In this study, we conduct a detailed investigation of one such mechanism, namely the electrokinetic coupling. We have developed a numerical model to simulate this process at the pore-scale, incorporating a refined model of the electrical double layer. The model is used to conduct a detailed sensitivity analysis to elucidate the relative importance of several chemical–physical parameters on the intensity of the electrokinetic coupling. We found that permeability reduction due to this mechanism is likely to occur only if the effective pore-radius is smaller than 10⁻⁶ m. We also observed that electrokinetic coupling is strongly sensitive to electrophoretic mobility, which is normally reduced in clays compared to free-water conditions. Based on these findings, we set up a suite of stochastic pore-network simulations to quantify the extent of permeability reduction. We found that only if the effective pore-radius is ranging from 5 × 10⁻⁷ m to 5 × 10⁻⁸, electrokinetic coupling can be responsible for a 5–20% reduction of the intrinsic permeability, and, therefore, this mechanism has a minor impact on situations of practical environmental or mining interest.     

Degradation of homogeneous polymer solutions in high shear turbulent pipe flow

This study quantifies degradation of polyethylene oxide (PEO) and polyacrylamide (PAM) polymer solutions in large diameter (2.72 cm) turbulent pipe flow at Reynolds numbers to 3 × 10⁵ and shear rates greater than 10⁵ 1/s. The present results support a universal scaling law for polymer chain scission reported by Vanapalli et al. (2006) that predicts the maximum chain drag force to be proportional to Re ^3/2, validating this scaling law at higher Reynolds numbers than prior studies. Use of this scaling gives estimated backbone bond strengths from PEO and PAM of 3.2 and 3.8 nN, respectively. Additionally, with the use of synthetic seawater as a solvent the onset of drag reduction occurred at higher shear rates relative to the pure water solvent solutions, but had little influence on the extent of degradation at higher shear rates. These results are significant for large diameter pipe flow applications that use polymers to reduce drag.     

Flow of drag-reducing surfactant solutions in rough pipes

The paper reports the results of experimental study of the flow of hexadecyltrimethylammonium chloride (CTAC) solutions with addition of sodium salicylate (NaSal) in the rough pipes. Measurements were performed in the range of the surfactant concentration from 200 to 400 ppm at a constant molar ratio CTAC/NaSal of 1:2. Five pipes of the relative roughness k/D varying from 1.2 × 10^?2 to 5.6 × 10^?2, obtained by the covering of inner surface of the pipes with glued silicon carbide particles of different size, were studied. The roughness was observed to increase the drag of flow of CTAC/NaSal solutions already at Reynolds numbers higher than 800. With increasing relative roughness k/D, the critical value of Reynolds number, at which the drag reduction disappears, was found to decrease. However, no influence of the roughness on the critical shear stress was noted. The ratio of the critical Reynolds number for rough pipes to that of hydraulically smooth pipes was independent of the surfactant concentration. The degree of drag reduction by the flow of surfactants was greater in rough pipes than in smooth pipes.     

Origin of regime transition to turbulent flow in bubble column: Orifice- and column-induced transitions

The possible events during bubble formation on an orifice were investigated using a rectangular bubble column (30 cm × 30 cm × 100 cm). The gas flow rate through a single orifice was adjusted from 0.1 dm³/min to 5.0 dm³/min covering a high flow rate regime. At the high gas flow rate, the bubble formation process was complicated by diverse events, such as wake effect, channeling, and orifice-induced turbulent flow. The detachment period could be used to discern the bubble formation steps because it was strongly affected by the above events. The bubble size distribution around the orifice was also analyzed to gain a clearer understanding of the bubble formation process. Above the rate of 3.0 dm³/min through a single orifice, the detachment period converged to a value of 25 ms irrespective of the orifice diameter. The bubble size distribution also showed little difference in this range of gas flow rate. This could be explained by the development of turbulent flow around the orifice. A 0.15 m in-diameter bubble column was tested to investigate the effect of orifice-induced turbulent flow on the regime transition in which the homogeneous flow regime is converted into the heterogeneous flow regime in the column. Obvious distinction between the orifice- and column-induced transitions was observed.     

Effects of deformed volume, volume fraction and particle size on the deformation behaviour of W/Cu composites

Tungsten/copper (W/Cu) particle reinforced composites were used to investigate the scaling effects on the deformation and fracture behaviour. The effects of the volume fraction and the particle size of the reinforcement (tungsten particles) were studied. W/Cu-80/20, 70/30 and 60/40 wt.% each with tungsten particle size of 10 μm and 30 μm were tested under compression and shear loading. Cylindrical compression specimens with different volumes (D_S = H) were investigated with strain rates between 0.001 s⁻¹ and about 5750 s⁻¹ at temperatures from 20 °C to 800 °C. Axis-symmetric hat-shaped shear specimens with different shear zone widths were examined at different strain rates as well. A clear dependence of the flow stress on the deformed volume and the particle size was found under compression and shear loading. Metallographic investigation was carried out to show a relation between the deformation of the tungsten particles and the global deformation of the specimens. The size of the deformed zone under either compression or shear loading has shown a clear size effect on the fracture of the hat-shaped specimens.The quasi-static flow curves were described with the material law from Swift. The parameters of the material law were presented as a function of the temperature and the specimen size. The mechanical behaviour of the composite materials were numerically computed for an idealized axis-symmetric hat-shaped specimen to verify the determined material law.     

Experiment on smooth,circular cylinders in cross-flow in the critical Reynolds number regime

Experiments were conducted for 2D circular cylinders at Reynolds numbers in the range of 1.73 × 10⁵–5.86 × 10⁵. In the experiment, two circular cylinder models made of acrylic and stainless steel, respectively, were employed, which have similar dimensions but different surface roughness. Particular attention was paid to the unsteady flow behaviors inferred by the signals obtained from the pressure taps on the cylinder models and by a hot-wire probe in the near-wake region. At Reynolds numbers pertaining to the initial transition from the subcritical to the critical regimes, pronounced pressure fluctuations were measured on the surfaces of both cylinder models, which were attributed to the excursion of unsteady flow separation over a large circumferential region. At the Reynolds numbers almost reaching the one-bubble state, it was noted that the development of separation bubble might switch from one side to the other with time. Wavelet analysis of the pressure signals measured simultaneously at θ = ±90° further revealed that when no separation bubble was developed, the instantaneous vortex-shedding frequencies could be clearly resolved, about 0.2, in terms of the Strouhal number. The results of oil-film flow visualization on the stainless steel cylinder of the one-bubble and two-bubble states showed that the flow reattachment region downstream of a separation bubble appeared not uniform along the span of the model. Thus, the three dimensionality was quite evident.     

Low Pressure Gas Percolation Characteristic in Ultra-low Permeability Porous Media

Low pressure gas percolation characteristic in ultra-low permeability porous media is investigated in this article through core flow experiments. The results show that the wall-slip layer covers more than 10% of the average porous channel radius on account of minimum pore size when the permeability is below 0.1 × 10^?3μ m ² order, and seepage behavior is contrasted to that in mid-high permeability pore media. When the gas pressure is not high enough, the flow regime turns into transitional flow instead of slip flow, and nonlinear relationship between the measured gas permeability and the reciprocal of average pressure exists. The gas measuring permeability experiment would be influenced by the non-linear relationship. If Klinkenberg-corrected method is applied to speculate the equivalent liquid permeability, the extrapolated value will become less or minus. Simultaneously, actual gas flow velocity at the outlet is beyond the calculated value with Klinkenberg formula. A new gas seepage model based on the general slip boundary condition is derived from the homogenization technique in this article. At last the flow model is examined to be suitable for representing the gas flow behavior in ultra-low permeability media and estimating the absolute permeability from single-point, steady-states measurements.     

Generalized Solution for 1-D Non-Newtonian Flow in a Porous Domain due to an Instantaneous Mass Injection

Non-Newtonian fluid flow through porous media is of considerable interest in several fields, ranging from environmental sciences to chemical and petroleum engineering. In this article, we consider an infinite porous domain of uniform permeability k and porosity f{\phi} , saturated by a weakly compressible non-Newtonian fluid, and analyze the dynamics of the pressure variation generated within the domain by an instantaneous mass injection in its origin. The pressure is taken initially to be constant in the porous domain. The fluid is described by a rheological power-law model of given consistency index H and flow behavior index n; n, < 1 describes shear-thinning behavior, n > 1 shear-thickening behavior; for n = 1, the Newtonian case is recovered. The law of motion for the fluid is a modified Darcy’s law based on the effective viscosity μ _ef , in turn a function of f, H, n{\phi, H, n} . Coupling the flow law with the mass balance equation yields the nonlinear partial differential equation governing the pressure field; an analytical solution is then derived as a function of a self-similar variable η = rt ^β (the exponent β being a suitable function of n), combining spatial coordinate r and time t. We revisit and expand the work in previous papers by providing a dimensionless general formulation and solution to the problem depending on a geometrical parameter d, valid for plane (d = 1), cylindrical (d = 2), and semi-spherical (d = 3) geometry. When a shear-thinning fluid is considered, the analytical solution exhibits traveling wave characteristics, in variance with Newtonian fluids; the front velocity is proportional to t ^(n-2)/2 in plane geometry, t ^{(2n-3)/(3−n)} in cylindrical geometry, and t ^{(3n-4)/[2(2−n)]} in semi-spherical geometry. To reflect the uncertainty inherent in the value of the problem parameters, we consider selected properties of fluid and matrix as independent random variables with an associated probability distribution. The influence of the uncertain parameters on the front position and the pressure field is investigated via a global sensitivity analysis evaluating the associated Sobol’ indices. The analysis reveals that compressibility coefficient and flow behavior index are the most influential variables affecting the front position; when the excess pressure is considered, compressibility and permeability coefficients contribute most to the total response variance. For both output variables the influence of the uncertainty in the porosity is decidedly lower.     

Turbulence Characteristics in Flows Over Solid and Porous Square Ribs Mounted on Porous Walls

PIV measurements have been performed for turbulent flows in a rib-mounted channel whose bottom wall is made of a porous layer. The ratio of the rib and channel heights is fixed at 0.5. The effects of the wall and rib permeability are investigated focusing on the separating and reattaching flows at the bulk Reynolds number of 10³???10⁴. Three kinds of foamed ceramics are employed as the porous media. They have the same porosity of 0.8 but each permeability is different from the others. Its normalized values by the rib height are 0.89 × 10^???4, 1.47 × 10^???4 and 3.87 × 10^???4. Two kinds of square cylinder ribs: an impermeable smooth solid rib or a permeable porous rib which is made of the same porous medium as that for the bottom wall are used. The obtained turbulent velocity fields of the solid rib flows indicate that the turbulent intensity behind the rib becomes weak and the recirculation bubble in the clear channel tends to vanish as the the wall permeability increases. In the porous rib flow, the recirculation and the reattachment point shift downstream and turbulence becomes weaker due to the bleeding flow through the rib. In the higher permeability cases, the recirculation bubble hardly exists due to the flows through not only the bottom wall but also the porous rib. From the measurements, it is suggested that in the solid rib flows, a reverse flow region exists inside the porous wall whereas in porous rib flows, such reverse flow does not exist at higher permeability.     

Simultaneous determination of shear and extensional viscosities and wall slip by on-line rheometry with parameter fitting: an application to EPDM rubber

Shear and extensional viscosities and wall slip are determined simultaneously under extrusion processing conditions using an on-line rheometer. Because it is not possible to independently control flow rate and temperature, classical methods for interpretation of capillary data cannot be used with on-line rheometry. This limitation is overcome using computational optimization to fit parameters in a flow model. This consists of three parts, representing shear viscosity, extensional viscosity, and wall slip. Three-parameter, power law forms, based on local instantaneous deformation rates and including temperature dependence, are used for each, and analytic solutions applied for entry flow and flow in the capillary. For entry flow, the Cogswell–Binding approach is used, and for developed flow in the capillary a solution incorporating wall slip is derived. The rheometer, with interchangeable capillaries, is mounted in place of the die on a rubber profile extrusion line. Pressure drops and temperatures for extrusion of an EPDM rubber through 2 mm diameter capillaries of length 0, 2, 3, 4, and 5 mm are logged and flow rates determined for a range of extruder speeds (5 to 20 rpm). Pressures ranged from 60 to 75 bar and temperatures from 86 to 116 °C. Mean flow velocity in the capillaries was between 5 × 10⁻³ and 5 × 10⁻¹ m s⁻¹. The nine material parameters are optimized for best fit of the analytic pressure drops to experimental data, using about 100 data points, with the Levenberg–Marquardt method. It is concluded that flow is dominated by extension and wall slip. Shear flow appears to play little part. The slip model indicates that slip velocity increases much more rapidly than the wall shear stress (in the range 0.5–1 MPa) and decreases with temperature for a given stress level. Results for the (uniaxial) extensional viscosity represent an engineering approximation to this complex phenomenon at the high strains (approximately 200) and high extension rates (up to 800 s⁻¹) applying in the extrusion. Results indicate a slight extension hardening and a decrease with temperature. Results are put into the context of the available studies in the literature, which, particularly with regard to wall-slip and extensional flow, consider conditions far removed from those applying in industrial extrusion. The present methods provide a powerful means for flow characterization under processing conditions, providing data suitable for use in computer simulations of extrusion and optimization of die design.     

Dynamical deformation of a flat liquid–liquid interface

The passage of solid spheres through a liquid–liquid interface was experimentally investigated using a high-speed video and PIV (particle image velocimetry) system. Experiments were conducted in a square Plexiglas column of 0.1 m. The Newtonian Emkarox (HV45 50 and 65% wt) aqueous solutions were employed for the dense phase, while different silicone oils of different viscosity ranging from 10 to 100 mPa s were used as light phase. Experimental results quantitatively reveal the effect of the sphere’s size, interfacial tension and viscosity of both phases on the retaining time and the height of the liquid entrained behind the sphere. These data were combined with our previous results concerning the passage of a rising bubble through a liquid–liquid interface in order to propose a general relationship for the interface breakthrough for the wide range of Mo ₁/Mo ₂ ∈ [2 × 10⁻⁵–5 × 10⁴] and Re ₁/Re ₂ ∈ [2 × 10⁻³–5 × 10²].     

Flow Laws in Metal Foams: Compressibility and Pore Size Effects

The aim of our experimental work was to establish a simple relation between the flow parameters and the morphological parameters of metallic foam. We used foam samples made from different metals or alloys (Cu, Ni, Ni-Cr, etc) and of various thicknesses. Pore size ranged between 500 and 5000 μm. We measured the pressure profiles in foam samples using a specific experimental set-up of 12 pressure sensors distributed 1 cm apart along the main flow axis. The experimental loop made it possible to use indifferently water or air as working fluid. For the study of the gas (air) flow, velocities ranged roughly from 0 up to 20 m/s and for the liquid (water) flow, velocities ranged between 0 and 0.1 m/s. The measurements of the pressure gradients were performed systematically. We validated the Forchheimer flow model. The influence of the compressibility effects on permeability and inertia coefficient was emphasized. We demonstrated that the pore size Dp in itself is sufficient to describe flow laws in such high porosity material: K and β are respectively proportional to Dp² and Dp⁻¹.     

Dynamic heat and moisture transfer in bulky PAN nanofiber mats

In this study a non-conventional electrospinning technique was designed for the production of high bulky polyacrylonitrile (PAN) nanofiber mats. Optimum nanofiber mats are achieved with 15 wt.% solution of PAN in dimethylformamide. Such mats result in a bulk porosity which is as high as 99.9 and a density as low as 0.84 × 10⁻³ g/cm³. The effect of the porosity of nanofiber mats on the air permeability and coupled heat and moisture transfer of fibers was investigated. Based on the results, high bulky nanofiber mats possess high heat and moisture transfer. Experimental data reveal that upon a slight decrease in the bulk porosity, air permeability and heat transfer decrease noticeably, while moisture transfer variation is low.     

Bluff-body drag reduction using a deflector

A passive flow control on a generic car model was experimentally studied. This control consists of a deflector placed on the upper edge of the model rear window. The study was carried out in a wind tunnel at Reynolds numbers based on the model height of 3.1 × 10⁵ and 7.7 × 10⁵. The flow was investigated via standard and stereoscopic particle image velocimetry, Kiel pressure probes and surface flow visualization. The aerodynamic drag was measured using an external balance and calculated using a wake survey method. Drag reductions up to 9% were obtained depending on the deflector angle. The deflector increases the separated region on the rear window. The results show that when this separated region is wide enough, it disrupts the development of the counter-rotating longitudinal vortices appearing on the lateral edges of the rear window. The current study suggests that flow control on such geometries should consider all the flow structures that contribute to the model wake flow.     

Numerical analysis of turbulent convection heat transfer from an array of perforated fins

Numerical investigation is made for three-dimensional fluid flow and convective heat transfer from an array of solid and perforated fins that are mounted on a flat plate. Incompressible air as working fluid is modeled using Navier–Stokes equations and RNG based k ? ? turbulent model is used to predict turbulent flow parameters. Temperature field inside the fins is obtained by solving Fourier’s conduction equation. The conjugate differential equations for both solid and gas phase are solved simultaneously by finite volume procedure using SIMPLE algorithm. Perforations such as small channels with square cross section are arranged streamwise along the fin’s length and their numbers varied from 1 to 3. Flow and heat transfer characteristics are presented for Reynolds numbers from 2 × 10⁴ to 4 × 10⁴ based on the fin length and Prandtl number is taken Pr = 0.71. Numerical computations are validated with experimental studies of the previous investigators and good agreements were observed. Results show that fins with longitudinal pores, have remarkable heat transfer enhancement in addition to the considerable reduction in weight by comparison with solid fins.     

Smoothed particle hydrodynamics simulation of non-Newtonian moulding flow

Smoothed particle hydrodynamics (SPH) has been widely applied in simulating fluid flow because of its attractive properties, for example, it is fully Lagrangian and mesh free. However, this method usually uses the explicit method to solve the conservation equations and in this form it is only suitable to momentum dominated flows with low viscosity. In polymer processing, the fluid is non-Newtonian with high viscosity, O(10³) to O(10⁴) Pa-s say, and the pressure is high as O(10⁶) to O(10¹⁰) Pa. The algorithm of the standard SPH is infeasible in this case, because only very small time steps can be used for a stable simulation. We have developed an implicit SPH for non-Newtonian flow, which is completely matrix free, to solve the equation system iteratively and robustly. The artificial pressure is introduced between particles to stabilize the SPH system avoiding the tensile instability. The fluid is compressible under high pressure. Realistic state equations for polymers, such as the Tait and SSY [16] equations are adopted to describe the density/pressure relations. The method is finally applied to the simulation of moulding flow of a modified power law fluid with the zero shear rate viscosity of 1.22 × 10⁴ Pa-s, Reynolds number of 3 × 10^?4 to 6 × 10^?5 and the highest pressure of O(10⁸) to O(10¹⁰) Pa.     

Numerical investigation of particle deposition inside aero-shielded solar cyclone reactor: A promising solution for reactor clogging

Solar cracking of methane is considered to be an attractive option due to its CO₂ free hydrogen production process. Carbon particle deposition on the reactor window, walls and exit is a major obstacle to achieve continuous operation of methane cracking solar reactors. As a solution to this problem a novel “aero-shielded solar cyclone reactor” was created. In this present study the prediction of particle deposition at various locations for the aero-shielded reactor is numerically investigated by a Lagrangian particle dispersion model. A detailed three dimensional computational fluid dynamic (CFD) analysis for carbon deposition at the reactor window, walls and exit is presented using a Discrete Phase Model (DPM). The flow field is based on a RNG k–ε model and species transport with methane as the main flow and argon/ hydrogen as window and wall screening fluid. Flow behavior and particle deposition have been observed with the variation of main flow rates from 10–20 L/min and with carbon particle mass flow rate of 7 × 10⁻⁶ and 1.75 × 10⁻⁵ kg/s. In this study the window and wall screening flow rates have been considered to be 1 L/min and 10 L/min by employing either argon or hydrogen. Also, to study the effect of particle size simulations have also been carried out (i) with a variation of particle diameter with a size distribution of 0.5–234 μm and (ii) by taking 40 μm mono sized particles which is the mean value for the considered size distribution. Results show that by appropriately selecting the above parameters, the concept of the aero-shielded reactor can be an attractive option to resolve the problem of carbon deposition at the window, walls and exit of the reactor.     

Tomographic and time resolved PIV measurements on a finite cylinder mounted on a flat plate

Tomographic and time resolved PIV measurements were performed to examine the 3D flow topology and the flow dynamic above the upper surface of a low-aspect ratio cylinder at Re ≈ 1 ×  10⁵. This generic experiment is of fundamental interest because it represents flow features which are relevant to many applications such as laminar separation bubbles and turbulent reattachment. At Re  ≈ 1 × 10⁵, laminar separation bubbles arise on the side of the cylinder. Furthermore, on the top of the cylinder a separation with reattachment is of major interest. The tomographic PIV measurement, which allows to determine all three velocity components in a volume instantaneously, was applied to examine the flow topology and interaction between the boundary layer and wake structures on the top of the finite cylinder. In the instantaneous flow fields the tip vortices and the recirculation region becomes visible. However, it is also observed that the flow is quite unsteady due to the large separation occurring on the top of the cylinder. In order to study the temporal behaviour of the separation, time resolved PIV was applied. This technique allows capturing the dynamic processes in detail. The development of vortices in the separated shear layer is observed and in addition regions with different dominant frequencies are identified.     

The effect of a small isolated roughness element on the forces on a sphere in uniform flow

The effect of an isolated roughness element on the forces on a sphere was examined for a Reynolds number range of 5 × 10⁴ < Re < 5 × 10⁵ using a novel sting-mounted sphere apparatus. The roughness element was a circular cylinder, and its width and height was varied to be 1, 2, and 4% of the sphere diameter. At subcritical Re, a lateral force is produced in the direction of the roughness, while at supercritical Re, the force is in the opposite direction. This is caused by asymmetric boundary layer separation, as shown using particle image velocimetry. At supercritical Re, a roughness element that is only 1% the sphere diameter produces a lift to drag ratio of almost one. It was found that the isolated roughness element has the largest effect on the lateral forces when it is located between a streamwise angle of about 40° and 80°. In addition to the mean forces, the unsteady forces were also measured. It was found that at subcritical Re, vortex shedding is aligned to the plane of the roughness element. In addition, the probability distribution of the forces was nearly Gaussian for subcritical Re, but for supercritical Re, the skewness and kurtosis deviate from Gaussian, and the details are dependent on the roughness size. A simple model developed for the vortical structure formed behind the roughness element can be extended to explain aspects of nominally smooth sphere flow, in which external disturbances perturb the sphere boundary layer in an azimuthally local sense. These results also form the basis of comparison for an investigation into the effectiveness of a moving isolated roughness element for manipulating sphere flow.