Influence of relative humidity on surface conductivity of germanium

A study was made of the influence of the relative humidity (from 0.5–90%) on the surface conductivity of bothp- andn-type germanium having differing resistivity. It was. found that the range of changes in the surface potential did not depend on the volume properties of germanium. An analysis of the experimental results shows that the surface potential has values approximately in the range from _s =–3kT/q to _s =+5kT/q for a change in humidity from 0.5 to 90%. Assuming that the Fermi level changes on the outer side of the oxide layer by approximately the same value as on the germaniumgermanium oxide boundary as a result of the increase and decrease of slow states, it follows that the levels of the slow centres are considerably distant from the Fermi level during the whole humidity range. It is also shown that on the first monomolecular layer of adsorbed water there is an increment of (7.5±0.8) x 10¹⁰ donor levels per cm². This increase in levels either decreases with the number of adsorbed monomolecular layers of water and for 90% humidity has approximately the value 2×10¹⁰ cm^–2 or remains almost unchanged with the number of layers, if it is assumed that for _s =6.0kT/q the Fermi level passes through the centres of adsorbed water.

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0,5 90% p n. . , _s =– 3kT/q _s =+ 5kT/q 0,5 90%. , - , , . , (7,5 ±0,8). 10¹⁰ cm². 90% . 2. 10¹⁰ cm^–2 , , , _s =6,0kT/q .

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In conclusion the author thanks Dr. J. Taue for instigating this work and S. Koc, C. Sc., for remarks and the interest with which he followed the work. He also thanks A.Müller for measuring the Hall constant in the samples.     

ВЛИЯНИЕ СОДЕРЖАНИЯ К ИСЛОРОДА НА ЭЛЕКТРИЧЕСКИЕ И ТЕ РМОЭЛЕКТРИЧЕСКИЕ СВОЙСТВА ТРОЙНОЙ СИС ТЕМЫ Вi2Те3−x Sе x

, Bi₂Te_3–x Se _x . , , . , , . .

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Influence of oxygen content on electric and thermoelectric properties of ternary system Bi₂Te_3–x Se _x

A study is made of the influence of oxygen, contained in the semi-conducting system Bi₂Te_3–x Sé _x , on the electric and thermoelectric properties. It is shown that the addition of oxygen to the prepared samples Bi₂Te_2.4Se_0.6 causes a decrease in electric conductivity while the thermoelectric force remains unchanged. This influence is connected with a decrease in the mobility of the electrons but their concentration is not influenced by the presence of oxygen. Conclusions are reached as to the influence of oxygen on the efficiency of the conversion of thermal energy into electric energy and vice versa.

     

强磁场下Pt电阻温度传感器的磁致电阻效应研究

以Pt电阻温度传感器(Pt-111)为研究对象,研究了其在0～16T磁场下、4.2～300K温区内的磁致电阻效应.结果表明:Pt-111在0～16T场强、4.2～77K温区内,磁效应随场强的增加和温度的降低而明显升高,77～300K温区内温度计受磁场的影响较小,其中在16T下,4.2K和300K处的磁效应分别为48.2%和1.07%;在4.2-77K温区,Pt-111由磁阻引起的测量误差场强的升高和温度的降低而明显升高,在16T、4.2K处和16T、77K处的温度测量误差分别为18.3K和1.69K.Pt-111不推荐应用在77K以下的磁场环境.     

Zum Problem der Exoelektronenemission

Zusammenfassung Es werden die zwei einfachsten Fälle der Exoelektronenemission untersucht und auf Grund dessen geeignete Verfahren zur Verarbeitung der Versuchsergebnisse vorgeschlagen.

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Der Zerfall des77Kr

⁷⁷Kr (T _1/2=1.2 h) was produced by bombarding⁷⁶Se with 48 MeV-α-particles. After irradiation the radioactive⁷⁷Kr gas was collected in glass ampoules filled with charcoal and cooled by liquid air. The decay of⁷⁷Kr has been investigated using Ge(Li)-counters and a Ge(Li)-Ge(Li)-coincidence circuit. 27 γ-transitions, 13 of them unknown up to the present, have been found and their relative intensities have been determined. A level scheme for⁷⁷Kr→⁷⁷Br having 14 levels is proposed. This accounts for all the observed γ-transitions.     

Analytic Properties of the Structure Function for the One-Dimensional One-Component Log–Gas

The structure function S(k; ) for the one-dimensional one-component log–gas is the Fourier transform of the charge–charge, or equivalently the density–density, correlation function. We show that for |k|j in the power series expansion of f(k; ) about k=0 is of the form of a polynomial in /2 of degree j divided by (/2)^j. The bulk of the paper is concerned with calculating these polynomials explicitly up to and including those of degree 9. It is remarked that the small k expansion of S(k; ) for the two-dimensional one-component plasma shares some properties in common with those of the one-dimensional one-component log–gas, but these break down at order k⁸.     

Effect ofV K centers on positron annihilation in KCl and Ag-doped KCl

Positron lifetime spectra have been measured at 77 K for KCl and Ag-doped KCl before and after x-irradiation at 77 K and after annealing at room temperature. Radiation at 77 K reduces the intensity of the intermediate lifetime (τ₂) component. Radiation-induced defects were monitored optically and by ESR. The experiment shows that the changes observed in the positron decay are associated with the presence ofV _K centers.     

Photoluminescence in powdered crystalline GeSe2

The decrease of photoluminiscence (PL) intensity under continuous excitation in powdered crystalline GeSe₂ was observed at 77 K. The intensity of PL decreased by ～ 50 % in 2.10³s. The characteristics of the PL band for the powdered samples at 77 K are identical with those for crystals, but the temperature dependence of the PL intensity and the peak of the PL spectrum in the temperature range 77–200 K for powdered and bulk crystalline samples are different.     

Ion-molecule reactions of 2-methoxyethanol with some amines, carboxylic acids and amino acids under chemical ionization conditions

2-Methoxyethanol chemical ionization of amines, carboxylic acids and amino acids has been found to produce numerous adduct ions. The most intense adduct ions for amines are [M + H](+) and [M + 77](+), for carboxylic acids [M + 27](+), [M + 59](+) and [M + 77](+), and for amino acids [M + H](+), [M + 13](+), [M + 27](+) and [M + 77](+). Either the adduct ion [M + H](+) or [M + 77](+) was the most abundant ion found for amino acids. The proton affinities of amino acids are noticed to control the formation of the [M + H](+) and [M + 77](+) ions. The relative abundance of [M + 13](+) and [M + 27](+) ions varied for different amino acids being most intense for phenylalanine and aspartic acid. Copyright 1999 John Wiley & Sons, Ltd.     

C77N+异构体的稳定性和电子光谱研究

用INDO系列方法对C78(C2V)的等电子体C77N+的所有21种可能异构体进行系统的理论研究.研究结果表明,最稳定异构体是由C78(C2V)沿Y方向椭球短轴所穿过的C(78)-C(73)键上的原子C(78)被N+取代所形成,椭球长轴附近的原子被取代所形成的异构体能量较低,取代位置附近易成为进一步反应的中心.用INDO/SCI方法计算了C77N+电子光谱,表明其吸收峰与C78(C2V)相比发生红移,对特征吸收峰进行了理论指认,讨论吸收峰红移的原因.     

Evaluation of channel hot carrier effects in n-MOS transistors at 77 K with the charge pumping technique

With the charge pumping technique, the role of hot holes in the channel hot carrier degradation of short channel n-MOS transistors is shown to be less pronounced at 77 K than at 300 K. Also fewer fast interface states are generated at 77 K for the same substrate current level in the low gate bias regime. Furthermore, the dominant device degradation is found to be in the high gate bias regime at 77 K, in contrast to the case of 300 K. This is due to the presence of negative charge in the oxide or in acceptor-type interface states.     

纳米Ni在77 K温度下压缩行为的研究

利用低温力学测试系统研究了电化学沉积纳米Ni在77 K温度下的压缩行为. 室温下纳米Ni 的屈服强度为 2.0 GPa, 77 K温度下的屈服强度为3.0 GPa, 压缩变形量则由室温的10%左右下降到5%. 借助应变速率敏感指数、激活体积、扫描电子显微和高分辨透射电子显微分析, 对纳米Ni的塑性变形机制进行了表征. 研究表明, 在77 K温度下的塑性变形主要是由晶界-位错协调变形主导, 晶界本征位错弓出后无阻碍地在晶粒内无位错区运动, 直至在相对晶界发生类似切割林位错行为. 同时分析了弓出位错的残留位错部分在协调塑性变形时起到的增加应变相容性和减小应力集中的作用. 利用晶界-位错协调机制和残留位错运动与温度及缺陷的相关性揭示了纳米Ni室温和77 K温度压缩性能差异的内在原因. 关键词： 塑性变形 强度 位错     

Die Anwendung von 77Ge-markierten germaniumorganischen Verbindungen zur Untersuchung von Materialflüssen in Erdöverarbeitungsanlagen

Für Traceruntersuchungen in der erdölverarbeitenden Industrie wird der Einsatz von ⁷⁷Ge-markierten germaniumorganischen Verbindungen vorgeschlagen. Mit Hilfe von ⁷⁷Ge-markierten Germaniumtetraäthyl werden die Zirkulationszeit des Rücklaufs und die Verdampfungszeit der Erdölfraktionen auf den entsprechenden Stufen der Destillationskolonnen sowie mit ⁷⁷Ge-markiertem Germanium-tetra-n-amyl die lineare Geschwindigkeit des Erdöls in den einzelnen Sektionen des Vorheizers bestimmt.     

Asymptotically abelian systems

We study pairs { , } for which is aC*-algebra and is a homomorphism of a locally compact, non-compact groupG into the group of *-automorphisms of . We examine, especially, those systems { , } which are (weakly) asymptotically abelian with respect to their invariant states (i.e. |A _g (B) — _g (B)A 0 asg for those states such that ( _g (A)) = (A) for allg inG andA in ). For concrete systems (those with -acting on a Hilbert space andg _g implemented by a unitary representationg U _g on this space) we prove, among other results, that the operators commuting with and {U _g } form a commuting family when there is a vector cyclic under and invariant under {U _g }. We characterize the extremal invariant states, in this case, in terms of weak clustering properties and also in terms of factor and irreducibility properties of { ,U _g }. Specializing to amenable groups, we describe operator means arising from invariant group means; and we study systems which are asymptotically abelian in mean. Our interest in these structures resides in their appearance in the infinite system approach to quantum statistical mechanics.     

On the generation of nanograins in pure copper through uniaxial single compression

Attempts at generating nanograins through uniaxial single compression were made by deforming copper samples at 298 K and 77 K. At 298 K, dynamically-deformed samples (DDS) become softer, in contrast to quasi-statically deformed samples (QDS), which show a hardness close to the saturation value. The microstructure of DDS is characterised by deformation twins and equiaxed micron-sized grains, and the observed softening is due to the occurrence of recrystallisation (RX). At a reduced temperature of 77 K, nanograins are generated in DDS, whereas QDS show forest dislocations and twins. The generation of nanograins, which evolve through rotational DRX, is associated with the formation of shear bands with an amorphous structure. Compared with twinning, it appears that amorphisation plays a more pronounced role in high strain rate deformation at reduced temperatures (77 K). The hardness of DDS, obtained from compression at 77 K, exceeds the saturation value by 16%, whereas that of QDS corresponds approximately to saturation.     

Tunable UV radiation at short wavelengths (188–240 nm) generated by sum-frequency mixing in lithium borate

Sum-frequency mixing (₃=₁+₂) of UV laser radiation (₁=266 nm and 213 nm) and tunable coherent infrared light (₂=1.2–2.6 m) in lithium borate (LBO) generates radiation at short wavelengths (₃=188–242 nm). The UV radiation at ₁ is produced by the fourth and fifth harmonic of a pulsed Nd-YAG laser. The infrared light is generated with an optical parametric oscillator of beta barium borate. The phase-matching angle is measured as function of ₃ and compared with calculated values. For UV laser radiation at shorter wavelengths (173 nm₁213 nm) the calculations predict an extension of the tuning range of the sum-frequency generated at ₃ to wavelengths as short as the LBO transmission cutoff at 160 nm.     

Decay of the Bethe–Salpeter Kernel and Bound States for Lattice Classical Ferromagnetic Spin Systems at High Temperature

We consider lattice classical ferromagnetic spin systems at high temperature (1) with nearest neighbor interactions and even single-spin distributions (ssd). Associated with each system is an imaginary time lattice quantum field theory. It is known that there is a particle of mass m–ln in the energy-momentum spectrum. If s ⁴–3s ²²<0, where s ^k is the kth moment of the ssd, and is sufficiently small, we show that in the two-particle subspace there is no mass spectrum up to 2m. For >0 we show that the only mass spectrum in (m, 2m) is a bound state of mass m _b=2m+ln(1–)+O(), where =(+2s ²²)^–1. A bound on the decay of the kernel of a Bethe–Salpeter equation is obtained and used to prove these results.     

氢在碳纳米纤维中的低温吸附储存特性

利用容积法测量了77K下氢在一种碳纳米纤维上的吸附等温线。采用分子模拟的方法模拟了77K下氢分子在平板状碳纳米纤维中的吸附,碳纳米纤维的石墨层层间距分别为0.335nm、0.6nm、0.9nm以及1.5nm。模拟结果表明:石墨层层间距为0.335nm的碳纳米纤维在77K下吸附储氢密度很难达到DOE的能量密度标准;当板间距为0.9nm时,系统吸附储氢的重量密度和体积密度均能达到最大,且在77K、1MPa下,能达到DOE的能量密度标准。     

Photochemical transformations of the azidonitroxyl radical in glassy media

The kinetic characteristics of the photochemical decomposition of the azido group of 3-azido-4-hydroxyimino-2,2,6,6-tetramethylpiperidine-1-oxyl in solid matrices at 293 and 77 K were studied. It was revealed that the presence of the nitroxyl radical center in the molecule is responsible for the realization of the radical mechanism of the decomposition of the azido group. The values of the quantum yield φ of the decomposition of the azido group were found to be 0.056 in toluene at 77 K, 0.14 in polystyrene at 77 K, and 0.16 in polystyrene at 293 K. It was demonstrated that the number of radicals remaining after photolysis correlates with the molecular mobility of the medium.     

Abnormal variation of magnetic properties with Ce content in(PrNdCe)_2Fe_(14)B sintered magnets prepared by dual alloy method

Resource-saving(PrNdCe)_2Fe_(14)B sintered magnets with nominal composition(PrNd)_(15-x)Ce_xFe_(77)B_8(x=0–10)were prepared using a dual alloy method by mixing(PrNd)_5Ce_(10)Fe_(77)B_8 with(PrNd)_(15)Fe_(77)B_8 powders. For Ce atomic percent of 1% and 2%, coercivity decreases dramatically. With further increase of Ce atomic percent, the coercivity increases, peaks at 6.38 kOe in(PrNd)_(11)Ce_4Fe_(77)B_8, and then declines gradually. The abnormal dependence of coercivity is likely related to the inhomogeneity of rare earth chemical composition in the intergranular phase, where Pr Nd concentration is strongly dependent on the additive amount of(PrNd)_5Ce_(10)Fe_(77)B_8 powders. In addition, for Ce atomic percent of 8%,7%, and 6% the coercivity is higher than that of magnets prepared by the conventional method, which shows the advantage of the dual alloy method in preparing high abundant rare earth magnets.