The Schrödinger equation and canonical perturbation theory

LetT ₀(, )+V be the Schrödinger operator corresponding to the classical HamiltonianH ₀()+V, whereH ₀() is thed-dimensional harmonic oscillator with non-resonant frequencies =(₁, ... , _d ) and the potentialV(q ₁, ... ,q _d) is an entire function of order (d+1)^–1. We prove that the algorithm of classical, canonical perturbation theory can be applied to the Schrödinger equation in the Bargmann representation. As a consequence, each term of the Rayleigh-Schrödinger series near any eigenvalue ofT ₀(, ) admits a convergent expansion in powers of of initial point the corresponding term of the classical Birkhoff expansion. Moreover ifV is an even polynomial, the above result and the KAM theorem show that all eigenvalues _n (, ) ofT ₀+V such thatn coincides with a KAM torus are given, up to order , by a quantization formula which reduces to the Bohr-Sommerfeld one up to first order terms in .     

Quantum evolution and classical flow in complex phase space

For a class of holomorphic perturbations of the harmonic oscillator inn degrees of freedom a local solution of the time-dependent Schrödinger equation in the Bargmann representation is constructed which pointwise propagates, to leading order in , along the classical trajectories in complex phase space.     

Field theoretical construction of an infinite set of quantum commuting operators related with soliton equations

The quantum version of an infinite set of polynomial conserved quantities of a class of soliton equations is discussed from the point of view of naive continuum field theory. By using techniques of two dimensional field theories, we show that an infinite set of quantum commuting operators can be constructed explicitly from the knowledge of its classical counterparts. The quantum operators are so constructed as to coincide with the classical ones in the 0 limit (; Planck's constant divided by 2). It is expected that the explicit forms of these operators would shed some light on the structure of the infinite dimensional Lie algebras which underlie a certain class of quantum integrable systems.     

Isospectral transformations in relativistic and nonrelativistic mechanics

The modified Korteweg de-Vries hierarchy of partial differential equations generating transformations of the one-dimensional Dirac equation, is shown to reduce in the limitc to the Korteweg de-Vries hierarchy, generating isospectral transformations of the Schrödinger equation. The former hierarchy reduces into relativistic and the latter into nonrelativistic isoperiodic transformation in the limit0.     

Probability interpretation of particle(s) along classical trajectories

The theory of divergent series is used to show that the probability density of a wavemechanical state becomes classical trajectories (for a single particle or many interacting particles) in the limit 0. The probability interpretation is claimed to be valid even if a classical particle idea is inserted into the theory. The idea particle is claimed as a classical entity valid for 0. Finally, the double slit experiment is illustrated as an example and interpreted by the above theory. The interpretation is that the interaction between the incident and interference beams and the double slit is approximately described by the wave theory (interference mechanism).     

WKB properties of the time-dependent Schrödinger system

It is shown that the time-dependent WKB expansion highlights some of the hidden properties of the Schrödinger equation and forms a natural bridge between that equation and the functional integral formulation of quantum mechanics. In particular it is shown that the leading (zero- and first-order in ) terms in the WKB expansion are essentially classical, and the relationship of this result to the classical nature of the WKB partition function, and of the anomalies in quantum field theory, is discussed.     

Semi-classical asymptotics in solid state physics

This article studies the Schrödinger equation for an electron in a lattice of ions with an external magnetic field. In a suitable physical scaling the ionic potential becomes rapidly oscillating, and one can build asymptotic solutions for the limit of zero magnetic field by multiple scale methods from homogenization. For the time-dependent Schrödinger equation this construction yields wave packets which follow the trajectories of the semiclassical model. For the time-independent equation one gets asymptotic eigenfunctions (or quasimodes) for the energy levels predicted by Onsager's relation.     

The Biot-Savart-Ampère law and the vacuum fieldB (3)

It is shown that the longitudinal vacuum fieldB ⁽³⁾ emerges from the Biot-Savart-Ampère law governing the motion of an electron with intrinsic spin moving at the speed of light, in which case the expression forB ⁽³⁾ is identical with that obtained from the Dirac equation of one electron accelerated to the speed of light by an electromagnetic field. Use of an O(3), non-Abelian, gauge geometry forB ⁽³⁾ identifies the quantized photon momentum appearing in the Dirac equation witheA ⁽⁰⁾, wheree is the charge on the electron andA ⁽⁰⁾ the amplitude of the vector potential. The condition =eA ⁽⁰⁾ can be obtained in turn from the relativistic Hamilton-Jacobi equation of an electron accelerated to the speed of light by an electromagnetic field.     

The nonrelativistic Schrödinger equation in “quasi-classical” theory

The author has recently proposed a quasi-classical theory of particles and interactions in which particles are pictured as extended periodic disturbances in a universal field (x, t), interacting with each other via nonlinearity in the equation of motion for . The present paper explores the relationship of this theory to nonrelativistic quantum mechanics; as a first step, it is shown how it is possible to construct from a configuration-space wave function (x ₁,x ₂,t), and that the theory requires that satisfy the two-particle Schrödinger equation in the case where the two particles are well separated from each other. This suggests that the multiparticle Schrödinger equation can be obtained as a direct consequence of the quasi-classical theory without any use of the usual formalism (Hilbert space, quantization rules, etc.) of conventional quantum theory and in particular without using the classical canonical treatment of a system as a crutch theory which has subsequently to be quantized. The quasi-classical theory also suggests the existence of a preferred absolute gauge for the electromagnetic potentials.     

On the pointwise behavior of semi-classical measures

In this paper we concern ourselves with the small asymptotics of the inner products of the eigenfunctions of a Schrödinger-type operator with a coherent state. More precisely, let _j and E _j denote the eigenfunctions and eigenvalues of a Schrödinger-type operator H with discrete spectrum. Let _(x,) be a coherent state centered at the point (x, ) in phase space. We estimate as 0 the averages of the squares of the inner products ( _a ^(x,) , _j ) over an energy interval of size around a fixed energy, E. This follows from asymptotic expansions of the form for certain test function and Schwartz amplitudes a of the coherent state. We compute the leading coefficient in the expansion, which depends on whether the classical trajectory through (x, ) is periodic or not. In the periodic case the iterates of the trajectory contribute to the leading coefficient. We also discuss the case of the Laplacian on a compact Riemannian manifold.Research supported in part by NSF grant DMS-9303778     

A method of obtaining the rate of perihelion precession in a system of two charged masses

The motion of a charged test body around a massive charged source can be described by the Klein-Gordon equation with gravitational and electromagnetic fields. When this equation is transformed into a coordinate system rotating with angular velocity , it is found that for each state with=R(u)/uY _j,k (, ) expit, there is a corresponding rate of rotation _n,j,k at which the general reiativistic Klein-Gordon equation approximately simplifies into a Schrödinger-Kepler equation, whose characteristic energies differ from those of the equation for a hydrogenlike system because the coupling factorsGmM andqQ must be multiplied by (1+4E/mc ² ) and (1+2E/mc ² )^1/2, respectively, in the general reiativistic case. The energy levels in the fixed frame are found to be- _fixed = _rtating -k _n,j,k , wheren,j, k are the principal, angular momentum, and azimuthal quantum numbers. Applied to the case of a pair of rotating charged bosons of zero spin, the resulting fine structure agrees with the known fine-structure levels of this problem. Applied to the motion of Mercury around the Sun, the first-order calculation gives a rate of perihelion precession of 42.98 sec arc/century. If the Sun and Mercury had electrical chargesQ andq, then to the first order the rate of precession would be approximately 42.98 (1–3y) sec arc/century. (Herey is the ratio of the electric to gravitational force.) Consideration of upper limits on the field strength on the surfaces of the Sun and Mercury, indicated by Stark shifts and molecular binding energy, show that the electric part of the rate of precession, (–129y), is far below 0.1 sec arc/century, and so need not be considered in the test of general relativity based on Mercury's perihelion precession.     

Short-time propagator on curved spaces

It is shown that the standard WKB-approximation (the approximation of the first order in) to the propagator is not sufficient for the construction of the short-time propagator on curved spaces. The proper short-time propagator can be obtained by means of the second order (in) WKB-approximation and then no subtraction of a quantum correction proportional to ² from the original Lagrangian is necessary.The authors are indebted to J. Tolar for valuable critical comments and advices.     

On the extreme relativistic limit of arbitrary spin wave equations

The extreme relativistic limit (E-representation) of the wave equation in the Schrödinger formi/t =H describing particles and anti-particles of spin s and non-zero rest mass m is presented here. As the wave function has just the minimum number of 2(2s+1) components, the necessity of avoiding redundant components by auxiliary conditions does not arise. Relevant expressions are given for the infinitesimal generators of the Poincaré group and for the operators representing the observables in this representation.     

Notes on the classical and the nonrelativistic limits in quantum mechanics

A method is presented which can be used to discuss both the classical and also the nonrelativistic limit of quantum mechanics. A one-to-one correspondence may be established between the asymptotic convergence of the resolvent and that of the timedependent solution. In so far as the question of dynamics is concerned we investigate the relation between families of nonrelativistic Hamiltonians and the corresponding Dirac-Hamiltonians when c± or when c±0. The nonrelativistic free theory formally shows the same pattern when ±0 (the classical limit) or when ±. The investigation finally shows how the asymptotic convergence of the relativistic theory can take place under some fairly general conditions of the radiation field.     

Kac-Moody symmetry of generalized non-linear Schrödinger equations

The classical non-linear Schrödinger equation associated with a symmetric Lie algebra =km is known to possess a class of conserved quantities which from a realization of the algebrak []. The construction is now extended to provide a realization of the Kac-Moody algebrak[, ^–1] (with central extension). One can then define auxiliary quantities to obtain the full algebra [, ^–1]. This leads to the formal linearization of the system.     

Levinson's Theorem for the Schrödinger Equation in One Dimension

Levinson's theorem for the one-dimensional Schrödinger equation with asymmetric potential which decays at infinity faster thanx ^–2 is established by theSturm-Liouville theorem. The critical case where the Schrödinger equation hasa finite zero-energy solution is also analyzed. It is demonstrated that the numberof bound states with even (odd) parityn ₊(n _–) is related to the phase shift ₊ (0)[_– (0)] of the scattering states with the same parity at zero momentum as ₊ (0)+ /2 =n ₊ and _– (0) =n _– for the noncritical case, and ₊ (0) =n ₊ and_– (0) – /2 =n _– for the critical case.     

The simplified Fermi accelerator in classical and quantum mechanics

We review the simplified classical Fermi acceleration mechanism and construct a quantum counterpart by imposing time-dependent boundary conditions on solutions of the free Schrödinger equation at the unit interval. We find similiar dynamical features in the sense that limiting KAM curves, respectively purely singular quasienergy spectrum, exist(s) for sufficiently smooth wall oscillations (typically ofC ² type). In addition, we investigate quantum analogs to local approximations of the Fermi map both in its quasiperiodic and irregular phase space regions. In particular, we find pure point q.e. spectrum in the former case and conjecture that random boundary conditions are necessary to model a quantum analog to the chaotic regime of the classical accelerator.     

Spontaneous symmetry breaking in a time-dependent space-time

Spontaneous symmetry breaking of a ⁴ quantum of field theory in a time-dependent space-time, de Sitter space, is discussed in the Schrödinger picture. Instead of the usual cutoff method we use an-regularization procedure to deal with the divergent integrals.     

The Phase of a Quantum Mechanical Particle in Curved Spacetime

We investigate the quantum mechanical wave equations for free particles of spin 0, 1/2, 1 in the background of an arbitrary static gravitational field in order to explicitly determine if the phase of the wavefunction is S/ = p dx /, as is often quoted in the literature. We work in isotropic coordinates where the wave equations have a simple manageable form and do not make a weak gravitational field approximation. We interpret these wave equations in terms of a quantum mechanical particle moving in medium with a spatially varying effective index of refraction. Due to the first order spatial derivative structure of the Dirac equation in curved spacetime, only the spin 1/2 particle has exactly the quantum mechanical phase as indicated above. The second order spatial derivative structure of the spin 0 and spin 1 wave equations yield the above phase only to lowest order in . We develop a WKB approximation for the solution of the spin 0 and spin 1 wave equations and explore amplitude and phase corrections beyond the lowest order in . For the spin 1/2 particle we calculate the phase appropriate for neutrino flavor oscillations.     

Some results on electronic two- and one photon raman scattering in CdS

Two photon Raman scattering (TPRS) via virtually excited biexcitons is observed in CdS over a rather large spectral region in a scattering configuration which favours stimulated emission. We observe either a pure longitudinal exciton or-for the first time—a bound exciton (I ₂) as final state particles. Furthermore, the anomaly in the relation between _exc and _R at _exc= E_blex is observed for the first time in a II–VI compound, indicating an energy of the ₁ biexciton level of 5.098 eV in agreement with two photon absorption measurements. With an applied magnetic fieldB, the corresponding shift of the exciton eigenenergies can be observed. For the longitudinal exciton, the diamagnetic shift is 0.35 meV atB=10T forBc in agreement with theoretical predictions. In this configuration also a stimulated one photon spin flip Raman scattering is observed, yielding the well known electronicg-value of 1.78.