共查询到20条相似文献,搜索用时 15 毫秒
1.
Preparation,Structural Determination,and Characterization of Electronic Properties of Bis‐silylated and Bis‐germylated Lu3N@Ih‐C80 下载免费PDF全文
Prof. Dr. Masahiro Kako Kyosuke Miyabe Dr. Kumiko Sato Dr. Mitsuaki Suzuki Dr. Naomi Mizorogi Dr. Wei‐Wei Wang Prof. Dr. Michio Yamada Prof. Dr. Yutaka Maeda Prof. Dr. Marilyn M. Olmstead Prof. Dr. Alan L. Balch Prof. Dr. Shigeru Nagase Prof. Dr. Takeshi Akasaka 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(46):16411-16420
Bis‐silylated and bis‐germylated derivatives of Lu3N@Ih‐C80 ( 3 , 4 , 5 ) were successfully synthesized by the photochemical addition of disiliranes 1 a , 1 b or digermirane 2 , and fully characterized by spectroscopic, electrochemical, and theoretical studies. Interestingly, digermirane 2 reacts more efficiently than disiliranes 1 a and 1 b because of its good electron‐donor properties and lower steric hindrance around the Ge?Ge bond. The 1,4‐adduct structures of 3 , 4 , 5 were unequivocally established by single‐crystal X‐ray crystallographic analyses. The electrochemical and theoretical studies reveal that the energy gaps between the highest occupied molecular orbital (HOMO) and the lowest unoccupied molecular orbital (LUMO) of the 1,4‐adducts are remarkably smaller than those of Lu3N@Ih‐C80, because the electron‐donating groups effectively raise the HOMO levels. It is also observed that germyl groups are slightly more electron‐donating than the silyl groups on the basis of the redox properties and the HOMO–LUMO energies of 4 and 5 . Bis‐silylation and bis‐germylation are effective and versatile methods for tuning the electronic characteristics of endohedral metallofullerenes. 相似文献
2.
Inside Back Cover: Isolation of CeLu2N@Ih‐C80 through a Non‐Chromatographic,Two‐Step Chemical Process and Crystallographic Characterization of the Pyramidalized CeLu2N within the Icosahedral Cage (Chem. Eur. J. 29/2015) 下载免费PDF全文
Prof. Dr. Steven Stevenson Hannah R. Thompson Kristine D. Arvola Kamran B. Ghiassi Prof. Dr. Marilyn M. Olmstead Prof. Dr. Alan L. Balch 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(29):10579-10579
3.
4.
《化学:亚洲杂志》2017,12(12):1391-1399
Photochemical carbosilylation of Sc3N@Ih ‐C80 with silirane 1 afforded two corresponding [5,6]‐adducts, 2 and 3 , and a [6,6]‐adduct, 4 . The structural and electronic properties of these products were characterized by means of spectroscopic, electrochemical, and theoretical methods. The structure of 2 was disclosed by means of single‐crystal X‐ray crystallographic analysis. Thermal isomerization of 3 to 2 was observed, whereas that of 2 to 3 proceeded less efficiently at 100 °C. Upon heating under the same conditions, adduct 4 underwent facile decomposition to afford Sc3N@Ih ‐C80, or isomerized into small amounts of 2 and 3 . The relative stabilities of 2 , 3 , and 4 were rationalized through the results of theoretical calculations. In contrast, adducts 2 , 3 , and 4 were stable under the photolytic conditions employed for carbosilylation. The photochemical functionalization of Sc3N@Ih ‐C80 represents a convenient synthetic method to obtain thermally labile fullerene‐based products. 相似文献
5.
Inside Cover: Modular Synthesis of Linear Bis‐ and Tris‐monodentate Fused [6]Polynorbornane‐Based Ligands and their Assembly into Coordination Cages (Chem. Eur. J. 10/2015) 下载免费PDF全文
Mark D. Johnstone Eike K. Schwarze Prof. Dr. Guido H. Clever Dr. Frederick M. Pfeffer 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(10):3834-3834
6.
Cover Picture: Peptoid‐Ligated Pentadecanuclear Yttrium and Dysprosium Hydroxy Clusters (Chem. Eur. J. 7/2015) 下载免费PDF全文
Dr. Dominique T. Thielemann Anna T. Wagner Dr. Yanhua Lan Dr. Pascual Oña‐Burgos Prof. Dr. Ignacio Fernández Prof. Dr. Esther S. Rösch Dr. Dominik K. Kölmel Prof. Dr. Annie K. Powell Prof. Dr. Stefan Bräse Prof. Dr. Peter W. Roesky 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(7):2709-2709
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
Cover Picture: Coordination Chemistry of N‐Heterocyclic Nitrenium‐Based Ligands (Chem. Eur. J. 19/2015) 下载免费PDF全文
Dr. Yuri Tulchinsky Dr. Sebastian Kozuch Dr. Prasenjit Saha Assaf Mauda Dr. Gennady Nisnevich Dr. Mark Botoshansky Dr. Linda J. W. Shimon Prof. Mark Gandelman 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(19):6965-6965
17.
18.
19.
20.
Lucy Rutten Dr. Birgit Wieczorek Jean‐Paul B. A. Mannie Cornelis A. Kruithof Dr. Harm P. Dijkstra Dr. Maarten R. Egmond Prof. Martin Lutz Dr. Robertus J. M. Klein Gebbink Prof. Piet Gros Prof. Gerard van Koten Prof. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2009,15(17):4211-4211
The interfacial enzyme cutinase…? shown at the air–water interface on the cover, was site‐selectively modified with two different ECE‐pincer–metal complexes. The resulting cutinase–pincer–metal hybrids crystallized under halide‐rich conditions to give monomeric crystal structures, but also crystallized under halide‐poor conditions to form a metal‐induced dimer. See the Full Paper by R. J. M. Klein Gebbink, P. Gros, G. van Koten et al. on page 4270 ff. , for details of the chemistry and the crystal structures. Photograph: View from the island of Saba (Netherlands Antilles) taken by Birgit Wieczorek. Design: Birgit Wieczorek and Cornelis A. Kruithof.