Transition from small to big charged unilamellar vesicles

The transition from small to big unilamellar vesicles predicted by a Poisson-Boltzmann Cell Model for the thermodynamics of a dilute phase of unilamellar charged vesicles is characterized. The radius as a function of experimental parameters is calculated and the coexistence region of small and big vesicles is identified. We further investigate the physical meaning in terms of simplified models, which allow for an identification of the role of parameters like the surface charge density or the Debye-length. Connections to experiments are discussed. Received: 20 October 1997 / Received in final form: 9 February 1998 / Accepted: 9 March 1998     

Superluminal pulse propagation in an erbium fiber laser

It is well known that saturating gain media can give rise to superluminal pulse propagation velocity. In most mode-locked lasers the effect is unmeasurably small and has not yet been directly demonstrated. We present experiments on the initial transient of an erbium fiber laser that show a dynamic shift in the propagation velocity to a value larger than the medium’s linear group velocity as the pulse builds up. Received: 14 December 1998 / Revised version: 21 May 1999 / Published online: 25 August 1999     

The effect of doping and processing conditions on the optical performance of Rh:BaTiO3

We demonstrate the advantages of using high levels of rhodium (2000–3200 ppm) to dope barium titanate for achieving finite absorption coefficients (0.36 cm^-1), high two-beam coupling gain (11.5 cm^-1), and acceptable response time (7 s) at 1.06 μm. We also report on the mass spectroscopy measurements on Rh:BaTiO₃ samples indicating a small segregation coefficient for rhodium (below 0.01) and the presence of a relatively large concentration (6000 ppm) of unintentionally added strontium. Received: 20 November 1998 / Revised version: 25 January 1999 / Published online: 12 April 1999     

Laser spectroscopy with a pulsed, narrowband infrared optical parametric oscillator system: a practical, modular approach

-1 in a single scan. The potential of the OPO system for linear and nonlinear-optical spectroscopy is demonstrated by recording high-resolution photoacoustic absorption and coherent anti-Stokes Raman spectra of methane, as a gas and in a pulsed supersonic free jet. This narrowband tunable infrared source is shown to scan reliably with an optical bandwidth as small as 0.007 cm^-1 (210 MHz) full width half maximum (fwhm), close to the fourier-transform limit. Received: 5 February 1998/Revised version: 6 March 1998     

Strain relaxation at cleaved surfaces studied by atomic force microscopy

Atomic force microscopy (AFM) in air is used to study the (110) cleaved surface of strained (100) In_xGa_1-xAs/ InP heterostructures for different compositions and thicknesses of the ternary compound layers. We find that the elastic strain relaxation induces a surface undulation of a few ? amplitude, even for very small misfits, provided the layers are thick enough. Using finite-element calculations of the strain relaxation near the cleaved edge, we reproduce quantitatively the AFM observations for compressive- as well as for tensile-strained layers with an accuracy better than 0.1 nm. This demonstrates the ability of AFM to quantify strain distributions by making use of surface profile measurements. Received: 9 November 1998 / Accepted: 11 March 1999 / Published online: 7 July 1999     

Spontaneous SU(2) symmetry breaking in one-dimensional quantum antiferromagnet

We present a Bethe Ansatz based investigation of a one-dimensional (1D) Heisenberg spin chain in a real 3D crystal lattice. We have shown that due to an influence of the lattice distortion on a crystalline field of ligands of magnetic ions, a Heisenberg antiferromagnetic spin chain is unstable under the appearance of a magnetic anisotropy of the “easy-plane” type. The effects of an external magnetic field and nonzero temperature onto such a phase transition are studied. Received: 19 January 1998 / Revised: 16 March 1998 / Accepted: 17 March 1998     

Study of transient photorefractive beam coupling in high- and low-molar-mass liquid crystal mixtures

We observed transient signals of Bragg grating formation in high-performance photorefractive high- and low-molar-mass liquid crystal mixtures (HL-LCMs). These transient signals including oscillation-like behavior can be explained by a complex time constant in the case of a finite applied dc field. The time constant for the space-charge field to reach its steady state and the oscillation frequency are estimated. Received: 30 October 1998 / Revised version: 14 December 1998 / Published online: 24 February 1999     

A tunable diode laser system for the remote sensing of on-road vehicle emissions

2 O, and NO₂ emissions have been measured with this instrument. The system is also capable of measuring CO, NH₃, H₂CO, CH₃OH, and other small molecules in vehicle exhaust. Received: 18 May 1998/Revised version: 1 July 1998     

Saturation spectroscopy of the A-X transition of the ICl molecule

We describe the first saturation spectroscopy experiment concerning the A-X transition of ICl with considerably better resolution than previous works. Form our data, improved constants for the hyperfine structure of the excited state are determined. The A-X transition of ICl could be used to develop a set of secondary frequency standards and its metrologic qualities are discussed. Received: 27 July 1998 / Received in final form: 30 November 1998     

An energy approach to the modelling of particle removal by pulsed laser irradiation

An energy model to explain particle removal mechanism has been developed. This model is based on a detailed investigation of contact deformation of a particle on a solid surface, as well as particle motion during the process of substrate surface expansion under uniform laser irradiation. Calculation results show that small particles mainly gain kinetic energy during pulsed laser irradiation, whereas large particles mainly gain elastic deforming potential energy. The particle removal condition is derived from the viewpoint of energy. The relationship of particle removal efficiency with laser fluence and particle size is discussed. Theoretical results are compared with experimental results. Received: 30 July 1998 / Accepted: 14 December 1998 / Published online: 17 March 1999     

Holographic recording in amorphous side-chain polymers: a comparison of two different design philosophies

Recently, Bieringer et al. [1] reported on the optical properties of liquid-crystalline side-chain polymers. These photoaddressable systems showed light-induced modulations Δn of their refractive index of up to 0.06. We present similar materials and compare them with a novel ansatz reaching birefringence levels of up to 0.2 [2]. This was achieved by donor–acceptor substitutions of the chromophores and by introducing a new type of second side chain. We discuss the different photophysical properties of the two materials under the point of view of potential applications. Received: 16 November 1998 / Revised version: 18 December 1998 / Published online: 7 April 1999     

Etalon effect in wave-mixing experiments with photorefractive crystals

We present investigations of the etalon effect in sillenite photorefractive crystals with a pulsed frequency-doubled Nd:YAG laser and show its influence on two- and four-wave mixing. In four-wave mixing the etalon effect allows changes of the diffraction efficiency by more than 80%. Results are supported by theoretical considerations. Received: 15 April 1998/Revised version: 19 June 1998     

Theory of EPR on a rotating sample: An illustration of Berry's phase

We describe the theory of EPR in a crystal field multiplet under sample spinning. Berry phases arise because the crystal field is of lower symmetry than the full rotation group. The formal development is limited to pure J multiplets, crystal field doublets, and field and rotation axes parallel to a principal axis. Received: 4 August 1997 / Received in final form: 19 December 1997 / Accepted: 28 January 1998     

Laser emission under flashlamp pumping of a new crystal: Nd-doped strontium-lanthanum-aluminate (Nd:ASL)

1-x Nd_yLa_x-yMg_xAl_12-xO₁₉) is a new material, tunable in the 1–1.1 μm band. We present the first results of pulsed laser emission of this crystal under flashlamp pumping. We obtain a slope efficiency of 3.3% with a maximum average power of 40 W at 40 Hz in free-lasing regime. Nd:Cr codoping of ASL is also tested, but with much lower efficiency. Received: 12 June 1998/Revised version: 30 September 1998     

A method for single-pass distortion correction using holography in rhodium-doped barium titanate

We present a holographic method of one-way image transmission with ‘real-time’ correction of distortion through an optical system. The technique is demonstrated using a crystal of photorefractive rhodium-doped barium titanate as the holographic medium and corrects for phase distortions imposed upon a US Air Force test chart. This technique is suitable for applications in both cw and pulsed regimes, and for either fixed or changing distortions. Received: 26 October 1998 / Revised version: 19 December 1998 / Published online: 12 April 1999     

Size-selected, supported clusters: the interaction of carbon monoxide with nickel clusters

We report on the size-dependent chemical reactivity of nickel clusters with up to 30 atoms. Monodispersed Ni₃₀ clusters show a higher reactivity for CO dissociation than Ni₁₁ and Ni₂₀. Under our experimental conditions the smallest nickel clusters (Ni_x, x<4) produce nickelcarbonyl complexes. These results demonstrate that such small clusters are unique for catalytic reactions not only due to their high surface-to-volume ratio but also essentially because of the distinctive properties of different cluster sizes. In addition thermal desorption spectroscopy of CO shows that on average four molecules are weakly adsorbed per Ni₁₁ at saturation coverage. Using an isotopic mixture of ¹²CO and ¹³CO, infrared spectroscopy reveals the existence of a vibrational coupling interaction between the four COs. A semi-classical model of interacting dipoles is applied to correlate the observed vibrational frequency shifts with the arrangement of the COs on the cluster. This simple analysis favors a three-dimensional structure for the deposited clusters. Received: 23 March 1998/Accepted: 25 August 1998     

Transverse effects and mode couplings in OPOS

00 pump field. The corresponding differential equations for the time evolution of the self-consistent mode amplitudes are derived for typical cavity geometries including the propagation integrals within the crystal. We discuss the new physical effects introduced by these couplings in some typical cases. This includes a change of the OPO threshold and stable simultaneous oscillation of several mode pairs with fixed relative phases as well as oscillating self-pulsing type solutions. Received: 12 January 1998/Accepted: 11 February 1998     

Flashlamp-pumped Nd:KGW laser in MOPA configuration: comparative study of several rods

The laser performance of the Nd:KGW crystal has been studied in a master oscillator and power amplifier configuration (MOPA). Several crystals from two different producers were investigated for the oscillator and the amplifier. A maximum single-pass gain of 25 was observed in free-running and Q-switched mode. We obtained a maximum output amplified energy of 400 mJ at 30 Hz (with a pulse duration of 10 to 30 ns) with a divergence less than 3 mrad. We also studied the limitations of this configuration due to the very high gain of the Nd:KGW crystal. Received: 21 September 1998 / Revised version: 10 January 1999 / Published online: 19 May 1999     

Non-steady-state photocurrents in SnS2 crystals

We report on non-steady-state photocurrent measurements of SnS₂ grown by vapor transport method. The main characteristics of photoinduced carriers, such as type of photoconductivity, average diffusion length, dielectric relaxation time, and the Debye screening length, were estimated for the excitation wavelengths in the red and blue region of the spectrum. Received: 12 November 1998 / Revised version: 22 December 1998 / Published online: 31 March 1999     

Intracavity frequency-tripling of actively mode-locked diode-pumped Nd:YAG laser

We report the first diode-pumped solid-state laser operating in cw-mode-locked regime and simultaneously achieving intracavity frequency-tripling. This laser provide UV picosecond pulses (λ=355 nm) of 10 ps duration with 0.5 mW average power at 150 MHz repetition rate. A different set of adjustments gave rise to a Q-switched mode-locked regime. Trains of hundred UV pulses of 60 ps duration and 4 W peak power were produced in this latter case at 50 kHz repetition rate. Received: 12 October 1998 / Revised version: 12 December 1998 / Published online: 26 May 1999