Hard tissue ablation with a free running Er:YAG and a Q-switched CO2 laser: a comparative study

The Er:YAG and the CO₂ laser are competitors in the field of hard tissue ablation. The use of Er:YAG lasers (2.94 μm, pulse length _L of 100 to 200 μs) show smaller areas of thermal defects then ‘‘superpulsed’’ CO₂ lasers with pulse lengths of approximately 100 μs. Only the development of a Q-switched CO₂ laser (9.6 μm, τ_L=250 ns) allowed for similar results. In this paper new results for the Er:YAG and the Q-switched CO₂ laser under the influence of water spray will be presented. Several parameters are of special interest for these investigations: the specific ablation energy, which shows a minimum for the CO₂ laser at an energy density of 9 J/cm ² and a broad shallow minimum in the range of 10 to 70 J/cm² for the Er:YAG laser, and comparison of the cut-shape and depth. Surface effects and cutting velocity are discussed based on SEM pictures. Received: 19 July 2000 / Revised version: 1 November 2000 / Published online: 30 November 2000     

Lasers for materials processing: specifications and trends

An overview is given of the types of lasers dominating the field of laser materials processing. The most prominent lasers in this field are the CO₂ and the Nd: YAG laser. The domain of CO₂ lasers is applications which demand high laser powers (up to 30 kW are available at present), whereas the domain of Nd:YAG lasers is micro-machining applications. In the kilowatt range of laser output power, the two types of lasers are in competition. New diffusion-cooled CO₂ laser systems are capable of output laser powers of several kilowatts, with good beam qualities, while still being quite compact. The output power and beam quality of Nd:YAG lasers has been improved in recent years, so that Nd:YAG lasers are now an alternative to CO₂ lasers even in the kilowatt range. This is especially true for applications that demand optical fibre transmission of the laser beam, which is possible with Nd:YAG laser light but not with the longerwavelength light emitted by CO₂ lasers. The main problem in solid-state lasers such as Nd:YAG is the thermal lensing effect and damage due to thermal stresses. In order to reduce thermal loading, cooling has to be enhanced. Several alternative geometries have been proposed to reduce thermal loading and, by this, thermal lensing effects. There are now slab and tube geometries which allow much higher output powers than the conventionally used laser rods. A very new scheme proposes a thin slab whose cooled side is also used as one of the laser mirrors, so that thermal gradients occur mainly in the direction of the beam propagation and not perpendicular to it, as is the case in the other geometries. As well as CO₂ and Nd:YAG lasers, semiconductor laser diodes are very promising for direct use of the emitted light or as pump sources for Nd:YAG and other solid-state lasers. When packaging together thousands of single laser diodes, output powers of several kilowatts can be realized. Major problems are collimation of the highly divergent laser beams and cooling of the laser diode bars.     

Remote sensing of volcanic gases with a DFB-laser-based fiber spectrometer

We demonstrate monitoring of H₂O and CO₂ emitted in a volcanic area, using a spectrometer equipped with two distributed feedback (DFB) semiconductor diode lasers. Each laser is resonant with a molecular species and is fiber-coupled to allow remote operation of the spectrometer. Recordings of H₂O and CO₂ lines made at the Solfatara volcano, in southern Italy, are shown, and the application of such a spectrometer as a new tool for the continuous monitoring and surveillance of volcanoes is discussed. Received: 28 June 1999 / Revised version: 20 December 1999 / Published online: 23 February 2000     

Design considerations and scaling laws for high power convective cooled CW CO2 lasers

Various criteria for designing high power convective cooled CO₂ lasers have been discussed. Considering the saturation intensity, optical damage threshold of the optical resonator components and the small-signal gain, the scaling laws for designing high power CW CO₂ lasers have been established. In transverse flow CO₂ lasers having discharge of square cross-section, the discharge lengthL and its widthW for a specific laser powerP (Watt) and gas flow velocityV (cm/s) can be given byL = 1.4 x 10⁴ p ^1/2 V ^-1 cms andW = 0.04P ^1/2 cms. The optimum transmitivity of the output coupler is found to be almost constant (about 60%), independent of the small signal gain and laser power. In fast axial flow CO₂ lasers the gas flow should be divided into several discharge tubes to maintain the flow velocity within sonic limit. The discharge length in this type of laser does not depend explicitly on the laser power, instead it depends on the input power density in the discharge and the gas flow velocity. Various considerations for ensuring better laser beam quality are also discussed.     

Theoretical prediction on the wavelength-temperature shift in pulsed TE CO2 lasers

The wavelength-temperature shift observed in pulsed TE CO₂ lasers is discussed theoretically by means of Six-temperature model rate equations for tunable TE CO₂ lasers. Numerical calculations of the temperature-wavelength shift in a pulsed TE CO₂ laser with a simple plano-concave stable resonator, whether excited by conventional low-inductance fast-discharge scheme or by a long-pulse Pulser/sustainer discharge scheme, show that the laser output wavelengths are within the 10P branch as the ambient temperature varies from 228 to 338 K, but will change as the ambient temperature varies. The laser output wavelengths will move to the transition lines with longer wavelengths in the 10P branch as the ambient temperature increases and vice versa. The calculated results also illustrate that near the ambient temperature of 310 K, the laser is more likely to operate on multi-transition lines. Considering this wavelength-temperature shift, the chilling device adopted in high-power high repetition rate TE CO₂ lasers is important in maintaining a stable laser output spectra as well as a stable laser output power. The numerical results also suggest that a frequency agile resonator is highly recommended if stable laser output spectra are required in TE CO₂ lasers.     

CO2 laser drives extreme ultraviolet nano-lithography — second life of mature laser technology

It was shown both theoretically and experimentally that nanosecond order laser pulses at 10.6 micron wavelength were superior for driving the Sn plasma extreme ultraviolet (EUV) source for nano-lithography for the reasons of higher conversion efficiency, lower production of debris and higher average power levels obtainable in CO₂ media without serious problems of beam distortions and nonlinear effects occurring in competing solid-state lasers at high intensities. The renewed interest in such pulse format, wavelength, repetition rates in excess of 50 kHz and average power levels in excess of 18 kiloWatt has sparked new opportunities for a matured multi-kiloWatt CO₂ laser technology. The power demand of EUV source could be only satisfied by a Master-Oscillator-Power-Amplifier system configuration, leading to a development of a new type of hybrid pulsed CO₂ laser employing a whole spectrum of CO₂ technology, such as fast flow systems and diffusion-cooled planar waveguide lasers, and relatively recent quantum cascade lasers. In this paper we review briefly the history of relevant pulsed CO₂ laser technology and the requirements for multi-kiloWatt CO₂ laser, intended for the laser-produced plasma EUV source, and present our recent advances, such as novel solid-state seeded master oscillator and efficient multi-pass amplifiers built on planar waveguide CO₂ lasers.     

Novel considerations of functions of helium and nitrogen in a fast flow CO2 laser

In a research of fast axial flow CO₂ laser sustained by 150 kHz silent discharge, we found the optimized gas mixing ratio was CO₂:N₂:He=1:22:5 or the content of helium was only about 18%. This result upset the situation of common CO₂ lasers in which the most important laser gas is helium. An explanation of our particular results and supporting experimental evidence are given.     

Diffractive scanning mechanism for laser marker

We present a new idea of marking based on spectral properties of CO₂ laser radiation. The idea has been illustrated on RF excited waveguide CO₂ lasers in different configurations: single channel, multi-waveguide and slab-waveguide ones. The pulse operation of the laser has been considered as well. The advantage of the presented diffraction marker is avoiding complicated and fallible mechanical elements. The only executive elements of the marker are a diffraction grating and a piezoceramic transducer. It has been shown that the slab-waveguide configuration of the RF excited CO₂ laser equipped with an unstable resonator is the most promising configuration for application to the diffraction marker.     

Amplification and measurement of single 1.6–3.5 ps Pulses generated by a distributed feedback dye laser

Twenty FIR laser lines with wavelengths between 146 and 2000 m have been observed from deuterated formyl fluoride (DCOF) optically pumped with isotopic CO₂ lasers. Tunable diode laser measurements on thev ₄ band of DCOF were combined with earlier high precision spectroscopic data on thev ₃ andv ₄ bands, and enabled identification of the transitions responsible for 9 of the new FIR lines.     

Coherent tunable far infrared radiation

Tunable, cw, far infrared (FIR) radiation has been generated by nonlinear mixing of radiation from two CO₂ lasers in a metal-insulator-metal, (MIM) diode. The FIR difference-frequency power was radiated from the MIM diode antenna to a calibrated indium antimonide bolometer. Two-tenths of a microwatt of FIR power was generated by 250 mW from each of the CO₂ lasers. Using the combination of lines from a waveguide CO₂ laser, with its larger tuning range, with lines from CO₂, N₂O, and CO₂ isotope lasers promises complete coverage of the entire far infrared band from 100 to 5000 GHz (3–200 cm^–1) with stepwise-tunable cw radiation.Contribution of the National Bureau of Standards, not subject to copyright     

Novel colliding plasma pulse clipper and optical isolator for high power infra-red lasers

The properties of a high density plasma focus produced inside a ring target with an Nd laser have been investigated. Studies of the axial propagation of a CO₂ laser beam through the plasma focus have shown that the device can be used either as a fast pulse clipper or as an optical isolator for high power infra-red lasers. Self-focussing, strong refraction and defocussing and non-classical absorption of the CO₂ laser beam have all been observed.     

Effect of the active medium temperature on the operation of fast-flow CO2 lasers

A new formula is obtained for estimating the output power of fast-flow CO₂ lasers. It is shown that a higher specific output power of these CO₂ lasers in comparison with sealed-off CO₂ lasers is caused mainly by the higher saturation intensity of the former. It is concluded that the temperature of the laser active medium affects almost only the charge stability and that, under stable discharge conditions, the same output power can be obtained at different temperatures of the active medium.     

CO2 gas resonance absorption at CO2 laser wavelength in?multiple laser coating

Multiple laser beams demonstrate many advantages as energy sources in diamond synthesis. In a reported amazingly-fast multiple laser coating technique, CO₂ gas is claimed as the sole precursor or secondary precursor for forming a diamond or diamond-like carbon, which remains poorly understood. The absorption coefficient changes under the irradiation of multiple lasers are one of the keys to resolve the mysteries of multiple laser beam coating processes. This study investigates the optical absorption in CO₂ gas at the CO₂ laser wavelength. The resonance absorption process is modeled as an inverse process of the lasing transitions of CO₂ lasers. The well-established CO₂ vibrational-rotational energy structures are used as the basis for the calculations with the Boltzmann distribution for equilibrium states and the three-temperature model for non-equilibrium states. Based on the population distribution, our predictions of the CO₂ absorption coefficient changes as a function of temperature are in agreement with the published data.     

Efficient ablation of organic polymers polyether sulphone and polyether ether ketone by a TEA CO2 laser with high perforation ability

Organic polymer (PES: PolyEther Sulphone and PEEK: PolyEther Ether Ketone) ablation with oscillation-line selected TEA CO₂ lasers is successfully demonstrated. With different irradiation conditions the ablative etch-rate slopes were varied, which means that the ablation process is dependent on the ablation conditions such as incident laser intensity and ambient gas. In perforation processing of the PEEK film, the TEA CO₂ laser had a higher etch rate of 42 m/pulse at a fluence of 70 J/cm² in vacuum than the XeCl laser.     

Diffusion of excited state molecules in FIR- and CO2-lasers

Both standing waves in laser oscillators and spatially inhomogenous cross sections of laser beam and pumprate cause a non-uniform distribution of excited state molecules in longitudinal and transversal direction, respectively. This spatial hole burning however is smoothed by diffusion of the excited molecules. The effect of diffusion is investigated theoretically for an optically pumped far infrared laser as well as the corresponding CO₂ pump laser. It is found, that the remaining spatial hole burning in the direction of wave propagation is negligible within CO₂ lasers but not within FIR lasers. Concerning the transversal direction it can be shown that in the FIR laser diffusion takes no effect, whereas the transversal distribution of the excited molecules in the CO₂ laser is significantly influenced by diffusion.FIR ring lasers avoid longitudinal spatial hole burning, which leads to the common assumption that they use the active medium more efficient than conventional standing wave lasers, hence delivering higher output powers. This expected advantage is levelled out to a great extent by diffusion.     

Modeling of Plasma-Chemical Reactions in Gas Mixture of CO2 lasers. II. Theoretical Model and its Verification

In the paper we have modelled plasma-chemical reactions in the CO₂ low pressure, DC excited lasers. A good agreement of theoretical and experimental results has been achieved. It has been proved that neglect of reactions with electronic excited species or heterogeneous recombination leads to almost 50% overestimation of CO₂ equilibrium conversion. The relation of CO₂ equilibrium conversion to the reduced field E/N, pressure and current density depends on discharge conditions and mainly on the role played in discharge by ambipolar diffusion. This role decreases with an increase of the discharge diameter and of the mixture convection velocity. The CO₂ equilibrium conversion increases with growth of E/N and j and with decrease of pressure for discharges in small, sealed-off laser systems. The CO₂ equilibrium conversion is not always a monotone function of p in large, convection cooled lasers. It does not depend so much on E/N as the electron temperature alone if conversions in different mixtures are compared.     

Modelling of RF CO2 Laser Pulses

The usual laser rate equations have been applied to fit energy and shape of pulsed emissions of RF CO₂ single mode lasers starting from the discharge and cavity parameters. The model well reproduce the laser behaviour, if to fit the turn-off normally observed in these lasers we introduce a phase laser gain correction related to the frequency chirp.     

Near-infrared trace-gas sensors based on room-temperature diode lasers

2 monitor designed for field applications using room-temperature diode lasers are presented. Near-infrared DFB lasers operating at 1.57 μm and around 2.0 μm have been used for CO₂ measurements. At ambient concentration levels a resolution of more than two orders of magnitude has been demonstrated at 1.57 μm, at 2 μm the precision is in the order of 0.1 ppm CO₂, and for trace analysis a detection limit of 10 ppb has been obtained. The measurements demonstrate the capability of near-infrared DFB diode lasers for the precise determination of CO₂ concentrations as required for climatological, medical, or industrial applications. Received: 24 February 1998/Revised version: 27 April 1998     

Dynamical analysis of acousto-optically Q-switched CO2 laser

A compacted size high power CO₂ laser has been developed using an acousto-optically (AO) Q-switch. Performance characteristics have been investigated as a function of output mirror transmittance. The theory of six-temperature model for CO₂ lasers has firstly been utilized to analyze the dynamical process in the AO Q-switched CO₂ laser. This theory perfectly explains the behavior of energy transfer between different molecules in laser gain medium, and describes the shape of pulse laser. The calculated pulse waveforms are in good agreement with the experimental result. Both the experimental and theoretical results present that the optimal value of output mirror transmittance is 39%. Under this condition, the measured peak power is 4750 W and pulsed width is 160 ns, which is consistent with the calculations. Six-temperature model is a perfect theory for CO₂ laser kinetics, which will lay a theoretical foundation for the laser optimum design.     

Study of dielectric corona pre-ionization in hybrid TEA lasers

In this paper a theoretical analysis of single mode hybrid CO₂ lasers is studied that to describe the process of the dynamic emission in this lasers types and based on the Landau – Teller six-temperature model for the CO₂-N₂-He-CO system. The main discharge region is considered as a time dependent nonlinear RLC circuit. The electric circuit equations (including the ionization rate equations), the equations of laser (including stored energy density in CO₂ modes) and equations of laser intensities are coupled and solved numerically. Then the effects of the ionizer dielectric parameters on the output laser intensity are obtained. Application of this model gives more output energy than that have obtained by the previous works.