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含间苯基聚醚醚酮酮的合成与性能研究 总被引:5,自引:0,他引:5
含间苯基聚醚醚酮酮的合成与性能研究林权,王一凡,张万金,吴忠文,尹玖梅(吉林大学化学系,长春,130023)(中国科学院长春应用化学研究所)关键词聚醚醚酮酮,间苯基,熔点,玻璃化转变温度聚芳醚酮类高聚物具有优异的热、电、机械性能.全对苯基位聚醚醚酮酮... 相似文献
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酞侧基聚芳醚酮的热学性能谢红卫,李滨耀(中国科学院长春应用化学研究所长春130022)关键词酞侧基聚芳醚酮,pvT行为,导热系数,定压比热容酞侧基聚芳醚酮(PEK-C)具有较高的玻璃化转变温度,其流变加工性能和力学性能已被广泛研究[1~3],被证明是... 相似文献
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氢键型聚芳醚酮共聚物的合成与表征 总被引:1,自引:0,他引:1
氢键型聚芳醚酮共聚物的合成与表征王忠刚,陈天禄,徐纪平(中国科学院长春应用化学研究所长春1300220)关键词氢键,聚芳醚酮,合成,表征高分子链之间的氢键相互作用可以有效地提高聚合物的性能[1,2].本工作通过共聚反应,在酚酞型聚芳醚酮PEK-C分子... 相似文献
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酞侧基聚芳醚酮的撕裂不稳定性韩艳春,杨宇明,李滨耀,冯之榴(中国科学院长春应用化学研究所长春130022)关键词酞侧基聚芳醚酮,撕裂不稳定性,延性撕裂由Paris等[1]根据弹塑性断裂理论发展的撕裂模量理论是表征延性材料失稳的重要理论之一。当裂纹扩展... 相似文献
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分子结构对聚芳醚酮薄膜透气性的影响 总被引:1,自引:0,他引:1
分子结构对聚芳醚酮薄膜透气性的影响王忠刚,陈天禄,徐纪平(中国科学院长春应用化学研究所长春130022)关键词聚芳醚酮,气体分离膜,结构-性能关系为了改善聚合物薄膜的透气性能,开发具有高透气性和高选择性的膜材料,人们对膜分子结构与透气性能间的关系进行... 相似文献
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通过模型化合物ArOArCOArArCOArOAr(Ar为苯基或1,4-亚苯基)的全优化模型,得到芳环之间的平均二面角为37.5°,由其结构参数建立了刚性链聚芳醚酮(砜)类均聚物分子结构与其熔点及玻璃化温度的关系式,据此较好地了预测了新品种均聚物的热性能。 相似文献
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几种Cardo聚芳醚砜膜的气体透过行为王忠刚,陈天禄,徐纪平(中国科学院长春应用化学研究所长春130022)关键词Cardo聚芳醚砜,膜,气体分离近年来的研究结果表明:同时增加聚合物的自由体积和限制分子链的链段活动性可以同时改善聚合物的气体透过系数和... 相似文献
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Willart JF Hédoux A Guinet Y Danède F Paccou L Capet F Descamps M 《The journal of physical chemistry. B》2006,110(23):11040-11043
Kinetic investigations of the polymorphic form alpha of anhydrous trehalose have been performed below its apparent melting temperature (Tm) by differential scanning calorimetry (DSC) and X-ray diffraction. The results reveal a spontaneous isothermal vitrification process which indicates that the phase alpha is in a very unusual superheating situation. This behavior has been attributed to the fact that the effective melting temperature (Tm(eff)) of the phase alpha is likely to be located far below the glass transition temperature (Tg) of this compound. The high viscosity of the liquid trehalose between Tm(eff) and Tg is thus invoked to explain the long lifetime of the phase alpha in this temperature range. 相似文献
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Mehta Sanjay Raghuvanshi R. S. Panda A. K. 《Journal of Thermal Analysis and Calorimetry》1998,52(2):559-564
Melt polymerization conditions for D,L-lactide initiated with tetraphenyltin were studied with regard to polymer molecular
weight. The present study was undertaken to investigate the progress of polymerization of D,L-lactide through differential
scanning calorimetry (DSC), and also to explore the correlation between melt polymerization conditions and molecular weight.
The physical characteristics, such as glass transition temperature (Tg) of the polymer and melting transition (Tm) of D,L-lactide
are correlated with GPC data. DSC data shows that the Tm of D,L-lactide is 122.8 at 150°C polymerization time. ΔHf is 83.2
J g-1, and Tg of polymer is untraceable. At 180°C the Tm is 101.4°C, ΔHf is 34 J g-1, and Tg is around 29.5°C. The drop in
Tm and ΔHf clearly shows the conversion of D,L-lactide to polymer. The maximum increment to molecular weight of polymer is
achieved at 160°C and 8 h. After a short induction period, the slow polymerization of D,L-lactide resulted in maximal molecular
weight followed by an almost constant value of molecular weight.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
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反气相色谱法研究结晶聚合物的结晶行为 总被引:2,自引:0,他引:2
:采用反气相色谱法(IGC)测定了结晶聚合物聚乙二醇(PEG)的熔点和结晶度,探讨了探针分子的性质、固定相中聚合物的涂布量对测定结果的影响,同时与热分析(DSC)方法测得的结果作了比较。结果表明,IGC法测定结晶性聚合物熔点和结晶度是一种非常实用可靠的技术,其优点在于并不依赖100%纯结晶聚合物的性质,PEG的熔点测得值为67℃,结晶度为89.7%,测定结果与DSC法的测得值(Tm=67.9℃,Xc=90.6%)相近,所测定的结果与探针分子的性质无关,但受PEG在担体上的涂布量的影响显著。 相似文献
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The crystallization and melting behavior of polymers is of theoretical importance. In this work, poly(butylene succinate)(PBS) was selected as an example to study such behavior at low supercooling via introduction of the extended-chain crystal(ECC) of the same polymer as nucleating agent. The crystallization of PBS with its ECC as nucleating agent in a wide temperature range(90–127 °C) and the following melting behavior were studied. It is revealed that the melting point(T_m, for T_c≥113 °C) and the annealing peak temperature(T_a, for T_c=90–100 °C) show similar asymptotic behavior. Both T_m and T_a approach to a value of ca. 3.3 °C higher than the corresponding T_c when the crystallization time tc approaches the starting point. That is to say, the Hoffman-Weeks plot is parallel to T_m=T_c line. The crystallization line became parallel to the melting line when PBS was crystallized at T_c higher than 102 °C. Based on these results, we propose that the parallel relationship and the intrinsic similarity between the T_a and the T_m observed at the two ends of the T_c range could be attributed to the metastable crystals formed at the beginning of crystallization. 相似文献
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Kato K Walde P Koine N Ichikawa S Ishikawa T Nagahama R Ishihara T Tsujii T Shudou M Omokawa Y Kuroiwa T 《Langmuir : the ACS journal of surfaces and colloids》2008,24(19):10762-10770
Different types of nonionic vesicles were prepared from commercial Span 80 (also called sorbitan monooleate), as an inexpensive, biocompatible alternative to conventional phospholipid-based vesicles (liposomes). The vesicles were characterized by different techniques and comparison was made with vesicles formed from POPC (1-palmitoyl-2-oleoyl- sn-glycero-3-phosphocholine) or DOPC (1,2-dioleoyl- sn-glycero-3-phosphocholine). Dynamic light scattering measurements, electron microscopy analyses, and two types of fusion assays indicate that Span 80 vesicles are stable for at least 7 days at 4 or 25 degrees C, while storage at 42 degrees C causes irreversible vesicle fusion. This indicates that Span 80 vesicles are thermoresponsive with vesicle fusion occurring at elevated temperature. This property may be related to headgroup dehydration and is certainly not directly linked to the phase transition temperature (Tm) of the vesicles, since the Tm is below -30 degrees C, as determined by differential scanning calorimetry (DSC). The measured Tm value for Span 80 vesicles is lower than in the case of DOPC or POPC, correlating with a higher fluidity of Span 80 vesicles as compared to POPC or DOPC vesicles, as determined with DPH (1,6-diphenyl-1,3,5-hexatriene) as fluorescent membrane probe. High fluidity correlates with increased leakage of entrapped water-soluble dye molecules. Addition of cholesterol and soybean phosphatidylcholine lowers the extent of leakage, allowing a tuning of the bilayer permeability. 相似文献
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SYNTHESIS OF LIQUID CRYSTALLINE COPOLYESTERS WITH T-SHAPED TWO-DIMENSIONAL MESOGENIC UNIT AND CROWN ETHER CYCLE 总被引:1,自引:0,他引:1
A novel series of liquid crystalline copolyesters with T-shaped two-dimensional mesogenic unit and crown ether cycle of cis-4,4′-bis(4-hydroxyphenylazo)dibenzo-18-crown-6 was prepared via solution condensation polymerization from 4,4′-(α,ω-hexanedioyloxy)dibenzoyl dichloride(M_1),2-(4′-ethoxyphenyl)hydroquinone(M_2)and cis-4,4′-bis(4- hydroxyphenylazo)dibenzo-18-crown-6(M_3).The molecular weights of copolyesters are not high,and the intrinsic viscosity [η]of copolyesters ranges from 0.29-0.43.The monomer... 相似文献
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利用DSC方法研究了不同热历史条件对尼龙1212熔融行为的影响.不同的热历史条件下,在DSC曲线上,观察到尼龙1212产生2个或3个熔融峰,依据聚合物结晶理论,对各峰的来源进行了分析.在160℃下不同温度退火120 min的尼龙1212样品DSC曲线上,低温结晶熔融峰主要由低温结晶形成的一些微晶体或者片晶熔融产生,其晶体完善程度较差,熔融峰值较低,峰面积较小;主熔融峰是由样品在淬火过程中形成的晶体和升温过程中低温结晶形成的晶体的熔融重结晶形成较为完善的晶体熔融所产生,熔融峰值较高,峰面积较大.在不同的升温速率条件下,熔融峰温度有所移动,表明不同升温速率条件下产生的熔融峰的结晶晶型是相同的.在不同结晶时间下结晶,延长结晶时间对较高完善程度晶体的生长有利.在不同温度下依次退火处理的样品,熔融产生两个附加峰,这两个附加峰的峰温都比它们相应的退火温度高,而峰高和峰面积随退火温度降低而减小.根据等温结晶结果,由Hoffman方法确定了尼龙1212的平衡熔融温度为202.8℃. 相似文献
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Tienhsiung Ku Peiyu Lu Chenhsiung Chan Tsusheng Wang Szuming Lai Pingchiang Lyu Naiwan Hsiao 《Computational Biology and Chemistry》2009,33(6):445-450
Proteins of both hyperthermophilic and mesophilic microorganisms generally constitute from the same 20 amino acids; however, the extent of thermal tolerance of any given protein is an inherent property of its amino acid sequence. The present study is the first to report a rapid method for predicting Tm (melting temperature), the temperature at which 50% of the protein is unfolded, directly from protein sequences (the Tm Index program is available at http://tm.life.nthu.edu.tw/). We examined 75 complete microbial genomes using the Tm Index, and the analysis clearly differentiated hyperthermophilic from mesophilic microorganisms on this global genomic basis. These results are consistent with the previous hypothesis that hyperthermophiles express a greater number of high Tm proteins compared with mesophiles. The Tm Index will be valuable for modifying existing proteins (enzymes, protein drugs and vaccines) or designing novel proteins having a desired melting temperature. 相似文献