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1.
1 INTRODUCTIONCertaincoppercomplexeshavebeenshowntohaveunusualchemicalpropertiessuchasoxygentransfer,oxidativeadditionandhomogenouscatalytichydrogenation[1].Oxidativeadditionreactionsarekeystepsintheactivationofσbondsinagreatnumberofcatalyticprocess.Cop…  相似文献   

2.
1 INTRODUCTIONAsatypeofimportanceprecursor,alotoforganolanthanidechloridecomplexeshavebeensynthesizedandstructurallycharacterized[1].Thebimetalliccomplexescontainingalkalimetal,Cp2Ln(μCl)2M(L)(Cp=η5C5H5orC5Me5;M=Li,Na;L=THF,TMEDA),isamainstructuretype.Inthecourseo…  相似文献   

3.
IntroductionOrganometallicandcoordinationcomplexeshavere centlyemergedaspotentialbuildingblocksfornonlinearoptical (NLO )materials .1 6Comparedwithorganicmolecules ,metalcomplexescanhavealargervarietyofstructuresandamuchgreaterdiversityoftunableelec tronic…  相似文献   

4.
1 INTRODUCTION1 ,1 0 Phenanthroline 5,6 dione (L)carriesano quinonemoietywithpH depen dentelectroactivityandcanformstablecomplexeswithawidevarietyofmetalions,andthesolutionchemistryandelectrochemistryofitstransitionmetalcomplexeshavebeenextensivelystudied[1,2 ].H…  相似文献   

5.
1 INTRODUCTIONRareEarth (RE)elementsareappliedinagricultureandmedicine .Therfore,betterunderstandingofthebondingofREionsinthecomplexeswithaminoacidsisnecessary .ThecrystalstructureofREcomplexeswiththesimplestaminoacidglycinewerestudiedbefore[1- 4].Toresearch…  相似文献   

6.
1 INTRODUCTIONPeroxovanadium ( pV )complexesare potentproteintyrosinephosphatasein hibitorswithinsulin mimesispropertiesandcouldpossiblybedevelopedintoanewkindoforaldrugforthetreatmentofdiabetes[1~ 3].Recently ,thiskindofcompoundhasreceivedconsiderableattent…  相似文献   

7.
1 INTRODUCTIONCu(I)complexeswithphosphineandarsineligandsarewellknown〔1〕.ForCuphosphinecomplexes,theCu∶ligandratiovariesfrom1∶1to1∶4andcoordinationgeometryofCu(I)rangesfromlineartotrigonal,thentotetrahedralextremes;forexample,the1∶2adductsCu(PPh3)…  相似文献   

8.
MagneticPropertiesofHeteropolyComplexesα┐NamHn[GaW9M3(H2O)3O37]·16H2O(M=Co(Ⅱ),Mn(Ⅱ),Cr(Ⅲ))*WANGLi**,LIUZong-rui**,ZHOUYun-sha...  相似文献   

9.
IntroductionOrganotin(IV)complexeswerewidelyusedasbio cides,fungicidesandinindustryashomogeneouscata lysts.1 6 Morerecently ,pharmaceuticalpropertiesofalkyltin(IV)complexeswithN ,N dialkyldithiocarba mateligandshavebeeninvestigatedfortheirantitumouractivity.7,8…  相似文献   

10.
1INTRODUCTIONCoppercomplexeshavealargevarietyofstericstructuresandplayanimportantroleincatalysingtheenzymaticactivities,which...  相似文献   

11.
1 INTRODUCTIONDimolybdenumalkynecomplexes〔Mo2(μR1C≡CR2)(CO)4(η5C5H5)2〕canreactwithavarietyofreagentssuchasphosphines,thiols,elementalsulfur,Ru3(CO)12andCo2(CO)8〔1-4〕.Intheproductsthealkyneligandisusuallyretained.Sometimes,alkynescissionoccurs.Being…  相似文献   

12.
1 INTRODUCTIONOneofourcurrentinterestsfocusesonthedesignandsynthesesofpolyazamacrocyclicligands,andthestabilitiesofcorrespondingmetalcomplexes.Twopolyazadiphenolmacrocycles,R(babp) 2 (dfc) 2 andR (bac) 2 (dfp) 2 ;[1 ]oneoctaaza macrocycle,BPBD ;[2 ,3]andseveralhexaazama…  相似文献   

13.
1 IntroductionAwidevarietyoftrinuclearoxo carboxylatocomplexeshavebeensynthesizedandstudiedfortheirinterestingchemicalandphysicalproperties[1 ].Thevibrationalspectraofmostofthesecompounds,whichgivemuchinformationaboutthestructureandelectrondelocalization…  相似文献   

14.
1 INTRODUCTIONRecently,bridgedbinuclearcomplexesoffirstrowtransitionmetalshavereceivedmuchattentiononaccountoftheirbiologicalrelevanceandcondensedphasemagneticproperties[1,2].Intheseresearches,manybridgedligandswhichplayimportantroleshavebeenusedasuseful…  相似文献   

15.
INTRODUCTIONThesynthesisofpolynuclearcopper lanthanoidcomplexesisofspecialinterestforsev eralreasons〔1-4〕.Thesecomplexesareim...  相似文献   

16.
1 INTRODUCTIONMetal organicchemicaldeposition(MOCVD)isanappealingtechniqueforelec tronicapplications.AsoneoftheMOCVDsourcematerialsforYBCOsuperconductorfilms,bis( 2 ,2 ,6,6 tetramethyl 3,5 heptanedionate)bariumhasbeenextensivelyusedinthepast[1~ 3].Thelargesizeofthe…  相似文献   

17.
SpectroelectrochemicalStudiesontheInteractionsofComplexesofCu(phen)2+2andCu(bpy)2+2withDNAZHAOGuang-chao,ZHUJun-jieandCHENHon...  相似文献   

18.
1 INTRODUCTIONStudiesofthecoordinationchemistryofzinc(II)havearousedmoreandmoreinterestinlastdecadeinviewoftheirbiologicalmodelingapplica tions[1 ,2 ] andsolid statematerials[3 ,4] .WehavebeeninterestedinthestudyoftransitionmetalcomplexesofN oxopyridine 2 thiol(…  相似文献   

19.
StudiesonRareEarthComplexeswithOpen-chainCrownEthers(Ⅶ)──Preparation,CharacterizationandStructureofRareEarthComplexeswithN,N'...  相似文献   

20.
InvestigationonMagneticPropertiesofExchangeCoupledTransitionMetalComplexesⅡ.TheoreticalModelforTrinuclearComplexesXieXiu-Lan;...  相似文献   

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