Residual polarization of negative muons implanted in C60 and K3C60

Negative muons captured by atoms with zero nuclear spin usually retain about 1/6 of their initial spin polarization P_0 after cascading down to their lowest Bohr orbital. This is particularly observed for μ^- implanted into graphite and diamond. However, μ^- implanted into a powder of the fullerene C₆₀ are found to show essentially zero residual polarization. A residual polarization of \sim P_0/6 is again seen in metallic K₃C₆₀. We speculate that these results are to be explained on the basis of hyperfine effects after completion of the muonic cascade. This revised version was published online in August 2006 with corrections to the Cover Date.     

Superparamagnetic properties of C60Co3 complexes

Preparation of fullerites containing cobalt and analyses of reactions based on semiempirical quantum calculations are described. The magnetic properties of thermally treated C₆₀Co₃ samples: Curie constant (C≈3500 emu K/mol Oe) temperature and field dependencies of magnetization and nonequilibrium effects of magnetization are interpreted in terms of superparamagnetic blocking model of the compound.     

Molecular structure ofC 60 and highT c superconductivity ofK 3 C 60

This research was supported in part by the U.S. Department of Energy.     

13C Hyperfine interactions in CD3C60 and the distribution of unpaired spin on the C60 cage

¹³C hyperfine interactions obtained for CD₃C₆₀ are compared with previous data for MuC₆₀ and used to map the unpaired spin distribution on the C₆₀ surface of these radicals with the help of semi-empirical and density functional calculations. It is concluded that the unpaired spin is predominantly located on seven atoms near the point of attachment of the substituent.     

C60、C60F60及C60H60“分子滚珠”的压缩特性与电子结构

采用量子分子动力学技术,模拟了C60、C60F60与C60H60分子的压缩过程,计算了这些"分子滚珠"受压变形后的电子结构.根据计算结果,对比、分析了三种分子的压缩力学特性以及压缩变形对其电子结构的影响.研究表明,1)三种分子的抗压缩载荷与能量吸收能力有C60F60＞C60H60＞C60的排序,但抗变形能力相当;2)随着压缩变形的增大,三种分子的化学活性增加,但相同应变下,C60F60和C60H60分子有着比C60更好的化学稳定性.