The viscosity of normal butane,isobutane and their mixtures

The paper reports measurements of the viscosity of normal butane and isobutane at atmospheric pressure in the temperature range 25–195°C. In addition, the viscosity of mixtures of the two gases has been determined in the more limited temperature range 25–100°C. The absolute accuracy of the viscosity data is estimated as ±0.2%, whereas the ratio of the viscosity of the two pure components is determined with an uncertainty of ±0.1%. The viscosity data allow the evaluation of the diffusion coefficients for the n-butane-i-butane system.The experimental data demonstrate that there are discernible differences between the intermolecular potentials for the pair-interactions n-C₆H₁₀-n-C₄H₁₀; and i-C₄H₁₀-i-C₄H₁₀. All of the experimental data can be correlated within their experimental uncertainty with the aid of the extended law of corresponding states developed by Kestin, Ro and Wakeham. The optimum values of the two scaling parameters, σ_ij and ?_ij, for each interaction which secure this agreement are determined.     

The viscosity and diffusion coefficients of eighteen binary gaseous systems

The paper reports accurate measurements of the viscosity of the eighteen binary gaseous systems: CF₄ with He, Ne, Ar, N₂, CO₂, CH₄; SF₆ with He, Ne, Ar, N₂, CO₂, CH₄, CF₄ and O₂ with He, Ne, CO₂, CF₄, SF₆. The measurements were performed in a high-precision oscillating-disk viscometer at atmospheric pressure and in the temperature range 25–200°C for the systems containing CH₄ or SF₆ and in the temperature range 25–400°C for the remainder. The reported viscosities are believed to be accurate to within ±0.1% at room temperature and to within ±0.2% at 400°C.It is shown that the data conform to the extended law of corresponding states developed by Kestin, Ro and Wakeham despite the complexity of some of the component gases. The standard deviation between the experimental values and those calculated from the law of corresponding states is only 0.3% which is commensurate with the uncertainty in the experimental results.Binary diffusion coefficients derived from the mixture viscosity data are also presented; they have an estimated uncertainty of ±2%.     

Electron resonance spectra of NCS and vibronically-excited NCO in the gas phase

Near 25 °C, ab initio calculations of the zero-density viscosity of helium gas η _He have an uncertainty of approximately 0.001%, which is 1/40th of the uncertainty of the best measurements. The uncertainties of the published calculations for neon and argon are probably much larger. This paper presents new measurements of the viscosities of neon, argon, and krypton at 25 °C made with a capillary viscometer that was calibrated with helium. The resulting viscosity ratios are η _Ne/η _He?=?1.59836?±?0.00037, η _Ar/η _He?=?1.13763?±?0.00030, and η _Kr/η _He?=?1.27520?±?0.00040. The argon ratio agrees with a recent, unpublished calculation to within the combined uncertainty (measurement plus calculation) of 0.032%. The neon ratio is smaller than the calculated value by 0.13%.     

Electrochemical capacitance of porous NiO–CeO2 binary oxide synthesized via sol–gel technique for supercapacitor

Nanocrystalline NiO–CeO₂ binary oxide as a novel electrode material for ultracapacitor was synthesized via glycol assisted citrate sol–gel method. Unique cubic phases with aggregated crystalline microstructure of NiO–CeO₂ mixed oxides were examined by X-ray diffraction and transmission electron microscope. The observed electrochemical measurements further reveal the strong pseudocapacitance features of the mixed oxides at different current density. Binary oxide annealed at 500 °C shows an optimum specific capacitance (C _s ) of 305 Fg^?1 at the constant current density of 1 Ag^?1. The achieved C _s value undoubtedly certifies that in combination with NiO the structural stability and redox property of CeO₂ have been enhanced. Especially, increasing the calcination temperature binary oxide has shown well reversible redox features which confirm the high chemical and thermal stability of CeO₂ and it could be involve in the charge storage process effectively by their strong Ce³⁺/Ce⁴⁺ redox couples. Capacity retention and cyclic stability of the electrode was quite good, only ～5 % capacity fading was observed after 1,000 cycles. Moreover, binary oxide calcined at 700 °C exhibits a specific capacitance of 167 Fg^?1 at the constant current density of 1 Ag^?1 which states that presence of CeO₂ with NiO have controlled the grain growth and maintains their porous microstructure even at 700 °C. This facilitates to the redox process at both NiO and CeO₂ active surfaces at elevated temperature significantly.     

Aes study of the segregation behaviour of silicon in high-silicon steel during oxidation

The segregation behaviour of silicon during oxidation of a high-silicon steel has been investigated by AES. The results show that silicon seems to have two states of oxidation: one leading to the formation of SiO_x and iron oxides when the oxidation and the following heat treatments in vacuum are performed below 500°C and the other occurring at temperatures higher than 500°C, leading to the formation of SiO₂ and segregation of this species toward the surface without oxidation of iron.     

A search for deeply bound pionic states of xenon produced in the 136Xe(d, 3He)135Xeπ-bound reaction

A search for deeply bound pionic states of xenon produced in the ¹³⁶Xe(d, ³He)¹³⁵Xe_π-bound reaction at E _d = 500 MeV is reported. The population of the 1s pionic-atom state of ¹³⁵Xe is observed on the predicted level of the cross section ～ 40 μb/sr. The binding energy of the 1s state, B = 2.9 ± 0.5 MeV, however, is lower than theoretically predicted.     

Nano-SiC implantation into the structure of carbon/graphite materials made by pyrolysis (carbonization) of the precursor system coal tar pitch/poly(dimethylsiloxane)

Conversion of the air-cured poly(dimethylsiloxane) {–O–Si(CH₃)₂–}_n to SiC during co-pyrolysis with a coal tar pitch is studied with reference to the related SiO₂/pitch system. Each binary mixture is first homogenized at 160 °C followed by carbonization at 500 °C under argon to afford initial carbonizates. In both cases, one part of the initial carbonizate is further pyrolyzed at 1300 °C and another part at 1650 °C under an argon flow resulting in composite products. All products are studied with FT-IR, XRD, and XPS spectroscopic methods supplemented with SEM and ‘wet’ Si-analyses, when applicable. Carbothermally assisted conversion of both silicon precursors to nanocrystalline SiC embedded in the evolving C-matrix, i.e. nano-SiC/C composites, is evident only after the 1650 °C carbonization stage.     

Elastic constants and attenuation changes in annealed BaO crystals

Acoustical velocities and attenuation changes were measured on BaO crystals at 23°C, in the as-recieved condition and after 170 hrs annealing at 1150°C (P_O2 ≈ 10^-6 atm.). Effects of attenuation and computed C_ij are discussed.     

Peculiarities of the formation of high-defect states in mechanocomposites and powders of niobium and aluminum under severe deformation in planetary ball mills

The microstructural peculiarities of Nb powder and Nb + Al powder mixtures after mechanical activation in a high-energy planetary ball mill were investigated by transmission electron microscopy. The materials revealed two-level structural states: nanograins of size from 50 to 100 nm that contain subgrains of size ～20 nm and less with low-angle misorientation boundaries, elastic lattice curvature gC _ij ≈100°…200°μm^?1, curl or curvature gradient ?χ _ij /? _r > 100 μm^?2 and high (up to 10E μm^?1) local stress gradients (couples). An important factor in the formation of the above states is the capability of nano-objects to reach high elastic lattice curvature, high gradients of this curvature, and high local internal stress gradients at rather low absolute values of the internal stress.     

Local atomic and magnetic structures of nanocrystalline Fe75Cr10B15 alloy

The crystal, local atomic and magnetic structures of Fe₇₅Cr₁₀B₁₅ alloys annealed at 440?C473°C for 5 min have been studied using X-ray diffraction and ⁵⁷Fe M?ssbauer spectroscopy. At the annealing temperature T _a = 440°C, nanocrystals of the ??-Fe phase (??1%) precipitate in the amorphous matrix of the alloy. The complete crystallization of the amorphous alloy occurs at T _a = 473°C with the formation of ??-Fe nanocrystals 26 ± 2 nm in size and nanocrystals of tetragonal boride t-Fe₃B 47 ± 2 nm in size. It has been found that chromium atoms are located in nanocrystals of the ??-Fe and y-Fe₃B types. The distribution functions of hyperfine fields in the nanocrystalline Fe₇₅Cr₁₀B₁₅ alloy reconstructed from the M?ssbauer spectra (at T _a = 473°C) show that there are three allowed states of iron atoms in the ??-Fe phase and three equally probable crystallographic nonequivalent states of iron in the t-(Fe,Cr)₃B phase. The chromium concentration x in the ??-Fe(Cr) phase is found to be ??10 at %. The substitution of chromium atoms for iron atoms in t-Fe₃B substantially decreases local magnetic moments of the iron atoms.     

Direct determination of intermolecular potentials from gaseous transport coefficients alone

Intermolecular pair-potential energy functions are given for all the unlike interactions of the monatomic gases. The potentials are obtained by direct inversion of experimental measurements of low density binary mixture viscosity and diffusion coefficients. In those cases where these data extend to sufficiently low temperatures to enable the potential well depth ε/k to be determined, the values obtained for this parameter are Kr-Xe 220 ± 5 K, Ar-Xe 170 ± 5 K, Ar-Kr 165 ± 10 K, Ne-Xe 70 ± 5 K, Ne-Kr 60 ⁺¹⁰ _-5 K, Ne-Ar 60 ± 5 K. For the systems He-Xe, He-Kr, He-Ar and He-Ne only the repulsive branch of the potential energy function is obtained. For all systems the potentials are shown to reproduce well other macroscopic data not used in their construction. The agreement with thermal diffusion data is particularly encouraging. The independent determination of this wide range of potentials provides a direct test of both the hypothesis that they are conformal and the validity of parameter mixing rules. Significant deviations from conformality are found at the extremes of small and large intermolecular separations. No simple combining rules reproduce the potential parameters quantitatively, but the direction in which empirical modifications should be made is clearly suggested.     

Amorphous-crystalline transition in Ge films by photoemission

Photoelectron second-derivative, energy distribution spectra reveal subtle changes in the density-of-states of vapour-deposited, amorphous Ge films, arising from microstructural ordering processes. Evidence is presented for ‘ideal’ amorphous Ge films, prepared at a deposition temperature T_s = 120 ± 20°C, which undergo an abrupt amorphous-crystalline transition upon annealing to T_A ? 230 ± 10°C. These films are thought to approach closely the random-network Polk-model. High densities of localized states in the pseudogap are observed in imperfect films.     

The β-moments for the second-forbidden β-decay from137Cs,the CVC theory,and the residual interactions

Theβ-moments of the 7/2⁺(1.176 MeVβ ^?)3/2⁺ transition in the decay of¹³⁷Cs have been extracted from the available experimental data. We have obtained the following values: 〈R _ij 〉/R ²=0.035±0.020, 〈iT _ij 〉/R ²=0.067±0.036, and ?0.085≦〈S _ijk ～>/R ²≦0.085. These results show that theβ-moments are reduced with respect to those evaluated by means of the conventional pairing model. These quenching effects are similar to those previously found in the analyses of first-forbiddenβ-decays and are attributed to residual charge-exchange interactions. The results forΛ(=?〈iA _ij 〉/ξ〈R _ij 〉) are discussed in the light of the predicitons of the CVC theory.     

Nonisothermal nucleation in the CuCl solid solution in glass: Formation of two distributions of nanoparticles of a new phase in the solid solution with a negative jump of the nucleation temperature

The processes of nonisothermal nucleation in the CuCl solid solution in glass with a negative jump of the nucleation temperature have been investigated using optical spectroscopy and exciton-thermal analysis. Two distributions of CuCl nanoparticles differing in the average radii R (2.3 and 14.0 nm) have been obtained for the temperature drop from T ₁ = 700°C to T ₂ = 500°C. The formation of two distributions of CuCl particles has been numerically simulated and the agreement between the experimental and calculated radius distributions of CuCl particles has been obtained.     

The determination of theK-shell fluorescence yield of xenon by use of the proportional counter method

The wall-less proportional counter filled with propane with a small admixture of xenon was used as a spectrometer of electrons emitted by xenon atoms when photoelectrically excited by americium-241γ-rays and erbiumKα rays. TheK-shell fluorescence yield of xenon as extracted from spectra ammounts toω _k=0.889(1±0.01).     

High-resolution infrared spectrum of the fundamental band of LiCl at a temperature of 830°C

High-resolution Fourier transform spectra of ⁶LiCl and ⁷LiCl have been recorded at 830°C. A total of 2522 lines have been measured at 0.006 cm⁻¹ resolution in the 500- to 730-cm⁻¹ region. The data for all four isotopic species have been fit with a standard deviation of 0.00027 cm⁻¹ using 19 isotopically invariant rovibrational constants including five Δ_ij correction terms to the usual Dunham Y_ij terms. Comparison is made with the constants derived from a direct fit of the observed transitions to a Dunham potential function with only 13 coefficients including for Δ correction terms. The gas phase band center for the v = 1–0 transition of ⁷Li³⁵Cl is 634.0753(7) cm⁻¹.     

Decomposition of a solid solution in the ω phase of the Ti-Zr system under high pressure

Phase separation in the hexagonal ω modification of the Ti-Zr system was observed. The ω → ω₁ + ω₂ decomposition in an equiatomic TiZr alloy after prolonged thermal treatment at P = 5.5 ± 0.6 GPa and T = 440 ± 30°C was revealed using x-ray diffraction. It is found that the concentration dependence of the specific volume of the ω phase of Ti-Zr alloys deviates from the Vegard law to higher values. An isobaric section of the equilibrium P-T-x phase diagram of the Ti-Zr system is shown to have the shape of an eutectoid diagram at pressures higher than 8 GPa.     

The microwave spectrum of a second N-gauche rotamer of allylamine

The microwave spectra of the ground and five excited states of a second gauche rotamer of allylamine have been measured and assigned. Three of the excited states belong to the same mode, most probably the CC torsion, the second and third vibrational states present a symmetrical splitting due to tunneling effect. The spectrum was conclusively identified as due to the N-gauche, lone-electron-pair trans form by means of the N-quadrupole coupling constants and dipole moment components. The variation observed for the quadrupole coupling constants in the different vibrationally excited states was explained by a suitable model. The ground state constants are (in MHz) A₀ = 23 957.05 ± 0.048, B₀ = 4 229.96 ± 0.025, C₀ = 4 154.91 ± 0.025, χ_aa = ? 1.48 ± 0.04, χ_bb - χ_cc = ? 1.42 ± 0.04, and (in D) ∥μ_a∥ = 0.766 ± 0.010, ∥μ_b∥ = 0.700 ± 0.005, ∥μ_c∥ = 0.290 ± 0.020.The excited states of the N-cis, lone-electron-pair trans form were also measured and assigned; two of these states appear to belong to the CC torsion as indicated by their intertial defects. The potential hindering the internal CC rotation was calculated using the relative intensity data of the N-cis and N-gauche forms as well as the tunneling splittings. A three-term cosine potential was fitted to the data yielding (in cm^?1) V₁ = ? 77 ± 85, V₂ = 170 ± 126, V₃ = 663 ± 95. The Dennison-Uhlenbeck potential was used for an approximate calculation of the N-trans barrier separating the two identical N-gauche forms. The barrier obtained was 1.9 ± 0.3 Kcal/mole.     

Precision lifetime measurements with the coincident high-velocity DSA method in inverse reactions

Mean lives of low-lying states of ¹⁸O, ³⁰Si, ³³S and ³⁴S have been measured with the Dopplershift attenuation method by heavy-ion bombardment of ²H and ³H targets. The γ-ray Doppler patterns are observed with a large Ge(Li) detector at 0° in coincidence with protons around 180°, so that the experiments are performed with high-velocity, mono-energetic and unidirectional beams of nuclei in well-defined excited states. Interpretation of the γ-ray patterns measured with Mg, Al, Cu and Ag as slowing-down material, with accurately known experimental stopping powers yields consistent results with small errors: ¹⁸O, τ_nm (1.98 MeV) = 2790 ± 110 fs; ³⁰Si, τ_m(2.24) = 351 ± 19 fs and τ_m(3.50) = 89 ± 8 fs; ³³S, τ_m(0.84) = 1650 ± 50 fs and τ_m(2.31) = 206 ± 8 fs; ³⁴S, τ_m(2.13) = 470 + 20 fs and τ_m(3.30) = 196 ± 13 fs. The deduced transition strengths are compared with results from large-scale shell-model calculations.     

Stability and surface properties of GeSi alloy films on Si(111) substrate

Several GeSi alloy films with different surface properties were prepared from a 500 Å thick Ge film that had previously been grown on a Si(111)-7×7 substrate by molecular beam epitaxy. The films were prepared by combinations of sputtering, annealing and Ge deposition from an evaporator. The surface properties were studied by Auger electron spectroscopy (AES) and by low energy electron diffraction (LEED). A novel LEED system employing position-sensitive detection was used. The Ge film surface gave a superposition of 7×7 and c(2×8) LEED patterns. A 7×7 → 1×1 phase transition was observed at 425±10°C. An irreversible 7×7 → c(2×8) transition was observed when the sample was heated above 500°C. The Ge film melted at 750±30°C and formed a Ge_xSi_1−x (x = 0.85±0.05) alloy whose surface gave a 7×7 LEED pattern. A 7×7 → 1×1 phase transition was observed at 600±0.15°C. Prolonged sputtering and annealing resulted in a Ge_xSi_1−x (x = 0.53±0.05) alloy whose surface gave a 5×5 LEED pattern. An apparent 5×5 → 1×1 phase transition was observed at 870±10°C but at that temperature the film was converted irreversibly to one with a much lower Ge atom fraction (x = 0.025±0.005) whose surface gave a 7×7 LEED pattern. A surface with a 5×5 pattern identical to that for the x = 0.53 alloy was prepared by deposition or Ge on Si. A similar 5×5 surface was prepared by deposition of Ge on a facetted GeSi alloy surface originally showing a superposition of 5×5 and 7×7 patterns. The intensity distributions in all of the 7×7 LEED pattern were found to be similar to those for Si(111)-7×7 at nearly the same electron energies. The characteristics of the 7×7 → 1×1 phase transitions were discussed in direct comparison with those of the Si(111)7×7 → 1×1 and Ge(111)-c(2×8) → 1×1 transitions observed with the same LEED system.