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用相对速率方法分别考察了OH自由基与DMS在氮气、空气和氧气体系的反应速率常数. 发现使用HONO和CH3ONO作为OH自由基发生剂时,基态氧原子O(3P)对动力学的测定有很大的影响. H2O2为OH自由基的发生剂,室温下在氮气、空气及氧气体系下的速率常数分别为4.50×10-12,8.56×10-12和11.31×10-12 cm3/(molecule?s).在287~338 K,测得氮气和空气体系下的阿累尼乌斯表达式分别为:kair=(7.24±0.28)×10-13exp[(770.7±97.2)/T],kN2=(3.40±0.15)×10-11exp[-(590.3±165.9)/T 相似文献
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对α-蒎烯、β-蒎烯和O3的大气反应进行了初步实验室模拟,利用长光程傅里叶变换红外光谱技术结合相对速率法测得在1.0×105Pa,296±3K条件下,α-蒎烯、β-蒎烯和O3气相反应的速率常数分别为2.83×1017cm3@molecule-1@s-1和1.48×1017cm3@molecule-1@s. 相似文献
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α,β-蒎烯气相臭氧化速率常数的测定 总被引:1,自引:0,他引:1
对α 蒎烯、β 蒎烯和O3的大气反应进行了初步实验室模拟 ,利用长光程傅里叶变换红外光谱技术结合相对速率法测得在 1 0× 10 5Pa,2 96± 3K条件下 ,α 蒎烯、β 蒎烯和O3气相反应的速率常数分别为2 83× 10 17cm3·molecule-1·s-1和 1 4 8× 10 17cm3·molecule-1·s-1。 相似文献
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采用多晶LaB6材料制成平板二极管阴极,阳极采用钼材料,阴极采用热传导与热辐射加热,加热体为石墨。实验研究了不同阴极温度、不同真空度下的脉冲发射特性,并对热发射稳定性进行了分析。结果表明: 在动态真空系统中, 阴极发射面积为0.012 1 cm2, 工作真空度为2×10-4 Pa, 阴极温度分别为1 600, 1 650和1 700 ℃,在脉冲宽度为40 ms、重复频率为107 Hz的条件下,最大脉冲发射电流密度分别为34.0,44.0和53.8 A/cm2; 2×10-4,5×10-4和2×10-3 Pa压强下的发射能力没有明显的差异;脉冲宽度的变化不影响发射电流密度的变化。 相似文献
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用高温固相法合成的NiFe2O4陶瓷粉末,选取Cu为金属陶瓷的金属相成分,研究了氧分压对Cu-NiFe2O4金属陶瓷的相成份的影响,结果表明:当烧结温度为1150℃,氧分压大于2.23Pa时,Cu被大量氧化;氧分压小于4.2×10-3Pa时,Cu和离解的Ni反应生产Cu3.8Ni合金,试样的导电性或抗氧化性都会降低,1150℃下烧结制备Cu-NiFe2O4金属陶瓷的最佳氧分压是(0.3-42.0)×10-2Pa。 相似文献
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采用锆泵作为吸气泵,设计出静态保真空模拟实验装置。在该实验装置上进行了保真空可行性实验,装置在经过10 d的保真空后,真空度为1.4×10-3 Pa 。在模拟保真空实验成功实现的基础上,用常规微波管技术设计加工了“硬管”器件,并进行保真空实验,静态下真空度经过15 d仍能维持在2×10-2 Pa。该器件在峰值电压为330 kV的条件下,输出微波功率达到650 MW,脉宽为40 ns,主频为3.68 GHz,性能比普通器件有很大改善,微波脉宽更宽,频谱更单一,而且稳定性很高。 相似文献
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保持CO2激光的单脉冲能量为61.4~64.6 J,采用高精度冲击摆系统进行了不同气压下吸气模式激光推进冲量耦合系数的实验测试,分析了对应的高度特性。结果表明:气压为2.8×104~1×105 Pa,即距离地面0~10 km时,冲量耦合系数大约3.5×10-4 N·s·J-1,上下波动幅度低于5%;气压低于2.8×104 Pa,即高度大于10 km时,冲量耦合系数呈二次曲线显著下降;当气压降至1×103 Pa,即距离地面约31 km高度时,耦合系数仅为9.7×10-5 N·s·J-1。 相似文献
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Guided-Wave Two-Dimensional Acousto-Optic Scanner Using Proton-Exchanged Lithium Niobate Waveguide 总被引:1,自引:0,他引:1
Two-dimensional scanning of a 0.6328 mum guided-light beam has been realized using noncolinear acousto-optic (AO) coplanar Bragg diffraction together with colinear AO guided-mode to substrate radiation-mode conversion in a Z-cut Xpropagation LiNbO3 proton-exchanged (PE) waveguide. The two surface acoustic (SAW) waves utilized are at the center frequencies of 500 and 200 MHz, propagating in the Y and X axes, respectively. Two-dimensional scanning of approximately 720 resolvable light beam spots, namely, 18 40 (horizontal vertical) scanning, has been demonstrated using a light beam of 1.0 mm aperture. The total number of resolvable beam spots can be greatly increased from 720 by simply utilizing SAW transducers of larger bandwidth and a light beam of greater aperture. It should also be possible to significantly increase the diffraction efficiency from 3 % by optimizing the parameters of the PE waveguide and the SAWs. 相似文献
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A simple technique of pulse compression, based on the linear chirp compensation of self-phase modulation (SPM) spectra in dispersion shifted fibers, is demonstrated. The optimization procedure is carried out, for a short span of a single-mode fiber, using a parabolic law, which describes the behavior of the squared output pulse width versus the pump peak power in the case of Gaussian pulses. The experimental results give a minimum pulse duration of 233 fs, which is in good agreement with the model. Shorter and coherent pulses, down to 90 fs, have been obtained by inserting an interference filter at the optical output. 相似文献
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S. G. Nedel’ko M. A. Krysyuk A. L. Apanasenko L. N. Lymarenko Z. T. Moroz 《Journal of Applied Spectroscopy》1997,64(1):55-61
Results of a study of the effect of γ-radiation on the spectral luminescence properties of cadmium tungstate crystals doped
with silver, bismuth, and molybdenum cations are presented. Spectral characteristics of the nondnnnoped crystals are briefly
described. Absorption and photo and X-ray luminescence spectra of the crystals taken before and after exposure to γ-radiation
(5.5·104 Gy) are compared. It is found that the spectral characteristics of the crystals doped with silver, bismuth, and molybdenum
cations do not change markedly after the exposure. The relation between the type of impurity-induced defects, individual characteristics
of the impurity cations, and the character of the effect of γ-radiation on the spectral luminescence properties of impure
crystals is analyzed (preliminarily).
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 64, No. 1, pp. 55–60, January–February, 1997. 相似文献
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The Shanghai Synchrotron Radiation Facility(SSRF)booster ring,a full energy injector for the storage ring,is deigned to accelerate the electron beam energy from 150MeV to 3.5GeV that demands high extraction efficiency at the extraction energy with low beam loss rate when electrons are ramping.Closed orbit distortion(COD)caused by bending magnet field uniformity errors which affects the machine performance harmfully could be effectively reduced by bending magnet location sorting.Considering the affections of random errors in measurement,both ideal sorting and realistic sorting are studied based on measured bending magnet field uniformity errors and one reasonable combination of bending magnets which can reduce the horizontal COD by a factor of 5is given as the final installation sequence of the booster bending magnets in this paper. 相似文献
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A multi-conjugate adaptive optics (MCAO) can offer a possibility of widening field of view (FOV) characterized by the isoplanatic angle, and the choose of conjugate height becomes a basic problem for MCAO, which influences the size of iosplanatic angle. Considering the application of lidar, the isoplanatic angle's expressions of two deformable mirrors (DMs) MCAO for uplink and downlink are deduced. The effects of conjugate heights for dual-conjugate AO are thoughtfully discussed, and the isoplanatic angles are further analyzed. The results show that the isopanatic angle varies with the conjugate height and reaches the maximum as the conjugate height is at the optimal altitude. Moreover, the optimal conjugate height changes with the propagation distance. 相似文献
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Due to the limit of response speed of the present single-photon detector, the code rate is still too low to come into practical use for the present quantum key distribution (QKD) system.A new idea is put up to design a quick single-photon detector.This quick single-photon detector is composed of a multi-port optic-fiber splitter and many avalanche photo diodes (APDs).Au of the ports with APDs work on the time division and cooperate with a logic discriminating and deciding unit driven by the clock signal.The operation frequency lies on the number N of ports, and can reach N times of the conventional single-photon detector.The single-photon prompt detection can come true for high repetition-rate pulses.The applying of this detector will largely raise the code rate of the QKD, and boost the commercial use. 相似文献
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We measure the waveform and phase curves of short optical pulses before and after transmission over different lengths of fibers by use of the pulse analyzer with the frequency-resolved optical gating (FROG),and numerically simulate pulse evolution under the experimental conditions.The nonlinear coefficient of the fiber is given by comparing the experimental results with the numerical ones.Difference between the experiment and numerical simulation is analyzed. 相似文献
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Resonance scattering of elastic spherical shell and cylindrical shell while the surrounding fluid medium has absorption is studied. The normal mode solution derived using exact elastic theory and the separation of variables is still applicable. However, the scattering form function has to be modified for the absorbing medium, otherwise the unreasonable result would be obtained. The backscattering form function in the absorbing medium is redefined, and the form function of elastic spherical and cylindrical shell with vacuum or solid matter filled is calculated in various absorption conditions. The results show that the absorption of surrounding fluid leads to notable attenuation of the coincidence resonances in the mid-frequency, but it has a little influence on the low-frequency resonance scattering induced by the filler inside the shell. 相似文献