Synthesis and Crystal Structure of an Ionic Compound [Fe(CN)_6·(PhCH_2NC_9H_7)_4]·12H_2O

A novel ionic compound [Fe(CN)6(PhCH2NC9H7)4]·12H2O (C70H80FeN10O12, Mr = 1309.29) has been synthesized and its structure was characterized by IR, elemental analysis and X-ray diffraction. The compound crystallizes in triclinic, space group P1, with a = 10.968(7), b = 11.466(7), c = 14.077(8) , α = 87.014(7), β = 78.124(7), γ = 72.708(7)o, V = 1654.1(17) 3, Z = 1, Dc = 1.314 g·cm–3, F(000) = 692, μ = 0.298 mm–1, the final R = 0.0519 and wR = 0.1355. The building unit of the title compound consists of four (PhCH2N+C9H7) ions, one [Fe(CN)6]4– anion, and a dozen water molecules. According to the structural analysis, [Fe(CN)6]4– ions are linked together by O–H···O and O–H···N hydrogen bonds, while (PhCH2N+C9H7) and [Fe(CN)6]4– ions interact with each other by electrostatic force to form an ionic compound.     

Synthesis and Crystal Structure of an Ionic Compound [Fe(CN)6(phCH2NC5H5)3]·(H2O)4

A novel ionic compound [Fe(CN)6(phCH2NC5H5)3]·(H2O)4(Mr = 794.71) has been synthesized and its structure was characterized by IR, elemental analysis and X-ray diffraction. The compound crystallizes in monoclinic, space group P21/c with a = 10.837(2), b = 16.551(3), c = 23.402(5) (A), β = 97.531(4)°V = 4161.0(15)(A)3, Z = 4, Dc = 1.269 g/cm3, F(000) = 1668, μ = 0.414 mm-1, R = 0.0479 and wR = 0.1232. The building unit of the title compound consists of three (phCH2N C5H5) ions, one [Fe(CN)6]3- anion and four water molecules. According to the structural analysis, [Fe(CN)6]3- are linked together by O-H…N and O-H…O hydrogen bonds, but [Fe(CN)6]3- and [(phCH2N C5H5)3] ions are bound by electrostatic force to form an ionic compound.Keywords: N-benzyl-pyridine, ferricyanic anion, crystal structure, supramolecular, ionic compound.     

Synthesis and Crystal Structure of a Cyano-bridged Bimetallic Complex[La(betaine)_2(H_2O)_6Fe(CN)_6]·2H_2O

1 INTRODUCTION In the last decade, cyano-bridged Prussian Blueanalogues[1] have been intensively studied from theviewpoint of application as functionalized molecule-based magnets[2], chemical sensor materials[3], fluo-rescent materials[4] and zeolitic-type materials[5, , 6]etc. In 1976, a series of cyano-bridged three-dimen-sional rare earth hexacyanometalates(IIILnM(CN)6?nH2O (M = Fe or Cr, n = 4 or 5) were crystallized andsubjected to single-crystal X-ray analysis[7]. …     

Synthesis and Crystal Structure of an Ionic Compound [Fe（CN）6·（PhCHeNC9H7）4]·12H2O

A novel ionic compound [Fe（CN）6·（PhCHeNC9H7）4]·12H2O
（C70H80FeN10O12, Mr = 1309.29） has been synthesized and its structure was characterized by I-R, elemental analysis and X-ray diffraction. The compound crystaUizes in triclinic, space group P1, with a = 10.968（7）, b = 11.466（7）, c = 14.077（8）A, α= 87.014（7）, β= 78.124（7）, γ = 72.708（7）°, V = 1654.1（17）A3, Z = 1, Dc = 1.314 g·cm^-3, F（000） = 692, p = 0.298 mm^-1, the final R = 0.0519 and wR = 0.1355. The building unit of the title compound consists of four （PhCH2N＋C9H7） ions, one [Fe（CN）6]4- anion, and a dozen water molecules. According to the structural analysis, [Fe（CN）6]4- ions are linked together by O-H…O and O-H…N hydrogen bonds, while （PhCH2N＋C9HT） and [Fe（CN）6]4- ions interact with each other by electrostatic force to form an ionic compound.     

Synthesis and Crystal Structure of a Cyano-bridged Bimetallic Complex:[NdFe(CN)_6(DMF)_4(H_2O)_3]H_2O

1 INTRODUCTION In recent years, cyano-bridged heterometallic coordination compounds have inspired remarkable attention due to their rich and interesting structures and magnetic behaviors. However, these studies were mainly focused on the transition metals. Although several unusual cyanide bridging lanthanide-transition metal complexes have been re- ported[1～6], this field continuously possesses tre- mendous researching potentialities. As regardsPrussian Blue lanthanide complex, divers…     

Synthesis and Crystal Structure of a Hydrogen-bonded Supramolecular Compound [(C_6H_5N_2O)_3·Cu_1._5]·6H_2O

1 INTRODUCTION The binding of metal ions by proteins and pep- tides is of fundamental interest due to the impor- tance of metal ions in biological systems. Metals may be part of the active sites of enzymes, stabilize the macromolecular structure of proteins and affect enzymes or membranes to control cell metabolism[1]. Therefore, for many years there has been a great in- terest in the study of complexes able to mimic these active sites of metalloproteins. In this case, metal complexes of…     

Synthesis and Crystal Structure of[C_6H_5CH_2C_5H_4ErCl_2(THF)_3]·THF

ＳｙｎｔｈｅｓｉｓａｎｄＣｒｙｓｔａｌＳｔｒｕｃｔｕｒｅｏｆ［Ｃ_６Ｈ_５ＣＨ_２Ｃ_５Ｈ_４ＥｒＣｌ_２（ＴＨＦ）_３］·ＴＨＦＧａｏＦｕ－Ｘｉｎｇ；ＷｅｉＧｅ－Ｃｈｅｎｇ；ＪｉｎＺｈｏｎｇ－Ｓｈｅｎｇ；ＣｈｅｎＷｅｎ－Ｑｉ（ＣｈａｎｇｃｈｕｎＩｎｓｔｉ?..     

Synthesis, Crystal Structure and Luminescence Property of [Co(hmz)_2(H_2O)_4]·2H_2O

A new mononuclear Co(II) complex, [Co(hmz)2(H2O)4]·2H2O, has been synthesized by the reaction of Co(CH3COO)2·4H2O with 1-(4-hydroxyphenyl)-5-mercaptotetrazole (Hhmz). It crystallizes in the monoclinic system, space group P21/n with a = 13.502(5), b = 6.718(3), c = 13.972(6) , β = 117.532(4)o, V = 1123.9(8) 3, Z = 2, M r = 553.45, F(000) = 570, Dc = 1.635 g/cm3, μ = 1.008 mm–1, the final R = 0.0272 and wR = 0.0684 for 2194 observed reflections (I > 2σ(I)). The Co(II) is six-coordinated by two nitrogen atoms from two hmz–1 ligands and four water molecules, forming an octahedral geometry. The intermolecular hydrogen bonding and offset-panel π-π stacking interactions between the adjacent molecules extend the compound into a three- dimensional supramolecular framework. The title compound emits strong blue fluorescent light (λem(max) = 427 nm) at room temperature and is red-shifted compared with free ligand Hhmz (λem(max) = 342 nm).     

Crystal Structure of [CH_3CH(OH)COO]_2Fe(H_2O)_2·H_2O

<正> The title compound C6H16O9Fe, Mr = 288. 13, was synthesized and crystallized in monoclinic space group P21/c, a = 9. 409(4), b = 5. 812(4), c= 22. 122(7)(?) , β=90. 80(3)°. V = 1209. 6(?)3, Z = 4, Dc=1. 572g/cm3, F(000) = 592, μ = 12. 73cm-1, R = 0. 063, Rw= 0. 068 for 1191 observed reflections. The iron atom is surrounded by O(1 - 6) in a distorted octahedron.     

Syntheses and Crystal Structures of Two Cyano-bridged Bimetallic Complexes [Ce(DMSO)_4(H_2O)_3Fe(CN)_6]·H_2O and [La(DMSO)_4(H_2O)_3Co(CN)_6]·H_2O(DMSO = Dimethylsulfoxide)

1INTRODUCTION Recently,cyano-bridged lanthanide-transition me-tal complexes have been extensively investigateddue to their potential applications as precursors in the preparation of rare earth orthoferrites,fluores-cent and magnetic materials[1].Various complexes of this system have been obtained in order to ex-plore the relations between structures and pro-perties by using different ligands,such as DMF,4,4?-bipy,and so on,to fill the coordination sites of lanthanide ions[2～9].But up to…     

Synthesis and Crystal Structure of a Sandwiched Trinuclear Complex [Tl_2(18-Crown-6)_2Pt(CN)_4]·2H_2O

1 INTRODUCTION Tetracyanoplatinate ion often forms one-dimen- sional chain compounds, and the Pt–Pt spacings are often only 0.01~0.3 ? longer than those in Pt metal (2.78 ?). The studies of room-temperature electrical conductivities of these complexes indicate that the shorter the Pt–Pt separations in the chains are, the higher the electrical conductivity is[1~3]. Tetracyano- platinate ion may also stack with suitable planar cations into one-dimensional materials such as [Pt- (CNR)4]…     

Synthesis and Crystal Structure of Ni_3(admt)_6(NCS)_6·C_2H_5OH·2H_2O

1　INTRODUCTIONCoordination compounds with 1 ,2 ,4 triazole as a ligand have interesting fea tures,notonly because ofthe very interesting magnetic propertiesofthese complex es,but also because ofrich modes ofcoordination〔1〕.Particularly,the coordinationbehavioroftriazoletowardsa numberoftransition metalthiocyanatesshowsremark abledifferences〔2 - 6〕.On unsubstitution at N4 ,thetriazole ring hasmonodentate,1 ,2 and 2 ,4 bridging forms.These three modes were all observed in the Ni( II)…     

Synthesis, Crystal Structure and Spectral Properties of [Ce(NO_3)_5(H_2O)_2]·2(Hphen)·(H_2O)

1 INTRODUCTION Recently, the ternary or quaternary mixed anion complexes of cerium(III) containing 1,10-phenanthroline (phen) have attracted considerable attention due to their rich structural chemistry and appealing magnetic properties[1]. Panagiotopou…     

Synthesis and Crystal Structure of Co(C_6NO_2H_4)_3. H_2O

1INTRoDUCTIONAlotofresultsoncobaltcomplexstructureshavebeenreportedforseveraldecades.Theinterestofresearchinthisfieldhasneverbeenreducedbecausethecobaltcomplexesplayaveryimportantroleinthelifescienceandcatalysis,etc[1-6).WereportherethesynthesisandstructureofcomplexCo(C,NO,H'),.H,O.2EXPERIMENTALAllreagentsandsolventsusedareofARgradefromcommericalsourceswithoutfurtherpurification.ThetitlecompoundCo(C,NO,H,),.H,Owassynthesizedbythefollowingmethod.When2.4g(ca.1mmol)ofCoCl2.6H2Ow…     

Hydrothermal Synthesis and Crystal Structure of Iron Molybdophosphate Fe[Mo_6O_(12)(OH)_3(H_2PO_4)(HPO_4)_2(PO_4)]_2- [Fe(2,2′-bipy)(H_2O)_2]_2[Fe(2,2′-bipy)_3]_2·6H_2O

1 INTRODUCTION Organic-inorganic hybrid materials and polyoxo-metalates have received much attention because of their intriguing structural diversity and potential applications in molecular adsorption, ion exchange, heterogeneous catalysis and nanotech nology as well as in electrical, magnetic and photochemical areas[1, 2]. One of the important ad- vances in the design of new organic-inorganic hybrid materials is utilizing poly- oxometalates’ coordination ability to produce poly- oxoanio…     

Synthesis and Crystal Structure of a Novel Supramolecular Compound [Mg(H_2O)_6](C_(16)H_(11)O_4SO_3)_2·10H_2O

IntroductionMolecularpolymerwithonedimensionalormultidimen sionalstructureassemblingthroughhydrogenbondsisanim portantresearchcontentinthesupramolecularchemistryandcrystalenginnering .1,2 Withthedevelopmentofnewtypefunctionalmaterialssuchasmolecularmagnetic ,selectedcatalysis ,reversiblecatalysis ,reversiblehost guestmolecular(ion)exchangeetc.,3themoleculardesignandsynthesishavealreadyattractedconsiderableattentioninsupramolecu larsystem .Thesupramolecularcomplexesandorganiccom poundscontainin…     

Synthesis and Crystal Structure of Compound [Fe(Phen)_3][(μ-oxo)Fe_2Cl_6]DMF

1 INTRODUCTION Recently polynuclear iron (Ⅲ) clusters have attracted considerable attention in bioinorganic chemistry due to their presence in the protein ferritin and the related materical hemosiderin[1, 2]. The binuclear oxo-bridge non-haem iron com- plexes (containing the FeⅢOFeⅢ unit) which provide models for the diiron site in the protein involved in the storage (haemrythrin) and on the reductive activation (methanemonoxygenas， ribonclectidereductas) of dioxygen[3,4]. Also, wel…     

Synthesis and Crystal Structure of a One-dimensional Azido-bridged Manganese (II) Compound [Mn(N_3)_2(H_2O)_3·C_6H_(12)N_4]_n

1 INTRODUCTION The azide anion is a good bridging ligand for di- valent metal ions to form discrete, one-dimensional, two-dimensional or three-dimensional complexes. In recent years, these complexes have drawn consider- able attentions for their interesting magnetic charace- ristics which attribute to the efficient magnetic coup- ling ability of the azido bridges[1]. When the azide anion acts as a bridging ligand, two typical modes are adopted: end-to-end (EE, μ1, 3) or end-on (EO, μ1…     

Synthesis and Structure of anti-Configuration Complex [Cu(tssb)_2]·2[(H_3O)Cl]·4H_2O

1 INTRODUCTION The complexes of amino acid Schiff base have attracted considerable attention because of their bio- activities[1, 2]. Taurine is a special amino acid in be- ings, and recently the complexes of taurine conden- sation salicylaldehyde Schiff …     

Synthesis and Structure of a Novel Compound [Cu_2(EDTA)(Py)_2(H_2O)_2]·2H_2O

1 INTRODUCTION Multinuclear coordination compounds have attrac-ted much attention due to their distinctive optical, elec-tric and magnetic properties as well as enzyme ana-logue[1～4]. It is important for carboxylic acid to de-sign this compound[5～8]. EDTA is a useful titrant formetal determination because EDTA molecule is easyto coordinate with a metal atom (1:1). Other types ofEDTA-M compounds are seldom to know except Ln2-M3(EDTA)3(H2O)11?12H2O[5] and (UO2 )2EDTA[9]. …