Investigation of the spectra of depolarized light scattering in two viscous liquids

The fine structure of the Rayleigh line wing was studied experimentally in a broad temperature range in the viscous guaiacol liquid. The propagation velocity and the absorption coefficient of the transverse hypersound were determined by the Rayleigh line wing spectra at temperatures from ?27 to ?85°C. The transverse hypersound absorption is shown to pass through its maximum at a temperature of ?34°C. The experimental data for two vitrifying viscous liquids, namely, guaiacol and salol were analyzed. The limiting elastic bulk moduli were found to intersect at the crystallization temperature and the limiting shear modulus to vanish at this temperature. These and other specific features of the guaiacol and salol behavior at the crystallization temperature, revealed in this and previous our studies, point to the possibility of the existence of two phases in a liquid.     

The temperature dependence of the Rayleigh line wing and depolarized combinational scattering line widths in critical mixtures

It has been experimentally found that at approaching the critical temperature of the exfoliating mixture carbon-disulfide-ethanol the widths of the Rayleigh line wing and the depolarized combinational scattering line drastically decrease. The same phenomenon was observed for 3 nitrobenzene combinational line scattering in a nitrobenzene—n-hexane mixture.     

Temperature dynamics of polarized and depolarized light scattering in a critical mixture

The results of Rayleigh line wing width, Landau-Placzek ratio and hypersound velocity temperature dependence at approaching the critical temperature of the exfoliating mixture of n-hexadecane-β, β'-dichlordiethyl ether are given.     

Ionic contribution to Rayleigh line wing under conditions of light scattering by liquid electrolytic solutions

A theoretical treatment is performed of the mechanism (suggested in N. F. Bunkin andA. V. Lobeev, Z. Phys. Chem. 214, 269 (2000)) of ionic effect on the Rayleigh line wing under conditions of light scattering by liquid electrolytic solutions. The mechanism consists essentially in that the fluctuation electric field caused by Brownian motion of ions dissolved in a liquid leads, because of the Kerr polarization effect, to fluctuations of optical anisotropy of the scattering medium. The spectral characteristics of the Rayleigh line wing are obtained using the fluctuation-dissipative theorem as applied to equilibrium thermal electromagnetic field. Expressions are derived for the integral intensity and spectral width (Δν) of the Rayleigh line wing in terms of parameters of liquid solution such as the temperature T, the viscosity η, the concentration of dissolved ions n _i, and the coefficient of their diffusion D _i. It is demonstrated that Δν ∝ exp(?W/2T), where W is the activation energy of ion mobility b _i = D_i/T. The possible region of validity of developed theoretical concepts as applied to the experimental data for the Rayleigh line wing in electrolytic solutions is discussed.     

Depolarized light scattering in a 2.6-lutidine-water solution near the critical point

The spectra of depolarized Rayleigh light scattering, i.e., the Rayleigh line wing (RLW), and Raman scattering in a solution with the lower critical point in the phase separation diagram is experimentally studied. The Rayleigh line wing is studied to 30 cm^?1 from the exciting light frequency; the Raman scattering line (RSL) is studied in the near profile region. In the vicinity of the lower critical point, as well as in solutions with the upper critical point, strong narrowing of the RLW and RSL is observed. In this case, the conditions arise for the manifestation of the profile in the Rayleigh line spectrum, which is caused by the interaction of concentration and anisotropy fluctuations. Previously, this spectral line was theoretically predicted by I. A. Chaban in [1].     

Propagation of transverse hypersound in solution with stratification region

The fine structure of the Rayleigh line wing depolarized spectrum in a form of a triplet caused by the light scattering by transverse hypersonic waves was detected in a critical solution with a closed stratification region at low temperatures. The propagation velocity of transverse hypersound and its absorbance were measured. The temperature dependence of the shear modulus in solution was calculated. The temperature dependence of the shear modulus was compared to temperature dependences of limiting bulk elastic moduli. The results obtained suggest that the solution structure changes in passing through the stratification region at changing temperature.     

Four-photon laser spectroscopy of translational vibrations of a proton in water and hexagonal ice

For the first time, translational vibrations of a proton in H₂O, D₂O, HDO, and hexagonal ice were found in the Rayleigh line wing using four-photon polarization spectroscopy.     

壁稳氩弧等离子体光谱诊断

本文建立适当的氩弧等离子体柱模型的计算机进行Ａｒ（Ｉ）线的重构，修正了光谱测量中的线翼损失，傍线重叠及自吸现象产生的影响。通过实验。诊断出局部热力学平衡状态下各工作电流的氩弧等离子体温度。     

Fluctuations in fluids out of thermal equilibrium

After a brief review of dynamic correlations in equilibrium fluids, we consider the long-range correlations between the fluctuations in a fluid subjected to a large stationary temperature gradient. These long-range correlations enhance and modify the Rayleigh spectrum of the fluid. We elucidate that the modifications of the Rayleigh line are determined by the coupling of the entropy fluctuations to the transverse velocity fluctuations. Recent attempts to test the theoretical predictions with the aid of light-scattering experiments are discussed.     

Fluctuations in a fluid under a stationary heat flux II. Slow part of the correlation matrix

The general formulas, derived in a previous paper, are used to calculate the correlation functions of the hydrodynamic variables in the Rayleigh-Bénard system. The behavior of the correlation functions on a time scale slow compared to that of sound propagation is determined, using systematically nonequilibrium hydrodynamic eigenmodes. These (slow) eigenmodes of the linearized Boussinesq equations in the presence of gravity and a temperature gradient are the viscous and the visco-heat modes. They are determined for ideal heat-conducting plates with stick boundary conditions. The visco-heat modes are found to behave qualitatively different from those obtained with slip boundary conditions. Using these eigenmodes, the slow part of the correlation functions can be determined explicitly. On a small length scale, as probed by light scattering, we recover the same expression for the Rayleigh line as quoted in the literature. On larger length scales, as probed by microwaves, the coupling of gravity to the temperature gradient gives rise to a convective instability (heating form below) or to propagating visco-heat modes (heating from above). The corresponding correlation functions and the Rayleigh line are calculated and discussed.     

Frequency-dependent polarization of incoherently excited fluorescence

We use detailed-balance considerations to relate the frequency-dependent polarization of atomic fluorescence excited by broad-band radiation to the polarization properties of the collision-induced fluorescence line excited by narrow-band radiation. The polarization of the fluorescence in the first case must display a change when the detected frequency is tuned outside the bandwidth, due to the contribution of Rayleigh scattering. In the special case of adiabatic reorientation followed by emission in the quasistatic wing of the spectral line, we derive explicit expressions for the frequency-dependent polarization in terms of the contributions to the quasistatic profile from the various interatomic difference potentials.     

Detection of the structure of the wing of the Rayleigh line in ice, water, and heavy water using four-photon polarization spectroscopy

The spectral structure of the wing of the Rayleigh line in ice, ordinary water (H₂O), and heavy water (D₂O) is recorded in the frequency range 0–50 cm⁻¹ by means of four-photon polarization spectroscopy. It is shown that this structure can be explained by the collective rotational motion of molecules in cells determined by the structure of hexagonal ice. Pis’ma Zh. éksp. Teor. Fiz. 69, No. 1, 12–14 (10 January 1999)     

Quasi-Elastic Light Scattering in Congruent Lithium Niobate Crystals

Raman scattering spectra in the frequency range of 5–75 cm^–1 in lithium niobate samples with various structural imperfections were obtained. It is shown that the intensity of quasi-elastic light scattering on the wing of the Rayleigh line demonstrates an exponential dependence on the concentration of large-scale defects in the samples. Calibration curves for the intensity of quasi-elastic scattering dependence at low frequencies on the acoustic quality factor are constructed.     

The N2-broadened water vapor absorption line shape and infrared continuum absorption—II. Implementation of the line shape

The total line shape model of the previous paper is tested using a set of experimental room temperature H₂O continuum measurements of high quality. Parameters of the far wing component of the total line shape are determined from near band experimental data. Grating spectrometer measurements from 300 to 650 cm^?1 are used to determine unknown far wing parameters of the pure rotational band of H₂O. CO and HF laser measurements taken in the 5 and 3 μm regions are used to determine the far wing parameters of the ν₂ and ν₁, ν₃ fundamental bands, respectively.The total line shape model is applied to the 10 and 4 μm transmission windows with encouraging success. A significant increase in the self-broadening ability of H₂O over N₂ is predicted in the far wing. This procedure allows the proper modeling of the absorption coefficient vs H₂O partial pressure dependence in all window regions. A negative temperature is predicted by the model in the continuum. The observed rate of the temperature decrease is not predicted by the model; however, this limitation is related to the approximations made on the interaction potentials and the perturbation expansion of the Hamiltonians. Although the total line shape has limitations, it does demonstrate the importance of considering far wings of absorption lines in continuum absorption.     

Raman spectra and thermal disordering of the crystalline structure of benzene

Disordering of rotational degrees of freedom of molecules in a benzene crystal is investigated from Raman spectra. Nonuniform smearing of the spectrum of librational vibrations to the wing of the Rayleigh line is established. The changes observed are interpreted on the basis of calculations of frequencies, intensities, vibration modes, and barriers to molecular reorientations in the crystal by the method of atom-atom potentials. The line broadening in the spectrum of external vibrations by reorientations of molecules in the crystal as a function of their mode is analyzed. Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 66, No. 3, pp. 394–400, May–June, 1999.     

Li(2p $\leftarrow$ 2s) + Na(3s) pressure broadening in the far-wing and line-core profiles

This work reports pressure-broadening line-wing and line-core of the lithium Li (2p $\leftarrow$ 2s) resonance line perturbed by ground sodium Na (3s) atoms. In far-wing regions, the calculations are performed quantum-mechanically and are intended to examine the photoabsorption coefficients at diverse temperatures. The results show the existence of three satellites, in the blue wing near the wavelengths 470 nm and in the red wing around 862 nm and 1070 nm. For the line-core region, by adopting the simplified Baranger model, the line-width and line-shift rates are determined, and their variation law with temperature is examined. No published data were found to compare these results with.     

分布式光纤布里渊散射温度传感实验系统

提出一种基于布里渊光时域反射计法的分布式光纤布里渊散射温度传感系统.光源采用窄谱半导体激光器.声光调制器将光源调制成窄脉冲,并由高增益光纤放大器放大,产生高功率光脉冲信号,提高了自发布里渊散射信号的强度.采用双通马赫-曾德干涉仪将布里渊散射从瑞利散射中分离出来,在一段4.25 km长的光纤上进行分布式温度传感的实验研究.双通马赫-曾德干涉仪对瑞利散射进行了很好的抑制,得到了比较纯净的随温度变化的布里渊散射信号.     

Direct spectroscopic observation of multiple-charged-ion acceleration by an intense femtosecond-pulse laser

We have observed evidence of the emission of energetic He-and H-like ions of fluorine more than 1 MeV produced via the optical field ionization (OFI) from a solid target irradiated by an intense I=(2-4)x10(18) W/cm(2) (60 fs, lambda=800 nm), obliquely incident p-polarized pulse laser. The measured blue wing of He(alpha), He(beta), and Ly(alpha) lines of fluorine shows a feature of the Doppler-shifted spectrum due to the self-similar ion expansion dominated by superthermal electrons with the temperature T(h) approximately 100 keV. Using a collisional particle-in-cell simulation, which incorporates the nonlocal-thermodynamic-equilibrium ionization including OFI, we have obtained the plasma temperature, line shape, and maximal energy of accelerated ions, which agree well with those determined from the experimental spectra. The red wing of ion spectra gives the temperature of bulk plasma electrons.     

锶460.7 nm法拉第色散光学滤波器的滤波特性分析

分析了处于夫琅禾费暗线的Sr 460.7nm法拉第色散光学滤波器线翼和线芯工作的滤光特性,研究了磁场,温度和池长对滤波特性的影响,讨论了在其最佳的工作条件下,线芯透射率为95％,线宽为1．47GHz。     

EHD convection in dielectric micropolar fluid layer

The onset of instability in a layer of dielectric micropolar fluid under the simultaneous action of an AC electric field and temperature gradient has been investigated. The dispersion relation has been derived and various critical values of non-dimensional Rayleigh number in the fluid layer have been determined. The influence of micropolar viscosity and electric Rayleigh number on the onset of convection has been analyzed. Thermal Rayleigh number has been computed for various values of electric Rayleigh number for the onset of instability. The stabilizing and destabilizing effects of electric Rayleigh number, micropolar viscosity and Prandtl number have been discussed.