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1.
The third-order nonlinear optical response of a triphenylmethane dye (Acid blue 7) was studied using the Z-scan technique with a continuous-wave He–Ne laser radiation at 633 nm. The magnitude and sign of the third-order nonlinear refractive index n2 of aqueous solution of Acid blue 7 dye were determined; the negative sign indicates a self-defocusing optical nonlinearity in the sample studied. The negative nonlinear refractive index n2 and nonlinear absorption coefficient β were estimated to be −1.88 × 10−7 cm2/W and −3.08 × 10−3 cm/W, respectively, corresponding to Re(χ(3)) = −8.35 × 10−6 esu, and Im(χ(3)) = −6.88 × 10−7 esu. The experimental results show that Acid blue 7 dye have potential applications in nonlinear optics.  相似文献   

2.
Bi2Te3 films were prepared by thermal evaporation technique. X-ray diffraction analysis for as-deposited and annealed films in vacuum at 150 °C were polycrystalline with rhombohedral structure. The crystallite size is found to increase as the film thickness increases and has values in the range 67–162 nm. The optical constants (the refractive index, n, and absorption index, k) were determined using transmittance and reflectance data in the spectral range 2.5–10 μm for Bi2Te3 films with different thicknesses (25–99.5 nm). Both n and k are independent on the film thickness in the investigated range. It was also found that Bi2Te3 is a high refractive index material (n has values of 4.7–8.8 in the wavelength range 2.5–10 μm). The allowed optical transitions were found to be direct optical transitions with energy gap  eV. The optical conductivities σ1 = ƒ() and σ2 = f() show distinct peaks at about 0.13 and 0.3 eV, respectively. These two peaks can be attributed to optical interband transitions.  相似文献   

3.
杨志清  王飞利  林常规 《物理学报》2013,62(18):184211-184211
实现玻璃微晶化过程控制的基础是要充分认识其析晶行为及动力学机理. 利用示差扫描量热法和析晶热处理等手段, 研究发现 20GeS2·80Sb2S3硫系玻璃属于表面析晶, 在268℃(Tg+30℃)下热处理60 h, 可以获得表面约40 μm的Sb2S3晶层复合玻璃陶瓷样品. 在此基础上, 利用非等温法从理论上分析该玻璃的析晶动力学机理. 计算得到其析晶活化能Ec为(223.6±24.1)kJ·mol-1, 在热处理温度(268℃)下的析晶速率常数K为1.23×10-4 s-1, 属于较难析晶的玻璃组成; 玻璃的晶体生长指数m和晶体生长维数n均为2, 表明其Sb2S3相的析晶行为是二维生长过程, 与析晶实验结果完全相符. 由此可知, 对于Sb2S3晶体复合的硫系玻璃陶瓷样品可通过玻璃粉末压片烧结、带铸法或丝网印刷法制备获得, 为今后功能硫系玻璃的开发提供实验依据和理论指导. 关键词: 硫系玻璃 微晶化 析晶动力学 析晶行为  相似文献   

4.
Well-crystallized Ba0.5Sr0.5TiO3 thin films with good surface morphology were prepared on MgO(1 0 0) substrates by pulsed laser deposition technique at a deposition temperature of 800 °C under the oxygen pressure of 2 × 10−3 Pa. X-ray diffraction and atomic force microscopy were used to characterize the films. The full width at half maximum of the (0 0 2) Ba0.5Sr0.5TiO3 rocking curve and the root-mean-square surface roughness within the 5 μm × 5 μm area were 0.542° and 0.555 nm, respectively. The nonlinear optical properties of the films were determined by a single beam Z-scan method at a wavelength of 532 nm with laser duration of 55 ps. The results show that Ba0.5Sr0.5TiO3 thin films exhibit a fast third-order nonlinear optical response with the nonlinear refractive index and nonlinear absorption coefficient being n2 = 5.04 × 10−6 cm2/kW and β = 3.59 × 10−6 (m/W), respectively.  相似文献   

5.
The uniform antimony-rich surface layer on Fe2O3 was carried out via thermal spreading of Sb2O3 and Sb2O4. TG–DTA results indicate that the oxidation temperature of Sb2O3 was decreased ca. 100 K due to thermal spreading effect. Although Sb2O4 is almost catalytically inert for oxidation of isobutane and Fe2O3 is a typical non-selective catalyst for this reaction, the formation of antimony-rich layer suppresses the combustion reactions and favors the partial oxidation reactions. When Sb2O4 instead of Sb2O3 was used as antimony resource, the enrichment of antimony on Fe2O3 surface was much lower. However, the reaction atmosphere of isobutane oxidation enhances antimony spreading over Fe2O3 surface. According to Mars–Van Krevelen mechanism, some Sb2O4 in catalysts could be intermediately reduced into Sb2O3 during reaction of isobutene oxidation, which thermal spreading is much easier. As shown by Raman results, the Sb2O4 that has been spread on Fe2O3 surface is probably amorphous.  相似文献   

6.
This study is focused on calculation of the electronic structure and optical properties of non-metal doped Sb2Se3 using the first-principles method. One and two N atoms are introduced to Sb and Se sites in a Sb2Se3 crystal. When one and two N atoms are introduced into the Sb2Se3 lattice at Sb sites, the electronic structure shows that the doping significantly modifies the bandgap of Sb2Se3 from 1.11 eV to 0.787 and 0.685 eV, respectively. When N atoms are introduced to Se sites, the material shows a metallic behavior. The static dielectric constants ε1(0) for Sb16Se24, Sb15N1Se24, Sb14N2Se24, Sb16Se23N1, and Sb16Se22N2 are 14.84, 15.54, 15.02, 18.9, and 39.29, respectively. The calculated values of the refractive index n(0) for Sb16Se24, Sb15N1Se24, Sb14N2Se24, Sb16Se23N1, and Sb16Se22N2 are 3.83, 3.92, 3.86, 4.33, and 6.21, respectively. The optical absorbance and optical conductivity curves of the crystal for N-doping at Sb sites show a significant redshift towards the short-wave infrared spectral region as compared to N-doping at Se sites. The modulation of the static refractive index and static dielectric constant is mainly dependent on the doping level. The optical properties and bandgap narrowing effect suggest that the N-doped Sb2Se3is a promising new semiconductor and can be a replacement for GaSb due to its very similar bandgap and low cost.  相似文献   

7.
The chromium(II) antimony(III) sulphide, [Cr((NH2CH2CH2)3N)]Sb4S7, was synthesised under solvothermal conditions from the reaction of Sb2S3, Cr and S dissolved in tris(2-aminoethyl)amine (tren) at 438 K. The products were characterised by single-crystal X-ray diffraction, elemental analysis, SQUID magnetometry and diffuse reflectance spectroscopy. The compound crystallises in the monoclinic space group P21/n with a=7.9756(7), b=10.5191(9), c=25.880(2) Å and β=90.864(5)°. Alternating SbS33− trigonal pyramids and Sb3S63− semi-cubes generate Sb4S72− chains which are directly bonded to Cr(tren)2+ pendant units. The effective magnetic moment of 4.94(6)μB shows a negligible orbital contribution, in agreement with expectations for Cr(II):d4 in a 5A ground state. The measured band gap of 2.14(3) eV is consistent with a correlation between optical band gap and framework density that is established from analysis of a wide range of antimony sulphides.  相似文献   

8.
9.
薛丁江  石杭杰  唐江 《物理学报》2015,64(3):38406-038406
硒化锑(Sb2Se3)是一种二元单相化合物, 原料储量大、毒性低、价格便宜; 同时其禁带宽度合适(~1.15 eV), 吸光系数大(>105 cm-1), 长晶温度低, 非常适合制作新型低成本低毒的薄膜太阳能电池, 理论光电转换效率可达30%以上. 目前文献报道的Sb2Se3薄膜太阳能电池效率已达3.7%, 初步证明了Sb2Se3材料在薄膜太阳能电池应用方面的巨大潜力. 本文综述了近年来Sb2Se3太阳能电池的研究进展, 着重介绍了Sb2Se3的材料特性和薄膜制备及相关理论研究, 阐述了不同结构电池器件的研究进展, 并对其发展趋势进行了展望.  相似文献   

10.
Transparent Ni2+-doped MgO–Al2O3–SiO2 glass ceramics without and with Ga2O3 were synthetized. The precipitation of spinel nanocrystals, which was identified as solid solutions in the glass ceramics, could be favored by Ga2O3 addition and their sizes were about 7.6 nm in diameter. The luminescent intensity of the Ni2+-doped glass ceramics was largely enhanced by Ga2O3 addition which could mainly be caused by increasing of Ni2+ in the octahedral sites and the reduction of the mean frequency of phonon density of states in the spinel nanocrystals of solid solutions. The full width at half maximum (FWHM) of emissions for the glass ceramics with different Ga2O3 content was all more than 200 nm. The emission lifetime increased with the Ga2O3 content and the longest lifetime is about 250 μs. The Ni2+-doped transparent glass ceramics with Ga2O3 addition have potential application as broadband optical amplifier and laser materials.  相似文献   

11.
We investigate bidirectional teleportation that works in a fair and efficient manner. Two explicit protocols are proposed to realize bidirectional teleportation with a controller. One is a symmetric protocol for two-qubit states. The other is an asymmetric protocol for single-and two-qubit states. We then devise a universal protocol for arbitrary n_1-and n_2-qubit states via a(2n_1+2n_2+1)-qubit entangled state, where n_1≤n_2.The receiver only needs to perform the single-qubit recovery operation, which is derived by a general expression. Moreover, a(2n_1+1)-bit classical communication cost can be saved within the controller's broadcast channel by the use of network coding technology.  相似文献   

12.
郭海涛  张鸣杰  许彦涛  肖旭升  杨志勇 《中国物理 B》2017,26(10):104208-104208
The structures of pseudo-binary GeS_2–Sb_2S_3, GeS_2–CdS, Sb_2S_3–CdS, and pseudo-ternary GeS_2–Sb_2S_3–CdS chalcogenide systems are systematically investigated by Raman spectroscopy. It is shown that a small number of [S_3Ge–GeS_3]structural units(SUs) and-S-S-/S8 groups exist simultaneously in GeS_2 glass which has a three-dimensional continuous network backbone consisting of cross-linked corner-sharing and edge-sharing [GeS_4] tetrahedra. When Sb_2S_3 is added into GeS_2 glass, the network backbone becomes interconnected [GeS_4] tetrahedra and [SbS_3] pyramids. Moreover, Ge atoms in[S_3Ge–GeS_3] SUs tend to capture S atoms from Sb_2S_3, leading to the formation of [S_2Sb–SbS_2] SUs. When CdS is added into GeS_2 glass, [Cd_4GeS_6] polyhedra are formed, resulting in a strong crystallization tendency. In addition, Ge atoms in[S_3Ge–GeS_3] SUs tend to capture S atoms from CdS, resulting in the dissolution of Ge–Ge bond. Co-melting of Sb_2S_3 or CdS with GeS_2 reduces the viscosity of the melt and improves the homogeneity of the glass. The GeS_2 glass can only dissolve up to 10-mol% CdS without crystallization. In comparison, GeS_2–Sb_2S_3 glasses can dissolve up to 20-mol% CdS,implying that Sb_2S_3 could delay the construction of [Cd_4GeS_6] polyhedron and increase the dissolving amount of CdS in the glass.  相似文献   

13.
Preferred crystal orientation and low electrical resistivity are required for ZrNx films applied in electronic devices. In this paper, effects of N2:(N2+Ar) flow ratio (F(N2)) and substrate temperature on the properties of the films deposited on glass substrate by reactive dc sputtering are investigated. In a wide range of F(N2) (4–24%), the films show fcc NaCl structure. While for F(N2) in the ranges of 5–12, 12–24 and >24%, the films show (1 1 1)/(2 0 0), (1 1 1) only and amorphous structures, respectively. The electrical resistivity increases with F(N2) from 5 to 24%, and can be controlled to some extent by changing the substrate temperature.  相似文献   

14.
Ti substituted BiFe1−xTixO3+δ films have been prepared on indium–tin oxide (ITO)/glass substrates by the sol–gel process. The films with x=0.00–0.20 were prepared at an annealing temperature of 600 °C. X-ray diffraction patterns indicate that all films adopt R3m structure and the films with x=0 and 0.10 show pure perovskite phase. Cross-section scanning shows the thickness of the films is about 300 nm. Through 0.05 Ti substitution, the 2Pr increases to 8.30 μC/cm2 from 2.12 μC/cm2 of the un-substituted BiFeO3 film and show enhanced ferroelectricity at room temperature. The 2Pr values are 2.63 and 0.44 μC/cm2 for the films with x=0.01 and 0.2, respectively. Moreover, the films with x=0.05 and 0.10 show enhanced dielectric property since the permittivity increases near 150 at the same measuring frequency. Through the substitution of Ti, the leakage conduction is reduced for the films with x=0.05–0.20.  相似文献   

15.
The nonlinear optical properties of metal Au and Ag colloidal solutions prepared by the chemical reaction method were investigated by a single beam Z-scan technique. Under CW 633 nm excitation, the Au and Ag colloidal solutions exhibited a large thermal-induced refractive index n2. At the same time, the thermo-optic coefficients dn/dT of the Au and Ag colloidal solutions were obtained. The mechanism responsible for the process of nonlinear refraction was discussed in term of laser heating effect.  相似文献   

16.
The magneto-optic Cotton-Mouton effect constant C, light refraction index n and density ρ of binary solutions of toluene in carbon tetrachloride, -picoline and β-picoline in 1,4-dioxane have been measured at different concentrations. The results have been used for the calculation of the molar CM constants of the solutions. By extrapolating the values CM = CM(f2) for the concentration f2 → 0, the constant C2M = gasC2M of the dipolar component of the solution has been found, which is interpreted as the Cotton-Mouton gas constant. For all solutions, the reduction factors of the dissolved component have been calculated and their linear dependence on the solution concentration has been found.  相似文献   

17.
Recently the nonlinear effects of the azo-dye doped liquid crystals have attracted much interest. In this paper the nonlinear refractive indices, n2, of two dyes (Sudan Black B, Sudan III) doped nematic liquid crystal were measured at low laser powers using moiré deflectometry technique. The results show when a nonlinear sample is placed in moiré deflectometry setup, the moiré fringe patterns will rotate around the beam center because of self-focusing effect in the sample. By measuring this rotation, the magnitude and the sign of nonlinear refractive index were calculated. The n2 values for Sudan black B is larger than Sudan III, because of some differences in molecular structure and molecular polarization.  相似文献   

18.
c-Axis oriented GaN nanocrystalline thin films were fabricated by nitridation of three different thin films of -GaO(OH), -Ga2O3 or β-Ga2O3 obtained by sol–gel technique on amorphous quartz glass substrates. All these GaN thin films showed near band edge emission at 390 nm and yellow luminescence at 570 nm. The crystalline nature and c-axis orientation as well as luminescence properties of the GaN thin films increased by several times by using a buffer layer of GaN on the substrate.  相似文献   

19.
乔北京  陈飞飞  黄益聪  戴世勋  聂秋华  徐铁峰 《物理学报》2015,64(15):154216-154216
在Ge-Se二元体系中引入相同摩尔比的Ga, Sn, Sb, Te四种元素, 使用熔融淬冷法制备了一系列硫系玻璃. 利用吸收光谱获得了不同元素引入下硫系玻璃能带结构的变化, 并结合拉曼光谱详细研究了产生光学特性变化的微观表征. 使用Z扫描方法测试了各个硫系玻璃样品在1550 nm波长下的三阶非线性参数, 发现加入Sn的玻璃的三阶非线性折射率n2最大, 达到了6.36×10-17 m2/W, 且其品质因子大于23, 表明Sn引入能够增强硫系玻璃在通信波段的三阶非线性, 这一研究结果为以后的高性能红外器件的设计及制备提供了一种环保且性能优良的候选材料.  相似文献   

20.
It is known that the Korteweg–de Vries (KdV) equation is a geodesic flow of an L2 metric on the Bott–Virasoro group. This can also be interpreted as a flow on the space of projective connections on S1. The space of differential operators Δ(n)=∂n+u2n−2++un form the space of extended or generalized projective connections. If a projective connection is factorizable Δ(n)=(∂−((n+1)/2−1)p1)(∂+(n−1)/2pn) with respect to quasi primary fields pi’s, then these fields satisfy ∑i=1n((n+1)/2−i)pi=0. In this paper we discuss the factorization of projective connection in terms of affine connections. It is shown that the Burgers equation and derivative non-linear Schrödinger (DNLS) equation or the Kaup–Newell equation is the Euler–Arnold flow on the space of affine connections.  相似文献   

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